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© 2020 COLUMBIA Technologies.
Company History
1
John H Sohl III
www.columbiatechnologies.com
jsohl@columbiatechnologies.com
+1-301-455-7644
High-Resolution
Remedial Design
Characterization
© 2020 COLUMBIA Technologies. 2
SOIL
PERMEABILITY
LNAPL
CHEMISTRY
SPATIAL
ALIGNMENT
VAPOR PHASE
DISSOLVED
PHASE
3/12/2017 MIP Cross-Section D-D': PID
http://www.prinmath.com/leecamp4/review/html/mip_xsecDD_PID.html 1/2
Home | Index | Previous | Next
Depth to Water & Water Level Elevations
Hydraulic Conductivity
Water Quality Concentrations
Soils Concentrations
HPT/MiHpt Evaluations (Electrical Conductivity, Injection Pressure, Flow)
GROUND
WATER
© 2020 COLUMBIA Technologies. 3
Network for Industrially Contaminated Land in Africa
(NICOLA)
Global Awareness
© 2020 COLUMBIA Technologies.
WHY HIGH-RESOLUTION?
4
© 2020 COLUMBIA Technologies. 5
Preliminary
Investigation
Secondary
Investigation
Corrective
Action
Long Term
Monitoring
Our Mission:
Control the Cost of Remediation
© 2020 COLUMBIA Technologies.
Preliminary
Investigation
Secondary
Investigation
Corrective
Action
Long Term
Monitoring
6
Controlling the Cost of RemediationCharacterization
Monetization
OPTIONS
© 2020 COLUMBIA Technologies. By F Payne: Remediation Hydraulics
© 2020 COLUMBIA Technologies. By F Payne: Remediation
© 2020 COLUMBIA Technologies.
By F Payne: Remediation
© 2020 COLUMBIA Technologies. 10
Back Diffusion from Clays = REBOUND
(Consider Mass Flux Discharge in RDC)
Courtesy Tom Sale, PhD, Colorado State University (Go RAMS)
© 2020 COLUMBIA Technologies.
Mass Loading is in the Soil
0
20
40
60
80
100
120
Ground Water Soil
11
0
0.5
1
1.5
2
2.5
Ground Water Soil
Soil and Ground Water
Contamination (ppm)
Contaminant Load
mg / 100 cu. ft.
If you design to only treat the dissolved phase contaminant,
you get REBOUND
© 2020 COLUMBIA Technologies.
RISK BASED VS. REMEDIATION
MEASUREMENTS
12
© 2020 COLUMBIA Technologies.
SmartData Solutions®
Professional
Services
Advanced Hi-
Res 3D
Sensors
Real-Time
Analytics
© 2020 COLUMBIA Technologies.
Who We Are
© 2020 COLUMBIA Technologies.
CHOOSING THE RIGHT
SCALE APPROPRIATE TOOLS
TO SUPPORT SUCCESSFUL OUTCOMES
15
© 2020 COLUMBIA Technologies.
START WITH MACHINE
MEASUREMENTS
16
© 2020 COLUMBIA Technologies.
Direct Push Technologies
17Source: Geoprobe Systems, Inc.
• OIP Probe: Robust with
simple connection to the
trunkline.
• Driveable: Using 7822 series
machines and drive cushions.
• Compatible: With Geoprobe
1.5 inch and 1.75 inch rod
systems.
3
OIP Description
© 2020 COLUMBIA Technologies.
HYDRAULIC PROFILING TOOL (HPT)
– SOIL PERMEABILITY
18
© 2020 COLUMBIA Technologies. 19
Use Hydraulic Profiling Tool (HPT)
to Measure Soil Pore Pressure
Pressure
More Permeable
Less Permeable
© 2020 COLUMBIA Technologies.
Example Cost of Uncertainty
Enhanced Bio-Remediation Injection
• 1.0 MG/L PCE CONTAMINATION
• 400 FT WIDE x 1000 FT LONG x 40 FT THICK
• COMPETING ELECTRON ACCEPTORS
• DO 5 MG/L
• NO3 5 MG/L
• SO4 100 MG/L
• MN 5 MG/L
• FE 50 MG/L
• CH4 10 MG/L
20
35% INCREASE IN AMENDMENT REQUIRED !
