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1º - INTERNATIONAL MEETING ON IRONMAKING



      HIGH PRODUCTIVITY AND COKE RATE REDUCTION
             AT SIDERAR BLAST FURNACE #2(1)

                                                                    Oscar Lingiardi(2)
                                                                      Oscar Burrai(2)
                                                                  Claudio Partemio(2)
                                                            Fernando Giandoménico(2)
                                                                  Pedro Etchevarne(3)
                                                             Juan Manuel Gonzalez(3)



Siderar is the largest steel company in Argentina and is located in San Nicolás, in the
Province of Buenos Aires. It is a fully integrated producer of hot and cold rolled strip
and products of higher value added such as coated products: galvanized, electro-
galvanized, pre-painted, formed sheets for road construction and tinplate. Presently,
Siderar operates a blast furnace to meet the hot metal needs.
Increasing productivity was a goal of Siderar BF2 ,and was achieved by increasing
blast enrichment as the level of natural gas injection was increased.

The combined injection of natural gas and oxygen was performed from the very
beginning of #2 blast furnace start up(1 ) , also following these targets:

1. Increased production, meeting the BOF process requirements.

2. Balanced coke plant production, thus preventing coke import.




KEY WORDS : blast furnace, productivity, coke rate.


(1)   Paper to be presented in the 1st International Meeting on Ironmaking,
      September 24th to 26th, 2001 – Belo Horizonte / MB – Brasil.
(2)   SIDERAR SAIC - Planta Gral. Savio – Blast Furnace 2 - CC 801 - (2900) San
      Nicolás - Fax (54) 3461- 438267
(3)   Instituto Argentino de Siderurgia (IAS) - Carlos M. Della Paolera 226 -
      C1001ADB Buenos Aires - Fax (54) 11 - 4311 4016




                                          355
1º - INTERNATIONAL MEETING ON IRONMAKING




                       Blast Furnace # 2 Technical Description.

The main characteristics of blast furnace # 2 are shown in Table I.


                        Table I – Main Characteristics of BF #2

                           Start Up Date          September 1995
                       Hearth Diameter (m/ft)        10.4 / 34
                       Inner Volume (m3/cuft)      2421 / 85510
                          Working Volume           2134 / 75373
                              (m3/cuft)
                         Number of Tuyeres               27
                              Taphole             2 (west – south)
                             Hot Stoves           3 (Mc Kee HW)
                        Charging Equipment              Skip
                              Injection             Natural Gas
                          Cooling System               Plates
                           Tuyeres Type             2 – chamber
                          Slag Treatment           INBA System
                           Gas Cleaning           Bischoff System


Basic considerations about productivity.

In a blast furnace, productivity can be expressed as the relation between the
generated reducing gases flow rate and the gas consumption per produced hot metal
ton.

Productivity ~ gas flow rate / specific gas volume

Thus, in order to increase productivity it is necessary to raise the gas flow rate or
reduce the specific gas volume.

Gas flow rate: it is the quantity of gases which go through a packed bed, represented
by Ergun's Equation :

∆P / H ~ K * V 2 * ρ

where :

∆P / H : pressure drop
K : burden permeability index
V : shaft gas velocity
ρ : gas density




                                           356
1º - INTERNATIONAL MEETING ON IRONMAKING



Burden permeability is a physical properties function of the raw materials such as
particle mean size, porosity, shape factor, and fines generation during degradation at
the temperatures reached in the blast furnace stack as well.

Gas density is associated with the bosh generated gases composition according to
the type of substitute fuel injected at the tuyeres level. The resulting gas density is
inversely proportional to their H2 content(2).

Specific gas volume : the injection of O2 to the air blast (oxygen blast enrichment)
reduces the specific gas flow causing a reduction of the top temperature and an
increase of the adiabatic flame temperature ( RAFT ) in the tuyeres.
These effects are compensated by the injection of substitute fuels. Therefore, the
combined injection of oxygen and fuel at tuyeres level is a valid alternative to
increase productivity and reduce the coke rate at the same time.

