The document provides a 10 step procedure for students to enroll for examinations through the new SMASH portal. It explains that students should visit the SMASH portal website and enter their login credentials to access their online account. From there, they should click on the "Enrollment" module and "Enrollment Request" option to begin filling out the examination enrollment form, selecting details like country, state, and exam combination. It advises students who already started an earlier enrollment request to click "Complete Enrollment Request" instead of starting a new one. Once all details are filled, students can select a payment gateway to pay their fees and receive an instant fee receipt upon successful payment.