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ADVANCES IN GHEE
PROCESSING
By
Gayathri Devi M K,
M.Tech Dairy Technology,
CFDT, TANUVAS, Chennai-52.
gdkrishnan97@gmail.com
GHEE
DEFINITION:
According to FSSR-2011, ghee means the pure heat
clarified fat derived solely from milk or curd or from desi
(cooking) butter or from cream to which no colouring matter
or preservative has been added.
PRINCIPLE:
 Concentration
 Heat clarification
 Removal of residue
METHODS
Desi method
DC CB
ADVANCES IN INDUSTRIAL METHOD OF
GHEE MAKING
PROCESS AT PANCHMAHAL DAIRY
Under Total Quality Management
Focus on reducing fat and SNF losses. Inclusion
of serum separator (SS) with butter melting vat
and Spiro heaters.
PROCESS:
Raw chilled milk
(5˚C)
Filtration &warming to
55-60˚C
Cream separation
Pasteurization at 90-92˚C for16
sec
Spiro heater tank
50-60˚C
Serum separator
Molten butter tank
60ºC
Cools to 10-12˚C
CBMM
Primary settling tank
Ghee kettle at
113˚C
Clarification at
95˚C
Cool to 45˚C
Packaging & storage
Ghee process
PARAMETERS
Moisture 0.18%
FFA 0.16% oleic acid
Reichert Meissl Value 32
Polenske value 1.6
Butyrometer reading at 40ºC 41-42
Baudouin’s test Negative
Innovated Method:
ADVANTAGES
Steam :
Hot water in spiral heater
Fat % in melted butter increased to as high
as 95%
Serum:
0.8% fat, 8% SNF.
Serum residue in the effluent also decreased.
Savings Innovated
method
Traditional
method
Steam 70Kg 250Kg
SNF Recovery 1500Kg 135Kg
Fat loss 2% 3%
• As per this method annual saving
amounting to Rs.190 lakhs could be obtained
by considering 12000 kg of ghee made in all
365 days.
• Since, last five years Panchmahal dairy is
making Ghee using this method.
Continuous ghee making based on
Flash evaporation
It was conceived by Abichandani et.al (1978).
It consists of,
• Receiving-cum heating vat
• Gravity separator
• Scraped surface heat exchanger
• Vapor separator
• Positive displacement pump
PROCESS:
1) Butter is heated to 70-75˚C- Steam pressure
1kg/cm2.
2)Steam is admitted into the jacket of thin film
SSHE.
3) Centrifugal action of the rotor causes the
product to spread uniformly on heating
surface.
4)Product is recirculated for 20-30 minutes.
5)When desired temperature is attained valve
v5 is closed , outlet valve v6 is opened.
SSHE
• The rate of water evaporation-75-80kg/hm2.
• Rotor revolved at a speed of 2.45m/s.
• Saving of 0.17 kg steam / kg ghee is achieved.
• Evaluation:
Moisture- 0.21%
FFA- 0.29%
FLAVOUR
Free Fatty Acids:
6.12mg/g of ghee.
C4-C10(VFA) formed during storage.
Methyl ketones:
Butter- 5 to 10 ppm(Ghee 87% higher than butter)
Lactones:
Cream ghee-43ppm
Butter ghee-33 ppm
Desi ghee-29 ppm
FREE FATTY ACIDS
• FFA are undesirable in milk fat because short
chain homologues are responsible for rancid
flavour and also to catalyze the fat oxidation.
• C6-C10 FFA account for only about 5-10% of
the total FFA in ghee(flavour).
• The absence of short chain FFA C2-C4 in ghee
is due to volatilization during heat clarification
of butter.
CARBONYL:
• Glyoxal and methyl glyoxal react with amino
acids to produce carbonylic compounds.
• From lipid oxidation, ketoglycerides and
carbonylic compounds are formed.
• Desi ghee made from buffalo milk contains
higher conc. of carbonyl.
LACTONE:
• Coconut like aroma
• Delta lactones and gamma lactones were high in
cow milk ghee.
• The level of lactones increases with increase in
temperature.
• 5-10% of gamma lactone.
• Delta lactone to gamma lactone ratio is 6:1 to
20:1
Flavour
compounds
Ghee residue Ghee
FFA (µm/g) 627.5 53.6
Carbonyl (µm/g) 43.4 4.3
Lactones (µm/g) 3992.9 30.3
Miscellaneous substances
• Decomposition products include acrolein,
dimethyl sulphide, alcohols, diols and
denatured protein compounds
• Indole and skatole (3-methylindole) which
contribute to the desirable flavour of butter
could also pass over into ghee.