Taking into account the factors which maximize a blast furnace's productivity, the
following items were addressed:

•   Burden quality
•   Burden distribution
•   Combined Injection of Natural Gas and Oxygen


Burden.

The composition of the burden used at Siderar BF2 since the beginning of its current
campaign is shown in Figure 1.


                             BF #2 - Burden Composition
                        %sinter          %pellet             %lump ore
           100

            80

            60
       %
            40

            20

             0
                 1995        1996     1997         1998     1999     2000



                              Figure 1 Burden composition

Sinter: The percentage in the blast furnace burden is limited to 30 – 40 %,
depending on the productive level of the blast furnace. This value represents the
maximum production capacity of the sinter plant.




                                          357
1º - INTERNATIONAL MEETING ON IRONMAKING



The fines generated during its handling and transportation are eliminated by means
of screens installed at the blast furnace and the fines generated inside the blast
furnace by degradation during low temperature reduction are controlled through the
RDI (degradation reduction index) test.

As regards its chemical composition, the percentage of MgO is controlled, fixing it on
the basis of MgO requirements in blast furnace slag and the basicity index, a
parameter linked to sinter production.

Sinter quality requirements related to its physical resistance and degradation inside
the blast furnace are shown in Table II.


                                Table II : Sinter Quality

                          CaO/SiO2                          2.10 ± 0.07
                          MgO (%)                           1.80 ± 0.20
                          SiO2 (%)                          5.75 ± 0.30
                           FeO (%)                            < 8.00
                            P (%)                             < 0.050
                        Na2O+K2O (%)                          < 0.090
                           ZnO (%)                            < 0.015

                       Shatter Index (%)                      > 85.0
                           RDI (%)                            < 20.0


Lump Ore: Lump ore maximization in the blast furnace burden has been a
permanent goal for Siderar due to the strong economic impact it represents vis-a-vis
the utilization of imported pellet (3). Its use in BF2 has increased progressively since
the beginning of the campaign (20 %) reaching a participation of 40 % during the
year 2000. It is worth mentioning now, and as explained later, that its high
participation in the burden did not represent any obstacle to reaching productivity
levels of 2.8 t / d m 3 W.V ( 2.5 t / d m3 I.V ).
Lump quality requirements are shown in Table III .

                             Table III : Lump Ore Quality

                                 Parameter             Value
                                  % > 1 ½”              <5
                                  %<¼”                  <5
                                  RDI (%)              < 20
                                Decrepitation
                               (% < 6.35 mm)           <4
                                   IT (%)              > 85
                                   IA (%)              < 10
                               Reducibility (%)        > 50




                                           358
1º - INTERNATIONAL MEETING ON IRONMAKING



Pellet: Burden participation of this raw material imported from Brazil has been
decreasing as the burden percentage of lump ore increased.
The physical quality requirements of pellet are shown in Table IV.

                                      Table IV : Pellet Quality
                                       Parameter           Value
                                       % < 5 mm              <5
                                      % > 18 mm              <5
                                         IT (%)             > 93
                                         IA (%)             < 6.5
                                        RDI (%)             < 10

Pellet, as lump ore, is screened before entering the BF.

Metallurgical Coke.

Coke plays a fundamental role in the blast furnace process.
Cold and hot properties( see Table V ) should be controlled in order to improve the
gases distribution in the stack, and percolation of liquids in the hearth (dead man
permeability )as well. In Figure 2 we can see the evolution of Siderar's coke mesh
size since the beginning of the campaign, in which the metallurgic coke size was
gradually increased with the intention of improving permeability in the center of the
furnace, increasing small coke generation at the same time. The latter is a necessary
resource to meet the fuel requirements in the wall at high fuel injection rates.

