The CoLaBATS project consortium brought together academics, research institutes, recyclers, chemists and equipment producers with expertise in developing a new hydrometallurgical process for extracting multiple metals from battery waste. The international consortium included companies and research organizations from Spain, France, the UK, and Sweden with relevant experience in battery recycling, solvent extraction, materials processing, and industrial scale technology development.
SYSTEM OF PUBLIC PERCEPTION OF CARBON DIOXIDE SEQUESTRATION PROJECTSIAEME Publication
Global warming and climate change problems have led to the consolidation of international efforts to reduce atmospheric carbon dioxide. The technology of carbon capture and storage is the key link in the strategy aimed at cutting carbon dioxide emissions. The article gives a view of positive and negative aspects of the introduction of the carbon dioxide sequestration technology. The authors have determined the impact of the project’s public perception on the efficiency of its execution. The authors have revealed factors, which influence the way the public perceives carbon dioxide sequestration projects; a model has been developed to form public perception of carbon capture and storage projects and recommendations on how to form the positive attitude of stakeholders to these projects
Research Coordination Network on Carbon Capture, Utilization and Storage Funded by National Science Foundation in USA - A.-H. Alissa Park, Columbia University - UKCCSRC Strathclyde Biannual 8-9 September 2015
SYSTEM OF PUBLIC PERCEPTION OF CARBON DIOXIDE SEQUESTRATION PROJECTSIAEME Publication
Global warming and climate change problems have led to the consolidation of international efforts to reduce atmospheric carbon dioxide. The technology of carbon capture and storage is the key link in the strategy aimed at cutting carbon dioxide emissions. The article gives a view of positive and negative aspects of the introduction of the carbon dioxide sequestration technology. The authors have determined the impact of the project’s public perception on the efficiency of its execution. The authors have revealed factors, which influence the way the public perceives carbon dioxide sequestration projects; a model has been developed to form public perception of carbon capture and storage projects and recommendations on how to form the positive attitude of stakeholders to these projects
Research Coordination Network on Carbon Capture, Utilization and Storage Funded by National Science Foundation in USA - A.-H. Alissa Park, Columbia University - UKCCSRC Strathclyde Biannual 8-9 September 2015
2021 hidalgo et al. - development of an innovative process involving the us...Jokin Hidalgo
Development of an innovative process involving the use of
ionic liquids for the recovery and purification of rare earths
from permanent magnets and NIMH batteries
Presently most electrical/electronic equipment (EEE) is not designed for recycling, let alone for circulation. Plastics in these products account for 20% of material use, and through better design, significant environmental and financial savings could be gained.
Technological solutions and circular design opportunities already exist, but they haven’t been implemented yet.
Some challenges, such as ease of disassembly, could be resolved through better communication and by sharing learnings across the value chain.
Instead of WEEE, we should focus on developing CEEE: Circular Electrical and Electronic Equipment.
The case examples of this report show how different stages of the lifecycle can be designed so that plastics circulation becomes possible and makes business sense.
Current commercial thermoelectric devices incorporate p-type semiconductor materials that are produced from expensive and rare elements, namely tellurium, which is toxic and predominantly sourced in China. As an alternative approach for the replacement of the tellurium-based p-type semiconductor materials, START proposes a unique technological solution and value-chain based on a “waste material-waste heat to power” methodology. This approach implies the production of sulphide p-type semiconductor materials that will incorporate, amongst others, discarded mining waste sulphides, mainly consisting of the tetrahedrite-tennantite mineral series. Thus, the project concept also includes the stages of material processing, device design and production, testing and validation (Fig. 2). The aim is to produce a TE device reaching TRL6, with the START TE device demonstrated in industrial processes. As a first step, several historical European mining sites have been targeted for collection of tetrahedrite-tennantite minerals, namely: a) Austria: Leogang (Nöckelberg, Barbarastollen) and Schwaz (Sandpocher, Antonihalde, Sigmundhalde), b), Germany: Rammelsberg mine, Bergwerkswohlfahrt mine, c) Portugal: Neves Corvo, Barrigão and Brancanes mines, d) Slovakia: Rožňava mine, e) Spain: La Sierrecilla, El Corriellu, Peña Negra, Torres de Albarracín, Lanteira mines, amongst others. The collected minerals are undergoing processing and will feed the material processing in the upcoming stages.
The Circular Economy - a Powerful Force for Climate MitigationEIT Climate-KIC
Transformative innovation for prosperous and low-carbon industry
This report investigates how a more circular economy can contribute to cutting CO2 emissions. It explores a broad range of opportunities for the four largest materials in terms of emissions (steel, plastics, aluminium, and cement) and two large use segments for these materials (passenger cars and buildings).
