Operators work on operands to produce new expressions. Unary operators take one operand, binary operators take two operands, and ternary operators take three operands. When multiple operators are present in an expression, operator precedence and associativity determine the order of evaluation. Precedence follows algebraic conventions such as multiplication before addition. Associativity determines whether operators are evaluated left-to-right or right-to-left. Parentheses can be used to override precedence.