                               Table V : Metallurgical Coke Quality

                                       Parameter           Value
                                        Stability          > 60
                                       Hardness            > 66
                                       % > 75 mm          14 max
                                     Ash content (%)          <8
                                        CSR (%)               > 68



                                 Blast Furnace #2 - Coke Mesh Size
                       50

                       40

                       30
                  mm




                       20

                       10

                        0
                              1995     1996   1997     1998    1999   2000


                                     Figure 2 : Coke Mesh Size




                                                359
1º - INTERNATIONAL MEETING ON IRONMAKING



Burden Distribution : the burden distribution control philosophy implemented in
Siderar BF2 in order to meet the high productivity requirements is based on the
following :
• Ensuring a stable burden descent. The current practice consists in spiralling coke
    and ore, ensuring a central column with a limited area which contains 100 % of
    the coke.
• Adjusting the gases flow in the wall to avoid high heat load without generating
    inactive zones. The goal is to work with 35 % of the coke in the wall.
• To achieve a good solid-gas contact to guarantee an efficiency which minimizes
    fuel consumption.
In Figure 3 we can see the efficiency profile of CO ( etaCO ) characteristic of a high
productivity run at Siderar BF2 .

                                                          BF #2 - Eta CO

                                   Point 1-Center                Point 2                          Point 3
                                   Point 4                       Point 5                          Point 6 -Wall
        60

        50
    %
        40

        30

        20
             06     08                  10          12      14         16       18       20       22       00
                                                            Time (hr)



                                                Figure 3 : Eta CO Radial Profile

Combined Injection of Natural Gas and Oxygen : the combined injection of natural
gas and oxygen has been widely used by Siderar (4) and other integrated plants ( 5) to
increase productivity, reducing coke rate at the same time. The evolution of
productivity versus oxygen enrichment is presented in Figure 4.
                                                Productivity (*) vs. O2 Enrichment
                                     2.80
                                     2.70
                                     2.60
                    (THM/d/m3WV)




                                     2.50
                                     2.40
                                     2.30
                                                                            y = 0.096x + 1.9395
                                     2.20                                       R2 = 0.8447
                                     2.10
                                     2.00
                                            2       4 3     5         6                       7        8
                                                   O2 Enrichment. (%)
              (*) Corret to 1150 °C, 25 g/Nm3 and no scrap



                                   Figure 4 : Productivity vs Oxygen Enrichment




                                                                 360
1º - INTERNATIONAL MEETING ON IRONMAKING



Blast oxygen enrichment raises the adiabatic flame temperature (RAFT), while
natural gas moderates it, because it requires energy for its cracking.
In Figure 5 we can see the evolution of RAFT versus natural gas injection rate. It is
worth mentioning that BF2 operated in a stable way at temperatures lower than 2000
°C.

The primary reason for this operational condition is explained by the presence of high
concentrations of hydrogen in the bosh gases (Figure 6), which affect the thermal
and chemical balance of the blast furnace.

                                                RAFT vs. Gas Rate
                       2200

                       2150

                       2100
               °C
                       2050

                       2000

                       1950
                                40Figure50
                                         5     : RAFT vs Natural Gas Rate
                                                    60     70      80       90   100
                                                     Gas Rate (Kg/tHM)


                                     Figure 5 : Flame temperature (RAFT).

                                           Top and Bosh Hydrogen.

                           20


                           16
                    % H2




                           12


                            8


                            4
                                40        50       60         70     80     90   100
                                                    Gas Rate (kg/THM)
                    Top H2              Bosh H2


                                 Figure 6 : Bosh H2 vs Natural Gas Rate

The high hydrogen concentrations enable the minimization of the solution loss
reaction as indicated in Figure 7.




                                                        361
1º - INTERNATIONAL MEETING ON IRONMAKING




                                                          Reduction of FeO vs. Gas rate
                                25

                                20




              FeO (kgmol/tHM)
                                 Figure 7 : Reduction of FeO vs Natural Gas Rate
                                15


                                10

                                 5

                                 0
                                       40                 50              60              70      80          90   100

                                Ind.Red.                       Dir.Red.                   Gas Rate (kg/tHM)


                                                         Figure 7 : Solution loss reaction.


Replacement Rate.

The replacement ratio for a supplemental fuel is defined as the kilograms of coke that
are displaced as a result of the injection of a kilogram of fuel. Higher replacement
ratios are achieved with natural gas than with other supplemental fuels because its
higher hydrogen content increases the amount of indirect reduction that takes place
and so decreases the extent of the highly endothermic solution loss reaction.