The key conclusion is that a more circular economy can make deep cuts to emissions from heavy industry: in an ambitious scenario, as much as 296 million tons CO2 per year in the EU by 2050, out of 530 Mt in total – and some 3.6 billion tonnes per year globally. Making better use of the materials that already exist in the economy thus can take EU industry halfway towards net-zero emissions. Moreover, doing so often is economically attractive. Initiatives for a more circular economy therefore deserve a central place in EU climate and industrial policy.
2021 hidalgo et al. - development of an innovative process involving the us...Jokin Hidalgo
Development of an innovative process involving the use of
ionic liquids for the recovery and purification of rare earths
from permanent magnets and NIMH batteries
Presently most electrical/electronic equipment (EEE) is not designed for recycling, let alone for circulation. Plastics in these products account for 20% of material use, and through better design, significant environmental and financial savings could be gained.
Technological solutions and circular design opportunities already exist, but they haven’t been implemented yet.
Some challenges, such as ease of disassembly, could be resolved through better communication and by sharing learnings across the value chain.
Instead of WEEE, we should focus on developing CEEE: Circular Electrical and Electronic Equipment.
The case examples of this report show how different stages of the lifecycle can be designed so that plastics circulation becomes possible and makes business sense.
Current commercial thermoelectric devices incorporate p-type semiconductor materials that are produced from expensive and rare elements, namely tellurium, which is toxic and predominantly sourced in China. As an alternative approach for the replacement of the tellurium-based p-type semiconductor materials, START proposes a unique technological solution and value-chain based on a “waste material-waste heat to power” methodology. This approach implies the production of sulphide p-type semiconductor materials that will incorporate, amongst others, discarded mining waste sulphides, mainly consisting of the tetrahedrite-tennantite mineral series. Thus, the project concept also includes the stages of material processing, device design and production, testing and validation (Fig. 2). The aim is to produce a TE device reaching TRL6, with the START TE device demonstrated in industrial processes. As a first step, several historical European mining sites have been targeted for collection of tetrahedrite-tennantite minerals, namely: a) Austria: Leogang (Nöckelberg, Barbarastollen) and Schwaz (Sandpocher, Antonihalde, Sigmundhalde), b), Germany: Rammelsberg mine, Bergwerkswohlfahrt mine, c) Portugal: Neves Corvo, Barrigão and Brancanes mines, d) Slovakia: Rožňava mine, e) Spain: La Sierrecilla, El Corriellu, Peña Negra, Torres de Albarracín, Lanteira mines, amongst others. The collected minerals are undergoing processing and will feed the material processing in the upcoming stages.
The Circular Economy - a Powerful Force for Climate MitigationEIT Climate-KIC
Transformative innovation for prosperous and low-carbon industry
This report investigates how a more circular economy can contribute to cutting CO2 emissions. It explores a broad range of opportunities for the four largest materials in terms of emissions (steel, plastics, aluminium, and cement) and two large use segments for these materials (passenger cars and buildings).
The key conclusion is that a more circular economy can make deep cuts to emissions from heavy industry: in an ambitious scenario, as much as 296 million tons CO2 per year in the EU by 2050, out of 530 Mt in total – and some 3.6 billion tonnes per year globally. Making better use of the materials that already exist in the economy thus can take EU industry halfway towards net-zero emissions. Moreover, doing so often is economically attractive. Initiatives for a more circular economy therefore deserve a central place in EU climate and industrial policy.
EIT RM Summit 2020, September 30 [CROCODILE]Jokin Hidalgo
The CROCODILE project will showcase innovative metallurgical systems based on advanced pyro-, hydro-, bio-, iono- and electrometallurgy technologies for the recovery of cobalt and the production of cobalt metal and upstream products from a wide variety of secondary and primary European resources. CROCODILE will demonstrate the synergetic approaches and the integration of the innovative metallurgical systems within existing recovery processes of cobalt from primary and secondary sources at different locations in Europe, to enhance their efficiency, improve their economic and environmental values, and will provide a zero-waste strategy for important waste streams rich in cobalt such as batteries.
More than 140+ experts presented their inspiring projects and connected with over 700+ participant worldwide during this year’s online edition of the Raw Material Summit 2020 that took place on 29-30 September 2020. The innovative technologies of PLATIRUS projects and its latest project results were one of the successful presentations hosted by the project coordinator TECNALIA along with the support of the partner Monolithos Ltd. (Iakovos Yakoumis) during the EASME session H2020 – Innovation and innovators along the raw materials value chain on 30 September.
PLATIRUS consortium held a presentation sharing insights about the PLATInum group metals Recovery Using Secondary raw materials. The Platirus concept, partnership along with the technologies developed were presented by Guillermo Pozo (TECNALIA), while Iakovos Yakoumis (Monolithos Ltd) presented the incorporation of Deep-Eutectic-Solvents (DES) Leaching Technology developed in the framework of Platirus to MONOLITHOS’ integrated circular economy model for manufacturing new automotive catalysts from 100% recycled Platinum Group Metals (EIT Raw Materials CEBRA Up-Scaling Project).
