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BONDING
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TERMINOLOGIES
 ADHESION :
Attraction between unlike molecules
 COHESION :
Attraction between like molecules
 MECHANICAL BONDING :
Strong attachment of 2 substances
accomplished mechanically rather than by
molecular attraction
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 CONTACT ANGLE:
 Angle between the wetting medium and the
tooth surface
 AIR POCKETS:
- Created during the spreading of adhesive
- Cause bond failure
 TENSILE BOND STRENGTH
 SHEAR BOND STRENGTH
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Nature of enamel
 Highly mineralised tissue
 Hardest tissue in human body
 Clinically visible
 No regenerative capacity
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Morphology
 Enamel prisms
 Extend from DEJ to
outer surface at
varying angles
 Prismless enamel
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Longitudinal section under
microscope
 Wider prisms
 Narrower Interprismatic
substance
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Cross section
 Keyhole / fish like pattern
 Head 5 microns
 Head - incisal region
 Tail - cervical region
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 Prisms contain
hydroxyapatite crystals
 Run parallel to long
axis of prism and
become perpendicular
as they approach tail
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Acquired pellicle
 Precipitation of salivary proteins
 Forms almost immediately
 Removed by pumicing
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Factors affecting enamel
solubility
 Pre – eruptive factors
 Post – eruptive factors
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Pre – eruptive factors
 Affect chemical and histological
characteristics of enamel prior to
emergence in oral cavity
1. hypoplasia
2. hypocalcification
3. fluorosis
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Post eruptive factors
 Affect the enamel solubility after eruption
1. topically applied fluorides
2. organic pellicle
3. plaque
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Factors affecting bonding to
ideally etched surface
 Patient operator
saliva
Contact
with lip and
tongue
Oil / water via
spray
Rubbing /
touching etched
surfacewww.indiandentalacademy.com
Properly bonded
bracket
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Over extended bonding medium
onto unetched enamel
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Interfaces
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HISTORY
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BANDING M.E MAGILL - 1871
Negative factors :
 Time and skill
 Impacted teeth
 Decalcification /discoloration
 Gingival irritation
 Unaesthetic
 Placement of separators is painful
 Closure of band spaces
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The goal was to have brackets tubes and
other attachments directly cemented on the
tooth surface to eliminate problems
encountered with metal bands.
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MMA - Ist
material
Methyl Methacrylate
Catalyst - BPO
Difficulty in adhesion
 Polymerization shrinkage
 Pulpal irritation
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Buonocore - 1955
 Etched enamel with 85% phosphoric acid
to increase adhesive strength
 However adhesive strength could not be
maintained because of
1. Occlusal force
2. Wide range of oral thermal change
3. Wet environment
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G.V.Newman - 1965
 Feasibility of using Plastic brackets with
Epoxy resins
 Start of Direct bonding procedure
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In 1969 – I st
commercially available Ortho
adhesive was OIS Adhesive system
In 1970 - Bracket Bond ( GAC )
BPO – Amine catalyst system
Weak Adhesion
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In 1971 Fujio Miura et al
Orthomite ( MMA- TBB resin )
( Tri – N – Butyl Borane )
Resulted in increased adhesive strength
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MMA
 Powder and Liquid
 No filler
 Chemical adhesion with plastic brackets
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MMA adhesive
MERITS
 Plastic brackets
 Good storage stability
 Good penetration into enamel surface
 Less damage during debonding
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MMA adhesive
DEMERITS
 Fluctuating property between powder
liquid depending on operator technique
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Plastic Metal
Plastic- Enamel adhesive bond interface
Metal- Adhesive bracket interface
Metal – Mesh , perforated pad , foil mesh
MMA - BISGMA
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Drawbacks of BISGMA
1. Plastic brackets could not be used .
To overcome this the plastic bracket base
had to be partially dissolved
- PRIMER added
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Drawbacks of BISGMA
 Poor penetration due to increased viscosity
 MMA + BISGMA sealant
 This meant an additional step
DILUTED
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Drawbacks of BISGMA
 Active life was less than powder liquid
system
 Tooth surface damaged during debonding
with BISGMA [ filler - hardness]
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Orthomite
 Adhesive
 Powder [ PMMA]
 Liquid [MMA]
 Catalyst [ TBB]
 Coupling agent [ SILANE]
Added to increase penetration into enamel crevices
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 Orthomite II No silane
 Orthomite superbond 4 META
4 methacryloxy ethyl
trimellitate anhydride
could bond to metal [ NI-Cr] ,[ Co – C r]
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4 META
 Plastic + metal
 PRE PRIMED brackets
 Base was primed with adhesive
 Bracket base covered with PMMA powder
 Base dipped in monomer and pressed onto
etched surface.
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Bonding medium
ideal characteristics
 Non toxicity
 Adequate working and setting times
 Moderate viscosity
 Sufficient tensile and compressive strength
 Ability to wet etched surface
 Resist decomposition in the oral
environment
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Mechanism of polymerization
 Chemically activated - 2 paste system
BPO – tertiary amine
 Light activated - single paste system
consists of photo initiator +amine
Exposure of light of correct wavelength
produces an excited state of photo initiator
which interacts with the amine.