The achieved replacement of coke by natural gas in BF2 was of 1.2 kg coke / kg
natural gas as shown in Figure 8. The obtained replacement enabled a reduction in
the import of coke during the highest productivity periods.


                                                          Corrected Coke Rate vs. Gas rate
                                               500



                                               450
                                 CR (kg/tHM)




                                               400             y = -1.1683x + 482.31
                                                                      2
                                                                  R       = 0.9819

                                               350
                                                     0            20                 40          60           80   100

                                                                            Gas Rate (kg/tHM)


                                                           Figure 8 : Replacement Rate




                                                                                362
1º - INTERNATIONAL MEETING ON IRONMAKING



Hot metal quality.

The high natural gas injection rates achieved in BF2 had a noticeable impact on the
content and standard deviation of silicon in the hot metal as shown in Figures 9 and
10.

                                           Hot metal Si vs. Gas Rate
                     0.70

                     0.60

                     0.50
           % Si




                     0.40

                     0.30

                     0.20

                     0.10

                             40        50         60         70     80    90   100

                                                       Gas Rate


                                    Figure 9 : % Si vs Natural Gas Rate



                                             STD Silicon vs. Gas Rate
                     0.12




                     0.08
           STD (%)




                     0.04




                     0.00
                            40        50         60        70       80    90   100
                                                Gas Rate (kg/tHM)


                                  Figure 10 : STD Si vs Natural Gas Rate

At high productivities and natural gas injection rates, the ore-coke relation increases
and consequently the cohesive area is moved downwards, generating a lower
volume for the transfer of silicon to the hot metal.
The low standard deviation of silicon is related to the high hydrogen concentrations in
the bosh gases, which improve the burden descent.




                                                       363
1º - INTERNATIONAL MEETING ON IRONMAKING




Results.

Productivity increase and coke rate reduction have been Siderar BF2's permanent
challenges since the beginning of its campaign (Figures 11 and 12).
During the year 2000, the maximum annual average productivity of 2.81 t/d.m3WV (
2.46 t/d.m3 IV ) was achieved. Likewise, natural gas injection enabled the balance of
the coke oven production resulting in a consumption of 375 kg coke/t HM .


                                   BF #2 Productivity - THM/d.m3wv
                3.00

                2.75
                                                                                         2.80
                2.50
                                                               2.65       2.55
                                                  2.53
                2.25
                                     2.39
                2.00
                       1.98
                1.75

                1.50
                       1995          1996         1997         1998       1999           2000


                               Figure 11 : Blast Furnace Productivity.

                                                         Fuel Rate
                                      Coke Rate                       Natural Gas Rate
                550

                500    66

                450                  58
                                                  69
       Kg/tHM




                                                               85          78            79
                400

                350    467           419          399           376        380           375

                300

                250
                       1995          1996         1997         1998        1999          2000


                                          Figure 12 : Fuel Rate.


In Table VI representative operation periods are shown where higher than previously
presented annual average performances were achieved.
These values represent Blast Furnace #2 current objectives for the next years of the
campaign.




                                                   364
1º - INTERNATIONAL MEETING ON IRONMAKING




                  Table VI : High Performance Periods of Siderar BF 2


         Period                    Productivity               Coke Rate
                                  THM/d.m3WV                   kg/THM
     March 2000                       3.04                       360
    November 2000                     2.94                       363


Conclusion.

During the present campaign of the Blast Furnace #2 our objectives were to
maximize as much as possible the charge of lump ore in the burden and the use of
natural gas while not reducing the Blast Furnace productivity, nor increasing the Fuel
Rate, and maintaining a stable pig iron quality to meet the Steel Shop requirements.


References.