Tecnalia Research & Innovation - Oct 2018Jokin Hidalgo
Tecnalia Corporation is a Technology Corporation set up in 2001 with the principal aim of contributing towards the development of the economic and social environment by means of the use and promotion of Technological Innovation through the development and dissemination of Research in an international context.
Tecnalia Research & Innovation is a Technology Corporation set up in 2001 with the principal aim of contributing towards the development of the economic and social environment by means of the use and promotion of Technological Innovation through the development and dissemination of Research in an international context.
We develop technology and generate business opportunities for eco-industry and other industrial sectors, focusing our activities in solving their environmental problems …
IONIC LIQUIDS can replace traditional industrial processes such as electrodeposition, pyro and hydrometallurgy (solid-liquid extraction, liquid-liquid extraction, precipitation) for new eco-friendly, no volatile organic solvents containing, no energy- intensive, and cost effective processes .
Curso de Introducción a la Corrosión (2ª Edición) / 14-15 de Noviembre 2017 /...Jokin Hidalgo
La corrosión es una reacción química o electroquímica entre un material, generalmente metálico, y su entorno, que produce una pérdida de sus características. En un gran número de aplicaciones industriales cobra especial relevancia la compatibilidad de los materiales, equipos y sistemas con el ambiente en que se van a ubicar y las condiciones de servicio, que se manifiesta habitualmente en los fenómenos de la corrosión.
A través de este curso, impartido en esta segunda edición por reconocidos expertos de TECNALIA y de IR Corrosión, conoceremos con mayor profundidad los fenómenos que originan los procesos de corrosión, deteniéndonos para analizar aspectos específicos de la corrosión en ductos y en uniones soldadas. El curso presentará igualmente métodos para la protección contra la corrosión, así como técnicas para la monitorización o seguimiento de la corrosión.
Habida cuenta de que la protección contra la corrosión comienza por su prevención, a lo largo del curso veremos ensayos para la evaluación de la corrosión de los materiales, así como ensayos acelerados que permiten simular las condiciones que pueden causar los diferentes fenómenos de corrosión. Finalizaremos el curso viendo una serie de casos prácticos de análisis de fallos.
El curso combinará teoría con casos prácticos. Los asistentes recibirán documentación impresa que recogerá toda la información relevante del curso.
El curso está dirigido a todas aquellas personas interesadas en entender los fenómenos de corrosión que tienen lugar en diferentes aplicaciones industriales así como los medios disponibles para preverlos y evitarlos: ingenieros, técnicos, gerentes, responsables de ventas, responsables de mantenimiento, inspectores, etc.
Closing the loop on recycling of rare earth elementsJokin Hidalgo
REE4EU aims to realise a breakthrough in securing the availability of rare earth elements (REE) in Europe. This means providing, for the first time, a cost-effective and efficient REE extraction and direct rare earth alloys (REA) production route from abundantly available in-process and end-of-life REE waste streams. We hope to show that it is possible to maintain the whole value chain during permanent magnet production and electrodes for nickel metal hydride batteries using secondary raw materials, thus avoiding the dependency of importing expensive REE from China. The project might also open up market opportunities to stakeholders seeking sustainable REE recycling technologies.
REE4EU Newsletter | Issue n°4 | March 2017Jokin Hidalgo
REE4EU: Integrated High Temperature Electrolysis
(HTE) and Ion Liquid Extraction (ILE) for a Strong
and Independent European Rare Earth Elements
Supply Chain
Curso introducción a la corrosión tecnaliaJokin Hidalgo
Curso de Introducción a la Corrosión (14-15 de Noviembre de 2016):
La corrosión es una reacción química o electroquímica entre un material, generalmente metálico, y su entorno, que produce una pérdida de sus características. En un gran número de aplicaciones industriales cobra especial relevancia la compatibilidad de los materiales, equipos y sistemas con el ambiente en que se van a ubicar y las condiciones de servicio, que se manifiesta habitualmente en los fenómenos de la corrosión. A través de este curso, impartido por reconocidos expertos de TECNALIA, conoceremos con mayor profundidad los fenómenos que originan los diferentes procesos de corrosión, deteniéndonos para analizar aspectos específicos de la corrosión en ductos y en uniones soldadas. El curso presentará igualmente diferentes métodos para la protección contra la corrosión. Una de las áreas temáticas del mismo tratará la monitorización o seguimiento de la corrosión. Habida cuenta de que la protección contra la corrosión comienza por su prevención, a lo largo del curso veremos ensayos para la evaluación de la corrosión de los materiales, así como ensayos acelerados que permiten simular las condiciones que pueden causar los diferentes fenómenos de corrosión. Finalizaremos el curso viendo una serie de casos prácticos de análisis de fallos. El curso combinará teoría con casos prácticos. Los asistentes recibirán documentación impresa que recogerá toda la información relevante del curso. El curso está dirigido a todas aquellas personas interesadas en entender los fenómenos de corrosión que tienen lugar en diferentes aplicaciones industriales así como los medios disponibles para preverlos y evitarlos: ingenieros, técnicos, gerentes, responsables de ventas, responsables de mantenimiento, inspectores, etc.
