Chapter 10 photochemistry

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An approach for designing organic synthesis which involves breaking down of target molecule into available starting material by imaginary breaking of bonds (disconnection) and/or by functional group interconversion is known as disconnection approach or retrosynthesis or synthesis backward. The C-X disconnection approach is mainly applicable to a carbon chain attached to any of the heteroatoms like O, N, or S. Here, a bond joins the heteroatom (X) to the rest of the molecule like a C-O, C-N, or C-S group. This point is good point to initiate a disconnection. This is called a ‘One-group’ C-X disconnection as one would need to identify only one functional group like ester, ether, amide etc. to make the disconnection. How to choose a disconnection? These are the few general strategy which are important points introduced which apply to the whole of synthetic design rather than one particular area. The main choice is between the various disconnection, even such a simple disconnection as the following alcohol can be disconnected. We want to get back to simple starting materials and we shall do if we disconnect the bond which are: Towards the middle of the molecule thereby breaking into two reasonably equal halves rather than chopping off one or two carbon atoms from the end and, At a branch as this is more likely to give straight chain fragments and these are more likely to be available. Disconnections very often take place immediately adjacent to, or very close to functional groups in the target molecule. This is pretty much inevitable, given that functionality almost invariably arises from the forward reaction. A simple example is the weedkiller propanil used on rice fields. Amide disconnection gives amine obviously made from o-dichlorobenzene by nitration and reduction. All positions around the ring in o-dichlorobenzene are about the same electronically but steric hindrance will lead to dichloronitrobenzene being the major product This compound was needed for some research into the mechanisms of rearrangements. We can disconnect on either side of the ether oxygen atom, but (b) is much better because (a) does not correspond to a reliable reaction: it might be hard to control selective alkylation of the primary hydroxyl group in the presence of the secondary one. The disconnections we have made so far have all been of C–O, C–N, or C–S bonds, but, of course, the most important reactions in organic synthesis are those that form C–C bonds. We can analyze C–C disconnections in much the same way as we’ve analyzed C–X disconnections. The Zeneca drug propranolol is a beta-blocker that reduces blood pressure and is one of the top drugs worldwide. It has two 1,2-relationships in its structure but it is best to disconnect the more reactive amine group first. Arildone is a drug that prevents polio and herpes simplex viruses from ‘unwrapping’ their DNA, and renders them harmless.

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www.seribangash.com The Mariana Trench is one of the most remarkable geological features on Earth. Here are some details about it: Location: The Mariana Trench is located in the western Pacific Ocean, east of the Mariana Islands. It stretches for about 2,550 kilometers (1,580 miles) and is known as the deepest part of the world's oceans. Depth: The trench reaches incredible depths, with its deepest point known as the Challenger Deep, which plunges down to approximately 10,984 meters (36,037 feet) below sea level. To put this into perspective, if Mount Everest, the tallest mountain on Earth, were placed at the bottom of the Challenger Deep, its peak would still be over 2 kilometers (1.25 miles) underwater. Formation: The Mariana Trench was formed by the subduction of the Pacific Plate beneath the Mariana Plate. This process creates a deep trench as the heavier Pacific Plate is forced beneath the lighter Mariana Plate. Geological Features: The trench is characterized by steep, V-shaped valleys, and its walls are composed of highly compressed sedimentary rock. At the bottom of the trench, there are also large amounts of marine sediment. Pressure: The pressure at the bottom of the Mariana Trench is immense, reaching over 1,000 times the pressure at the surface. This extreme pressure creates a challenging environment for exploration and makes it difficult for organisms to survive. Exploration: Despite its extreme conditions, the Mariana Trench has been the subject of numerous scientific expeditions and explorations. One of the most famous explorations was the dive to the Challenger Deep by Swiss scientist Jacques Piccard and U.S. Navy Lieutenant Don Walsh in 1960. More recently, in 2012, filmmaker James Cameron made a solo dive to the bottom of the Challenger Deep in the Deepsea Challenger submersible. Biological Discoveries: Despite the harsh conditions, the Mariana Trench is home to a surprising variety of life forms, including unique species of deep-sea fish, crustaceans, and microbial life. Some organisms have adapted to survive in the extreme pressure and darkness of the trench. Environmental Importance: Studying the Mariana Trench provides valuable insights into the geology, biology, and oceanography of the deep sea. It also helps scientists better understand the processes that shape the Earth's crust and the distribution of life in the oceans. Conservation: Due to its remote location and extreme depths, the Mariana Trench has remained relatively untouched by human activity. However, there is growing concern about the potential impacts of deep-sea mining and pollution on this fragile ecosystem, highlighting the need for conservation efforts to protect this unique environment. https://seribangash.com/barber-shop-business-complete-guide-for-beginners/ https://seribangash.com/legend-virat-kohli-in-cricket-history/

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