1. F. Giandomenico, O. Lingiardi, J.M. González, M. Geerdes, “Start-up and
   optimization of Siderar No. 2 blast furnace”, AISE 1996 Annual Convention,
   Chicago, USA, September 1996, pp 81-99.
2. Joseph Poveromo, “Operational consideration for high level blast furnace fuel
   injection”, Ironmaking Conference Proceedings, Pittsburgh, PA, U.S.A. March
   1996, pp 79-92.
3. O Burrai, F Giandoménico, O. Lingiardi, C Partemio, P Etchevarne, J M Gonzalez
   . Extensive Use Of Lump Ore At Siderar’s Blast Furnace #2. Ironmaking
   Conference Proceedings, Toronto, Canada, March 1998, pp 1663-1669.
4. O. Lingiardi, O Burrai, C.Gomez Fuentealba , P Etchevarne, J M
   Gonzalez.Natural Gas Injection at Siderar #2 Blast Furnace. 58 Ironmaking
   Conference Proceedings, Chicago, USA, March 1999, pp 135-142
5. “The impact of high rates of fuel injection on coke reduction and productivity
   improvement in blast furnace”, White paper Industrial Products Division, (G.R.I.
   96/0226), July 1996.




                                         365

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Blast furnance

  • 1. 1º - INTERNATIONAL MEETING ON IRONMAKING HIGH PRODUCTIVITY AND COKE RATE REDUCTION AT SIDERAR BLAST FURNACE #2(1) Oscar Lingiardi(2) Oscar Burrai(2) Claudio Partemio(2) Fernando Giandoménico(2) Pedro Etchevarne(3) Juan Manuel Gonzalez(3) Siderar is the largest steel company in Argentina and is located in San Nicolás, in the Province of Buenos Aires. It is a fully integrated producer of hot and cold rolled strip and products of higher value added such as coated products: galvanized, electro- galvanized, pre-painted, formed sheets for road construction and tinplate. Presently, Siderar operates a blast furnace to meet the hot metal needs. Increasing productivity was a goal of Siderar BF2 ,and was achieved by increasing blast enrichment as the level of natural gas injection was increased. The combined injection of natural gas and oxygen was performed from the very beginning of #2 blast furnace start up(1 ) , also following these targets: 1. Increased production, meeting the BOF process requirements. 2. Balanced coke plant production, thus preventing coke import. KEY WORDS : blast furnace, productivity, coke rate. (1) Paper to be presented in the 1st International Meeting on Ironmaking, September 24th to 26th, 2001 – Belo Horizonte / MB – Brasil. (2) SIDERAR SAIC - Planta Gral. Savio – Blast Furnace 2 - CC 801 - (2900) San Nicolás - Fax (54) 3461- 438267 (3) Instituto Argentino de Siderurgia (IAS) - Carlos M. Della Paolera 226 - C1001ADB Buenos Aires - Fax (54) 11 - 4311 4016 355
  • 2. 1º - INTERNATIONAL MEETING ON IRONMAKING Blast Furnace # 2 Technical Description. The main characteristics of blast furnace # 2 are shown in Table I. Table I – Main Characteristics of BF #2 Start Up Date September 1995 Hearth Diameter (m/ft) 10.4 / 34 Inner Volume (m3/cuft) 2421 / 85510 Working Volume 2134 / 75373 (m3/cuft) Number of Tuyeres 27 Taphole 2 (west – south) Hot Stoves 3 (Mc Kee HW) Charging Equipment Skip Injection Natural Gas Cooling System Plates Tuyeres Type 2 – chamber Slag Treatment INBA System Gas Cleaning Bischoff System Basic considerations about productivity. In a blast furnace, productivity can be expressed as the relation between the generated reducing gases flow rate and the gas consumption per produced hot metal ton. Productivity ~ gas flow rate / specific gas volume Thus, in order to increase productivity it is necessary to raise the gas flow rate or reduce the specific gas volume. Gas flow rate: it is the quantity of gases which go through a packed bed, represented by Ergun's Equation : ∆P / H ~ K * V 2 * ρ where : ∆P / H : pressure drop K : burden permeability index V : shaft gas velocity ρ : gas density 356