Multi-source connectivity as the driver of solar wind variability in the heli...Sérgio Sacani
The ambient solar wind that flls the heliosphere originates from multiple
sources in the solar corona and is highly structured. It is often described
as high-speed, relatively homogeneous, plasma streams from coronal
holes and slow-speed, highly variable, streams whose source regions are
under debate. A key goal of ESA/NASA’s Solar Orbiter mission is to identify
solar wind sources and understand what drives the complexity seen in the
heliosphere. By combining magnetic feld modelling and spectroscopic
techniques with high-resolution observations and measurements, we show
that the solar wind variability detected in situ by Solar Orbiter in March
2022 is driven by spatio-temporal changes in the magnetic connectivity to
multiple sources in the solar atmosphere. The magnetic feld footpoints
connected to the spacecraft moved from the boundaries of a coronal hole
to one active region (12961) and then across to another region (12957). This
is refected in the in situ measurements, which show the transition from fast
to highly Alfvénic then to slow solar wind that is disrupted by the arrival of
a coronal mass ejection. Our results describe solar wind variability at 0.5 au
but are applicable to near-Earth observatories.
The increased availability of biomedical data, particularly in the public domain, offers the opportunity to better understand human health and to develop effective therapeutics for a wide range of unmet medical needs. However, data scientists remain stymied by the fact that data remain hard to find and to productively reuse because data and their metadata i) are wholly inaccessible, ii) are in non-standard or incompatible representations, iii) do not conform to community standards, and iv) have unclear or highly restricted terms and conditions that preclude legitimate reuse. These limitations require a rethink on data can be made machine and AI-ready - the key motivation behind the FAIR Guiding Principles. Concurrently, while recent efforts have explored the use of deep learning to fuse disparate data into predictive models for a wide range of biomedical applications, these models often fail even when the correct answer is already known, and fail to explain individual predictions in terms that data scientists can appreciate. These limitations suggest that new methods to produce practical artificial intelligence are still needed.
In this talk, I will discuss our work in (1) building an integrative knowledge infrastructure to prepare FAIR and "AI-ready" data and services along with (2) neurosymbolic AI methods to improve the quality of predictions and to generate plausible explanations. Attention is given to standards, platforms, and methods to wrangle knowledge into simple, but effective semantic and latent representations, and to make these available into standards-compliant and discoverable interfaces that can be used in model building, validation, and explanation. Our work, and those of others in the field, creates a baseline for building trustworthy and easy to deploy AI models in biomedicine.
Bio
Dr. Michel Dumontier is the Distinguished Professor of Data Science at Maastricht University, founder and executive director of the Institute of Data Science, and co-founder of the FAIR (Findable, Accessible, Interoperable and Reusable) data principles. His research explores socio-technological approaches for responsible discovery science, which includes collaborative multi-modal knowledge graphs, privacy-preserving distributed data mining, and AI methods for drug discovery and personalized medicine. His work is supported through the Dutch National Research Agenda, the Netherlands Organisation for Scientific Research, Horizon Europe, the European Open Science Cloud, the US National Institutes of Health, and a Marie-Curie Innovative Training Network. He is the editor-in-chief for the journal Data Science and is internationally recognized for his contributions in bioinformatics, biomedical informatics, and semantic technologies including ontologies and linked data.
Observation of Io’s Resurfacing via Plume Deposition Using Ground-based Adapt...Sérgio Sacani
Since volcanic activity was first discovered on Io from Voyager images in 1979, changes
on Io’s surface have been monitored from both spacecraft and ground-based telescopes.
Here, we present the highest spatial resolution images of Io ever obtained from a groundbased telescope. These images, acquired by the SHARK-VIS instrument on the Large
Binocular Telescope, show evidence of a major resurfacing event on Io’s trailing hemisphere. When compared to the most recent spacecraft images, the SHARK-VIS images
show that a plume deposit from a powerful eruption at Pillan Patera has covered part
of the long-lived Pele plume deposit. Although this type of resurfacing event may be common on Io, few have been detected due to the rarity of spacecraft visits and the previously low spatial resolution available from Earth-based telescopes. The SHARK-VIS instrument ushers in a new era of high resolution imaging of Io’s surface using adaptive
optics at visible wavelengths.