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Self cure Vs light cure
 Self cure
 Polymerization starts immediately
 Cannot manipulate setting time
 Air bubbles during mixing – reduce bond
strength
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Self cure Vs light cure
 Light cure
 Compared to UV ,visible light deeper
curing
 Long working time
 Excess material can be removed before
polymerization
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 Resin 2 types
 Acrylic resin MMA [plastic brackets]
 Diacrylate resins BISGMA[metal ]
 Filled / unfilled
 Quartz ,silica
 Particle size 3-20 microns impart abrasion
resistance
 Particle size-0.2 – 0.3 microns smooth
surface less abrasion resistance
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No mix adhesive
 Sets when one paste under light pressure is
brought together with a primer fluid on the
etched enamel or another paste on the tooth
to be bonded
 One adhesive component applied to
bracket base and other on tooth surface
 As soon as bracket is positioned it is
pressed firmly into place
 Curing occurs – 30-60 secs
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No mix adhesive
 ADVANTAGES
 Procedure simplified
DISADVANTAGES
 Little long term information available
on bond strength of paste – paste
system
 Liquid activators – allergic reactions
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Pre coated brackets
 Plastic / metal / ceramic
 Chemical /light cured
 ADVANTAGES
1. Consistent quality of adhesive
2. Reduced flash
3. reduced waste
4. Adequate bond strength
5. Improved cross infection control
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Evaluation of antimicrobial properties of
orthodontic composite resin combined with
benzalkonium chloride
Othman et al,AJO Sep2002
 The antimicrobial agent benzalkonium
chloride was added to a chemically cured
composite resin and the anti microbial
benefits and bond strength of the modified
composite were evaluated.
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 No significant difference between the
tensile bond strength between modified
composite and the original product
.
 The incorporated BAC added to anti
microbial properties of original composite
without altering it’s mechanical properties
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Advantages of bonding
 Esthetics
 Faster +simpler
 Less patient discomfort
 Arch length not increased
 Less gingival irritation
 Precise placement [aberrant tooth forms
banding is difficult.]
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Advantages of bonding
 Interproximal enamel reduction and
composite build up possible
 Bond artificial tooth surface
 Caries risk eliminated
 No band space closure
 Lingual brackets
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Disadvantages of bonding
 Weaker than bands
 Better access for cleaning does not
guarantee better oral hygiene
 No protection against interproximal caries
 Rebonding > Recementing
Adhesive > Cement
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BONDING PROCEDURE
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Bonding procedure
 Cleaning
 Enamel conditioning
 Sealing
 bonding
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Cleaning
 Remove organic
pellicle
 Pumicing
 Using rubber
cups/polishing brush
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Cleaning
 Pumice prophylaxis does not appear to
affect bond strength
 REISNAR ET AL
Buccal surfaces lightly abraded with TC bur
at slow speed 25000 rpm > Pumicing for
10 sec
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Enamel conditioning
 Acid etching
 Other alternatives to acid etching
1. Crystal growth
2. Sand blasting/air abrasion
3. Laser etching
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ACID ETCHING
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ACID ETCHING
 1955 BUONOCORE - 85%
phosphoric acid
 37% phosphoric acid – 15 to 60 sec
 15 sec – for young permanent teeth
 30 – 60 sec – adult teeth
 Longer periods - less retension due to loss
of enamel structure
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Acid etching
 Etchant should not be rubbed onto
tooth surface
 Rinsed with water spray
 Dried with moisture and oil free
source
White frosty appearance
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Alternative acids for etching
traditionally 30 – 40 %
Phosphoric acid
- 10 % Phosphoric acid
- 10 % Maleic acid
- 2.5 % Nitric acid
Etch enamel as well but have significant
lower bond strength
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Rationale of etching
Gwinnett,Matsui & Buonocore
 Primary mechanism of attachment of resin
Resin tags to etched surface
MICROMECHANICAL BOND
Acid etch removes 10 microns of enamel
Creates porous surface
Increases wettabilitywww.indiandentalacademy.com
Patterns of etching
Gwinnett & Silverstone
Type 1
- Selective removal of enamel prism cores
- Peripheries intact
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Type 2
Reverse process
- Peripheries removed
- Cores intact
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Type 3
- Less distinct
- Combination of 1 & 2
- Unrelated to Prism morphology
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Conc of Etchant
 50 % phophoric acid - 60 sec
Monocalcium Phosphate Monohydrate
 27 % & less
Dicalcium Phosphate Dihydrate
 30-40 % Most retentive surface(Silverstone)
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Etching Time
60 sec 30 – 40 % Phosphoric acid
Shorter etching time Reduced tensile
bond
strength
SEM studies Tensile bond strength,
Microleakage , Surface roughness
15 sec = 60 sec
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 fluorosis - no extra time needed
 Fluoridated Soln/gel = non fluoridated
 Acquired / developmental
demineralization
1. Avoid etching/ keep time minimal
2. apply sealant
3. Direct bonding
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Bond strength with various etching times
WEI NAN WANG ETAL AJO 1991
 Compared the tensile bond strength at
various etching times15,30, 60, 90,120 secs
 37 % phosphoric acid
 TBS was not statistically different for
15,30,60,90
 TBS decreased – 120 secs
 Debonding – fewer enamel fragments with
shorter etching times
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 Compared quality and quantity of enamel etch
produced by 37 % phosphoric acid and 2.5%
