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1/2020 | Baltic Transport Journal | 33
How to design, produce, use, and re-use batteries more sustainably
Charge!
by Gabrielė Vilemo Gotkovič
Rechargeable lithium-ion batteries could become the ‘new gold’ in the carbon-neutral future. In fact, the
decarbonisation of cars, trucks, and power grids depends on this fast-improving technology. Batteries
are expected to become one of the 21st
century’s key developments, and the market looks forward to
being worth tens of billions of euros by the middle of the 2020s. One million plug-in cars are needed to
be sold in 2020 to meet the EU’s car CO2
standards, and achieving the bloc’s 2030 goals requires sales to
go up by 40%. As a result, the European Commission has launched the EU Battery Alliance, championed
by 16 gigafactories, to support the creation of a green battery value chain catering to Europe’s demand.
U
nlike combustion engines that
literally burn oil, batteries do
not combust lithium or other
minerals such as cobalt and
nickel, which can be fully recovered and
used again. As such, battery-powered vehi-
cles are already, from a life-cycle perspec-
tive, better than traditional ones. However,
they still have an environmental impact,
which should (and can) be minimised in
order to achieve the EU’s climate and envi-
ronmental objectives. Successful policy
design has to consider sustainable battery
production, reuse and recycling, as well
as responsible sourcing of raw materials
globally to maximise industrial, climate,
and societal benefits.
A market-driven by regulations
towards sustainability
Just as for conventional cars, upstream
emissions in electric vehicles (EVs) are
associated with their production phase,
notably of lithium-ion batteries (LIB).
Unfortunately, little robust, primary up-
to-date data is available on the 20 odd mate-
rials, as well as complex and fast-evolving
processes used in LIB cell, module, and
pack manufacturing. The recent report by
Circular Energy Storage, commissioned
by the Brussels-based NGO Transport &
Environment (T&E), highlights the current
climate impact range of LIB batteries to be
between 39 kg CO2equivalent
/kWh and 196 kg
CO2e
/kWh, roughly the same as driving a
diesel car 11,800-to-89,400 km.
The T&E’s policy brief on battery regu-
lations in Europe outlines the following
reasons for this wide spectrum. First, there
is a significant absence of current primary
data, with much modelling based on stud-
ies dating back as far as 1999. While the
earlier pilots have a higher per kWh energy
input, the new gigafactories demonstrate
a significantly lower energy use due to
economies of scale and process efficiency
gains. Secondly, the lack of a consistent
calculation methodology often completely
ignores the reuse and recycling potential.
At the moment, industrial LIB recycling
is mainly limited to portable batteries,
excluding the volumes of batteries from
end-of-life EV vehicles. Consequently, this
makes it significantly more challenging to
accurately account for the real-life impact
of different recycling processes.
On this account, the urgent first step
for the EU battery regulations needs to be
put in place to maintain a robust and up-
to-date database of emission factors for
different battery materials and processes
which are at the cell level and are factory-,
process-, and location-specific.
The production of battery cells is the
most energy and carbon-intensive part of
making LIB, responsible for as much as 75%
of energy consumption. Figure 2 shows an
exemplary breakdown of different steps for
Nickel-Manganese-Cobalt 111 cell chemis-
try (currently on the market but getting fast
outdated). The detailed data on the latest
chemistries, such as NMC811 (eight parts
nickel, one-part manganese, and one-part
cobalt), is not readily available, yet these
are expected to have lower carbon foot-
prints. Nonetheless, the figure pinpoints
the general battery emissions ‘hot spots’
that should be taken into account when
legislating future EU battery regulation.
To reduce carbon and environmental
footprint of battery production, the EU sus-
tainable performance requirements should
incentivize, support, and foster deploy-
ing waste heat recovery processes, along
with technologies to green the prepara-
tion of precursors. Huge improvements
can come from better cathode coating
techniques that would make the cathode
powder mixing and coating processes more
efficient. The design of the future EU regu-
lations should also seek to incentivize the
set-up of vertically-integrated local supply
chains in order to drastically reduce trans-
port emissions as well as stimulate the
future battery production facilities to be
located near low-carbon energy sources.
It is important to speed up this process
so as to lower the overall carbon footprint
of batteries. This much-needed accelera-
tion can gain momentum via a compre-
hensive regulatory strategy. Mandatory
requirements on all battery manufactur-
ers whose products are found on the EU
market are necessary to measure and report
each battery’s carbon and energy footprint.