THE IMPORTANCE OF MARTIAN ATMOSPHERE SAMPLE RETURN.Sérgio Sacani
The return of a sample of near-surface atmosphere from Mars would facilitate answers to several first-order science questions surrounding the formation and evolution of the planet. One of the important aspects of terrestrial planet formation in general is the role that primary atmospheres played in influencing the chemistry and structure of the planets and their antecedents. Studies of the martian atmosphere can be used to investigate the role of a primary atmosphere in its history. Atmosphere samples would also inform our understanding of the near-surface chemistry of the planet, and ultimately the prospects for life. High-precision isotopic analyses of constituent gases are needed to address these questions, requiring that the analyses are made on returned samples rather than in situ.
Professional air quality monitoring systems provide immediate, on-site data for analysis, compliance, and decision-making.
Monitor common gases, weather parameters, particulates.
Richard's entangled aventures in wonderlandRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
Seminar of U.V. Spectroscopy by SAMIR PANDASAMIR PANDA
Spectroscopy is a branch of science dealing the study of interaction of electromagnetic radiation with matter.
Ultraviolet-visible spectroscopy refers to absorption spectroscopy or reflect spectroscopy in the UV-VIS spectral region.
Ultraviolet-visible spectroscopy is an analytical method that can measure the amount of light received by the analyte.
1. “Turning waste into a
resource through inno-
vative technologies,
processes and ser-
vices” (7th Framework
Programme)
CoLaBATS Consortium Members
Project Update:
The CoLaBATS project is now coming to the end after three years of
intense activity. The international consortium, which spans academ-
ics, research institutes, recyclers, chemists and equipment produc-
ers, has brought together expertise to deliver a completely new and
highly innovative hydrometallurgical process for leaching multiple
metals from battery waste black mass (electrodes and electrolytes).
The CoLaBATS technology has been designed to provide a multi-
stage process capable of extracting key high value individual metals
(Ni, Co, Cu, Ln, Zn), plus the extraction of other metal mixtures suit-
able for further refining.
The key outcome of the technology has been the ability to use novel
deep eutectic solvents for leaching metals from the black mass.
Compared to current hydrometallurgical processes that employ
strong acids, the deep eutectic solvent (DES) is much more benign.
The DES has a low vapour pressure, making it easier to handle, and
offering improved air quality in the workplace,.
In addition, the benefit of the project outcomes is the ability to reuse
the chemistry. The DES can be stripped of the metals and reused
in a closed loop process. The benefits of this are the reduction in
chemical costs for operating the plant, reduction of waste, and im-
proved environmental impacts compared to other hydrometallurgical
recycling processes.
Editorial:
The CoLaBATS project
has come to an end, with
the successful demonstra-
tion of the technology.
The pilot plant operated at
C-Tech Innovation has
processed over 10 kg of
both Li-ion and NiMH
black mass, the equivalent
of approximately 50 kg of
battery waste.
The CoLaBATS project
has also successfully
overcome issues such as
leaching from battery
black mass, liquid-liquid
separation for ionic liquids
and solvents and has cre-
ated methods for the sep-
aration and delivery of sin-
gle metal fractions suita-
ble for placing back into
the metals market.
The technology has prov-
en to be relatively robust,
being able to handle dif-
ferent black mass compo-
sitions, and metal ratios.
The robustness of the
technology is likely to ren-
der it applicable for use
with many other waste
materials and metal mix-
es. For the future, consor-
tium members are plan-
ning to utilise many of the
results in further waste
treatment strategies.
2. Zero Waste Europe
2
The feasibility of recycling is not the critical aspect of achieving a zero waste Eu-
rope, recycling comes down to the economic drivers to recover low concentration
strategic metals. In June, a zero waste conference was held in Brussels and
brought together industry experts interested in leading towards a zero waste Eu-
rope. The conference aimed to address the future EU roadmaps for zero-waste,
looking to identify current recycling obstacles and address actions required to
move Europe to a near-zero waste society.
The conference was designed to tackle three key waste value chains: ICT-waste
(waste electrical and electronic equipment, WEEE), End-of-Life Vehicles (ELV),
and packaging waste. These topics were chosen because they contribute a large
percentage to waste streams, and for ICT and vehicles, contain many strategic
metals and minerals. The environmental consequences of dumping these materi-
als include heavy metal poisoning of local habitats and waterways, release of
plasticizers and phthalates to the local environment, and the sheer volume of
waste generated occupying more and more landfill.
For example, EU plastic demand was 46.3 Mtonnes in 2013 of which, 63% was
post consumer plastic waste derived from packaging. Many municipalities have
recycling collection points designed to collect and separate this packaging waste
from household waste. For materials like cardboard, wood pallets, glass and ‘tin’
containers separation and recycling is fairly simple, cost effective and efficient.