CONJUGATED LINOLEIC ACID
• The cis-9, trans -11 octadecadienoic acid
• Cis-9, trans-11-octadecadienoic acid was
found to account for about 90% of total CLA
in various dairy products.
• CLA was reported to be a more effective
antioxidant than alpha-tocopherol and almost
as effective as butylated hydroxytoluene.
Ghee Residue
 Cephalin possesses(phospholipids) antioxidant properties.
 Phopholipids may exhibit antioxidant property by binding
metals and providing a synergism with phenolic
antioxidants.
 Fat insoluble compound had antioxidant property than fat
soluble compound
TEXTURE
Granularity of Ghee:
Due to the typical ratio of high melting
Triglyceride (palmitic & stearic) and low melting
triglyceride. LMTGD provides a liquid phase and
HMTGD gives a solid granular phase.
ANTIOXIDANT
• Soybean and sunflower @ 0.5%- Delay
oxidative rancidity.
• Amla juice @ 1.25%- Retard rancidity
due to high content of ascorbic acid and
Gallates.
• Curry leave @1%- Phenolic compound
(hydroxychavicol), ascorbic acids, amino acids.
INCREASE SHELF LIFE
• Phospholipids content of ghee has been
increased upto 40 mins holding time at 120˚C.
• Phospholipid from ghee residue could be
recovered by heating to 120˚C with equal
quantity of fat.
Ghee with curdy flavour,
 Blending of ghee prepared from sour milk
Incorporation of lassi powder at heating time
Blending of butter with fermented SM/ sour
BM..,in churning, in molten butter, before
clarification.
Clarification with vegetable leaves.
Flavour simulation studies..,
 Abraham and Srinivasan (1980) used a mixed culture
of lactococcus lactis C-10, lactococcus lactis subsp. lactis
biovar.diacetylactis DRC-1.
 Yadav and Srinivasan(1984) the ripening cream with
3% of the DRC-1 culture and incubation at 30˚C/18 hrs
clarification at 115˚C for 5 mins.
 Wadhwa and jain(1991) ghee flavour in butter oil
through skim milk dahi.
 Wadhwa and Bindal(1995) ghee residue for falvour
and keeping quality development in vanaspati, butteroil.
THANK YOU

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Advances in ghee

  • 1. ADVANCES IN GHEE PROCESSING By Gayathri Devi M K, M.Tech Dairy Technology, CFDT, TANUVAS, Chennai-52. gdkrishnan97@gmail.com
  • 2. GHEE DEFINITION: According to FSSR-2011, ghee means the pure heat clarified fat derived solely from milk or curd or from desi (cooking) butter or from cream to which no colouring matter or preservative has been added. PRINCIPLE:  Concentration  Heat clarification  Removal of residue
  • 4. ADVANCES IN INDUSTRIAL METHOD OF GHEE MAKING PROCESS AT PANCHMAHAL DAIRY Under Total Quality Management Focus on reducing fat and SNF losses. Inclusion of serum separator (SS) with butter melting vat and Spiro heaters.
  • 5. PROCESS: Raw chilled milk (5˚C) Filtration &warming to 55-60˚C Cream separation Pasteurization at 90-92˚C for16 sec
  • 6. Spiro heater tank 50-60˚C Serum separator Molten butter tank 60ºC Cools to 10-12˚C CBMM
  • 7. Primary settling tank Ghee kettle at 113˚C Clarification at 95˚C Cool to 45˚C Packaging & storage Ghee process
  • 8.
  • 9. PARAMETERS Moisture 0.18% FFA 0.16% oleic acid Reichert Meissl Value 32 Polenske value 1.6 Butyrometer reading at 40ºC 41-42 Baudouin’s test Negative Innovated Method:
  • 10. ADVANTAGES Steam : Hot water in spiral heater Fat % in melted butter increased to as high as 95% Serum: 0.8% fat, 8% SNF. Serum residue in the effluent also decreased.
  • 11. Savings Innovated method Traditional method Steam 70Kg 250Kg SNF Recovery 1500Kg 135Kg Fat loss 2% 3%
  • 12. • As per this method annual saving amounting to Rs.190 lakhs could be obtained by considering 12000 kg of ghee made in all 365 days. • Since, last five years Panchmahal dairy is making Ghee using this method.