Next, once accurate data have been col-
lected and data verification process estab-
lished, a mandatory CO2
threshold should
34 | Baltic Transport Journal | 1/2020
Fig. 1. Key chemistry phases in Nickel-Manganese-Cobalt 111 (NMC) battery manufacturing
Source for figs. 1-2: T&E’s GREEN POWERHOUSE. T&E blueprint for battery regulation in Europe (2019)
Chemical
reaction
Drying
Burning in
furnace
Coating
& drying
electrodes
Cell
manufacturing
& ageing
Assembly
(incl.
electronic
controls)
Assembly
Li hydroxide
or Li
carbonate
Sodium
hydroixide
Ni, Co, Mn
sulfate
Precursor
(=NMC
hydroxide)
Cathode
active material
(NMC)
Electrode Battery cell
Battery
module Battery pack
BMS
Anode active
material
(graphite)
be considered in order to ensure that all
future batteries follow manufacturing best
practise. Finally, EU research & innovation
funding should focus on improving bat-
tery manufacturing processes, e.g., better
coating techniques, industrial waste heat
recovery processes, and environmentally-
friendly and efficient recycling.
It is as equally important to ensure a
sustainable battery design strategy. For
instance, the use of hazardous materials in
manufacturing should be phased-out and
tightly controlled to spur innovation into
better methods, materials, and toxic-free
battery value chains. Batteries should also be
durable and have a long lifecycle, where the
design of battery cells and packs incorpo-
rates circularity from the outset to facilitate
disassembly, repair, and recycling.
Ultimately, innovative technologies
should be incorporated into battery man-
agement systems to provide standardised
access to key battery parameters and usage
data. A ‘battery passport’ would enable
innovative and smart services by providing
comprehensive and extensive information
on the product. Both static (i.a. battery pro-
duction date & location, carbon footprint)
and dynamic data (remaining capacity &
fade and voltage drop, charging history,
etc.) could be used to make the most of bat-
teries, especially if we consider their mul-
tifunctionality, when, e.g., EVs could serve
as energy storage points for the power grid.
The circular battery
When battery performance is no longer
good enough for a car or a truck (less range,
worse acceleration, etc.), it should be reused
in less demanding applications like in fork-
lifts or as a stationary energy storage/buffer
in high power charging stations (to reduce
peaks). Such second-life batteries will pro-
vide extra storage flexibility on the grid,
allowing for higher penetration of renewa-
bles across Europe. It is therefore important
to incentivize longer lifetime and remove
any barriers for reuse applications.
The ultimate goal is, however, to fully
recover all the valuable materials (lithium,
nickel, cobalt) found in batteries at the end of
their lives. While few people today question
the benefits of recycling, as it helps to secure
critical materials in Europe, currently the
market for LIB recycling is in China where
EU batteries are usually sent. An important
finding from one of the studies conducted
by Element Energy indicates that Europe
has inadequate recycling capacity, estimated
todayat33kt/year,deemedinsufficientshould
currently in use EVs reach the end of their
lifecycles in 2030 onwards. Similarly, there is
almost no commercial-scale LIB recycling in
Europe as things stand today, the majority of
“recycling” companies providing low-value
collection or shredding only. Europe should
perceive battery recycling as an asset, not a
burden, and an opportunity to create local
industries and jobs.
SUSTAINABILITY
Photo: Volvo
1/2020 | Baltic Transport Journal | 35
Batteries made responsibly
The growing battery demand for mobile
and grid applications has put into spot-
light the key metals used in lithium-ion
technology, namely cobalt, lithium, and
nickel. The attention has especially turned
to the implications of the EV boom has
had on cobalt, particularly the working
conditions in the mines of the Democratic
Republic of Congo (DRC), where around
two-thirds of the global cobalt production
are situated at present.
The transition to a zero-emission
economy in Europe should not come at
the expense of others. On the contrary,
if done responsibly, increased demand
for minerals mined in countries such
as the DRC could help support much-
needed development. Nonetheless, this
necessitates socially- and environmen-
tally-responsible ways of sourcing mate-
rials. It is important to acknowledge
that mining challenges in places like the
DRC are much deeper and older, which
makes them no better than widely criti-
cised practises in oil and gas industries.
Instead of bashing electric cars, the
European community should use their
increasing market share as a leverage to
put pressure on downstream companies
to clean up their supply chains as well as
on governments, to put solid governance
structures in place to solve problems in
both large-scale and artisanal mining in a
comprehensive and pan-industry manner.