However, plastic packaging waste comes in many forms and can be difficult to
distinguish. Contamination of one plastic with another polymer ,or other contami-
nants, significantly reduces the value of the secondary material, generating a final
material with little market value. In addition, by 2020 there will be 100 M scrapped
cars in Europe; these contain a mix of plastics, composites, metals, batteries, and
electronics. To meet the ELV Directive’s targets, 85% of the car must be recov-
ered for the materials (secondary raw materials) and up to a further 10% recov-
ered for energy.
The conference’s objective was to obtain an insight into the key areas that should
be focused on in order to significantly improve the efficiency of recycling in these
three sectors. Bottlenecks preventing improvements to the recycling of ELVs, ICT
and packaging were identified and, for all three topics, some of the same bottle-
necks arose. Primarily these were; performance of separation and sorting tech-
nology. There are many sophisticated new designs and technologies being
demonstrated and operated for the chemical separation of materials. However, all
these techniques run into the same issues – the cost of separating raw materials
from complex mixes. Physical separation of materials was identified as one of the
corner stone processes which needs improving in order to create a big impact on
recycling materials from packaging, WEEE and vehicles. For all the sophisticated
processes, the operational costs are often the sticking point.
Circular Economy designs and concepts need to be amalgamated with current
legislation, as well as migrating research and innovation policies to push for Circu-
lar Economy accomplishments. It has become apparent through decades of EC
investment that there are multiple technologies and approaches capable of recy-
cling mixed wastes to recover multiple materials, however, often it is the case that
these processes are not economically viable in the current metals market. A pro-
cess adopting a more synergistic approach optimising collection, sorting, pre-
treatment and development of the secondary metals market is required. The Co-
LaBATS project adds to this knowledge base and provides a possible new recov-
ery system for REE and other critical materials in regions which cannot afford
large pyrometallurgical processing units. The CoLaBATS project is best scaled up
to deal with large volumes of batteries, and to utilise the cyclic approach of the
chemistry process design, minimising chemical costs and improving economics
and metal recovery ratios. To improve upon this further, more detailed analysis of
the separation technology should take place, coupled with more intensive pre-
treatment, sorting, shredding and separation.
Recycling Tools
The ECOMAP
A map designed to locate sus-
tainable businesses and prod-
ucts.
http://the-ecomap.com/en/oikos-
ecomap/
Waste Markets in the
EU
An EC study on the internal
waste recycling and recovery
markets.
http://ec.europa.eu/environment/
waste/studies/index.htm
EIONET
European Topic Centre on Sus-
tainable Consumption and Pro-
duction
http://scp.eionet.europa.eu/facts
WastePortal
Information on urban waste man-
agement with an emphasis on
Low and Middle Income Coun-
tries
http://www.wasteportal.net/
3. 3
C-Tech Innovation, Capenhurst 15th
Sept 2016
Following the successful development and deploy-
ment of the new CoLaBATS battery recycling tech-
nology, the project team hosted a public dissemi-
nation event to interested attendees on 15th
Sep-
tember at C-Tech Innovation in Capenhurst, Ches-
ter as part of the project’s final progress meeting.
The event, which was attended by key personnel
from both industry and academia, was opened by
Dr Rod Kellner from Env-Aqua Solutions Ltd, who
gave an introduction to the structure of the event,
which included both a series of presentations and
a demonstration of the CoLaBATS technology. Dr
Bob Crawford, the project’s coordinator from C-
Tech Innovation Ltd than presented an overview of
the CoLaBATS project and its objectives. The
structures of typical batteries were outlined and it
was made clear how complex both battery struc-
tures and their chemical compositions actually
were. Battery types varied by basic chemistry and
manufacturer and, for each chemistry, the material
composition was also changing with time. Dr
Crawford showed data detailing the material make
up of a typical lithium-ion battery and described
how challenging it was to meet the legislatively
required recycling targets that were mandated.
The basic outline of the CoLaBATS metal recovery
process was then described; it utilised a liquid-
liquid extraction approach based on the use of
specially developed deep eutectic solvents. The
new process offered a number of key advantages
over conventional aqueous approaches and it was
possible to separate the valuable metals in high purity from those that
were of less value or contaminants.
Professor Martin Goosey of Env-Aqua Solutions then gave a presentation
detailing why battery recycling was becoming such an important issue.
Two key drivers were the current European ‘producer responsibility’ legis-
lation and the need to recover and conserve valuable material resources.
