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連續一級反應(Consecutive First-Order Reactions)
C
k
B
k
A  21
][
][
1 Ak
dt
Ad

][][
][
21 BkAk
dt
Bd

][
][
2 Bk
dt
Cd

假設 0t , 0][][ AA  , 0][ B , and 0][ C
 )exp(][][ 10 tkAA 
而 ][)exp(][
][
2101 BktkAk
dt
Bd

 )exp(][][
][
1012 tkAkBk
dt
Bd

dttkAktk
tk
B
t
)exp(][)(exp(
)exp(
1
][ 10
0
12
2
 
)]exp()[exp(
][
21
12
01
tktk
kk
Ak



))]exp(1())]exp(1([
][
][][][][
2112
12
0
0
tkktkk
kk
A
BAAC




Please plot two figures for [A], [B], and [C] as a function of time for the cases of
(b) .s1k,s10.0k 1
2
1
1

 (Let 0][][ AA  =1.0)

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Chem ex2 1082

  • 1. 連續一級反應(Consecutive First-Order Reactions) C k B k A  21 ][ ][ 1 Ak dt Ad  ][][ ][ 21 BkAk dt Bd  ][ ][ 2 Bk dt Cd  假設 0t , 0][][ AA  , 0][ B , and 0][ C  )exp(][][ 10 tkAA  而 ][)exp(][ ][ 2101 BktkAk dt Bd   )exp(][][ ][ 1012 tkAkBk dt Bd  dttkAktk tk B t )exp(][)(exp( )exp( 1 ][ 10 0 12 2   )]exp()[exp( ][ 21 12 01 tktk kk Ak    ))]exp(1())]exp(1([ ][ ][][][][ 2112 12 0 0 tkktkk kk A BAAC     Please plot two figures for [A], [B], and [C] as a function of time for the cases of (b) .s1k,s10.0k 1 2 1 1   (Let 0][][ AA  =1.0)