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B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 52 | P a g e
Durability Studies on Concrete and Comparison with Partial
Replacement of Cement with Rice Husk Ash and Sugarcane
Bagasse Ash in Concrete
B.SomeswaraRao *, N.Vidya Sagar Lal **, G.Naveen***.
*(PG Student in Dept. of Civil Engineering, GITAS, JNTU Kakinada, AP, India.)
** (Asst.Professor, Dept. of Civil Engineering, GITAS, JNTU-K, AP, India)
*** (Asst.Professor, Dept. of Civil Engineering, GITAS, JNTU-K, AP, India.)
ABSTRACT
This research work describes the feasibility of using the Rice Husk Ash (RHA) and Sugarcane Bagasse Ash
(SCBA) waste in concrete production as a partial replacement of cement. This present work deals with the effect
on strength and mechanical properties of concrete using RHA and SCBA instead of cement. The cement has
been replaced by rice husk ash, accordingly in the range of 0%, 5%, 10%, 15%, and 20% by weight. Concrete
mixtures with RHA, were produced, tested and compared in terms of compressive strengths with the
Conventional concrete. These tests were carried out to evaluate the mechanical properties for the test results of
7, 28, 60, 90 days for compressive strengths in normal water and in MgSO4 solution of 1%, 3% and 5%. Also
the durability aspect for rice husk ash concrete for sulphate attack was tested. Similarly the above tests were also
performed for SCBA. The result indicates that the RHA and SCBA improve concrete durability. Finally the test
results for RHA and SCBA were compared. Key words: Rice Husk Ash, Sugarcane Bagasse Ash, Concrete,
M35 grade concrete, cubes, cylinders, MgSO4, durability.
Keywords – M35 grade concrete, MgSO4 Solution, Rice Husk Ash, Sugarcane Bagasse Ash and UTM
I. INTRODUCTION
The challenge for the civil engineering
community in the near future will be to realize
projects in harmony with the concept of sustainable
development, and this involves the use of high-
performance materials and products manufactured at
reasonable cost with the lowest possible
environmental impact. Concrete is the most widely
used construction material worldwide. However, the
production of Portland cement, an essential
constituent of concrete, releases large amounts of
CO2 which is a major contributor to the greenhouse
effect and the global warming of the planet.
Moreover the developed countries are considering
very severe regulations and limitations on CO2
emissions. In this scenario, the use of supplementary
cementing materials (SCMs), such fly ash, slag,
silica fume, and rice husk ash and sugar cane
bagasse ash as a replacement for Portland cement in
Concrete presents one viable solution with multiple
benefits for the sustainable development of the
concrete industry.
The most commonly available SCM worldwide
is sugar cane bagasse ash, a by-product from the
combustion of sugar cane fibers. Sugar cane bagasse
ash, if not utilized has to be disposed of in landfills,
ponds or rejected in river systems, which may
present serious environmental concerns since it is
produced in large volumes. Instead of considering it
as a "Waste" product, research and development has
shown that sugar cane bagasse ash actually
represents a highly valuable concrete material. In
order to considerably increase the utilization of
sugar cane bagasse ash as replacement for cement,
such concrete must meet engineering performance
requirements that the comparable to those for
conventional Portland cement concrete and be cost
effective.
Rice husk which is an agricultural by–product is
abundantly available all over the world. Most of the
rice husk, which is obtained by milling paddy, is
going as waste materials even though some quantity
is used as bedding material, fuel in boilers, brick
kilns etc., the husk and its ash, which not only
occupy large areas causing space problems, but also
cause environmental pollution.
The present study was carried out on SCBA and
RHA obtained by controlled combustion of
sugarcane bagasse, which was procured from the
Andhra Pradesh province in India. Sugarcane
production in India is over 300 million tons/year
leaving about 10 million tons as unutilized and,
hence, wastes material. This project analyzes the
effect of SCBA and RHA in concrete by partial
replacement of cement at the ratio of 0%, 5%, 10%,
15% and 20% by weight. The experimental study
RESEARCH ARTICLE OPEN ACCESS
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 53 | P a g e
examines there compressive strength, split tensile
strength, flexural strength. The main ingredient
consists of Portland cement, SCBA/RHA, river sand,
coarse aggregate and water. After mixing, concrete
specimens were casted and subsequently all test
specimens were cured in water and in MgSO4
solution of 1%, 3% and 5% for 7 days, 28 days, 60
days and 90 days respectively. Also the durability
aspect for rice husk ash and sugarcane bagasse ash
concrete for sulphate attack was tested. Similarly the
above tests were also performed for SCBA/RHA.
The result indicates that the RHA and SCBA
improve concrete durability. Finally the test results
for RHA and SCBA were compared.
II. OBJECTIVE OF THE WORK
In this project objective is to study the
influence of partial replacement of cement with Rice
Husk Ash and sugarcane bagasse ash in concrete
subjected to different curing environments.
Experimental investigation on sulphate resistance of
concrete in MgSO4 solution. The variable factors
considered in this study were concrete grade of M35
& curing periods of 7days, 28 days, 60 and 90 days
of the concrete specimens. The parameter
investigated was the time in days to cause strength
deterioration factor of fully immersed concrete
specimens in fresh water & in 1%, 3% &5%MgSO4
solution. Rice Husk Ash and sugarcane bagasse ash
has been chemically & physically characterized &
partially replaced in the ratio of 0%, 5%, 10%, 15%,
and 20%. Fresh concrete tests like compaction factor
test and hardened concrete tests like compressive
strength at the age of 7days, 28 days, 60 and 90 days
was obtained. The compressive strength test results
of RHA and SCBA for 7,28,60,90 days are
compared.