nitric acid for 15 , 30 ,& 60 secs
Concluded
 37 % phosphoric acid - better etch for all 3
applications
 15 < 30 & 60
 30 = 60
 Supported use of 37% - 30 secs to get optimum
bond strength
ALASTAIR GARDNER , ROSS HOBSON AJO 2001
Acid etching
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The continuous brush acid technique
BAHARAV ,LANGSAM J PROSTH DENT 1987
 Aim was to determine whether mechanical
agitation of etchant would enhance
decalcification of enamel
 Non carious pre molars
1. Mesial half – 35% P04 acid[30 secs] left
undisturbed
2. Distal half – 35% po4 acid [30 secs]
continuously painted
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The continuous brush acid technique
 Results
 Continuous brushing of etchant - more
efficient dissolution of enamel
 Reduction of size of remaining crystals
 Hence increasing the potential space
between them for retension
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Acid etching
Iatrogenic factors
 Loss of enamel
 Retention of resin tags discoloration
 Leakage at the bracket interface - staining
 Enamel loss – debonding
 Surface roughness – debonding plaque
retention
 Softer enamel – prone decalcification
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Alternatives to acid etching
 CRYSTAL GROWTH
 SAND BLASTING/ AIR ABRASION
 LASER ETCHING
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Crystal growth
SMITH
 Polyacrylic acid – chemical bonding
 Purified polyacrylic acid- slight etching
 Polyacrylic acid + sulfate ion – crystalline
deposit
 CALCIUM SULPHATE DIHYDRATE
 Depends on concentration of sulfate ions
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Crystal growth
MAIJER AND SMITH
 Crystalline interface produced tensile bond
strength equivalent to conventional acid
etched surface
 Debonding fracture at crystal - resin
interface
 Other soln – sulphuric acid anion[more
reliable and uniform growth]
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Crystal growth
 Calcium sulfate crystals must enucleate
from bound calcium
 To achieve this some etching is required
 Enamel solubility ~ crystal enucleation
 Mechanical attachment is created around
the crystalline interface and superficially
etched enamel
MECHANISM OF RETENSION
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Crystal growth
 ARTUN AND BERGLAND
 Sulphuric acid - crystals not as long and
needle like as with polyacrylic acid but
were rounder and flatter
 Hence debonding was easier
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Advantages of crystal growth
 Debonding easier and quicker
 Little damage to enamel
 Minimal effect on outer fluoride containing
enamel
 No resin tags left behind
 Possibility of incorporating fluoride in
crystal interface – anticariogenic action
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Crystal growth - procedure
 One drop of viscous liquid placed on tooth
surface
 Left undisturbed for 30 secs
 Brush / swab should not be agitated as in
etching as it may affect crystal/enamel
interface
 Rinsed for 20 secs
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Crystal growth - procedure
 Forceful water spray to be avoided as it
will break crystals
 Look out for a dull whitish deposit
 Bracket bonded in usual way
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Sand blasting / air abrasion
 Makes use of high speed stream of
aluminium oxide particles [50/90
microns]propelled by air pressure
 Produces rough surface
 Used for cavity preparation
 Preparation of enamel /dentin
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Sand blasting
 Could contribute to better bond strength
with less enamel loss
 Factors affecting bond strength
1. Particle size
2. Air pressure
3. Exposure time
4. Microstructure of enamel surface
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Sand blasting
 Compared bond strength and enamel loss
between sand blasting and conventional
acid etching at varying exposure times and
air pressure
 Bond strength
Sand blasting < acid etching
 Enamel loss
Sand blasting < acid etching
WENDALA VAN WAVERAN ALBERT FEILZER
AJO 2000
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Laser etching
 LASER
 Light amplification by stimulated emission of
radiation
 3 elements
 Lasing medium [ solid/liquid/gas]
 Energy source[xenon flash lamp/electrical
discharge]
 Optical resonator
1. Coherence
2. Collimation
3. Monochromaticity
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Laser etching
 When laser strikes an object it may be
 Reflected
 Transmitted
 Scattered
 Absorbed
 Combination of above
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Laser etching
 In order to have an effect on tissue light
must be absorbed by some elements so that
the energy can be converted into other
forms
 Production of heat undesirable effects
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Classification
 Mode of excitation ( Continuous or
Pulsed)
 Wavelength
1. UV range(Krypton Flouride, Argon
Flouride)
2. Visible Light ( Helium , Neon )
3. Infra Red range ( carbon dioxide, Nd:Yag)
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Laser etching with Nd : Yag
 Studied the surface effects of dentin following
laser etching with Nd:Yag and evaluated the
shear bond strength of composite between treated
and untreated laser etched dentin
 Surface roughness
laser etched > unlased dentin
 Bond strength
Laser treated >unlased dentin
M.A WILSON ET AL
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Laser etching
 Shear bond strength of composite to laser
pre treated dentin increased by 300 %
 localised melting + recrystallization
 Fungiform projections
 The composite adapted to undercuts
&space between the dentin projections
LYDON COOPER ET AL
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Laser etching
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Pulsed krypton fluoride excimer
laser Dr Francis M
 Compared surface morphology, bond
strength,and ARI between acid etching and
3 different energy densities of pulsed
krypton fluoride laser
 440.460,480 MJ/cm2
 Concluded :
 TBS 460.> 480 >A E >440
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 SBS 480 > A E > 460 > 440
 SEM regular etch pattern similar to acid
etch seen with 460 & 480 MJ/cm2
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SEALING
Sealer / Primer / Intermediate resin
 Low viscosity resin which is applied
prior to bonding .
