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1. In several sentences, please discuss:
(a) what TMDLs are and how they are determined.
(b) at least three reasons why ammonia-nitrogen is detrimental to a receiving body of water (e.g.
stream)
and its inhabitants.
(c) why “dead zones” (e.g. in Gulf of Mexico) have little to no dissolved oxygen.
2. BOD determinations:
(a) Two water samples both have a BOD5 of 275.0 mg/L, however their k values are 0.0075 1/d
and 0.095 1/d,
respectively. What is the maximum BOD exerted by both water samples (ultimate BOD)?
(b) Why is this result important (hint: what does it mean if you want to compare a sample of
industrial
wastewater with that of municipal wastewater)?
(c) In several sentences, please discuss what the Streeter-Phelps dissolved oxygen (DO) sag
curve is?
(d) What management strategies can be in water quality management in rivers with respect to the
DO sag
curve?
3. In several sentences, please discuss:
(a) the difference between MCL and MCLG.
(b) what disinfection byproducts are and why we are concerned about them in drinking water
treatment
plants. Please provide some examples of them.
4. Shown below are the results of water quality analyses of Crater Lake at Mount Mazama,
Oregon. If the water
is treated with 40.00 mgl-1 of alum for turbidity coagulation, how much alkalinity will remain?
constituent expressed as mgl-1
total hardness CaCO3 28.0
calcium hardness CaCO3 19.0
magnesium hardness CaCO3 9.0
total iron Fe 0.02
sodium Na 11.0
total alkalinity CaCO3 29.5
chloride Cl 12.0
sulfate SO4 12.0
silica SiO2 18.0
total dissolved solids 83.0
pH 7.2
Solution
what TMDLs are and how they are determined
A TMDL (Total Maximum Daily Load) establishes the maximum amount of an impairing
substance or stressor that a waterbody can assimilate and still meet WQSs and allocates that load
among pollution contributors.
TMDLs are a tool for implementing State water quality standards. They are based on the
relationship between pollution sources and in-stream water quality conditions.
TMDL addresses a single pollutant or stressor for each waterbody.
A TMDL is the sum of the allowed pollutant loads for point sources, non-point sources,
projected growth and a margin of safety.
TMDL = Point Sources + Nonpoint Sources + Projected Growth + Margin of Safety
Load allocations are determined through the review of monitoring data and watershed modeling.
The tools used depends upon the complexity of the problem.
at least three reasons why ammonia-nitrogen is detrimental to a receiving body of water (e.g.
stream)and its inhabitants.
Nitrogen is an essential ingredient in the formation of proteins for cell growth. From complex
organisms like animals to the simple bacteria used to treat wastes in an activated sludge
treatment facility, every living thing needs some form of nitrogen to survive.
But too much nitrogen freely available in the environment can be a bad thing –
1. Excess nitrogen discharged into our waterways can contribute to eutrophication, the gradual
change of water bodies into marshes, meadows, then forests.
2. It can also contribute to massive algae blooms leading to oxygen depletion in water and its
associated problems. Certain forms of nitrogen can cause specific problems too.
3. Ammonia is toxic to fish, and nitrates at high enough dosages in the drinking water cause
methemoglobinemia in infants (Nitrates convert to nitrites in the stomach. These nitrites then
interfere with the oxygen-carrying capacity of the hemoglobin in blood).
why “dead zones” (e.g. in Gulf of Mexico) have little to no dissolved oxygen.
Dead zones are hypoxic (low-oxygen) areas in the world's oceans and large lakes, caused by
"excessive nutrient pollution from human activities coupled with other factors that deplete the
oxygen required to support most marine life in bottom and near-bottom water. (NOAA)."[2] In
the 1970s oceanographers began noting increased instances of dead zones. These occur near
inhabited coastlines, where aquatic life is most concentrated. (The vast middle portions of the
oceans, which naturally have little life, are not considered "dead zones".)
Less oxygen dissolved in the water is often referred to as a “dead zone” because most marine life
either dies, or, if they are mobile such as fish, leave the area. Habitats that would normally be
teeming with life become, essentially, biological deserts.
Hypoxic zones can occur naturally, but scientists are concerned about the areas created or
enhanced by human activity. There are many physical, chemical, and biological factors that
combine to create dead zones, but nutrient pollution is the primary cause of those zones created
by humans. Excess nutrients that run off land or are piped as wastewater into rivers and coasts
can stimulate an overgrowth of algae, which then sinks and decomposes in the water. The
decomposition process consumes oxygen and depletes the supply available to healthy marine
life.
Dead zones occur in many areas of the country, particularly along the East Coast, the Gulf of
Mexico, and the Great Lakes, but there is no part of the country or the world that is immune. The
second largest dead zone in the world is located in the U.S., in the northern Gulf of Mexico.