III. MATERIALS AND PROPERTIES
The materials used in research are:
1. Portland cement (53 grade)
2. Fine aggregate (4.75 mm down)
3. Coarse aggregate (20 mm down)
4. Rice Husk Ash
5. Sugarcane Bagasse Ash
6. Water
7. Admixtures
i. Cement
Ordinary Portland cement is by far the most
important type of cement. The manufacture of
cement is decreasing all over the world in view of
the popularity of blended cement on account of
lower energy consumption, environmental pollution,
economic and other technical reasons. In advanced
western countries the use of cement has come down
to about 40% of the total cement production. The
cement procured was tested for physical
requirements in accordance with IS: 12269-1987 and
for chemical requirements in accordance with IS:
4032-1977.
ii. Fine Aggregate
The sand obtained from river beds or quarries is
used as fine aggregate. Fine aggregate are material
passing through an IS sieve that is less than 4.75mm.
According to IS 383:1970 the fine aggregate
is being classified in to four different zone,
that is Zone-I, Zone-II, Zone-III, Zone-IV. Locally
available river sand in dry condition was used for the
preparation of specimens. The sand is tested for
various properties like specific gravity, bulk density
etc., and in accordance with IS 2386-1963.
iii. Coarse Aggregate
The coarse aggregate are granular materials
obtained from rocks and crushed stones. They may
be also obtained from synthetic material like slag,
shale, fly ash and clay for use in light-weight
concrete. The physical properties of coarse
aggregate like specific gravity, Bulk density, impact
value, gradation and fineness modulus are tested in
accordance with IS: 2386. The maximum size of
coarse aggregates used is 20 mm. The materials are
of uniform colour and have good angularity and it
will be free from dust and organic matter etc.
iv. Rice Husk Ash
The husk surrounds the paddy grain. During
milling of paddy about 78 % of weight is received as
rice, broken rice and bran. Rest 22 % of the weight
of paddy is received as husk. This husk is used as
fuel in the rice mills to generate steam for the
parboiling process.
v. Sugarcane Bagasse Ash
Sugarcane bagasse consists of approximately
50% of cellulose, 25% of hemicelluloses of lignin.
Each ton of sugarcane generates approximately 26%
of bagasse (at a moisture content of 50%) and 0.62%
of residual ash. The residue after combustion
presents a chemical composition dominates by
silicon dioxide (sio2). In spite of being a material of
hard degradation and that presents few nutrients, the
ash is used on the farms as a fertilizer in the
sugarcane harvests. In this sugarcane bagasse ash is
collected from agricultural fields.
vi. Water
The locally available potable water accepted for
local construction is used in the experimental
investigation after testing. The water used is potable
water collected from laboratory tap. The pH value
should not be less than 6.
vii. Magnesium Sulphate (Mgso4) Properties
The magnesium Sulphate is obtained from locally
and is manufactured in Molychem, Mumbai with
minimum assay of 99.8%.
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 54 | P a g e
Table 1: Analysis of Water (Limitations As Per IS:
456-2000)
S.
No.
Impurity
Max.
Limit
Results
1 PH Value 6 to 8.5 7.4
2 Suspended matter mg/lit 2000 350
3 Organic matter mg/lit 200 25
4 Inorganic matter mg/lit 3000 200
5 Sulphate (SO4) mg/lit 500 25
6 Chlorides (Cl) mg/lit
2000 for
P.C.C.
1000 for
R.C.C.
60
Table 2: Properties of MgSO4
S.
No.
Chemical
Volume
(%)
1 pH (5% water) 6.3
2 Free Alkali sol. (as NaOH) 0.008
3 Free Acid (as H2SO4) 0.01
4 Chlorides 0.02
5 Heavy metals (Pb) 0.0005
6 Arsenic 0.0002
7 Iron (Fe) 0.01
8 Selenium (Se) 0.001
9 Loss of Drying (at 450°c) 50.4
Table 3: Physical Properties of RHA
Table 4: Chemical Properties of RHA (Source)
S. No. Property Test Results
1 Density 96 kg/m3
2 Physical state Solid non-Hazardous
3 Appearance Very fine powder
4 Particle size 25 microns – mean
5 Color Gray
6 Specific gravity 2.3
Table 5: Physical properties of SCBA
S. No. Characteristic Test Results %
1 SiO2 % by mass 93.80
2 Al2o3 by mass 0.74
3 Fe2o3 by mass 0.30
4 Tio2 by mass 0.10
5 Cao by mass 0.89
6 Mgo by mass 0.32
7 Na2o by mass 0.28
8 K2o by mass 0.12
9 LOI 3.37
Table 6: Physical Properties of Fine and Coarse
Aggregate
S. No. Property Test Result
1. Density 575Kg/m3
2. Specific Gravity 2.2
3. Mean particle size 0.1-0.2 urn
4. Min specific surface area 420m2
/ kg
5. Particle shape Spherical
Table 7: Chemical properties of SCBA (Source)
S.
No.
Properties
Test results
Fine
Aggregate
Coarse
Aggregate
1.
Specific
gravity
2.60 2.74
2.