1. Necessary to achieve proper bond strength
2. Improve resistance to microleakage
3. Both reasons
4. Not needed at all
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Chemically cured
Sealant
Light cured
Ceen & Gwinnett
Found
Light cured sealant Chemically cured
 Protect enamel Polymerize poorly
adjacent to bracket Have low resistance
from discoloration to abrasion
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Evaluation of sealant in
orthodontic bonding
Wei Nanwang etal AJO 1991
 Evaluated the Tensile bond strength with and
without use of sealant
 They found no statistically significant
difference in the bond strength of the two
evaluated groups
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However the use of sealant
 May offer extra protection to enamel
during debonding
 As chances of enamel surface detachment
with out use sealant was greater.
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Self Etch Primer
Unique characteristic of some bonding
system is that they combine the
Etchant + Primer into single product
 Saves time
 Cost efficient
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Procedure For Self Etch
 Teeth are pumiced
 Self etch primer gently swirled on to each
enamel surface for 2 to 5 secs
 As pH rises , etchant is converted to primer
 Primer is thinned with burst of air
 No rinsing with water
 Bracket then bonded in usual way.
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Effect of self etch primer on
shear bond strength of
orthodontic brackets
Samir Bishara & Leigh Von Wald
AJO 2001
•Their study concluded that use of self
etch primer resulted in low but clinically
acceptable shear bond strength.
•Comparison of ARI scores – More
residual adhesive remained with self etch
primer.
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Bonding of stainless steel brackets to
enamel with new self etch primer
Ryan Arnold et al sep 2002
 Bond strength of stainless steel brackets
using Transbond self etch primer
Four groups
A- Conventional etchant with separate primer
B- Self etch –15 sec Before
C- Self etch - 2 min bonding
D-Self etch - 10 minwww.indiandentalacademy.com
Conclusion –
 No significant difference in bond strength
between the two groups.
 10 min delay in bonding after application
of self etch primer might not be deleterious
for adhesion
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Hydrophilic Primer ( MIP )
 Bond failure – Moisture contamination
 When etched enamel is wet most porosities
get plugged – Penetration of resin impaired
 Second molars – Access difficult
 Hydrophilic primer (HEMA & Maleic acid)
dissolved in acetone – 3M Unitek
( Transbond MIP )
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Hydrophilic Primer
S.J.Little Wood et al ( BJO 2000 )
In vitro study
 Compared the bond strength of bracket
bonded with hydrophilic primer with
conventional primer
 Concluded that the bond strength obtained
with hydrophilic prime were significantly
lower than conventional primer
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Pre primed brackets
 Stainless steel +plastic
 MERITS
 Simplification of bonding procedure
 Minimal wastage
 Less chance of contamination
 No air pockets
 Accuracy and consistency
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Bonding Procedure
Four steps
1. Transfer
2. Positioning
3. Fitting
4. Removal
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Transfer
 Adhesive put on
bracket base
 Bracket placed on
the tooth closed to
the correct position
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Positioning
 Proper vertical
and horizontal
positioning
( eg Using
placement
scaler with
parallel edges)
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fitting
 Bracket firmly
pushed towards
the tooth
surface with one
point contact
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Removal of excess
 Gingival irritation
 Plaque build up
 Better esthetics
 Prevents staining
and discoloration
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Curing lights
 Tungsten quartz halogen light
 Argon laser
 Xenon plasma arc light
 light emitting diode curing
units[LED]
 Pulsed xenon plasma arc light
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Tungsten quartz halogen curing
light
when electric energy is passed
Halogen bulb
Tungsten filament is heated
HEAT
LIGHT
Selective filters – blue light [ 400-500
microns] www.indiandentalacademy.com
Tungsten quartz halogen curing
light
 40 seconds per bracket
 15 minutes – both arches
Disadvantages
 Curing time consuming
 Light output < 1% of consumed electricity
 Lifetime – 100hrs
 High heat - degrades components of bulb
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Argon laser
 Introduced in the late 80’s &early 90’s
 Promised to reduce the curing time
dramatically
 480 microns wavelength
 Curing time
 3 secs – per bracket
 1 min – both arches
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Argon laser
 KELSEY ,POWELL
To equal bond strength of 40 sec exposure by
conventional curing light argon laser must
cure for 10 seconds
Disadvantages
 Laser unit large
 expensive
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Xenon plasma arch light
 Introduced in the late 1990’s
 Short exposure time at lower cost
 Curing time
3 – 5 secs per bracket
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Comparison of efficiency of xenon
plasma light and conventional curing
light Sheldon Newman et al AJO 2001
 Exposure time
40 secs - conventional curing light
3 , 6 , & 9 secs – xenon plasma light
 Bond strength
xenon light > with longer exposure time
 To equal bond strength of conventional curing
light the exposure time with xenon had to be 6 –9
seconds
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Light emitting diode curing units
Mills –1995
 Instead of hot filament – Halogen bulb.
