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CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
CONTRACT RESEARCH & TECHNOLOGY COMMERICALIZATION
AMERICAN MANGANESE
CATHODE RECYCLING TECHNOLOGY
CONTRACT REEARCH & TESTING COMPANY
The Cobalt Conference 2017
Cobalt Development Institute
Marrakech, Morocco
May 17/18, 2017
New Technologies That May Change the Economics of Recycling Lithium-Ion Batteries
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
JUST THE BEGINNING OF A NEW ERA
2
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
RAPIDLY GROWING MARKET
3
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
INEVITABLE FUTURE
4
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
LITHIUM ION BATTERY RECYCLING IS IN IT’S INFANCY
5
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
CURRENT OPTIONS
6
www.tesla.com/blog/mythbusters-part-3-recycling-our-non-toxic-battery-packs
SMELTER
SHRED AND COLLECT
METAL SLUDGE
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
APPLYING MINING TECHNOLOGY FOR RECYCLING LITHIUM ION BATTERIES
7
AMERICAN MANGANESE
CATHODE RECYCLING TECHNOLOGY DEVELOPMENT
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Mining Technology Developed for
Recovery of Mn from Low Grade Ores
8
BACKGROUND
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
From Mine to Product
9
Electrolytic Processing for EMD
Chemical Oxidation for CMD
MnCO3
MnO2
Button Cell
Batteries
Mn Mine
Low Grade Ore
LiB Cathode
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
THE OPPORTUNITY – LITHIUM ION BATTERY RECYCLING
Cost Breakdown of Lithium Ion Battery Pack
10
Cathode
25%
Battery Pack
Management System
16%
Pack Thermal System
8%
Anode
Materials
8%
Depreciation of
Equipment
8%
Cell Labor
8%
Land Cost for Cell
Manufacturing
6%
Cell Fixed Cost
6%
Pack Labor
5%
Current Collectors
3%
Separators
3%
Electrolyte
1% Other
3%
http://articles.sae.org/14195/
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
TOTAL VEHICLE LI-ION BATTERY WORLD MARKET
11
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
THE PROBLEM BECOMES THE OPPORTUNITY
12
$-
$1.0
$2.0
$3.0
$4.0
$5.0
$6.0
$7.0
$8.0
2015 2016 2017 2018 2019 2020 2021 2022 2023 2024
$USDBillion
Year
World Vehicle Li-ion Battery Cathode Market
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
EXPANDING MARKET FOR PERSONAL ELECTRONICS
13
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
COMPANIES AT THE FOREFRONT - INVESTING IN ELECTRONICS RECYCLING
14
Reference: www.apple.com
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
ESTIMATED VALUE OF CATHODE RAW MATERIALS FOR APPLE
15
Reference: Estimates based on calculations by Kemetco Research Inc.
iPhone 7 iPhone 7 Plus iPad Macbook References
Estimated Number of Units per Year 84753600 127130400 45590000 20000000Estimated from Annual Reports
Capacity (mAh) 1810 2900 10000 10000
LCO Capacity (mAh/g) 198 198 198 198
Weight of LCO per phone (g) 9.1 14.6 50.5 50.5
Weight of LCO (tonnes) 775 1862 2303 1010
Total Tonnes LiCoO2 775 1862 2303 1010
Weight of Co (Tonnes) 467 1121 1386 608
Weight of Li2CO3 (Tonnes) 292 703 869 381
Cost of Co ($US/tonne) $55,250 $55,250 $55,250 $55,250www.infomine.com
Li2CO3 ($US/tonnes) $14,500 $14,500 $14,500 $14,500www.energyresourcesdigest.com
Value in Co $25,775,923 $61,947,659 $76,603,230 $33,605,277
Value of Li2CO3 $4,240,836 $10,192,065 $12,603,303 $5,528,977
Total Cathode Raw Materials Value $30,016,759 $72,139,724 $89,206,533 $39,134,254
Estimated Total Cathode Raw Materials $230,497,270
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
SOCIAL ASPECT OF COBALT MINING
16
Reference: https://www.washingtonpost.com/graphics/business/batteries/congo-cobalt-mining-for-lithium-ion-battery/
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
CATHODE RECYCLING – ECONOMIC AND SOCIALLY RESPONSIBLE MINING
17
AMERICAN MANGANESE
CATHODE RECYCLING TECHNOLOGY
New Technologies That May Change the Economics of Recycling Lithium-Ion Batteries
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
HYDROMETALLURGICAL PROCESSING
USING SPENT CATHODE AS A RESOURCE
18
100% Extraction of Li and Co from LiCoO2
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Co Recovery
19
Selective Precipitation of Co(OH)2
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Li Recovery
20
Precipitation of Li2CO3
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Collected Products
21
Co(OH)2 & Li2CO3
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
XRD of Commercial Grade vs Regenerated LiCoO2
22
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Manufacture of Test Battery from Recycled Cathode
23
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Proof of Concept Achieved
24
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Simplified American Manganese Flowsheet