GW Flow Rate 0.5 FT/DAY 1.0 FT/DAY
EVO DEMAND (lbs) 263,210 356,389
Change GW flowrate from
0.5 to 1.0 FT/DAY
Source:
© 2020 COLUMBIA Technologies.
MEMBRANE INTERFACE PROBE (MIP)
– VOC SCREENING
21
© 2020 COLUMBIA Technologies.
Membrane Interface Probe
Source: Geoprobe Systems, Inc.
© 2020 COLUMBIA Technologies.
Membrane Interface Probe (MIP)
Quick Notes:
- Volatile Organic Compounds (VOCs)
- Typical Detection Limits:
-1 ppm petroleum fuels
-200 ppb chlorinated solvents
-Lower for Low-Level MIP
- Integrated Hydraulic Profiling Tool
- Performance Test Required!
© 2020 COLUMBIA Technologies. 24
Membrane Interface Probe (MIP)
Confirms chlorinated
compound
Halogen Specific Detector
Photo Ionization Detector
Chlorinated
Volatile Organic
Compounds
© 2020 COLUMBIA Technologies. 25
FID confirms PID
Flame Ionization Detector
Halogen Specific Detector
Photo Ionization Detector
Membrane Interface Probe (MIP)
Petroleum
Volatile Organic
Compounds
© 2020 COLUMBIA Technologies. 26
Combined Membrane Interface Probe and
Hydraulic Profiling Tool (MiHpt)
Probable Transport
Probable Storage
Halogen Specific Detector
Photo Ionization Detector
Pressure
© 2020 COLUMBIA Technologies.
OPTICAL IMAGING PROFILER (OIP)
(LNAPL)
27
© 2020 COLUMBIA Technologies. 28
• OIP Probe: Robust with
simple connection to the
trunkline.
• Driveable: Using 7822 series
machines and drive cushions.
• Compatible: With Geoprobe
1.5 inch and 1.75 inch rod
systems.
3
OIP Description
© 2020 COLUMBIA Technologies. 29
Typical OIP image of hydrocarbon
fluorescence using the UV light source.
OIP UV Image
7 mm
9.5 mm
5
© 2020 COLUMBIA Technologies. 30
The OIP Log
Log 8-1
• Images captured every
15mm (.05 ft.).
• Images are analyzed for
fluorescence in real time.
• The percent of the image
area representing fuel
fluorescence is recorded on
the log.
3.0m
0% detected
5.7m
50.2% detected
EC Log Fluorescence
(% area)
8
© 2020 COLUMBIA Technologies.
$$ of
Monitoring
Wells
NAPLDistribution
High-Resolution Mapping of
Petroleum Pipeline Leakage
Cost-effectively characterize
Contaminated sites
31
© 2014 COLUMBIA Technologies.
Petroleum Does Not Follow GW
Gradient
© 2020 COLUMBIA Technologies.
VOCs
Methane
O2
CO2
Source: API Bulletin 18
Managing Risk at LNAPL Sites 2nd
May 2018
32
© 2020 COLUMBIA Technologies.
SYSTEMATIC, DISCRETE SATURATED
SOIL SAMPLING - MASS
33
© 2020 COLUMBIA Technologies. 34
Systematic
Screening of Soil
© 2020 COLUMBIA Technologies. 35
Systematic Sampling
© 2020 COLUMBIA Technologies. 36MIP-PID MIP-FID HPT-Press EC
Monitoring Well Results
9.34 mg/L BTEX
0.33 mg/L MTBE
ND mg/L Naphthalene
4.5 % NAPL
Saturation
© 2020 COLUMBIA Technologies.
LNAPLvsGRO
Figure13March2019High-ResolutionSite
Characterization
Soil Sample Results
© 2020 COLUMBIA Technologies.
LNAPLvsGRO
Figure13March2019High-ResolutionSite
Characterization
© 2020 COLUMBIA Technologies.