Martin gave an introductory overview to the legislation and pointed out
that it typically became more stringent each time the European Commis-
sion revisited it; recycling targets were thus likely to increase from the cur-
rent 50% level. He detailed the huge volumes of batteries that were used
and consumed in the UK, and globally, each year, and discussed this in
the context of the subsequent waste stream and the valuable materials
they contained. There was also predicted to be a huge emerging demand
for new lithium-ion batteries for use in electric vehicles, which would turn
drive the demand for the materials from which they were made. There
was thus a real, and growing demand for new recycling and recovery
technologies such as that developed in the CoLaBATS project.
Project Dissemination Event
4. 4
Dissemination Event Continued:
Professor Karl Ryder from the University of
Leicester, then gave a presentation on the fun-
damental deep eutectic solvent technology that
was the basis of the novel CoLaBATS process.
Karl outlined the properties of ionic liquids and
the benefits they offered. They had low vapour
pressures and were generally non-toxic. They
also enabled chemical processes to be devel-
oped that were not possible in aqueous sys-
tems. He also described the work that had
been performed by the university as part of the
project to prepare low cost deep eutectic sol-
vents and detailed some of the other applica-
tions of deep eutectic solvents that had been
developed for related electronics applications.
These included processes for the deposition of
a range of metal coatings that showed superior
properties compared to existing processes. He
concluded by detailing how these new chemistries were playing an im-
portant role in the new CoLaBATS technology and how interest in these
unique materials was rapidly increasing. The number of papers pub-
lished on deep eutectic solvents and their applications was also continu-
ously increasing.
Clare Downs from C-Tech Innovation then concluded the presentation
session by giving a more detailed description of the specific CoLaBATS
process. She began be outlining the solvent extraction and metal specia-
tion approach that formed the unique fundamental basis of the CoLa-
BATS technology. The initial process development work had been car-
ried out on a small scale and had allowed determination of the separation
times. The technology had then been further developed around the use
of novel mixer settlers specially developed for this specific application.
The scaled-up demonstration unit had been running at C-Tech since
June and was currently being used to generate as much performance
information as possible. This data was subsequently fed into the opera-
tional costs analysis and life cycle assessment parts of the project. The
key performance benefits of the process were then outlined and it had
been found that the deep eutectic solvents could be recycled and reused
multiple times. Recovered cobalt had a greater
than 98 % purity and the mixed lanthanide
product was >95 % pure. Clare concluded the
presentation by detailing the future planned
work that would be undertaken to bring the pro-
ject to a successful conclusion.
The CoLaBATS team were also present at the
event and, following a wrap-up question and
answer session, the attendees were taken to C-
Tech’s development laboratories for a demon-
stration of the CoLaBATS equipment in opera-
tion. This highly successful event concluded
with a networking lunch where the attendees
were given the opportunity to ask the CoLa-
BATS team any final questions.
5. 5
Consortium:
Aprofitament i assesorament ambiental S.L. is a SME created by Cristobal
Hernandez in 2005. The company started in Les Franqueses del Vallès with
the recycling of all kind of batteries as his main market, the thing that has
made A3 different is that A3 started collecting the batteries and other hazard-
ous waste from the garages as oil filters, antifreeze and hydrocarbon mixtures.
A3 have the only precious metal recovery plant in Spain, recycling WEEE
and Catalytic converters. A3 recycle about 20.000 tons per year of WEEE,
batteries, and metal scrap issued from industry.
CEDRAT TECHNOLOGIES (CTEC) is a high tech SME based in the French
Innovation Valley, close to Grenoble, which provides innovative solutions in
the electrical and mechatronic fields, ranging from the development of soft-
ware tools, to the study, design and manufacture of systems. CTEC extensive
R&D activity is conducted by a multidisciplinary team of experts. Its laborato-
ries are equipped with a complete library of engineering software and special-
ised measurement apparatus. CTEC focuses its expertise on industry needs
for innovation and optimisation and is a member of EARTO (European Associ-
ation of Research and Technology Organisations).
At Chalmers University of Technology in the mid-2000s a new section was
established in the department of Chemical & Biological Engineering which is
named “Industrial Materials Recycling” (IMR). This is a section which is devot-
ed to the study of recycling, the primary aim of this section is to create recy-
cling methods for materials which cannot be recycled. Another key aim is to
produce recycling processes which produce products which are at least as
valuable as the original material was before it was fabricated into the product
which is being recycled.
C-Tech Innovation is one of the UK’s most successful research, technology
and innovation organisations. With clients across the globe in multiple sectors,
we are focused on delivering outstanding solutions helping them to maximise
their potential for success. We deliver government funded collaborative R&D
(EU, Innovate UK), one-to-one bespoke research and have a successful track
record in Innovation Voucher delivery.
An SME specialising in industrial end-of-life, waste treatment and pollu-
tion control, and has been instrumental in the design, installation and
promotion of waste minimisation and resource recovery systems and pro-
grammes with a global industrial client base.
