Similar to Marks, Julie, Barr Engineering, How to Treat Hazardous Waste Without Permit, at 2014 Missouri Hazardous Waste Seminar, November, 4, 2014, Columbia, MO
Similar to Marks, Julie, Barr Engineering, How to Treat Hazardous Waste Without Permit, at 2014 Missouri Hazardous Waste Seminar, November, 4, 2014, Columbia, MO (20)
Marks, Julie, Barr Engineering, How to Treat Hazardous Waste Without Permit, at 2014 Missouri Hazardous Waste Seminar, November, 4, 2014, Columbia, MO
1. How To Treat Hazardous Waste
Without a Permit
(and get away with it)
Julie Marks, P.E.
(573) 638-5015
2. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite
units
3. “Treatment” 40 CFR 260.10
10 CSR 25-3.260 incorporates w/out modification
Treatment means any method, technique, or process,
including neutralization, designed to change the
physical, chemical, or biological character or
composition of any hazardous waste so as to neutralize
such waste, or so as to recover energy or material
resources from the waste, or so as to render such waste
nonhazardous, or less hazardous; safer to transport,
store, or dispose of; or amenable for recovery,
amenable for storage, or reduced in volume.
4. Treatment means any method, technique, or
process, including neutralization, designed to
change the physical, chemical, or biological
character or composition of any hazardous waste
so as to neutralize such waste, or so as to recover
energy or material resources from the waste, or so
as to render such waste nonhazardous, or less
hazardous; safer to transport, store, or dispose of; or
amenable for recovery, amenable for storage, or
reduced in volume
5. Compaction
Shredding
Volatilization
Evaporation
Stabilization
Stripping
Decanting
Washing
Addition of
Water to
Dissolve
Packaging
Use of
Emulsifiers
during Tank
Cleanout to
reduce
flammable
vapor levels
6. Treatment means any method, technique, or
process, including neutralization, designed to
change the physical, chemical, or biological
character or composition of any hazardous waste
so as to neutralize such waste, or so as to recover
energy or material resources from the waste, or so
as to render such waste nonhazardous, or less
hazardous; safer to transport, store, or dispose of; or
amenable for recovery, amenable for storage, or
reduced in volume
7. Compaction
Shredding
Volatilization
Evaporation
Stabilization
Stripping
Decanting
Washing
Addition of
Water to
Dissolve
Packaging
Use of
Emulsifiers
during Tank
Cleanout to
reduce
flammable
vapor levels
8. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
40 CFR 264.1(g)(6), 265.1(c)(10), 270.1(c)(2)(v)
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
9. According to EPA…
Elementary neutralization units are tanks, tank systems,
containers, transport vehicles, or vessels used for neutralizing
wastes that are hazardous only because they exhibit the
corrosivity characteristic or because they are listed solely for
the characteristic of corrosivity (Section 260.10). A tank, tank
system, container, transport vehicle, or vessel that meets the
definition of an elementary neutralization unit is exempt from
permitting requirements under RCRA Subtitle C (Sections
264.1(g)(6), 265.1(c)(10), and 270.1(c)(2)(v)). In addition,
generators managing hazardous waste immediately upon
generation in an on-site elementary neutralization unit are not
required to count those wastes toward their monthly generator
status (Section 261.5(c)(2)).
10. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
40 CFR 264.1(g)(5), 265.1(c)(9), 270.1(c)(2)(iv)
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
11. a facility for the treatment of hazardous waste
which is directly connected to an industrial
production process and which is constructed and
operated in a manner which prevents the release
of any hazardous waste or any constituent thereof
into the environment during treatment. An
example is a pipe in which waste acid is
neutralized
40 CFR 260.10
Totally Enclosed Treatment Facility
12. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
40 CFR 270.1(c)(2)(vii)
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
13. 40 CFR 270.1(c)(2)(vii)
Persons adding absorbent material to
waste in a container (as defined in 40 CFR
260) and persons adding waste to
absorbent material in a container,
providing that these actions occur at the
time waste is first placed in the container;
and 264.17(b), 264.171, and 264.172 of this
chapter are complied with.
14. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
40 CFR 270.1(c)(3), 264.1(g), 265.1(c)(11)
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
15. “Immediate Response” not defined but
applies to the following situations:
• A discharge of hazardous waste
• An imminent and substantial threat of a discharge of
hazardous waste
• A discharge of a material which, when discharged,
becomes a hazardous waste
• An immediate threat to human health, public safety,
property, or the environment from the known or
suspected presence of military munitions, other
explosive material, or an explosive device.
16. Also exempt from substantive management
standards
40 CFR 264.1(g)(8)(i), 265.1(c)(11)
and Transportation Standards
RCRA Online 11363, 11370, 12016, 12758, 13574
but 40 CFR 264 Subpart C – Preparedness and
Prevention
and Subpart D – Contingency Plan and Emergency
Procedures
Still Apply
17. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
40 CFR 264.1(g)(6), 265.1(c)(10), 270.1(c)(2)(v)
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
18. Also exempts from the tank standards of
40 CFR 264/265 Subpart J and the air
emission standards of Subparts AA-CC
and
the generator, accumulation standards
in 40 CFR 262.34 – “Hazardous Waste”
marking or 90-day or 180- day
accumulation start dates.