 LED – junction of doped semi conductors.
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Light emitting diode curing units
Advantages;
 Lifetime 10, 000 hrs
 Requires no filters
 Resist shock and vibration
 Little power to operate
 Newer –GALLIUM NITRIDE ( LED )
400-500microns
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LED
 Optimum curing time ?
 Replace halogen bulbs ?
Mills et al ( BJO 1997 )
 Compared light source containing LED to
Halogen units
 Concluded – LED curing units cured
composites to significantly greater depths
when tested at 40 & 60 sec
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Polymerization of resin cement
with LED curing unit
William Dunn & Louis Taloumis
AJO sep 2002
 Compared the shear bond strength of
orthodontic brackets bonded to teeth with
conventional halogen light and LED curing
units .
 Concluded- LED curing units bonded
brackets to enamel as well as Halogen
based curing lights
www.indiandentalacademy.com
Pulsed Xenon Plasma Arc Light
Polymerization shrinkage
Internal stresses
Fracture of composite at tooth adhesive
interface
Microleakage / Caries
www.indiandentalacademy.com
Non Pulsed Xenon Plasma Arc
Light
Non Pulsed Plasma Arc Light Light
Rapid curing
Polymerization shrinkage
www.indiandentalacademy.com
Polymerization shrinkage – Over come
-Curing composite in layers
-Pulsed curing light
Pulsed curing light- unit light is a series of
pulse to polymerize the adhesive
Pulsed Xenon Plasma Arc Light
www.indiandentalacademy.com
Retrofitting curing light
 Most curing lights designed for restorative
dentistry
 Probes 10-11 mm
 Flooded over larger area
NEW POWER SLOT
 Tapered rectangular tip
 4 x 7 mm
 Closer to enamel – bracket interface
 Shorter curing times
www.indiandentalacademy.com
Bonding to artificial teeth
and restorations
www.indiandentalacademy.com
Bonding to porcelain
 Conventional acid etch ineffective
 WOOD ET AL –[1986] showed
1. Roughening porcelain surface
2. Adding a porcelain primer
3. Using highly filled resin
Increased
bond
strength
www.indiandentalacademy.com
Bonding to porcelain
 WOOD ET AL
 Showed that
 Bond strength to porcelain > or = bonding
to acid etched enamel
of natural teeth
 bond strength was high enough to damage
porcelain surface - debonding
www.indiandentalacademy.com
Bonding to porcelain
 Commonly used etchant – 9.8 % HF
acid gel 2-3 secs
 Microporosites –mechanical retension
 Frosty appearance
www.indiandentalacademy.com
Bonding to porcelain
 Surface preparation for orthodontic
bonding to porcelain
ZACHRISSON et al AJO 1996
HF acid gel = sand blasting + silane
 Some authors feel
Sand blasting + silane - high failure rates
www.indiandentalacademy.com
Bonding to porcelain - procedure
 Isolate
 Deglaze area by sand blasting 50 microns –
3 secs
 Etch 9.6%HF gel - 2 mins
 Rinse
 bond with BISGMA resin
 Use of silane optional
www.indiandentalacademy.com
Bonding to amalgam
 Improved bonding technique
 Modification of metal surface
[sand blasting,diamond bur roughening]
 Use of intermediate resin
 Use adhesive resin that bond chemically
to metal [4 META , 10 MDP BISGMA]
www.indiandentalacademy.com
Bonding to amalgam - procedure
 Sand blast with 50 microns al oxide for 3
secs
 Etch with 37% phosphoric acid 15 – 30
secs
 Apply sealant and bond with adhesive resin
 See that bonded attach is out of occlusion
with antagonist
www.indiandentalacademy.com
summary
 E+nx P+ B
 E +nxPB
Combined the primer and the bonding agent
into one soln
Needed good moisture control for good
results
 EP +B self etch primer
Gentler etching , elimination of water rinsing,
reduction in post operative sensitivity
www.indiandentalacademy.com
summary
 n x EPB Prompt L pop
Etchant primer and adhesive sealed in lollipop
shaped aluminium foil packet
Used for direct application on all composites
 ONE UP BOND
First EPB to contain color change
polymerisation indicators.