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1. In several sentences, please discuss(a) what TMDLs are and how.pdf

  • 1. 1. In several sentences, please discuss: (a) what TMDLs are and how they are determined. (b) at least three reasons why ammonia-nitrogen is detrimental to a receiving body of water (e.g. stream) and its inhabitants. (c) why “dead zones” (e.g. in Gulf of Mexico) have little to no dissolved oxygen. 2. BOD determinations: (a) Two water samples both have a BOD5 of 275.0 mg/L, however their k values are 0.0075 1/d and 0.095 1/d, respectively. What is the maximum BOD exerted by both water samples (ultimate BOD)? (b) Why is this result important (hint: what does it mean if you want to compare a sample of industrial wastewater with that of municipal wastewater)? (c) In several sentences, please discuss what the Streeter-Phelps dissolved oxygen (DO) sag curve is? (d) What management strategies can be in water quality management in rivers with respect to the DO sag curve? 3. In several sentences, please discuss: (a) the difference between MCL and MCLG. (b) what disinfection byproducts are and why we are concerned about them in drinking water treatment plants. Please provide some examples of them. 4. Shown below are the results of water quality analyses of Crater Lake at Mount Mazama, Oregon. If the water is treated with 40.00 mgl-1 of alum for turbidity coagulation, how much alkalinity will remain? constituent expressed as mgl-1 total hardness CaCO3 28.0 calcium hardness CaCO3 19.0 magnesium hardness CaCO3 9.0 total iron Fe 0.02 sodium Na 11.0 total alkalinity CaCO3 29.5 chloride Cl 12.0 sulfate SO4 12.0
  • 2. silica SiO2 18.0 total dissolved solids 83.0 pH 7.2 Solution what TMDLs are and how they are determined A TMDL (Total Maximum Daily Load) establishes the maximum amount of an impairing substance or stressor that a waterbody can assimilate and still meet WQSs and allocates that load among pollution contributors. TMDLs are a tool for implementing State water quality standards. They are based on the relationship between pollution sources and in-stream water quality conditions. TMDL addresses a single pollutant or stressor for each waterbody. A TMDL is the sum of the allowed pollutant loads for point sources, non-point sources, projected growth and a margin of safety. TMDL = Point Sources + Nonpoint Sources + Projected Growth + Margin of Safety Load allocations are determined through the review of monitoring data and watershed modeling. The tools used depends upon the complexity of the problem. at least three reasons why ammonia-nitrogen is detrimental to a receiving body of water (e.g. stream)and its inhabitants. Nitrogen is an essential ingredient in the formation of proteins for cell growth. From complex organisms like animals to the simple bacteria used to treat wastes in an activated sludge treatment facility, every living thing needs some form of nitrogen to survive. But too much nitrogen freely available in the environment can be a bad thing – 1. Excess nitrogen discharged into our waterways can contribute to eutrophication, the gradual change of water bodies into marshes, meadows, then forests. 2. It can also contribute to massive algae blooms leading to oxygen depletion in water and its associated problems. Certain forms of nitrogen can cause specific problems too. 3. Ammonia is toxic to fish, and nitrates at high enough dosages in the drinking water cause methemoglobinemia in infants (Nitrates convert to nitrites in the stomach. These nitrites then interfere with the oxygen-carrying capacity of the hemoglobin in blood). why “dead zones” (e.g. in Gulf of Mexico) have little to no dissolved oxygen. Dead zones are hypoxic (low-oxygen) areas in the world's oceans and large lakes, caused by "excessive nutrient pollution from human activities coupled with other factors that deplete the oxygen required to support most marine life in bottom and near-bottom water. (NOAA)."[2] In the 1970s oceanographers began noting increased instances of dead zones. These occur near
  • 3. inhabited coastlines, where aquatic life is most concentrated. (The vast middle portions of the oceans, which naturally have little life, are not considered "dead zones".) Less oxygen dissolved in the water is often referred to as a “dead zone” because most marine life either dies, or, if they are mobile such as fish, leave the area. Habitats that would normally be teeming with life become, essentially, biological deserts. Hypoxic zones can occur naturally, but scientists are concerned about the areas created or enhanced by human activity. There are many physical, chemical, and biological factors that combine to create dead zones, but nutrient pollution is the primary cause of those zones created by humans. Excess nutrients that run off land or are piped as wastewater into rivers and coasts can stimulate an overgrowth of algae, which then sinks and decomposes in the water. The decomposition process consumes oxygen and depletes the supply available to healthy marine life. Dead zones occur in many areas of the country, particularly along the East Coast, the Gulf of Mexico, and the Great Lakes, but there is no part of the country or the world that is immune. The second largest dead zone in the world is located in the U.S., in the northern Gulf of Mexico.