DISCRETE GROUNDWATER SAMPLING
- DISSOLVED PHASE CONTAMINATION
39
© 2020 COLUMBIA Technologies.
Integration of Multiple HRSC Tools
40© 2013 COLUMBIA Technologies.
1. Isolate
and Refine
the Source
Area
2.Determine
pathways
ofpermeability
3. Sample to confirm
mass and contaminant ID
and remediation
parameters
© 2020 COLUMBIA Technologies.
3/12/2017 MIP Cross-Section D-D': PID
Home | Index | Previous | Next
Mass FLUX Diagram
© 2020 COLUMBIA Technologies.
SPATIAL ALIGNMENT
42
© 2020 COLUMBIA Technologies.
MW-3
Recovery Zone
Contaminant Mass
RM-13
© 2020 COLUMBIA Technologies.
NATURAL SOURCE ZONE DEPLETION
(NSZD) – WATER & VAPOR
44
© 2020 COLUMBIA Technologies. 45
© 2020 COLUMBIA Technologies.
Source: API Bulletin 18 Managing Risk at LNAPL Sites 2nd edition, May 2018
46
VOCs
Methane
O2
CO2
© 2020 COLUMBIA Technologies. 47
VOCs
Methane
O2
CO2
© 2020 COLUMBIA Technologies.
Key Takeaway Points
• Remediation of contaminated land is a process with
many links (steps) in the Value Chain
• You can’t skip a step without losing time & money
• Technology is just one piece of the process but not the
most expensive piece
• An accurate Site Conceptual Model is the critical
leverage point to ensure proper cost-effective
remediation design and success
• High-resolution information is critical to minimizing
the uncertainty in the Site Conceptual Model
© 2020 COLUMBIA Technologies.
THINK.
RESTORE,
49
John Sohl, President/CEO
COLUMBIA Technologies
www.columbiatechnologies.com
jsohl@columbiatechnologies.com
+1-301-455-7644
Sustainably

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Columbia Technologies High-Resolution Remedial Design Characterization -SOHL 20200505

  • 1. © 2020 COLUMBIA Technologies. Company History 1 John H Sohl III www.columbiatechnologies.com jsohl@columbiatechnologies.com +1-301-455-7644 High-Resolution Remedial Design Characterization
  • 2. © 2020 COLUMBIA Technologies. 2 SOIL PERMEABILITY LNAPL CHEMISTRY SPATIAL ALIGNMENT VAPOR PHASE DISSOLVED PHASE 3/12/2017 MIP Cross-Section D-D': PID http://www.prinmath.com/leecamp4/review/html/mip_xsecDD_PID.html 1/2 Home | Index | Previous | Next Depth to Water & Water Level Elevations Hydraulic Conductivity Water Quality Concentrations Soils Concentrations HPT/MiHpt Evaluations (Electrical Conductivity, Injection Pressure, Flow) GROUND WATER
  • 3. © 2020 COLUMBIA Technologies. 3 Network for Industrially Contaminated Land in Africa (NICOLA) Global Awareness
  • 4. © 2020 COLUMBIA Technologies. WHY HIGH-RESOLUTION? 4
  • 5. © 2020 COLUMBIA Technologies. 5 Preliminary Investigation Secondary Investigation Corrective Action Long Term Monitoring Our Mission: Control the Cost of Remediation