The company’s ethos is to support industrial symbiosis, resourcefulness and
generate circular economies within industry. Recovery of materials from
waste products and effluents is a key business area for Env-Aqua Solutions.
The company designs and installs, on a turnkey basis, waste treatment and
recovery based plant and equipment.
6. 6
G & P Batteries is the UK’s leading authority on waste battery collection and
recycling. We offer a nationwide service for the collection of every kind of
waste battery or battery powered appliance. All batteries collected are taken to
our headquarters in Darlaston, West Midlands where they are sorted into vari-
ous chemistries and then stored until an optimum quantity is obtained for recy-
cling. Wherever possible, waste batteries are recycled within the UK.
The Materials Group at the University of Leicester (UoL) are the pioneers of
the Deep Eutectic Solvent (DES) technology that has grown in popularity and
application over recent years. Prof. Karl Ryder has been working in the field of
DESs for more than a decade now and his current interests are primarily fo-
cussed on developing electrochemical processes for modifying a range of me-
tallic surfaces and also developing novel polymer batteries. Much of the sur-
face modification work has revolved around the electroplating and elec-
tropolishing of a wide variety of real world substrates with the aim of replacing
current processes already used by industry.
Solvionic produces more than 100 ionic liquids and related products refer-
ences. Different quality standards are available depending on application. Vol-
umes are adapted to every step of a process i.e. from few grams to the ton
scale. Within the framework of sustainable development, Solvionic develops
selective chemistry branching from the use of ionic liquids. Solvionic is actively
engaged in the production of ionic liquids, the development of their applica-
tions and providing assistance to industrial projects in the field of energy stor-
age, new materials and catalysis. Solvionic is also the choice for a privileged
partnership offering dynamism, reactivity and competitiveness. Innovation,
high-tech control and quality of the products are the key factors to Solvionic’s
success today and Solvionic products and services are being marketed world-
wide.
TECNALIA RESEARCH & INNOVATION (www.tecnalia.com) is a private, independent, non-
profitapplied research centre of international excellence. Legally a Foundation, Tecnalia is the
leading private and independent research and technology organization in Spain and one of the
largest in Europe, employing1.299 people (198 PhDs) and with income of 102 Million € in 2014.
TECNALIA aims working with companies to promote the transformation of knowledge into
wealth to improve people’s quality of life by generating business opportunities for industry. TEC-
NALIA is based on 7 sectorial Business Divisions: Sustainable Construction, Energy and Envi-
ronment, Industry and Transport, ICT-European Software Institute, Health, Innovation Strate-
gies and Technological Services, which allow TECNALIA to provide personalized and multi-
disciplinary attention to our clients. TECNALIA has been granted over 250 patents and promot-
ed more than 30 spin-off companies.
Vienna University of Technology is Austria’s largest scientific-technical re-
search and educational institution and covers the classic engineering disci-
plines. In addition to basic research for the development of new methods and
strategies of synthesis, the focus of the Institute of Applied Synthetic Chemis-
try is on practice-oriented synthetic chemistry. The cornerstones of its activi-
ties are the synthesis and characterization of products that are industrially and
technologically exploitable and marketable as well as the development of tech-
nical manufacturing processes.
Consortium Focus:
7. This project has received funding from the Eu-
ropean Union’s Seventh Programme for re-
search, technological development and demon-
stration under grant agreement No 603482.
CoLaBATS www.colabats.eu
EWIT www.ewit.site
ProSUM www.prosumproject.eu
Closing the Loop www.closingtheloop.eu
Useful Links:
Upcoming EU
H2020 Calls:
SCS-13-2016-2017: New
solutions for sustainable
production of raw materials
7th March 2017
SC5-14-2016-2017: Raw
Materials Innovation Actions
7th March 2017
SC5-33-2017: Closing the
Water Gap
7th March 2017
FOF-06-2017: New product
functionalities through ad-
vanced surface manufactur-
ing processes for mass pro-
duction
19th January 2017
PILOTS-03-2017: Pilot lines
for manufacturing of nano-
textured surfaces with me-
chanically enhanced proper-
ties.
27th October 2016
Events -
19th October 2016
Brussels:
SCIENCE AND INNOVATION IN EUROPE: Horizon 2020 so
far, completing the European Research Area and next stages
for the Innovation Union http://bit.ly/2aumk44
15th November 2016
Barcelona:
EUROPEAN UTILITY WEEK 2016: A conference for connect-
ing the smart utility community. This will showcase new devel-
opments in grid optimisation, renewables, energy storage, stor-
age efficiency and more. http://eurobat.org/events
16th January 2017
London:
THE CHALLENGES OF HYDROGEN AND METALS: The Roy-
al Society is hosting a scientific discussion about producing hy-
drogen from renewable energy sources, and its damaging ef-
fects on metals used in its handling and storage.
7