  • 3. 1º - INTERNATIONAL MEETING ON IRONMAKING Burden permeability is a physical properties function of the raw materials such as particle mean size, porosity, shape factor, and fines generation during degradation at the temperatures reached in the blast furnace stack as well. Gas density is associated with the bosh generated gases composition according to the type of substitute fuel injected at the tuyeres level. The resulting gas density is inversely proportional to their H2 content(2). Specific gas volume : the injection of O2 to the air blast (oxygen blast enrichment) reduces the specific gas flow causing a reduction of the top temperature and an increase of the adiabatic flame temperature ( RAFT ) in the tuyeres. These effects are compensated by the injection of substitute fuels. Therefore, the combined injection of oxygen and fuel at tuyeres level is a valid alternative to increase productivity and reduce the coke rate at the same time. Taking into account the factors which maximize a blast furnace's productivity, the following items were addressed: • Burden quality • Burden distribution • Combined Injection of Natural Gas and Oxygen Burden. The composition of the burden used at Siderar BF2 since the beginning of its current campaign is shown in Figure 1. BF #2 - Burden Composition %sinter %pellet %lump ore 100 80 60 % 40 20 0 1995 1996 1997 1998 1999 2000 Figure 1 Burden composition Sinter: The percentage in the blast furnace burden is limited to 30 – 40 %, depending on the productive level of the blast furnace. This value represents the maximum production capacity of the sinter plant. 357
  • 4. 1º - INTERNATIONAL MEETING ON IRONMAKING The fines generated during its handling and transportation are eliminated by means of screens installed at the blast furnace and the fines generated inside the blast furnace by degradation during low temperature reduction are controlled through the RDI (degradation reduction index) test. As regards its chemical composition, the percentage of MgO is controlled, fixing it on the basis of MgO requirements in blast furnace slag and the basicity index, a parameter linked to sinter production. Sinter quality requirements related to its physical resistance and degradation inside the blast furnace are shown in Table II. Table II : Sinter Quality CaO/SiO2 2.10 ± 0.07 MgO (%) 1.80 ± 0.20 SiO2 (%) 5.75 ± 0.30 FeO (%) < 8.00 P (%) < 0.050 Na2O+K2O (%) < 0.090 ZnO (%) < 0.015 Shatter Index (%) > 85.0 RDI (%) < 20.0 Lump Ore: Lump ore maximization in the blast furnace burden has been a permanent goal for Siderar due to the strong economic impact it represents vis-a-vis the utilization of imported pellet (3). Its use in BF2 has increased progressively since the beginning of the campaign (20 %) reaching a participation of 40 % during the year 2000. It is worth mentioning now, and as explained later, that its high participation in the burden did not represent any obstacle to reaching productivity levels of 2.8 t / d m 3 W.V ( 2.5 t / d m3 I.V ). Lump quality requirements are shown in Table III . Table III : Lump Ore Quality Parameter Value % > 1 ½” <5 %<¼” <5 RDI (%) < 20 Decrepitation (% < 6.35 mm) <4 IT (%) > 85 IA (%) < 10 Reducibility (%) > 50 358
  • 5. 1º - INTERNATIONAL MEETING ON IRONMAKING Pellet: Burden participation of this raw material imported from Brazil has been decreasing as the burden percentage of lump ore increased. The physical quality requirements of pellet are shown in Table IV. Table IV : Pellet Quality Parameter Value % < 5 mm <5 % > 18 mm <5 IT (%) > 93 IA (%) < 6.5 RDI (%) < 10 Pellet, as lump ore, is screened before entering the BF. Metallurgical Coke. Coke plays a fundamental role in the blast furnace process. Cold and hot properties( see Table V ) should be controlled in order to improve the gases distribution in the stack, and percolation of