19. Wastewater treatment unit
means a device which:
(1) Is part of a wastewater treatment facility that is subject to
regulation under either section 402 or 307(b) of the Clean Water
Act; and
(2) Receives and treats or stores an influent wastewater that is a
hazardous waste as defined in §261.3 of this chapter, or that
generates and accumulates a wastewater treatment sludge that is
a hazardous waste as defined in §261.3 of this chapter, or treats or
stores a wastewater treatment sludge which is a hazardous waste as
defined in §261.3 of this Chapter; and
(3) Meets the definition of tank or tank system in 40 CFR 260.10 of this
chapter.
40 CFR 260.10
20. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
Various Federal Registers and RCRA Online docs
• Recycling
• Burning small quantities in onsite units
21. LQGs can treat hazardous waste in Containers, Tanks,
and Containment Bldgs subject to 40 CFR 262.34 for
90/180/270-days or less
SQG can treat in Containment Bldgs too, if they
agree to meet the 40 CFR 262.34(a) provisions,
otherwise, only treat in Containers or Tanks
No drip pads allowed in Mo. – 10 CSR 25-5.262(2)(C)4
22. Exemption does not cover:
Treatment involving elevation of temperature (burning,
detonation, evaporation) subject to 40 CFR 264 Subpart X and 265
Subpart P
Evaporation from the container because it would violate 40 CFR
265.173(a) that requires containers to have lids except when
adding or removing waste
Other Requirements:
Waste must be generated onsite
If treating in multiple vessels, clock does not restart
with each vessel
23. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling and Partial Recycling
40 CFR 261.6c&d
• Burning small quantities in onsite units
24. Although recycling is exempt from permitting…
Hazardous waste shipped to the recycling facility is still
regulated and must be manifested.
Recycling facility MAY or May NOT still need an EPA ID number,
use a manifest and report manifest discrepancies.
Storage of hazardous waste at the recycling facility is a RCRA
permitted activity.
Air emissions MAY or MAY NOT still be regulated in 40 264/265
Subpart AA and BB.
PROBABLY subject to 10 CSR 25-9.010 Resource
Recovery Regs
25. Recycling that is NEVER exempt:
Recycling in land disposal units (surface
impoundments, waste piles etc)
Burning for energy or material recovery
Incineration
26. Hazardous Waste Treatment Exemptions
• Elementary Neutralization Unit
• Totally Enclosed Treatment Facility
• Addition of Absorbent Material
• Immediate Response
• Wastewater Treatment Unit
• Treatment in 90/180/270-day units
• Recycling
• Burning small quantities in onsite units
40 CFR 266.108
27. Conditions must be met:
Waste must be burned onsite
Certain quantity/specification limitation
Must meet all other RCRA standards (such as
storage standards)
One time notification
Record keeping requirements
When planning processes or making modifications, keep these in mind. Use of these allows you to avoid the sometimes lengthy and time consuming process required to obtain a permit and maintain one.
definition of treatment
Discuss 1st half of definition - Activity must change the hazardous waste
Examples of ways to change hazardous waste
Discuss second half of definition – Looks at “intent” – so “treatment” not only changes the haz waste, but must do it for one of the reasons listed above
Compaction to reduce volume is treatment. If happens to compact during shipping, not treatment.
Shredding to reduce volume or make amenable for recovery is treatment
Evaporation to reduce volume is treatment
Volatilization to make material no longer hazardous is treatment
Stabilization of slag prior to disposal is treatment
Stripping VOCs from haz wastewater is treatment
Decanting liquid from a haz waste is treatment
Washing haz waste off spent bags so they can be reused is treatment
Adding water to dissolve plastic bags containing waste cyanide facilitates disposal but does not render it safer to dispose. Not treatment.
Emulsifier was part of the cleanout process to protect workers, intent isn’t to render less haz, so not treatment.
If corrosive and fails TCLP for something, you need a permit prior to treatment
Tank is the expansive def of tanks found in 260 – so flumes, gutters, troughs, and pipes, sumps that pass the “parking lot test” count as tanks
Transport vehicle is a vac truck, tank car, rail car
Vessel is a watercraft such as a ship, barge
Seldom granted
Huh? EPA says:
install a dust treatment system in the ductwork between a cupola furnace and its baghouse
a portable haz waste treatment system provided it is totally enclosed and connected to an industrial production process
Production wastes treated in-pipe
40 CFR 264.314 and 265.314 prevent landfilling bulk and containerized haz waste that contain liquids or free liquid to minimize the leaching of waste and waste constituents in landfills into gw.
However, EPA considers the deliberate mixing of absorbents with haz waste to be treatment.
Why only when waste is first placed in container? Its safer and reopening a container.
17(b) – absorbents and waste must be compatible so that the addition of absorbents do not result in fire, explosion, violent reactions, etc. Container must have solid structural integrity.
171 – containers in good condition
172 – materials containers are made of and the absorbents are compatible.
Must be immediate, activities conducted afterward are subject to RCRA permitting and substantive management standards
EPA says the facility must be subject to CWA, it does not have to have a permit or pretreatment standards for the exemption to apply.
Wastewater is waste that is substantially water with contaminants amounting to a few percent at most.
Sludge is any material that precipitates or otherwise is separated from wastewater during treatment.
Tanks can be air and stream strippers
180/270 depends on your quantity generated, distance to disposal site, compliance with additional requirements
Recycling is treatment, but EPA created the recycling exemption to encourage legitimate recycling.