Bulk Density
(Kg/m3
)
a) loose
b) compacted
1600 kg/m3
1750 kg/m3
1400 Kg/m3
1580 Kg/m3
3.
Fineness
Modulus
2.76 7.17
Table 8: Mix Proportions by Weight
Cement
(kgs)
Fine
aggregate
(kgs.)
Coarse
aggregate
(kgs.)
w/c
ratio
(lt.)
453.66 527.28 1225.30 186
1 1.16 2.70 0.41
S.
No.
Characteristic
Test
Results
%
1
(SiO2)+Al2O3, Fe2C3 % by
mass
85.0
2 SiO2% by mass 60.20
3 MgO % by mass 2.48
4 Total sulfur as SO3 % by mass 0.10
5 Available alkali as sodium
oxide (Na20) % by mass
4.32
6 Loss of ignition % by mass 5.10
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 55 | P a g e
IV. RESULTS
Compressive Strength of Concrete
Graph 1: Compressive strength results of RHA
concrete cured in normal water
Graph 2: Compressive strength results of SCBA
concrete cured in normal water
Graph 3: Compressive strength results of RHA
concrete cured in 1% Magnesium Sulphate
Graph 4: Compressive strength results of SCBA
concrete cured in 1% Magnesium Sulphate
Graph 5: Compressive strength results of RHA
concrete cured in 3% Magnesium Sulphate
Graph 6: Compressive strength results of SCBA
concrete cured in 3% Magnesium Sulphate
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 56 | P a g e
Graph 7: Compressive strength results of RHA
concrete cured in 5% Magnesium Sulphate
Graph 8: Compressive strength results of SCBA
concrete cured in 5% Magnesium Sulphate
Table 9: Compressive Strength results for cubes
cured in water
Sample
Designation
% of
RHA
7
days
28
days
60
days
90
days
W-0 0 36.89 45.83 55.69 57.98
W-05 5 37.72 46.75 56.16 58.69
W-10 10 38.79 47.69 58.63 60.23
W-15 15 35.86 44.78 56.43 59.16
W-20 20 35.78 43.79 55.57 56.23
Table 10: Compressive Strength results for cubes
cured in water
Sample
Designation
% of
SCBA
7
days
28
days
60
days
90
days
W-0 0 38.24 46.19 56.82 59.99
W-05 5 38.95 47.08 57.54 60.18
W-10 10 39.69 48.145 57.86 61.16
W-15 15 37.30 45.61 55.28 58.12
W-20 20 35.76 44.14 54.01 57.81
Table 11: Compressive Strength results for cubes
cured in 1% magnesium sulphate solution
Sample
Designation
% of
RHA
7
days
28
days
60
days
90
days
W-0 0 35.00 43.59 53.02 55.249
W-05 5 36.03 44.57 53.57 56.007
W-10 10 37.12 45.67 56.10 57.76
W-15 15 34.29 42.61 53.74 56.42
W-20 20 34.10 41.72 52.96 53.68
Table 12: Compressive Strength results for cubes
cured in 1% magnesium sulphate solution
Sample
Designation
% of
SCBA
7
days
28
days
60days 90days
W-0 0 35.34 42.68 52.99 56.46
W-05 5 36.62 43.70 53.85 57.37
W-10 10 37.12 44.99 54.68 58.85
W-15 15 34.99 42.55 51.98 55.12
W-20 20 34.38 41.14 50.12 54.4
Table 13: Compressive Strength results for cubes
cured in 3% magnesium sulphate solution
Sample
Designation
% of
RHA
7
days
28
days
60days 90days
W-0 0 35.17 44.60 54.28 56.10
W-05 5 36.54 45.67 54.93 56.97
W-10 10 37.98 46.86 57.89 58.96
W-15 15 34.88 43.58 55.34 57.60
W-20 20 33.68 42.68 54.47 54.70
Table 14: Compressive Strength results for cubes
cured in 3% magnesium sulphate solution
Sample
Designation
% of
SCBA
7
days
28
days
60days 90days
W-0 0 36.24 44.18 54.51 57.81
W-05 5 37.46 45.17 55.68 58.68
W-10 10 38.32 46.64 56.52 60.32
W-15 15 35.86 43.82 53.26 56.83
W-20 20 35.23 42.32 52.04 55.98
Table 15: Compressive Strength results for cubes
cured in 5% magnesium sulphate solution
Sample
Designation
% of
RHA
7
days
28
days
60days 90days
W-0 0 35.09 43.62 53.39 56.74
W-05 5 36.21 44.81 53.90 57.52
W-10 10 37.17 45.87 57.22 59.62
W-15 15 34.32 42.72 54.68 58.17
W-20 20 33.26 41.89 53.78 55.20
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 57 | P a g e
Table 16: Compressive Strength results for cubes
cured in 5% magnesium sulphate solution
Sample
Designation
% of
SCBA
7
days
28
days
60days 90days
W-0 0 35.69 43.62 53.72 57.36
W-05 5 36.8 44.6 54.56 57.88
W-10 10 37.52 46.14 55.6 59.16
W-15 15 35.32 43.22 52.64 55.6
W-20 20 34.68 41.88 51.39 55.19
V. CONCLUSION
When the compressive strengths of concrete
with 0%, 5%, 10%, 15% and 20% weight
replacement of cement with RHA and SCBA cured
in Normal Water and in 1%, 3%, 5% MgSO4
solution for 28 days.
The target mean strength has been increased for
the partial replacement of up to 10% by weight.