liquids in the hearth (dead man permeability )as well. In Figure 2 we can see the evolution of Siderar's coke mesh size since the beginning of the campaign, in which the metallurgic coke size was gradually increased with the intention of improving permeability in the center of the furnace, increasing small coke generation at the same time. The latter is a necessary resource to meet the fuel requirements in the wall at high fuel injection rates. Table V : Metallurgical Coke Quality Parameter Value Stability > 60 Hardness > 66 % > 75 mm 14 max Ash content (%) <8 CSR (%) > 68 Blast Furnace #2 - Coke Mesh Size 50 40 30 mm 20 10 0 1995 1996 1997 1998 1999 2000 Figure 2 : Coke Mesh Size 359
  • 6. 1º - INTERNATIONAL MEETING ON IRONMAKING Burden Distribution : the burden distribution control philosophy implemented in Siderar BF2 in order to meet the high productivity requirements is based on the following : • Ensuring a stable burden descent. The current practice consists in spiralling coke and ore, ensuring a central column with a limited area which contains 100 % of the coke. • Adjusting the gases flow in the wall to avoid high heat load without generating inactive zones. The goal is to work with 35 % of the coke in the wall. • To achieve a good solid-gas contact to guarantee an efficiency which minimizes fuel consumption. In Figure 3 we can see the efficiency profile of CO ( etaCO ) characteristic of a high productivity run at Siderar BF2 . BF #2 - Eta CO Point 1-Center Point 2 Point 3 Point 4 Point 5 Point 6 -Wall 60 50 % 40 30 20 06 08 10 12 14 16 18 20 22 00 Time (hr) Figure 3 : Eta CO Radial Profile Combined Injection of Natural Gas and Oxygen : the combined injection of natural gas and oxygen has been widely used by Siderar (4) and other integrated plants ( 5) to increase productivity, reducing coke rate at the same time. The evolution of productivity versus oxygen enrichment is presented in Figure 4. Productivity (*) vs. O2 Enrichment 2.80 2.70 2.60 (THM/d/m3WV) 2.50 2.40 2.30 y = 0.096x + 1.9395 2.20 R2 = 0.8447 2.10 2.00 2 4 3 5 6 7 8 O2 Enrichment. (%) (*) Corret to 1150 °C, 25 g/Nm3 and no scrap Figure 4 : Productivity vs Oxygen Enrichment 360
  • 7. 1º - INTERNATIONAL MEETING ON IRONMAKING Blast oxygen enrichment raises the adiabatic flame temperature (RAFT), while natural gas moderates it, because it requires energy for its cracking. In Figure 5 we can see the evolution of RAFT versus natural gas injection rate. It is worth mentioning that BF2 operated in a stable way at temperatures lower than 2000 °C. The primary reason for this operational condition is explained by the presence of high concentrations of hydrogen in the bosh gases (Figure 6), which affect the thermal and chemical balance of the blast furnace. RAFT vs. Gas Rate 2200 2150 2100 °C 2050 2000 1950 40Figure50 5 : RAFT vs Natural Gas Rate 60 70 80 90 100 Gas Rate (Kg/tHM) Figure 5 : Flame temperature (RAFT). Top and Bosh Hydrogen. 20 16 % H2 12 8 4 40 50 60 70 80 90 100 Gas Rate (kg/THM) Top H2 Bosh H2 Figure 6 : Bosh H2 vs Natural Gas Rate The high hydrogen concentrations enable the minimization of the solution loss reaction as indicated in Figure 7. 361
  • 8. 1º - INTERNATIONAL MEETING ON IRONMAKING Reduction of FeO vs. Gas rate 25 20 FeO (kgmol/tHM) Figure 7 : Reduction of FeO vs Natural Gas Rate 15 10 5 0 40 50 60 70 80 90 100 Ind.Red. Dir.Red. Gas Rate (kg/tHM) Figure 7 : Solution loss reaction. Replacement Rate. The replacement ratio for a supplemental fuel is defined as the kilograms of coke that are displaced as a result of the injection of a kilogram of fuel. Higher replacement ratios are achieved with natural gas than with other supplemental fuels because its higher hydrogen content increases the amount of indirect reduction that takes place and so decreases the extent of the highly endothermic solution loss reaction. The achieved replacement of coke by natural gas in BF2 was of 1.2 kg coke / kg natural gas as shown in Figure 8. The obtained replacement enabled a reduction in the import of coke during the highest productivity periods. Corrected Coke Rate vs. Gas rate 500 450 CR (kg/tHM) 400 y = -1.1683x + 482.31 2 R = 0.9819 350 0 20 40 60 80 100 Gas Rate (kg/tHM) Figure 8 : Replacement Rate 362