  • 13. Continuous ghee making based on Flash evaporation It was conceived by Abichandani et.al (1978). It consists of, • Receiving-cum heating vat • Gravity separator • Scraped surface heat exchanger • Vapor separator • Positive displacement pump
  • 14. PROCESS: 1) Butter is heated to 70-75˚C- Steam pressure 1kg/cm2. 2)Steam is admitted into the jacket of thin film SSHE. 3) Centrifugal action of the rotor causes the product to spread uniformly on heating surface. 4)Product is recirculated for 20-30 minutes. 5)When desired temperature is attained valve v5 is closed , outlet valve v6 is opened.
  • 15.
  • 16. SSHE
  • 17. • The rate of water evaporation-75-80kg/hm2. • Rotor revolved at a speed of 2.45m/s. • Saving of 0.17 kg steam / kg ghee is achieved. • Evaluation: Moisture- 0.21% FFA- 0.29%
  • 18. FLAVOUR Free Fatty Acids: 6.12mg/g of ghee. C4-C10(VFA) formed during storage. Methyl ketones: Butter- 5 to 10 ppm(Ghee 87% higher than butter) Lactones: Cream ghee-43ppm Butter ghee-33 ppm Desi ghee-29 ppm
  • 19. FREE FATTY ACIDS • FFA are undesirable in milk fat because short chain homologues are responsible for rancid flavour and also to catalyze the fat oxidation. • C6-C10 FFA account for only about 5-10% of the total FFA in ghee(flavour). • The absence of short chain FFA C2-C4 in ghee is due to volatilization during heat clarification of butter.
  • 20. CARBONYL: • Glyoxal and methyl glyoxal react with amino acids to produce carbonylic compounds. • From lipid oxidation, ketoglycerides and carbonylic compounds are formed. • Desi ghee made from buffalo milk contains higher conc. of carbonyl.
  • 21. LACTONE: • Coconut like aroma • Delta lactones and gamma lactones were high in cow milk ghee. • The level of lactones increases with increase in temperature. • 5-10% of gamma lactone. • Delta lactone to gamma lactone ratio is 6:1 to 20:1
  • 22. Flavour compounds Ghee residue Ghee FFA (µm/g) 627.5 53.6 Carbonyl (µm/g) 43.4 4.3 Lactones (µm/g) 3992.9 30.3
  • 23. Miscellaneous substances • Decomposition products include acrolein, dimethyl sulphide, alcohols, diols and denatured protein compounds • Indole and skatole (3-methylindole) which contribute to the desirable flavour of butter could also pass over into ghee.
  • 24. CONJUGATED LINOLEIC ACID • The cis-9, trans -11 octadecadienoic acid • Cis-9, trans-11-octadecadienoic acid was found to account for about 90% of total CLA in various dairy products. • CLA was reported to be a more effective antioxidant than alpha-tocopherol and almost as effective as butylated hydroxytoluene.
  • 25. Ghee Residue  Cephalin possesses(phospholipids) antioxidant properties.  Phopholipids may exhibit antioxidant property by binding metals and providing a synergism with phenolic antioxidants.  Fat insoluble compound had antioxidant property than fat soluble compound
  • 26. TEXTURE Granularity of Ghee: Due to the typical ratio of high melting Triglyceride (palmitic & stearic) and low melting triglyceride. LMTGD provides a liquid phase and HMTGD gives a solid granular phase.
  • 27. ANTIOXIDANT • Soybean and sunflower @ 0.5%- Delay oxidative rancidity. • Amla juice @ 1.25%- Retard rancidity due to high content of ascorbic acid and Gallates. • Curry leave @1%- Phenolic compound (hydroxychavicol), ascorbic acids, amino acids.
  • 28. INCREASE SHELF LIFE • Phospholipids content of ghee has been increased upto 40 mins holding time at 120˚C. • Phospholipid from ghee residue could be recovered by heating to 120˚C with equal quantity of fat.
  • 29. Ghee with curdy flavour,  Blending of ghee prepared from sour milk Incorporation of lassi powder at heating time Blending of butter with fermented SM/ sour BM..,in churning, in molten butter, before clarification. Clarification with vegetable leaves.
  • 30. Flavour simulation studies..,  Abraham and Srinivasan (1980) used a mixed culture of lactococcus lactis C-10, lactococcus lactis subsp. lactis biovar.diacetylactis DRC-1.  Yadav and Srinivasan(1984) the ripening cream with 3% of the DRC-1 culture and incubation at 30˚C/18 hrs clarification at 115˚C for 5 mins.  Wadhwa and jain(1991) ghee flavour in butter oil through skim milk dahi.  Wadhwa and Bindal(1995) ghee residue for falvour and keeping quality development in vanaspati, butteroil.