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04/01/12




EdExcel Additional Science
   Chemical Structures
      W Richards


    The Weald School
Compounds
                                               04/01/12




Compounds are formed
when two or more
elements are
chemically combined.
Some examples:             Methane
                                        Sodium
                                     chloride (salt)




                 Glucose
Some simple compounds…
                                        04/01/12




                                Carbon
Methane, CH4   Water, H2O    dioxide, CO2

                                  Key
                                Hydrogen

                                Oxygen
Ethyne, C2H2
                Sulphuric       Carbon
               acid, H2SO4
                                Sulphur
Bonding Revision
                                                04/01/12




Cl        Hi. My name’s Johnny Chlorine.
             I’m in Group 7, so I have 7
            electrons in my outer shell




                                           Cl
     I’d quite like to have a full outer
     shell. To do this I need to GAIN
      an electron. Who can help me?
Ionic Bonding Revision
                                                              04/01/12



Cl                 Here comes my friend again,
                         Sophie Sodium                          Na


                Hey Johnny. I’m in Group 1 so I have
                one electron in my outer shell. Unlike
                Harry, this electron is far away from
                the nucleus so I’m quite happy to get
     Okay             rid of it. Do you want it?


            -               +
 Cl                  Na


                                Now we’ve both got full outer shells
                                 and we’ve both gained a charge.
                                  We’ve formed an IONIC bond.
Covalent Bonding
                                                             04/01/12



Cl                            Here comes another one of my
                                friends, Harry Hydrogen




               Hey Johnny. I’ve only got one
               electron but it’s really close to              H
              my nucleus so I don’t want to lose
                     it. Fancy sharing?



     Cl   H

                              Now we’re both really stable.
                              We’ve formed a covalent bond.
Covalent bonding
                                                                      04/01/12


Consider an atom of hydrogen:

                Notice that hydrogen has just __ electron in its outer
                shell. A full (inner) shell would have __ electrons, so two
                hydrogen atoms get together and “_____” their electrons:


                       Now they both have a ____ outer shell and are
                       more _____. The formula for this molecule is H2.


When two or more atoms bond by sharing electrons we
call it ____________ BONDING. This type of bonding
normally occurs between _______ atoms. It causes the
atoms in a molecule to be held together very strongly
but there are ____ forces between individual molecules.
This is why covalently-bonded molecules have low melting
and boiling points (i.e. they are usually ____ or ______).

   Words – gas, covalent, non-metal, 1, 2, liquid, share, full, weak, stable
Dot and Cross Diagrams
                         04/01/12




 Water, H2O:



                     H
H              O
Dot and Cross Diagrams
                         04/01/12




Oxygen, O2:




    O         O
Dot and cross diagrams
                                                                 04/01/12


                              Water, H2O:
Step 1: Draw the atoms with        Step 2: Put the atoms together and
their outer shell:                 check they all have a full outer shell:

          H
                    O                         H       O        H
          H

                              Oxygen, O2:



      O             O                             O        O
Dot and cross diagrams
                                               04/01/12



Nitrogen, N2:                Methane CH4:

                                          H

        N       N
                                 H        C   H


                                          H

Ammonia NH3:                Carbon dioxide, CO2:

         H          N   H
                             O        C       O
                    H
04/01/12
 Other ways of drawing covalent bonds
Consider ammonia (NH3):



  H     N     H

        H
                          H   N   H

                              H
                                      H   N      H

                                          H
Group 7 – The halogens
                         04/01/12




                         F

                         Cl

                         Br

                          I

                         At
The Halogens - Chlorine
                                   04/01/12




         Each molecule has a strong force
         holding the atoms together, but
         the forces between molecules are
         very weak so chlorine is a gas at
         room temperature
The Halogens - Bromine
                                   04/01/12




         The forces between molecules are
         slightly stronger so bromine is a
         liquid at room temperature.
The Halogens - Iodine
                                                   04/01/12




Iodine is a solid at room temperature but with gentle
heating it will melt. The atoms will remain in pairs.
Forms of Carbon
                                                       04/01/12



                 1) Diamond – very hard, doesn’t conduct
                 electricity, very high melting point




2) Graphite – soft, does conduct
electricity, very high melting point




                    3) Buckminsterfullerene – 60 carbon
                    atoms arranged in a sphere
Metals
                                                                           04/01/12




                                                                   +       +   +
Metals are defined as elements that readily
lose electrons to form positive ions. There                        +       +   +
are a number of ways of drawing them:
                                                                   +       +   +


         -                               -         +       +           +
     +               +               +
                 -
                 -                                     +       +
             +               +
                         -
                                 -
                                                   +       +           +
 -   +               +               +
                         -
                                                 Delocalised electrons
Nanoscience
                                                      04/01/12



 Nanoscience is a new branch of science that refers to
 structures built from a few hundred atoms and are
 1-100nm big. They show different properties to the same
 materials in bulk. They also have a large surface area to
 volume ratio and their properties could lead to new
 developments in computers, building materials etc.