Whereas the compressive strengths at 15 and 20 %
replacement of RHA and SCBA are lower.
Due to slow Pozzolonic action the rice husk ash
(RHA) concrete achieves significant improvement in
its mechanical properties at later stages of curing but
still it reduces for 15 and 20 % replacement.
Due to slow pozzolanic reaction the Sugar Cane
Bagasse Ash (SCBA) concrete achieves significant
improvement in its mechanical properties at later
ages.
In concretes can be replaced with 20% SCBA
without sacrificing strength at later ages.
Both RHA and SCBA concrete is resistant
against sulphate attack up to 3%, but further increase
up to 5% of MgSO4 the decrease in compressive
strengths can be observed.
The workability of RHA concretes have
decreased in compared with ordinary concrete. It is
inferred that reduction in workability is due to large
surface area of RHA and SCBA.
REFERENCES
[1] R.Srinivasanan and K.Sathiya,
"Experimental Study on Bagasse Ash in
Concrete", International journal, Vol.5, No.
2, pp.60-66, fall 2010.
[2] Narayanan Neithalath, "An overview of
the benefits of using glass powder as a
partial cement replacement material in
concretes", The Indian Concrete
Journal, Feb 2011.
[3] Abhilash, C.K. Singh, Arbind Kumar
Sharma , “Study of the Properties of
Concrete by Partial Replacement of
Ordinary Portland Cement by Rice Husk
Ash”, International Journel of Earth
Sciences and Engineering, ISSN 0974-
5904, Volume 04, No 06 SPL, , pp. 965-
968, October 2011.
[4] S.THIROUGNANAME and
Dr.T.Sundararajan : “studies on rice husk
ash cement concrete”, IJCIET, IAEME,
Puducherry, India,2013.
[5] Er.S.A.Reddi, "Concrete Mix
Proportioning, Production, Transport
and Placement", Proceedings of
INCONTEST 2003, 10-12, Sep-2003 at
Kumaraguru College of Technology,
Coimbatore (India).
[6] Satish D.Kene, Pravin V.Domke, Sandesh
D.Deshmukh,R.S.Deotale,“assessment of
fly ash and rice husk ash”, IJERA, YCCE ,
Nagpur , 2013.
[7] Jan Skalny, Jacques Marchand and Ivan
Odler, consequences of sulfate attack on
concrete 2002. JayantiRajput , R.K. Yadav,
R. Chandak, “The Effect of Rice Husk Ash
used As Supplementary Cementing
Material On Strength Of Mortar”, Jabalpur,
June 2013.
[8] Karim, M.F.M. Zain, M. Jamil, F.C. Lai
and M.N. Islam Strength of Mortar and
Concrete as Influenced by Rice Husk Ash
A Review,2012.
[9] CCAA association , Sulphate resisting
concrete Australia , May 2011.
[10] Deepa G Nair, K. Siva Raman, and Job
Thomas Mechanical Properties of Rice
Husk Ash (RHA) - High strength Concrete.
[11] Gidde and A.P. Jivani Waste to Wealth -
Potential of Rice Husk in Indian Literature
Review Bharati Vidyapeeth Deemed
University College of Engineering pune
2007.
[12] Hilmi Bin Mahmud, Ghassan Abood
Habeeb Study on Properties of Rice Husk
Ash and Its Use as Cement Replacement
Material March 2010.
[13] V.S.Aigbodion, S.B.Hassan, T.Ause and
G.B.Nyior, Potential Utilization of Solid
Waste (Bagasse Ash) Department of
Metallurgical and Materials
Engineering,Ahmadu Bello University,
Samaru, Zaria, Nigeria.
[14] R.S. Khurmi [9] IS Code 456:2000
[15] M.L. Concrete Technologies
[16] N.Krishnam Raju Design of concrete mixes
[17] Lawrence Effect of sulfates on the setting
time of cement and strength of concrete
[18] Concrete Technology Theory of Practice by
M.S. Shetty, 1982.
[19] A M Neville Properties of Concrete English
language book society, Longman.
B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58
www.ijera.com 58 | P a g e
[20] Durable Concrete Structures Design Guide
by S. Rostam, AUG 1, 1992.
LIST OF I.S. CODES
[1.] I.S. 12269-1989: Specification for 53 grade
ordinary Portland cement
[2.] I.S. 383-1970: Specification for Coarse and
Fine Aggregate from Natural Sources for
Concrete.
[3.] I.S. 456-2000: Indian Standard Plain and
Reinforced Concrete – Code of Practice
[4.] I.S. 516-1959: Methods of test for strength of
concrete.
[5.] I.S. 1489-1991: Specification for Portland –
Pozzolana Cement Part I Fly ash based.
[6.] I.S.2386-1963(all parts): Methods of Tests
for Aggregates for Concrete.
[7.] I.S. 3085-1965: Methods of test for
permeability of cement and concrete.
[8.] I.S. 3812-1981: Indian Standard Specification
for Fly Ash for use as Pozzolana and
Admixture.
[9.] I.S. 10262-2009: Recommended guide lines
for concrete mix design.
[10.] I.S. 4031-1988 (PT2): Methods for physical
tests for hydraulic cements: Part 2
determination of fineness by specific surface
by Blaine’s air permeability method.
[11.] I.S. 4031-1988 (PT5): Methods for physical
tests for hydraulic cements: Part 5
determination of initial and final setting times.