Various certification schemes have
sought to improve sourcing of materials
(copper, tin, gold, and cobalt), e.g., the vol-
untary OECD Due Diligence Guidance for
responsible supply chains, supported by
the Responsible Business Conduct guide-
lines, acknowledged by many as the best
practice example in the field. T&E’s com-
parative analysis of the six largest global
supply chain certification schemes appli-
cable to the industrial cobalt production
in the DRC shows that while most schemes
are comprehensive in their design and sus-
tainability criteria, they nonetheless lack
rigorous and independent enforcement.
Crucially, traceability on where cobalt is
extracted and access to transparent infor-
mation on mining conditions remain most
schemes’ Achilles heel.
The focus, therefore, should be on
better enforcing of what is already in place.
Fortunately, the previous OECD guidelines
on responsible supply chains have already
been integrated into national or supra-
national legislation on conflict minerals
(tin, tantalum, tungsten, gold), such as the
US Dodd-Frank Act or the EU Conflicts
Minerals Regulation – but do not currently
apply to cobalt, nickel, or lithium.
A single, reliable, and enforceable
mechanism on which to base supply
chain due diligence, and the choice of
suppliers across all the materials, will
also benefit the EU battery industry,
which often gets lost in the myriad vol-
untary schemes applicable to individual
metals. Companies should not be pull-
ing out of, e.g., the DRC completely or
blankly refusing to buy from small-scale
miners; instead, downstream companies
should work with and require their sup-
pliers to improve mining conditions and
refining practices. In other words, the EU
trade and development policy should help
European companies source materials sus-
tainably via smart investment to improve
safety, health, and working conditions in
developing economies.
‘round the corner
Batteries – whether in vehicles or, at the
end of their life, as second life storage appli-
cations – offer a readily-available distributed
energy resource and can store electricity
cheaply, facilitating far greater integration
of renewables into Europe’s energy market.
The EU has the chance to ensure responsi-
ble corporate behaviour across the supply
chain by making green objectives manda-
tory instead of voluntary.
The e-mobility revolution is just ‘round
the corner, and Europe is rightly prioritis-
ing battery value chain development in its
industrial strategy.  ‚
Fig. 2. Energy used in MJ per kWh of Nickel-Manganese-Cobalt 111 (NMC) battery cell (excl. casting)
0 225 450 675 900
Precursor and Li2CO3	 Cathode production	 Anode + anode production	 Separator
Electrolyte		 Binder		 Current controls		 Cell production
181 228 99 835 87 216
SUSTAINABILITY
Photo: Tesla

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Charge! @BalticTransportJournal

  • 1. 1/2020 | Baltic Transport Journal | 33 How to design, produce, use, and re-use batteries more sustainably Charge! by Gabrielė Vilemo Gotkovič Rechargeable lithium-ion batteries could become the ‘new gold’ in the carbon-neutral future. In fact, the decarbonisation of cars, trucks, and power grids depends on this fast-improving technology. Batteries are expected to become one of the 21st century’s key developments, and the market looks forward to being worth tens of billions of euros by the middle of the 2020s. One million plug-in cars are needed to be sold in 2020 to meet the EU’s car CO2 standards, and achieving the bloc’s 2030 goals requires sales to go up by 40%. As a result, the European Commission has launched the EU Battery Alliance, championed by 16 gigafactories, to support the creation of a green battery value chain catering to Europe’s demand. U nlike combustion engines that literally burn oil, batteries do not combust lithium or other minerals such as cobalt and nickel, which can be fully recovered and used again. As such, battery-powered vehi- cles are already, from a life-cycle perspec- tive, better than traditional ones. However, they still have an environmental impact, which should (and can) be minimised in order to achieve the EU’s climate and envi- ronmental objectives. Successful policy design has to consider sustainable battery production, reuse and recycling, as well as responsible sourcing of raw materials globally to maximise industrial, climate, and societal benefits. A market-driven by regulations towards sustainability Just as for conventional cars, upstream emissions in electric vehicles (EVs) are associated with their production phase, notably of lithium-ion batteries (LIB). Unfortunately, little robust, primary up- to-date data is available on the 20 odd mate- rials, as well as complex and fast-evolving processes used in LIB cell, module, and pack manufacturing. The recent report by Circular Energy Storage, commissioned by the Brussels-based NGO Transport & Environment (T&E), highlights the current climate impact range of LIB batteries to be between 39 kg CO2equivalent /kWh and 196 kg CO2e /kWh, roughly the same as driving a diesel car 11,800-to-89,400 km. The T&E’s policy brief on battery regu- lations in Europe outlines the following reasons for this wide spectrum. First, there is a significant