when polymerized completely it shifts
from pink to tooth color
www.indiandentalacademy.com
Self Etch Primer
 Prompt L Pop
 Transbond self etch primer
Liquid begins to etch as soon as it is applied
www.indiandentalacademy.com
Etchant Primer
When two hydroxide
ions are converted
hydrogen ions are
realsed
www.indiandentalacademy.com
Crystal growth
JOHN ARTUN , S. BERGLAND AJO 1984
 Soln A – dil sulphuric acid+sodium
sulphate
 Soln B – 10% po4 acid +dil sulphuric acid
 Failure rates recorded – 6 months
 A > B > ACID ETCH
www.indiandentalacademy.com
Indirect bonding
www.indiandentalacademy.com
Indirect bonding
 SILVERMAN AND COHEN – 1972
 MMA and UV light activated unfilled
BISGMA
 MMA was applied to the plastic bracket
base on the patient’s model
 BISGMA –intermediary adhesive between
the patients etched enamel & pre set
adhesive on the bracket base
www.indiandentalacademy.com
Indirect bonding
 Updated technique – 1974 by same authors
 Used perforated metal bracket bases and
only one adhesive- BISGMA[ UV light
activated]
 Increased operator working time as
polymerization did not occur
www.indiandentalacademy.com
INDIRECT BONDING
ADVANTAGES
 Accurate bracket placement
 Decreasing the chair side time
 Avoiding band fitting on the posterior teeth
 Eliminating the need for separators
 Improved ability to bond the posteriors
 Improved patient comfort and hygiene
www.indiandentalacademy.com
INDIRECT BONDING
Disadvantages
 Technique sensitive
 Additional set of impressions need to be
taken
 Posterior attachments more likely to fail if
the patient chews on hard food
www.indiandentalacademy.com
Indirect bonding techniques
 Thomas technique
 Silicon transfer tray
 Double sealant technique
 Moin & Dogon technique
 Indirect method – Anoop Sondhi
 Indirect bonding for light cured composites
www.indiandentalacademy.com
THOMAS TECHNIQUE 1979
 Filled BISGMA resin placed into the
bracket bases
 Attached to the stone model
 Before setting all excess material is
removed from the cast around the brackets
 Transfer tray made of flexible material
 Tray + brackets removed from the cast as
single unit
www.indiandentalacademy.com
THOMAS TECHNIQUE
 Teeth of one arch isolated +etched
 Liquid unfilled resin formed the interface
between etched enamel and filled resin
 Liquid catalyst – tooth
 Base resin – brackets
 Unfilled resin not pre mixed – working
time increased
 tray seated held till polymerization is
complete
www.indiandentalacademy.com
Indirect bonding with silicone
transfer trays
 Pour the impression in stone
 mark the long axis and height on each
tooth
 Apply water soluble adhesive on each
bracket
 Position the bracket over the teeth on the
cast
www.indiandentalacademy.com
 Mix putty material press onto the cemented
brackets
 Tray is formed of sufficient thickness
 Model is immersed in hot water
 Mark the midline
 Patient is prepared for direct application
 Adhesive is placed on the base of brackets
 Tray is seated and held for 3 minutes
 Tray is peeled off excess adhesive on tooth
is removed
www.indiandentalacademy.com
Double sealant technique
 Adhesive paste rather than temporary
adhesives are used to bond the brackets
onto the cast
 Base + catalyst mixed placed on the
bracket bases
 Brackets placed on the tooth
 Tray is then formed placed in water
www.indiandentalacademy.com
 Embedded bracket bases are lightly abraded
with with a mounted stone
 Teeth are etched
 Bracket bases are painted with[ partB]catalyst
resin
 Teeth are painted with universal sealant
[partA]
 Tray is seated held for 3 min
 Adv – clean up simple due to less
flash[unfilled resin only]
www.indiandentalacademy.com
Indirect bonding
Moin & Dogon technique AJO 1977
 Pour impression in
stone
 A drop of sticky wax
is placed on teeth
surfaces of cast
 Brackets are warmed
over flame and set on
the cast
www.indiandentalacademy.com
Indirect bonding - Moin & Dogon technique
 Impression made with
polyether material
 Tray separated from cast
but brackets remain in
situ
 Bracket is removed from
the cast &warmed to
remove residual wax
 They are placed into the
impression
www.indiandentalacademy.com
 Teeth are pumiced,etched & isolated
 Enamel surface is sealed with mixture of
universal & catalyst sealant
 bracket base is covered with the adhesive
 tray is seated
Indirect bonding - Moin & Dogon technique
www.indiandentalacademy.com
Indirect bonding - Moin & Dogon technique
 Use of sticky wax-corrections can easily
&readily be made until optimal bracket
alignment is obtained
 Previously used
 Adhesive tape - bracket displacement
 Bonding resin – cleaning of bracket base
prior to bonding difficult and time
consuming
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
AJO 1999
 NEW INDIRECT BONDING MATERIAL
 3 M UNITEK / SONDHI RAPID SET
 Unique features
 Increased viscosity - silica fillers[5%]
 Quick set time – 30 secs
 Decreases the time needed for holding the
bonding tray
 Completely cured 2 min allowing rapid removal
of the tray
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Alginate impressions