[12.] IS: 269 -1989: Ordinary Portland cement - 33
Grade (Reaffirmed 2004).
[13.] IS: 455-1989: Portland Slag Cement
(Reaffirmed 2005).
[14.] I.S. 5513-1966: Vicat Apparatus.
[15.] I.S. 5514-1969: Apparatus used in “Le
Chatelier” test.

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Durability Studies on Concrete and Comparison with Partial Replacement of Cement with Rice Husk Ash and Sugarcane Bagasse Ash in Concrete

  • 1. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 52 | P a g e Durability Studies on Concrete and Comparison with Partial Replacement of Cement with Rice Husk Ash and Sugarcane Bagasse Ash in Concrete B.SomeswaraRao *, N.Vidya Sagar Lal **, G.Naveen***. *(PG Student in Dept. of Civil Engineering, GITAS, JNTU Kakinada, AP, India.) ** (Asst.Professor, Dept. of Civil Engineering, GITAS, JNTU-K, AP, India) *** (Asst.Professor, Dept. of Civil Engineering, GITAS, JNTU-K, AP, India.) ABSTRACT This research work describes the feasibility of using the Rice Husk Ash (RHA) and Sugarcane Bagasse Ash (SCBA) waste in concrete production as a partial replacement of cement. This present work deals with the effect on strength and mechanical properties of concrete using RHA and SCBA instead of cement. The cement has been replaced by rice husk ash, accordingly in the range of 0%, 5%, 10%, 15%, and 20% by weight. Concrete mixtures with RHA, were produced, tested and compared in terms of compressive strengths with the Conventional concrete. These tests were carried out to evaluate the mechanical properties for the test results of 7, 28, 60, 90 days for compressive strengths in normal water and in MgSO4 solution of 1%, 3% and 5%. Also the durability aspect for rice husk ash concrete for sulphate attack was tested. Similarly the above tests were also performed for SCBA. The result indicates that the RHA and SCBA improve concrete durability. Finally the test results for RHA and SCBA were compared. Key words: Rice Husk Ash, Sugarcane Bagasse Ash, Concrete, M35 grade concrete, cubes, cylinders, MgSO4, durability. Keywords – M35 grade concrete, MgSO4 Solution, Rice Husk Ash, Sugarcane Bagasse Ash and UTM I. INTRODUCTION The challenge for the civil engineering community in the near future will be to realize projects in harmony with the concept of sustainable development, and this involves the use of high- performance materials and products manufactured at reasonable cost with the lowest possible environmental impact. Concrete is the most widely used construction material worldwide. However, the production of Portland cement, an essential constituent of concrete, releases large amounts of CO2 which is a major contributor to the greenhouse effect and the global warming of the planet. Moreover the developed countries are considering very severe regulations and limitations on CO2 emissions. In this scenario, the use of supplementary cementing materials (SCMs), such fly ash, slag, silica fume, and rice husk ash and sugar cane bagasse ash as a replacement for Portland cement in Concrete presents one viable solution with multiple benefits for the sustainable development of the concrete industry. The most commonly available SCM worldwide is sugar cane bagasse ash, a by-product from the combustion of sugar cane fibers. Sugar cane bagasse ash, if not utilized has to be disposed of in landfills, ponds or rejected in river systems, which may present serious environmental concerns since it is produced in large volumes. Instead of considering it as a "Waste" product, research and development has shown that sugar cane bagasse ash actually represents a highly valuable concrete material. In order to considerably increase the utilization of sugar cane bagasse ash as replacement for cement, such concrete must meet engineering performance requirements that the comparable to those for conventional Portland cement concrete and be cost effective. Rice husk which is an agricultural by–product is abundantly available all over the world. Most of the rice husk, which is obtained by milling paddy, is going as waste materials even though some quantity is used as bedding material, fuel in boilers, brick kilns etc., the husk and its ash, which not only occupy large areas causing space problems, but also cause environmental pollution. The present study was carried out on SCBA and RHA obtained by controlled combustion of sugarcane bagasse, which was procured from the Andhra Pradesh province in India. Sugarcane production in India is over 300 million tons/year leaving about 10 million tons as unutilized and, hence, wastes material. This project analyzes the effect of SCBA and RHA in concrete by partial replacement of cement at the ratio of 0%, 5%, 10%, 15% and 20% by weight. The experimental study RESEARCH ARTICLE OPEN ACCESS