25
Provisional Patent Application Filed. More Intellectual Property in the Works
Proprietary Operations Not Shown
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Rough Estimates of Cathode Recycling Opportunity – for Electric Vehicles
 2024 - $7.6 USD Billion per Year Cathode Materials for Vehicles
 Cathode Value $21.07 USD per Kg (based on rough estimate of raw materials Nov
2017)
 360,700,000 kg of Cathode Materials per Year
 988 Metric Tonnes per Day Cathode Materials
 Note: Cathode Value $38.66 USD per Kg (as of May 2017 due to increase in Co
Price)
 UPDATED 2024 - $13.9 USD Billion per Year Cathode Materials for Vehicles
 Consumer Electronics is Potentially a Larger Market
26
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Rough Estimates of Reagent Cost
 Treating 1 Metric Tonne of LiCoO2 (Cathode)
 Input Reagents:
 0.33 Tonnes SO2 value at $196 USD
 1.00 Tonnes H2SO4 value at $200 USD
 1.62 Tonnes Na2CO3 value at $487 USD
 TOTAL REAGENT COST = $883 USD
 Output Values:
 0.38 Tonnes Li2CO3 value at $5,510 USD
 0.60 Tonnes Co (as metal) value at $33,150 USD
 TOTAL OUTPUT VALUE = $38,660 USD
 Note: Does not include utilities, amortized capital or labor
27
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Mining and Processing
28
LITHIUM
Mining: South America
Processing: South America
ALUMINUM
Mining: Australia
Refining: Middle East, Canada
NICKEL & COBALT
Mining: DRC, Canada
Smelting: China, Canada, Europe
Refining: China, Canada, Europe
MANGANESE
Mining: Africa
Refining: USA/China/Europe
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Potential Future Packaged Processing Plants
29
Similar Chemistry to Cyanide Destruction Plant Delivered to Gold Mine in 2015
Packed Plant Fabrication and Shipping Reagent Metering System
Reactor Reagent Storage
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
VALUE PROPOSITION FOR RECYCLING
30
CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION
LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY
Contacts
31
Larry Reaugh, President and CEO
Tel: (778) 574-4444
E-mail: lreaugh@amymn.com
Website: www.americanmanganeseinc.com
Norman Chow, President
Tel: (604) 273-3600
E-mail: nchow@kemetco.com
Website: www.kemetco.com

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AMERICAN MANGANESE CATHODE RECYCLING TECHNOLOGY

  • 1. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION CONTRACT RESEARCH & TECHNOLOGY COMMERICALIZATION AMERICAN MANGANESE CATHODE RECYCLING TECHNOLOGY CONTRACT REEARCH & TESTING COMPANY The Cobalt Conference 2017 Cobalt Development Institute Marrakech, Morocco May 17/18, 2017 New Technologies That May Change the Economics of Recycling Lithium-Ion Batteries
  • 2. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY JUST THE BEGINNING OF A NEW ERA 2
  • 3. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY RAPIDLY GROWING MARKET 3
  • 4. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY INEVITABLE FUTURE 4
  • 5. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY LITHIUM ION BATTERY RECYCLING IS IN IT’S INFANCY 5
  • 6. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY CURRENT OPTIONS 6 www.tesla.com/blog/mythbusters-part-3-recycling-our-non-toxic-battery-packs SMELTER SHRED AND COLLECT METAL SLUDGE
  • 7. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY APPLYING MINING TECHNOLOGY FOR RECYCLING LITHIUM ION BATTERIES 7 AMERICAN MANGANESE CATHODE RECYCLING TECHNOLOGY DEVELOPMENT
  • 8. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Mining Technology Developed for Recovery of Mn from Low Grade Ores 8 BACKGROUND
  • 9. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY From Mine to Product 9 Electrolytic Processing for EMD Chemical Oxidation for CMD MnCO3 MnO2 Button Cell Batteries Mn Mine Low Grade Ore LiB Cathode
  • 10. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY THE OPPORTUNITY – LITHIUM ION BATTERY RECYCLING Cost Breakdown of Lithium Ion Battery Pack 10 Cathode 25% Battery Pack Management System 16% Pack Thermal System 8% Anode Materials 8% Depreciation of Equipment 8% Cell Labor 8% Land Cost for Cell Manufacturing 6% Cell Fixed Cost 6% Pack Labor 5% Current Collectors 3% Separators 3% Electrolyte 1% Other 3% http://articles.sae.org/14195/
  • 11. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY TOTAL VEHICLE LI-ION BATTERY WORLD MARKET 11
  • 12. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY THE PROBLEM BECOMES THE OPPORTUNITY 12 $- $1.0 $2.0 $3.0 $4.0 $5.0 $6.0 $7.0 $8.0 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 $USDBillion Year World Vehicle Li-ion Battery Cathode Market
  • 13. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY EXPANDING MARKET FOR PERSONAL ELECTRONICS 13