  • 9. 1º - INTERNATIONAL MEETING ON IRONMAKING Hot metal quality. The high natural gas injection rates achieved in BF2 had a noticeable impact on the content and standard deviation of silicon in the hot metal as shown in Figures 9 and 10. Hot metal Si vs. Gas Rate 0.70 0.60 0.50 % Si 0.40 0.30 0.20 0.10 40 50 60 70 80 90 100 Gas Rate Figure 9 : % Si vs Natural Gas Rate STD Silicon vs. Gas Rate 0.12 0.08 STD (%) 0.04 0.00 40 50 60 70 80 90 100 Gas Rate (kg/tHM) Figure 10 : STD Si vs Natural Gas Rate At high productivities and natural gas injection rates, the ore-coke relation increases and consequently the cohesive area is moved downwards, generating a lower volume for the transfer of silicon to the hot metal. The low standard deviation of silicon is related to the high hydrogen concentrations in the bosh gases, which improve the burden descent. 363
  • 10. 1º - INTERNATIONAL MEETING ON IRONMAKING Results. Productivity increase and coke rate reduction have been Siderar BF2's permanent challenges since the beginning of its campaign (Figures 11 and 12). During the year 2000, the maximum annual average productivity of 2.81 t/d.m3WV ( 2.46 t/d.m3 IV ) was achieved. Likewise, natural gas injection enabled the balance of the coke oven production resulting in a consumption of 375 kg coke/t HM . BF #2 Productivity - THM/d.m3wv 3.00 2.75 2.80 2.50 2.65 2.55 2.53 2.25 2.39 2.00 1.98 1.75 1.50 1995 1996 1997 1998 1999 2000 Figure 11 : Blast Furnace Productivity. Fuel Rate Coke Rate Natural Gas Rate 550 500 66 450 58 69 Kg/tHM 85 78 79 400 350 467 419 399 376 380 375 300 250 1995 1996 1997 1998 1999 2000 Figure 12 : Fuel Rate. In Table VI representative operation periods are shown where higher than previously presented annual average performances were achieved. These values represent Blast Furnace #2 current objectives for the next years of the campaign. 364
  • 11. 1º - INTERNATIONAL MEETING ON IRONMAKING Table VI : High Performance Periods of Siderar BF 2 Period Productivity Coke Rate THM/d.m3WV kg/THM March 2000 3.04 360 November 2000 2.94 363 Conclusion. During the present campaign of the Blast Furnace #2 our objectives were to maximize as much as possible the charge of lump ore in the burden and the use of natural gas while not reducing the Blast Furnace productivity, nor increasing the Fuel Rate, and maintaining a stable pig iron quality to meet the Steel Shop requirements. References. 1. F. Giandomenico, O. Lingiardi, J.M. González, M. Geerdes, “Start-up and optimization of Siderar No. 2 blast furnace”, AISE 1996 Annual Convention, Chicago, USA, September 1996, pp 81-99. 2. Joseph Poveromo, “Operational consideration for high level blast furnace fuel injection”, Ironmaking Conference Proceedings, Pittsburgh, PA, U.S.A. March 1996, pp 79-92. 3. O Burrai, F Giandoménico, O. Lingiardi, C Partemio, P Etchevarne, J M Gonzalez . Extensive Use Of Lump Ore At Siderar’s Blast Furnace #2. Ironmaking Conference Proceedings, Toronto, Canada, March 1998, pp 1663-1669. 4. O. Lingiardi, O Burrai, C.Gomez Fuentealba , P Etchevarne, J M Gonzalez.Natural Gas Injection at Siderar #2 Blast Furnace. 58 Ironmaking Conference Proceedings, Chicago, USA, March 1999, pp 135-142 5. “The impact of high rates of fuel injection on coke reduction and productivity improvement in blast furnace”, White paper Industrial Products Division, (G.R.I. 96/0226), July 1996. 365