  • 2. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 53 | P a g e examines there compressive strength, split tensile strength, flexural strength. The main ingredient consists of Portland cement, SCBA/RHA, river sand, coarse aggregate and water. After mixing, concrete specimens were casted and subsequently all test specimens were cured in water and in MgSO4 solution of 1%, 3% and 5% for 7 days, 28 days, 60 days and 90 days respectively. Also the durability aspect for rice husk ash and sugarcane bagasse ash concrete for sulphate attack was tested. Similarly the above tests were also performed for SCBA/RHA. The result indicates that the RHA and SCBA improve concrete durability. Finally the test results for RHA and SCBA were compared. II. OBJECTIVE OF THE WORK In this project objective is to study the influence of partial replacement of cement with Rice Husk Ash and sugarcane bagasse ash in concrete subjected to different curing environments. Experimental investigation on sulphate resistance of concrete in MgSO4 solution. The variable factors considered in this study were concrete grade of M35 & curing periods of 7days, 28 days, 60 and 90 days of the concrete specimens. The parameter investigated was the time in days to cause strength deterioration factor of fully immersed concrete specimens in fresh water & in 1%, 3% &5%MgSO4 solution. Rice Husk Ash and sugarcane bagasse ash has been chemically & physically characterized & partially replaced in the ratio of 0%, 5%, 10%, 15%, and 20%. Fresh concrete tests like compaction factor test and hardened concrete tests like compressive strength at the age of 7days, 28 days, 60 and 90 days was obtained. The compressive strength test results of RHA and SCBA for 7,28,60,90 days are compared. III. MATERIALS AND PROPERTIES The materials used in research are: 1. Portland cement (53 grade) 2. Fine aggregate (4.75 mm down) 3. Coarse aggregate (20 mm down) 4. Rice Husk Ash 5. Sugarcane Bagasse Ash 6. Water 7. Admixtures i. Cement Ordinary Portland cement is by far the most important type of cement. The manufacture of cement is decreasing all over the world in view of the popularity of blended cement on account of lower energy consumption, environmental pollution, economic and other technical reasons. In advanced western countries the use of cement has come down to about 40% of the total cement production. The cement procured was tested for physical requirements in accordance with IS: 12269-1987 and for chemical requirements in accordance with IS: 4032-1977. ii. Fine Aggregate The sand obtained from river beds or quarries is used as fine aggregate. Fine aggregate are material passing through an IS sieve that is less than 4.75mm. According to IS 383:1970 the fine aggregate is being classified in to four different zone, that is Zone-I, Zone-II, Zone-III, Zone-IV. Locally available river sand in dry condition was used for the preparation of specimens. The sand is tested for various properties like specific gravity, bulk density etc., and in accordance with IS 2386-1963. iii. Coarse Aggregate The coarse aggregate are granular materials obtained from rocks and crushed stones. They may be also obtained from synthetic material like slag, shale, fly ash and clay for use in light-weight concrete. The physical properties of coarse aggregate like specific gravity, Bulk density, impact value, gradation and fineness modulus are tested in accordance with IS: 2386. The maximum size of coarse aggregates used is 20 mm. The materials are of uniform colour and have good angularity and it will be free from dust and organic matter etc. iv. Rice Husk Ash The husk surrounds the paddy grain. During milling of paddy about 78 % of weight is received as rice, broken rice and bran. Rest 22 % of the weight of paddy is received as husk. This husk is used as fuel in the rice mills to generate steam for the parboiling process. v. Sugarcane Bagasse Ash Sugarcane bagasse consists of approximately 50% of cellulose, 25% of hemicelluloses of lignin. Each ton of sugarcane generates approximately 26% of bagasse (at a moisture content of 50%) and 0.62% of residual ash. The residue after combustion presents a chemical composition dominates by silicon dioxide (sio2). In spite of being a material of hard degradation and that presents few nutrients, the ash is used on the farms as a fertilizer in the sugarcane harvests. In this sugarcane bagasse ash is collected from agricultural fields. vi. Water The locally available potable water accepted for local construction is used in the experimental investigation after testing. The water used is potable water collected from laboratory tap. The pH value should not be less than 6. vii. Magnesium Sulphate (Mgso4) Properties The magnesium Sulphate is obtained from locally and is manufactured in Molychem, Mumbai with minimum assay of 99.8%.