Task: research nanoscience
and find two current and/or
future applications of this
science.
04/01/12
Different ways of modelling atoms

   H   N    H        H   N   H


       H                 H
Chemical-based Therapy
                                                          04/01/12



Chemical-based therapy is the use of chemicals to alleviate an
illness. Here are two examples:

Chemotherapy – drugs that are used to kill cancer cells

Antibiotics – drugs that are used to kill bacteria that cause
illnesses such as tuberculosis and cholera
Homeopathy
                                                        04/01/12



Homeopathic medicines are drugs that contain compounds
that, if strong enough, would cause an illness. These drugs
induce symptoms so that the body is “kick-started” into
starting the natural healing process.
Homeopathy
                              04/01/12




For                 Against




       Homeopathy

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Ed chemical structures

  • 1. 04/01/12 EdExcel Additional Science Chemical Structures W Richards The Weald School
  • 2. Compounds 04/01/12 Compounds are formed when two or more elements are chemically combined. Some examples: Methane Sodium chloride (salt) Glucose
  • 3. Some simple compounds… 04/01/12 Carbon Methane, CH4 Water, H2O dioxide, CO2 Key Hydrogen Oxygen Ethyne, C2H2 Sulphuric Carbon acid, H2SO4 Sulphur
  • 4. Bonding Revision 04/01/12 Cl Hi. My name’s Johnny Chlorine. I’m in Group 7, so I have 7 electrons in my outer shell Cl I’d quite like to have a full outer shell. To do this I need to GAIN an electron. Who can help me?
  • 5. Ionic Bonding Revision 04/01/12 Cl Here comes my friend again, Sophie Sodium Na Hey Johnny. I’m in Group 1 so I have one electron in my outer shell. Unlike Harry, this electron is far away from the nucleus so I’m quite happy to get Okay rid of it. Do you want it? - + Cl Na Now we’ve both got full outer shells and we’ve both gained a charge. We’ve formed an IONIC bond.
  • 6. Covalent Bonding 04/01/12 Cl Here comes another one of my friends, Harry Hydrogen Hey Johnny. I’ve only got one electron but it’s really close to H my nucleus so I don’t want to lose it. Fancy sharing? Cl H Now we’re both really stable. We’ve formed a covalent bond.
  • 7. Covalent bonding 04/01/12 Consider an atom of hydrogen: Notice that hydrogen has just __ electron in its outer shell. A full (inner) shell would have __ electrons, so two hydrogen atoms get together and “_____” their electrons: Now they both have a ____ outer shell and are more _____. The formula for this molecule is H2. When two or more atoms bond by sharing electrons we call it ____________ BONDING. This type of bonding normally occurs between _______ atoms. It causes the atoms in a molecule to be held together very strongly but there are ____ forces between individual molecules. This is why covalently-bonded molecules have low melting and boiling points (i.e. they are usually ____ or ______). Words – gas, covalent, non-metal, 1, 2, liquid, share, full, weak, stable
  • 8. Dot and Cross Diagrams 04/01/12 Water, H2O: H H O
  • 9. Dot and Cross Diagrams 04/01/12 Oxygen, O2: O O
  • 10. Dot and cross diagrams 04/01/12 Water, H2O: Step 1: Draw the atoms with Step 2: Put the atoms together and their outer shell: check they all have a full outer shell: H O H O H H Oxygen, O2: O O O O
  • 11. Dot and cross diagrams 04/01/12 Nitrogen, N2: Methane CH4: H N N H C H H Ammonia NH3: Carbon dioxide, CO2: H N H O C O H
  • 12. 04/01/12 Other ways of drawing covalent bonds Consider ammonia (NH3): H N H H H N H H H N H H
  • 13. Group 7 – The halogens 04/01/12 F Cl Br I At
  • 14. The Halogens - Chlorine 04/01/12 Each molecule has a strong force holding the atoms together, but the forces between molecules are very weak so chlorine is a gas at room temperature
  • 15. The Halogens - Bromine 04/01/12 The forces between molecules are slightly stronger so bromine is a liquid at room temperature.
  • 16. The Halogens - Iodine 04/01/12 Iodine is a solid at room temperature but with gentle heating it will melt. The atoms will remain in pairs.
  • 17. Forms of Carbon 04/01/12 1) Diamond – very hard, doesn’t conduct electricity, very high melting point 2) Graphite – soft, does conduct electricity, very high melting point 3) Buckminsterfullerene – 60 carbon atoms arranged in a sphere
  • 18. Metals 04/01/12 + + + Metals are defined as elements that readily lose electrons to form positive ions. There + + + are a number of ways of drawing them: + + + - - + + + + + + - - + + + + - - + + + - + + + - Delocalised electrons
  • 19. Nanoscience 04/01/12 Nanoscience is a new branch of science that refers to structures built from a few hundred atoms and are 1-100nm big. They show different properties to the same materials in bulk. They also have a large surface area to volume ratio and their properties could lead to new developments in computers, building materials etc. Task: research nanoscience and find two current and/or future applications of this science.
  • 20. 04/01/12 Different ways of modelling atoms H N H H N H H H
  • 21. Chemical-based Therapy 04/01/12 Chemical-based therapy is the use of chemicals to alleviate an illness. Here are two examples: Chemotherapy – drugs that are used to kill cancer cells Antibiotics – drugs that are used to kill bacteria that cause illnesses such as tuberculosis and cholera
  • 22. Homeopathy 04/01/12 Homeopathic medicines are drugs that contain compounds that, if strong enough, would cause an illness. These drugs induce symptoms so that the body is “kick-started” into starting the natural healing process.
  • 23. Homeopathy 04/01/12 For Against Homeopathy