made
 working models poured
in stone
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 APC brackets used
and positioned over
the teeth excess
adhesive removed
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Bracket positions
checked
 Models are placed
in the TRIAD
curing unit 10
minutes
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Block the
undercuts
 Construct tray with
bioplast material
[1mm] thick
overlayered with
bioacryl
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Excess tray
material is
trimmed off with
scalpel
 Trays placed in the
TRIAD unit to
ensure that
uncured resin is
cured
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Prepare patient
 Pumice , Etch &
isolate
 Tray can be sectioned
if there is severe
crowding
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Small amounts of
resin A and B are
poured into the wells
 Resin A – tooth
surface
 Resin B – resin pads
in the tray
www.indiandentalacademy.com
Indirect bonding – ANOOP SONDHI
 Seat the tray over the
teeth
 Hold with uniform
pressure for 30
seconds
 Leave the tray on for
another 2 minutes to
ensure complete
polymerization
www.indiandentalacademy.com
Indirect bonding using light cured
composites Paul Kasrovi et al AJO 1997
 Brackets bonded on the
cast with laboratory
adhesive
 Bracket height gauges are
are secured in each
bracket slot with Dycal
www.indiandentalacademy.com
 Bonding agent
applied on the incisal
portion f the height
gauges
 Small bead of resin is
attached to the each
height gauge to the
incisal edge [occlusal
stop]
www.indiandentalacademy.com
The cast is kept in
the triad curing
unit to cure the
resin
www.indiandentalacademy.com
Resin tray material is rolled & adapted to the
occlusal stops and cured
www.indiandentalacademy.com
www.indiandentalacademy.com
 Pumice ,etch &
isolate
 Apply light cure
resin to the back
of the brackets &
seat the tray
firmly
www.indiandentalacademy.com
 Remove excess bonding
material around the teeth with a
scaler
 Light cure each bracket for 30
seconds
 Ligature cutter is used to cut the
height gauges
www.indiandentalacademy.com
Advantages
 Technique is highly predictable
& reproducible
 Visibility and accessibility from
start to finish
 Ability to remove composite
flash before curing
www.indiandentalacademy.com
The slot machine & indirect bonding
THOMAS CREEKMORE,RANDY KUNIK AJO 1993
 Anticipated results are frequently not achieved
in PAE
 Inaccurate bracket placement
 Variations in tooth structure
 Variations in the maxilla/mandibular relationship
 Tissue rebound
 Mechanical deficiencies of appliance
 One PAE prescription cannot fit all ortho pts
www.indiandentalacademy.com
 The development and refinement of the a system
to vary the orientation of the bracket arch wire
slot relative to the labial surface of each tooth
provides a solution to these problems
 The slot machine was developed to overcome
these deficiencies of the PAE
The slot machine & indirect bonding
THOMAS CREEKMORE,RANDY KUNIK AJO 1993
www.indiandentalacademy.com
 not really a bracket
placement device
 Rather it orients the arch
wire slot of the bracket
relative to the facial
surface
 Accomplished by holding
the archwire slot
stationary while
manipulating each tooth
to any tip angle , torque,
rotation & height .
The slot machine & indirect bonding
www.indiandentalacademy.com
 [ orientation templates & rotation guides]
www.indiandentalacademy.com
The slot machine & indirect bonding
 Once the labial surface is oriented as
desired the bracket
 The bracket which is held stationary by the
arch wire slot is attached to the tooth with
the bonding material
 bonding material then fills the gap between
the bracket base and the tooth
www.indiandentalacademy.com

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Bonding

  • 2. TERMINOLOGIES  ADHESION : Attraction between unlike molecules  COHESION : Attraction between like molecules  MECHANICAL BONDING : Strong attachment of 2 substances accomplished mechanically rather than by molecular attraction www.indiandentalacademy.com
  • 3.  CONTACT ANGLE:  Angle between the wetting medium and the tooth surface  AIR POCKETS: - Created during the spreading of adhesive - Cause bond failure  TENSILE BOND STRENGTH  SHEAR BOND STRENGTH www.indiandentalacademy.com
  • 4. Nature of enamel  Highly mineralised tissue  Hardest tissue in human body  Clinically visible  No regenerative capacity www.indiandentalacademy.com
  • 5. Morphology  Enamel prisms  Extend from DEJ to outer surface at varying angles  Prismless enamel www.indiandentalacademy.com
  • 6. Longitudinal section under microscope  Wider prisms  Narrower Interprismatic substance www.indiandentalacademy.com
  • 7. Cross section  Keyhole / fish like pattern  Head 5 microns  Head - incisal region  Tail - cervical region www.indiandentalacademy.com
  • 8.  Prisms contain hydroxyapatite crystals  Run parallel to long axis of prism and become perpendicular as they approach tail www.indiandentalacademy.com