  • 3. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 54 | P a g e Table 1: Analysis of Water (Limitations As Per IS: 456-2000) S. No. Impurity Max. Limit Results 1 PH Value 6 to 8.5 7.4 2 Suspended matter mg/lit 2000 350 3 Organic matter mg/lit 200 25 4 Inorganic matter mg/lit 3000 200 5 Sulphate (SO4) mg/lit 500 25 6 Chlorides (Cl) mg/lit 2000 for P.C.C. 1000 for R.C.C. 60 Table 2: Properties of MgSO4 S. No. Chemical Volume (%) 1 pH (5% water) 6.3 2 Free Alkali sol. (as NaOH) 0.008 3 Free Acid (as H2SO4) 0.01 4 Chlorides 0.02 5 Heavy metals (Pb) 0.0005 6 Arsenic 0.0002 7 Iron (Fe) 0.01 8 Selenium (Se) 0.001 9 Loss of Drying (at 450°c) 50.4 Table 3: Physical Properties of RHA Table 4: Chemical Properties of RHA (Source) S. No. Property Test Results 1 Density 96 kg/m3 2 Physical state Solid non-Hazardous 3 Appearance Very fine powder 4 Particle size 25 microns – mean 5 Color Gray 6 Specific gravity 2.3 Table 5: Physical properties of SCBA S. No. Characteristic Test Results % 1 SiO2 % by mass 93.80 2 Al2o3 by mass 0.74 3 Fe2o3 by mass 0.30 4 Tio2 by mass 0.10 5 Cao by mass 0.89 6 Mgo by mass 0.32 7 Na2o by mass 0.28 8 K2o by mass 0.12 9 LOI 3.37 Table 6: Physical Properties of Fine and Coarse Aggregate S. No. Property Test Result 1. Density 575Kg/m3 2. Specific Gravity 2.2 3. Mean particle size 0.1-0.2 urn 4. Min specific surface area 420m2 / kg 5. Particle shape Spherical Table 7: Chemical properties of SCBA (Source) S. No. Properties Test results Fine Aggregate Coarse Aggregate 1. Specific gravity 2.60 2.74 2. Bulk Density (Kg/m3 ) a) loose b) compacted 1600 kg/m3 1750 kg/m3 1400 Kg/m3 1580 Kg/m3 3. Fineness Modulus 2.76 7.17 Table 8: Mix Proportions by Weight Cement (kgs) Fine aggregate (kgs.) Coarse aggregate (kgs.) w/c ratio (lt.) 453.66 527.28 1225.30 186 1 1.16 2.70 0.41 S. No. Characteristic Test Results % 1 (SiO2)+Al2O3, Fe2C3 % by mass 85.0 2 SiO2% by mass 60.20 3 MgO % by mass 2.48 4 Total sulfur as SO3 % by mass 0.10 5 Available alkali as sodium oxide (Na20) % by mass 4.32 6 Loss of ignition % by mass 5.10
  • 4. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 55 | P a g e IV. RESULTS Compressive Strength of Concrete Graph 1: Compressive strength results of RHA concrete cured in normal water Graph 2: Compressive strength results of SCBA concrete cured in normal water Graph 3: Compressive strength results of RHA concrete cured in 1% Magnesium Sulphate Graph 4: Compressive strength results of SCBA concrete cured in 1% Magnesium Sulphate Graph 5: Compressive strength results of RHA concrete cured in 3% Magnesium Sulphate Graph 6: Compressive strength results of SCBA concrete cured in 3% Magnesium Sulphate
  • 5. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 56 | P a g e Graph 7: Compressive strength results of RHA concrete cured in 5% Magnesium Sulphate Graph 8: Compressive strength results of SCBA concrete cured in 5% Magnesium Sulphate Table 9: Compressive Strength results for cubes cured in water Sample Designation % of RHA 7 days 28 days 60 days 90 days W-0 0 36.89 45.83 55.69 57.98 W-05 5 37.72 46.75 56.16 58.69 W-10 10 38.79 47.69 58.63 60.23 W-15 15 35.86 44.78 56.43 59.16 W-20 20 35.78 43.79 55.57 56.23 Table 10: Compressive Strength results for cubes cured in water Sample Designation % of SCBA 7 days 28 days 60 days 90 days W-0 0 38.24 46.19 56.82 59.99 W-05 5 38.95 47.08 57.54 60.18 W-10 10 39.69 48.145 57.86 61.16 W-15 15 37.30 45.61 55.28 58.12 W-20 20 35.76 44.14 54.01 57.81 Table 11: Compressive Strength results for cubes cured in 1% magnesium sulphate solution Sample Designation % of RHA 7 days 28 days 60 days 90 days W-0 0 35.00 43.59 53.02 55.249 W-05 5 36.03 44.57 53.57 56.007 W-10 10 37.12 45.67 56.10 57.76 W-15 15 34.29 42.61 53.74 56.42 W-20 20 34.10 41.72 52.96 53.68 Table 12: Compressive Strength results for cubes cured in 1% magnesium sulphate solution Sample Designation % of SCBA 7 days 28 days 60days 90days W-0 0 35.34 42.68 52.99 56.46 W-05 5 36.62 43.70 53.85 57.37 W-10 10 37.12 44.99 54.68 58.85 W-15 15 34.99 42.55 51.98 55.12 W-20 20 34.38 41.14 50.12 54.4 Table 13: Compressive Strength results for cubes cured in 3% magnesium sulphate solution Sample Designation % of RHA 7 days 28 days 60days 90days W-0 0 35.17 44.60 54.28 56.10 W-05 5 36.54 45.67 54.93 56.97 W-10 10 37.98 46.86 57.89 58.96 W-15 15 34.88 43.58 55.34 57.60 W-20 20 33.68 42.68 54.47 54.70 Table 14: Compressive Strength results for cubes cured in 3% magnesium sulphate solution Sample Designation % of SCBA 7 days 28 days 60days 90days W-0 0 36.24 44.18 54.51 57.81 W-05 5 37.46 45.17 55.68 58.68 W-10 10 38.32 46.64 56.52 60.32 W-15 15 35.86 43.82 53.26 56.83 W-20 20 35.23 42.32 52.04 55.98 Table 15: Compressive Strength results for cubes cured in 5% magnesium sulphate solution Sample Designation % of RHA 7 days 28 days 60days 90days W-0 0 35.09 43.62 53.39 56.74 W-05 5 36.21 44.81 53.90 57.52 W-10 10 37.17 45.87 57.22 59.62 W-15 15 34.32 42.72 54.68 58.17 W-20 20 33.26 41.89 53.78 55.20