  • 14. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY COMPANIES AT THE FOREFRONT - INVESTING IN ELECTRONICS RECYCLING 14 Reference: www.apple.com
  • 15. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY ESTIMATED VALUE OF CATHODE RAW MATERIALS FOR APPLE 15 Reference: Estimates based on calculations by Kemetco Research Inc. iPhone 7 iPhone 7 Plus iPad Macbook References Estimated Number of Units per Year 84753600 127130400 45590000 20000000Estimated from Annual Reports Capacity (mAh) 1810 2900 10000 10000 LCO Capacity (mAh/g) 198 198 198 198 Weight of LCO per phone (g) 9.1 14.6 50.5 50.5 Weight of LCO (tonnes) 775 1862 2303 1010 Total Tonnes LiCoO2 775 1862 2303 1010 Weight of Co (Tonnes) 467 1121 1386 608 Weight of Li2CO3 (Tonnes) 292 703 869 381 Cost of Co ($US/tonne) $55,250 $55,250 $55,250 $55,250www.infomine.com Li2CO3 ($US/tonnes) $14,500 $14,500 $14,500 $14,500www.energyresourcesdigest.com Value in Co $25,775,923 $61,947,659 $76,603,230 $33,605,277 Value of Li2CO3 $4,240,836 $10,192,065 $12,603,303 $5,528,977 Total Cathode Raw Materials Value $30,016,759 $72,139,724 $89,206,533 $39,134,254 Estimated Total Cathode Raw Materials $230,497,270
  • 16. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY SOCIAL ASPECT OF COBALT MINING 16 Reference: https://www.washingtonpost.com/graphics/business/batteries/congo-cobalt-mining-for-lithium-ion-battery/
  • 17. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY CATHODE RECYCLING – ECONOMIC AND SOCIALLY RESPONSIBLE MINING 17 AMERICAN MANGANESE CATHODE RECYCLING TECHNOLOGY New Technologies That May Change the Economics of Recycling Lithium-Ion Batteries
  • 18. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY HYDROMETALLURGICAL PROCESSING USING SPENT CATHODE AS A RESOURCE 18 100% Extraction of Li and Co from LiCoO2
  • 19. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Co Recovery 19 Selective Precipitation of Co(OH)2
  • 20. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Li Recovery 20 Precipitation of Li2CO3
  • 21. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Collected Products 21 Co(OH)2 & Li2CO3
  • 22. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY XRD of Commercial Grade vs Regenerated LiCoO2 22
  • 23. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Manufacture of Test Battery from Recycled Cathode 23
  • 24. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Proof of Concept Achieved 24
  • 25. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Simplified American Manganese Flowsheet 25 Provisional Patent Application Filed. More Intellectual Property in the Works Proprietary Operations Not Shown
  • 26. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Rough Estimates of Cathode Recycling Opportunity – for Electric Vehicles  2024 - $7.6 USD Billion per Year Cathode Materials for Vehicles  Cathode Value $21.07 USD per Kg (based on rough estimate of raw materials Nov 2017)  360,700,000 kg of Cathode Materials per Year  988 Metric Tonnes per Day Cathode Materials  Note: Cathode Value $38.66 USD per Kg (as of May 2017 due to increase in Co Price)  UPDATED 2024 - $13.9 USD Billion per Year Cathode Materials for Vehicles  Consumer Electronics is Potentially a Larger Market 26
  • 27. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Rough Estimates of Reagent Cost  Treating 1 Metric Tonne of LiCoO2 (Cathode)  Input Reagents:  0.33 Tonnes SO2 value at $196 USD  1.00 Tonnes H2SO4 value at $200 USD  1.62 Tonnes Na2CO3 value at $487 USD  TOTAL REAGENT COST = $883 USD  Output Values:  0.38 Tonnes Li2CO3 value at $5,510 USD  0.60 Tonnes Co (as metal) value at $33,150 USD  TOTAL OUTPUT VALUE = $38,660 USD  Note: Does not include utilities, amortized capital or labor 27
  • 28. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Mining and Processing 28 LITHIUM Mining: South America Processing: South America ALUMINUM Mining: Australia Refining: Middle East, Canada NICKEL & COBALT Mining: DRC, Canada Smelting: China, Canada, Europe Refining: China, Canada, Europe MANGANESE Mining: Africa Refining: USA/China/Europe
  • 29. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Potential Future Packaged Processing Plants 29 Similar Chemistry to Cyanide Destruction Plant Delivered to Gold Mine in 2015 Packed Plant Fabrication and Shipping Reagent Metering System Reactor Reagent Storage
  • 30. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY VALUE PROPOSITION FOR RECYCLING 30
  • 31. CONTRACT RESEARCH & TECHNOLOGY COMMERCIALIZATION LITHIUM ION BATTERY – CATHODE RECYCLING TECHNOLOGY Contacts 31 Larry Reaugh, President and CEO Tel: (778) 574-4444 E-mail: lreaugh@amymn.com Website: www.americanmanganeseinc.com Norman Chow, President Tel: (604) 273-3600 E-mail: nchow@kemetco.com Website: www.kemetco.com