  • 6. © 2020 COLUMBIA Technologies. Preliminary Investigation Secondary Investigation Corrective Action Long Term Monitoring 6 Controlling the Cost of RemediationCharacterization Monetization OPTIONS
  • 7. © 2020 COLUMBIA Technologies. By F Payne: Remediation Hydraulics
  • 8. © 2020 COLUMBIA Technologies. By F Payne: Remediation
  • 9. © 2020 COLUMBIA Technologies. By F Payne: Remediation
  • 10. © 2020 COLUMBIA Technologies. 10 Back Diffusion from Clays = REBOUND (Consider Mass Flux Discharge in RDC) Courtesy Tom Sale, PhD, Colorado State University (Go RAMS)
  • 11. © 2020 COLUMBIA Technologies. Mass Loading is in the Soil 0 20 40 60 80 100 120 Ground Water Soil 11 0 0.5 1 1.5 2 2.5 Ground Water Soil Soil and Ground Water Contamination (ppm) Contaminant Load mg / 100 cu. ft. If you design to only treat the dissolved phase contaminant, you get REBOUND
  • 12. © 2020 COLUMBIA Technologies. RISK BASED VS. REMEDIATION MEASUREMENTS 12
  • 13. © 2020 COLUMBIA Technologies. SmartData Solutions® Professional Services Advanced Hi- Res 3D Sensors Real-Time Analytics
  • 14. © 2020 COLUMBIA Technologies. Who We Are
  • 15. © 2020 COLUMBIA Technologies. CHOOSING THE RIGHT SCALE APPROPRIATE TOOLS TO SUPPORT SUCCESSFUL OUTCOMES 15
  • 16. © 2020 COLUMBIA Technologies. START WITH MACHINE MEASUREMENTS 16
  • 17. © 2020 COLUMBIA Technologies. Direct Push Technologies 17Source: Geoprobe Systems, Inc. • OIP Probe: Robust with simple connection to the trunkline. • Driveable: Using 7822 series machines and drive cushions. • Compatible: With Geoprobe 1.5 inch and 1.75 inch rod systems. 3 OIP Description
  • 18. © 2020 COLUMBIA Technologies. HYDRAULIC PROFILING TOOL (HPT) – SOIL PERMEABILITY 18
  • 19. © 2020 COLUMBIA Technologies. 19 Use Hydraulic Profiling Tool (HPT) to Measure Soil Pore Pressure Pressure More Permeable Less Permeable
  • 20. © 2020 COLUMBIA Technologies. Example Cost of Uncertainty Enhanced Bio-Remediation Injection • 1.0 MG/L PCE CONTAMINATION • 400 FT WIDE x 1000 FT LONG x 40 FT THICK • COMPETING ELECTRON ACCEPTORS • DO 5 MG/L • NO3 5 MG/L • SO4 100 MG/L • MN 5 MG/L • FE 50 MG/L • CH4 10 MG/L 20 35% INCREASE IN AMENDMENT REQUIRED ! GW Flow Rate 0.5 FT/DAY 1.0 FT/DAY EVO DEMAND (lbs) 263,210 356,389 Change GW flowrate from 0.5 to 1.0 FT/DAY Source:
  • 21. © 2020 COLUMBIA Technologies. MEMBRANE INTERFACE PROBE (MIP) – VOC SCREENING 21
  • 22. © 2020 COLUMBIA Technologies. Membrane Interface Probe Source: Geoprobe Systems, Inc.
  • 23. © 2020 COLUMBIA Technologies. Membrane Interface Probe (MIP) Quick Notes: - Volatile Organic Compounds (VOCs) - Typical Detection Limits: -1 ppm petroleum fuels -200 ppb chlorinated solvents -Lower for Low-Level MIP - Integrated Hydraulic Profiling Tool - Performance Test Required!