  • 6. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 57 | P a g e Table 16: Compressive Strength results for cubes cured in 5% magnesium sulphate solution Sample Designation % of SCBA 7 days 28 days 60days 90days W-0 0 35.69 43.62 53.72 57.36 W-05 5 36.8 44.6 54.56 57.88 W-10 10 37.52 46.14 55.6 59.16 W-15 15 35.32 43.22 52.64 55.6 W-20 20 34.68 41.88 51.39 55.19 V. CONCLUSION When the compressive strengths of concrete with 0%, 5%, 10%, 15% and 20% weight replacement of cement with RHA and SCBA cured in Normal Water and in 1%, 3%, 5% MgSO4 solution for 28 days. The target mean strength has been increased for the partial replacement of up to 10% by weight. Whereas the compressive strengths at 15 and 20 % replacement of RHA and SCBA are lower. Due to slow Pozzolonic action the rice husk ash (RHA) concrete achieves significant improvement in its mechanical properties at later stages of curing but still it reduces for 15 and 20 % replacement. Due to slow pozzolanic reaction the Sugar Cane Bagasse Ash (SCBA) concrete achieves significant improvement in its mechanical properties at later ages. In concretes can be replaced with 20% SCBA without sacrificing strength at later ages. Both RHA and SCBA concrete is resistant against sulphate attack up to 3%, but further increase up to 5% of MgSO4 the decrease in compressive strengths can be observed. The workability of RHA concretes have decreased in compared with ordinary concrete. It is inferred that reduction in workability is due to large surface area of RHA and SCBA. REFERENCES [1] R.Srinivasanan and K.Sathiya, "Experimental Study on Bagasse Ash in Concrete", International journal, Vol.5, No. 2, pp.60-66, fall 2010. [2] Narayanan Neithalath, "An overview of the benefits of using glass powder as a partial cement replacement material in concretes", The Indian Concrete Journal, Feb 2011. [3] Abhilash, C.K. Singh, Arbind Kumar Sharma , “Study of the Properties of Concrete by Partial Replacement of Ordinary Portland Cement by Rice Husk Ash”, International Journel of Earth Sciences and Engineering, ISSN 0974- 5904, Volume 04, No 06 SPL, , pp. 965- 968, October 2011. [4] S.THIROUGNANAME and Dr.T.Sundararajan : “studies on rice husk ash cement concrete”, IJCIET, IAEME, Puducherry, India,2013. [5] Er.S.A.Reddi, "Concrete Mix Proportioning, Production, Transport and Placement", Proceedings of INCONTEST 2003, 10-12, Sep-2003 at Kumaraguru College of Technology, Coimbatore (India). [6] Satish D.Kene, Pravin V.Domke, Sandesh D.Deshmukh,R.S.Deotale,“assessment of fly ash and rice husk ash”, IJERA, YCCE , Nagpur , 2013. [7] Jan Skalny, Jacques Marchand and Ivan Odler, consequences of sulfate attack on concrete 2002. JayantiRajput , R.K. Yadav, R. Chandak, “The Effect of Rice Husk Ash used As Supplementary Cementing Material On Strength Of Mortar”, Jabalpur, June 2013. [8] Karim, M.F.M. Zain, M. Jamil, F.C. Lai and M.N. Islam Strength of Mortar and Concrete as Influenced by Rice Husk Ash A Review,2012. [9] CCAA association , Sulphate resisting concrete Australia , May 2011. [10] Deepa G Nair, K. Siva Raman, and Job Thomas Mechanical Properties of Rice Husk Ash (RHA) - High strength Concrete. [11] Gidde and A.P. Jivani Waste to Wealth - Potential of Rice Husk in Indian Literature Review Bharati Vidyapeeth Deemed University College of Engineering pune 2007. [12] Hilmi Bin Mahmud, Ghassan Abood Habeeb Study on Properties of Rice Husk Ash and Its Use as Cement Replacement Material March 2010. [13] V.S.Aigbodion, S.B.Hassan, T.Ause and G.B.Nyior, Potential Utilization of Solid Waste (Bagasse Ash) Department of Metallurgical and Materials Engineering,Ahmadu Bello University, Samaru, Zaria, Nigeria. [14] R.S. Khurmi [9] IS Code 456:2000 [15] M.L. Concrete Technologies [16] N.Krishnam Raju Design of concrete mixes [17] Lawrence Effect of sulfates on the setting time of cement and strength of concrete [18] Concrete Technology Theory of Practice by M.S. Shetty, 1982. [19] A M Neville Properties of Concrete English language book society, Longman.
  • 7. B.SomeswaraRao et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 5, Issue 11, (Part - 4) November 2015, pp.52-58 www.ijera.com 58 | P a g e [20] Durable Concrete Structures Design Guide by S. Rostam, AUG 1, 1992. LIST OF I.S. CODES [1.] I.S. 12269-1989: Specification for 53 grade ordinary Portland cement [2.] I.S. 383-1970: Specification for Coarse and Fine Aggregate from Natural Sources for Concrete. [3.] I.S. 456-2000: Indian Standard Plain and Reinforced Concrete – Code of Practice [4.] I.S. 516-1959: Methods of test for strength of concrete. [5.] I.S. 1489-1991: Specification for Portland – Pozzolana Cement Part I Fly ash based. [6.] I.S.2386-1963(all parts): Methods of Tests for Aggregates for Concrete. [7.] I.S. 3085-1965: Methods of test for permeability of cement and concrete. [8.] I.S. 3812-1981: Indian Standard Specification for Fly Ash for use as Pozzolana and Admixture. [9.] I.S. 10262-2009: Recommended guide lines for concrete mix design. [10.] I.S. 4031-1988 (PT2): Methods for physical tests for hydraulic cements: Part 2 determination of fineness by specific surface by Blaine’s air permeability method. [11.] I.S. 4031-1988 (PT5): Methods for physical tests for hydraulic cements: Part 5 determination of initial and final setting times. [12.] IS: 269 -1989: Ordinary Portland cement - 33 Grade (Reaffirmed 2004). [13.] IS: 455-1989: Portland Slag Cement (Reaffirmed 2005). [14.] I.S. 5513-1966: Vicat Apparatus. [15.] I.S. 5514-1969: Apparatus used in “Le Chatelier” test.