absence of current primary data, with much modelling based on stud- ies dating back as far as 1999. While the earlier pilots have a higher per kWh energy input, the new gigafactories demonstrate a significantly lower energy use due to economies of scale and process efficiency gains. Secondly, the lack of a consistent calculation methodology often completely ignores the reuse and recycling potential. At the moment, industrial LIB recycling is mainly limited to portable batteries, excluding the volumes of batteries from end-of-life EV vehicles. Consequently, this makes it significantly more challenging to accurately account for the real-life impact of different recycling processes. On this account, the urgent first step for the EU battery regulations needs to be put in place to maintain a robust and up- to-date database of emission factors for different battery materials and processes which are at the cell level and are factory-, process-, and location-specific. The production of battery cells is the most energy and carbon-intensive part of making LIB, responsible for as much as 75% of energy consumption. Figure 2 shows an exemplary breakdown of different steps for Nickel-Manganese-Cobalt 111 cell chemis- try (currently on the market but getting fast outdated). The detailed data on the latest chemistries, such as NMC811 (eight parts nickel, one-part manganese, and one-part cobalt), is not readily available, yet these are expected to have lower carbon foot- prints. Nonetheless, the figure pinpoints the general battery emissions ‘hot spots’ that should be taken into account when legislating future EU battery regulation. To reduce carbon and environmental footprint of battery production, the EU sus- tainable performance requirements should incentivize, support, and foster deploy- ing waste heat recovery processes, along with technologies to green the prepara- tion of precursors. Huge improvements can come from better cathode coating techniques that would make the cathode powder mixing and coating processes more efficient. The design of the future EU regu- lations should also seek to incentivize the set-up of vertically-integrated local supply chains in order to drastically reduce trans- port emissions as well as stimulate the future battery production facilities to be located near low-carbon energy sources. It is important to speed up this process so as to lower the overall carbon footprint of batteries. This much-needed accelera- tion can gain momentum via a compre- hensive regulatory strategy. Mandatory requirements on all battery manufactur- ers whose products are found on the EU market are necessary to measure and report each battery’s carbon and energy footprint. Next, once accurate data have been col- lected and data verification process estab- lished, a mandatory CO2 threshold should
  • 2. 34 | Baltic Transport Journal | 1/2020 Fig. 1. Key chemistry phases in Nickel-Manganese-Cobalt 111 (NMC) battery manufacturing Source for figs. 1-2: T&E’s GREEN POWERHOUSE. T&E blueprint for battery regulation in Europe (2019) Chemical reaction Drying Burning in furnace Coating & drying electrodes Cell manufacturing & ageing Assembly (incl. electronic controls) Assembly Li hydroxide or Li carbonate Sodium hydroixide Ni, Co, Mn sulfate Precursor (=NMC hydroxide) Cathode active material (NMC) Electrode Battery cell Battery module Battery pack BMS Anode active material (graphite) be considered in order to ensure that all future batteries follow manufacturing best practise. Finally, EU research & innovation funding should focus on improving bat- tery manufacturing processes, e.g., better coating techniques, industrial waste heat recovery processes, and environmentally- friendly and efficient recycling. It is as equally important to ensure a sustainable battery design strategy. For instance, the use of hazardous materials in manufacturing should be phased-out and tightly controlled to spur innovation into better methods, materials, and toxic-free battery value chains. Batteries should also be durable and have a long lifecycle, where the design of battery cells and packs incorpo- rates circularity from the outset to facilitate disassembly, repair, and recycling. Ultimately, innovative technologies should be incorporated into battery man- agement systems to provide standardised access to key battery parameters and usage data. A ‘battery passport’ would enable innovative and smart services by providing comprehensive and extensive information on the product. Both static (i.a. battery pro- duction date & location, carbon footprint) and dynamic data (remaining capacity & fade and voltage drop, charging history, etc.) could be used to make the most of bat- teries, especially if we consider their mul- tifunctionality, when, e.g., EVs could serve as energy storage points for the power grid. The circular battery When battery performance is no longer good enough for a car or a truck (less range, worse acceleration, etc.), it should be reused in less demanding applications like in fork- lifts or as a stationary energy storage/buffer in high power charging stations (to reduce peaks). Such second-life batteries will pro- vide extra storage flexibility on the grid, allowing for higher penetration of