  • 24. © 2020 COLUMBIA Technologies. 24 Membrane Interface Probe (MIP) Confirms chlorinated compound Halogen Specific Detector Photo Ionization Detector Chlorinated Volatile Organic Compounds
  • 25. © 2020 COLUMBIA Technologies. 25 FID confirms PID Flame Ionization Detector Halogen Specific Detector Photo Ionization Detector Membrane Interface Probe (MIP) Petroleum Volatile Organic Compounds
  • 26. © 2020 COLUMBIA Technologies. 26 Combined Membrane Interface Probe and Hydraulic Profiling Tool (MiHpt) Probable Transport Probable Storage Halogen Specific Detector Photo Ionization Detector Pressure
  • 27. © 2020 COLUMBIA Technologies. OPTICAL IMAGING PROFILER (OIP) (LNAPL) 27
  • 28. © 2020 COLUMBIA Technologies. 28 • OIP Probe: Robust with simple connection to the trunkline. • Driveable: Using 7822 series machines and drive cushions. • Compatible: With Geoprobe 1.5 inch and 1.75 inch rod systems. 3 OIP Description
  • 29. © 2020 COLUMBIA Technologies. 29 Typical OIP image of hydrocarbon fluorescence using the UV light source. OIP UV Image 7 mm 9.5 mm 5
  • 30. © 2020 COLUMBIA Technologies. 30 The OIP Log Log 8-1 • Images captured every 15mm (.05 ft.). • Images are analyzed for fluorescence in real time. • The percent of the image area representing fuel fluorescence is recorded on the log. 3.0m 0% detected 5.7m 50.2% detected EC Log Fluorescence (% area) 8
  • 31. © 2020 COLUMBIA Technologies. $$ of Monitoring Wells NAPLDistribution High-Resolution Mapping of Petroleum Pipeline Leakage Cost-effectively characterize Contaminated sites 31 © 2014 COLUMBIA Technologies. Petroleum Does Not Follow GW Gradient
  • 32. © 2020 COLUMBIA Technologies. VOCs Methane O2 CO2 Source: API Bulletin 18 Managing Risk at LNAPL Sites 2nd May 2018 32
  • 33. © 2020 COLUMBIA Technologies. SYSTEMATIC, DISCRETE SATURATED SOIL SAMPLING - MASS 33
  • 34. © 2020 COLUMBIA Technologies. 34 Systematic Screening of Soil
  • 35. © 2020 COLUMBIA Technologies. 35 Systematic Sampling
  • 36. © 2020 COLUMBIA Technologies. 36MIP-PID MIP-FID HPT-Press EC Monitoring Well Results 9.34 mg/L BTEX 0.33 mg/L MTBE ND mg/L Naphthalene 4.5 % NAPL Saturation
  • 37. © 2020 COLUMBIA Technologies. LNAPLvsGRO Figure13March2019High-ResolutionSite Characterization Soil Sample Results
  • 38. © 2020 COLUMBIA Technologies. LNAPLvsGRO Figure13March2019High-ResolutionSite Characterization
  • 39. © 2020 COLUMBIA Technologies. DISCRETE GROUNDWATER SAMPLING - DISSOLVED PHASE CONTAMINATION 39
  • 40. © 2020 COLUMBIA Technologies. Integration of Multiple HRSC Tools 40© 2013 COLUMBIA Technologies. 1. Isolate and Refine the Source Area 2.Determine pathways ofpermeability 3. Sample to confirm mass and contaminant ID and remediation parameters
  • 41. © 2020 COLUMBIA Technologies. 3/12/2017 MIP Cross-Section D-D': PID Home | Index | Previous | Next Mass FLUX Diagram
  • 42. © 2020 COLUMBIA Technologies. SPATIAL ALIGNMENT 42
  • 43. © 2020 COLUMBIA Technologies. MW-3 Recovery Zone Contaminant Mass RM-13
  • 44. © 2020 COLUMBIA Technologies. NATURAL SOURCE ZONE DEPLETION (NSZD) – WATER & VAPOR 44
  • 45. © 2020 COLUMBIA Technologies. 45
  • 46. © 2020 COLUMBIA Technologies. Source: API Bulletin 18 Managing Risk at LNAPL Sites 2nd edition, May 2018 46 VOCs Methane O2 CO2
  • 47. © 2020 COLUMBIA Technologies. 47 VOCs Methane O2 CO2
  • 48. © 2020 COLUMBIA Technologies. Key Takeaway Points • Remediation of contaminated land is a process with many links (steps) in the Value Chain • You can’t skip a step without losing time & money • Technology is just one piece of the process but not the most expensive piece • An accurate Site Conceptual Model is the critical leverage point to ensure proper cost-effective remediation design and success • High-resolution information is critical to minimizing the uncertainty in the Site Conceptual Model
  • 49. © 2020 COLUMBIA Technologies. THINK. RESTORE, 49 John Sohl, President/CEO COLUMBIA Technologies www.columbiatechnologies.com jsohl@columbiatechnologies.com +1-301-455-7644 Sustainably