renewa- bles across Europe. It is therefore important to incentivize longer lifetime and remove any barriers for reuse applications. The ultimate goal is, however, to fully recover all the valuable materials (lithium, nickel, cobalt) found in batteries at the end of their lives. While few people today question the benefits of recycling, as it helps to secure critical materials in Europe, currently the market for LIB recycling is in China where EU batteries are usually sent. An important finding from one of the studies conducted by Element Energy indicates that Europe has inadequate recycling capacity, estimated todayat33kt/year,deemedinsufficientshould currently in use EVs reach the end of their lifecycles in 2030 onwards. Similarly, there is almost no commercial-scale LIB recycling in Europe as things stand today, the majority of “recycling” companies providing low-value collection or shredding only. Europe should perceive battery recycling as an asset, not a burden, and an opportunity to create local industries and jobs. SUSTAINABILITY Photo: Volvo
  • 3. 1/2020 | Baltic Transport Journal | 35 Batteries made responsibly The growing battery demand for mobile and grid applications has put into spot- light the key metals used in lithium-ion technology, namely cobalt, lithium, and nickel. The attention has especially turned to the implications of the EV boom has had on cobalt, particularly the working conditions in the mines of the Democratic Republic of Congo (DRC), where around two-thirds of the global cobalt production are situated at present. The transition to a zero-emission economy in Europe should not come at the expense of others. On the contrary, if done responsibly, increased demand for minerals mined in countries such as the DRC could help support much- needed development. Nonetheless, this necessitates socially- and environmen- tally-responsible ways of sourcing mate- rials. It is important to acknowledge that mining challenges in places like the DRC are much deeper and older, which makes them no better than widely criti- cised practises in oil and gas industries. Instead of bashing electric cars, the European community should use their increasing market share as a leverage to put pressure on downstream companies to clean up their supply chains as well as on governments, to put solid governance structures in place to solve problems in both large-scale and artisanal mining in a comprehensive and pan-industry manner. Various certification schemes have sought to improve sourcing of materials (copper, tin, gold, and cobalt), e.g., the vol- untary OECD Due Diligence Guidance for responsible supply chains, supported by the Responsible Business Conduct guide- lines, acknowledged by many as the best practice example in the field. T&E’s com- parative analysis of the six largest global supply chain certification schemes appli- cable to the industrial cobalt production in the DRC shows that while most schemes are comprehensive in their design and sus- tainability criteria, they nonetheless lack rigorous and independent enforcement. Crucially, traceability on where cobalt is extracted and access to transparent infor- mation on mining conditions remain most schemes’ Achilles heel. The focus, therefore, should be on better enforcing of what is already in place. Fortunately, the previous OECD guidelines on responsible supply chains have already been integrated into national or supra- national legislation on conflict minerals (tin, tantalum, tungsten, gold), such as the US Dodd-Frank Act or the EU Conflicts Minerals Regulation – but do not currently apply to cobalt, nickel, or lithium. A single, reliable, and enforceable mechanism on which to base supply chain due diligence, and the choice of suppliers across all the materials, will also benefit the EU battery industry, which often gets lost in the myriad vol- untary schemes applicable to individual metals. Companies should not be pull- ing out of, e.g., the DRC completely or blankly refusing to buy from small-scale miners; instead, downstream companies should work with and require their sup- pliers to improve mining conditions and refining practices. In other words, the EU trade and development policy should help European companies source materials sus- tainably via smart investment to improve safety, health, and working conditions in developing economies. ‘round the corner Batteries – whether in vehicles or, at the end of their life, as second life storage appli- cations – offer a readily-available distributed energy resource and can store electricity cheaply, facilitating far greater integration of renewables into Europe’s energy market. The EU has the chance to ensure responsi- ble corporate behaviour across the supply chain by making green objectives manda- tory instead of voluntary. The e-mobility revolution is just ‘round the corner, and Europe is rightly prioritis- ing battery value chain development in its industrial strategy.  ‚ Fig. 2. Energy used in MJ per kWh of Nickel-Manganese-Cobalt 111 (NMC) battery cell (excl. casting) 0 225 450 675 900 Precursor and Li2CO3 Cathode production Anode + anode production Separator Electrolyte Binder Current controls Cell production 181 228 99 835 87 216 SUSTAINABILITY Photo: Tesla