  • 9. Acquired pellicle  Precipitation of salivary proteins  Forms almost immediately  Removed by pumicing www.indiandentalacademy.com
  • 10. Factors affecting enamel solubility  Pre – eruptive factors  Post – eruptive factors www.indiandentalacademy.com
  • 11. Pre – eruptive factors  Affect chemical and histological characteristics of enamel prior to emergence in oral cavity 1. hypoplasia 2. hypocalcification 3. fluorosis www.indiandentalacademy.com
  • 12. Post eruptive factors  Affect the enamel solubility after eruption 1. topically applied fluorides 2. organic pellicle 3. plaque www.indiandentalacademy.com
  • 13. Factors affecting bonding to ideally etched surface  Patient operator saliva Contact with lip and tongue Oil / water via spray Rubbing / touching etched surfacewww.indiandentalacademy.com
  • 15. Over extended bonding medium onto unetched enamel www.indiandentalacademy.com
  • 18. BANDING M.E MAGILL - 1871 Negative factors :  Time and skill  Impacted teeth  Decalcification /discoloration  Gingival irritation  Unaesthetic  Placement of separators is painful  Closure of band spaces www.indiandentalacademy.com
  • 19. The goal was to have brackets tubes and other attachments directly cemented on the tooth surface to eliminate problems encountered with metal bands. www.indiandentalacademy.com
  • 20. MMA - Ist material Methyl Methacrylate Catalyst - BPO Difficulty in adhesion  Polymerization shrinkage  Pulpal irritation www.indiandentalacademy.com
  • 21. Buonocore - 1955  Etched enamel with 85% phosphoric acid to increase adhesive strength  However adhesive strength could not be maintained because of 1. Occlusal force 2. Wide range of oral thermal change 3. Wet environment www.indiandentalacademy.com
  • 22. G.V.Newman - 1965  Feasibility of using Plastic brackets with Epoxy resins  Start of Direct bonding procedure www.indiandentalacademy.com
  • 23. In 1969 – I st commercially available Ortho adhesive was OIS Adhesive system In 1970 - Bracket Bond ( GAC ) BPO – Amine catalyst system Weak Adhesion www.indiandentalacademy.com
  • 24. In 1971 Fujio Miura et al Orthomite ( MMA- TBB resin ) ( Tri – N – Butyl Borane ) Resulted in increased adhesive strength www.indiandentalacademy.com
  • 25. MMA  Powder and Liquid  No filler  Chemical adhesion with plastic brackets www.indiandentalacademy.com
  • 26. MMA adhesive MERITS  Plastic brackets  Good storage stability  Good penetration into enamel surface  Less damage during debonding www.indiandentalacademy.com
  • 27. MMA adhesive DEMERITS  Fluctuating property between powder liquid depending on operator technique www.indiandentalacademy.com
  • 28. Plastic Metal Plastic- Enamel adhesive bond interface Metal- Adhesive bracket interface Metal – Mesh , perforated pad , foil mesh MMA - BISGMA www.indiandentalacademy.com
  • 29. Drawbacks of BISGMA 1. Plastic brackets could not be used . To overcome this the plastic bracket base had to be partially dissolved - PRIMER added www.indiandentalacademy.com
  • 30. Drawbacks of BISGMA  Poor penetration due to increased viscosity  MMA + BISGMA sealant  This meant an additional step DILUTED www.indiandentalacademy.com
  • 31. Drawbacks of BISGMA  Active life was less than powder liquid system  Tooth surface damaged during debonding with BISGMA [ filler - hardness] www.indiandentalacademy.com
  • 32. Orthomite  Adhesive  Powder [ PMMA]  Liquid [MMA]  Catalyst [ TBB]  Coupling agent [ SILANE] Added to increase penetration into enamel crevices www.indiandentalacademy.com
  • 33.  Orthomite II No silane  Orthomite superbond 4 META 4 methacryloxy ethyl trimellitate anhydride could bond to metal [ NI-Cr] ,[ Co – C r] www.indiandentalacademy.com
  • 34. 4 META  Plastic + metal  PRE PRIMED brackets  Base was primed with adhesive  Bracket base covered with PMMA powder  Base dipped in monomer and pressed onto etched surface. www.indiandentalacademy.com
  • 35. Bonding medium ideal characteristics  Non toxicity  Adequate working and setting times  Moderate viscosity  Sufficient tensile and compressive strength  Ability to wet etched surface  Resist decomposition in the oral environment www.indiandentalacademy.com
  • 36. Mechanism of polymerization  Chemically activated - 2 paste system BPO – tertiary amine  Light activated - single paste system consists of photo initiator +amine Exposure of light of correct wavelength produces an excited state of photo initiator which interacts with the amine. www.indiandentalacademy.com
  • 37. Self cure Vs light cure  Self cure  Polymerization starts immediately  Cannot manipulate setting time  Air bubbles during mixing – reduce bond strength www.indiandentalacademy.com
  • 38. Self cure Vs light cure  Light cure  Compared to UV ,visible light deeper curing  Long working time  Excess material can be removed before polymerization www.indiandentalacademy.com
  • 39.  Resin 2 types  Acrylic resin MMA [plastic brackets]  Diacrylate resins BISGMA[metal ]  Filled / unfilled  Quartz ,silica  Particle size 3-20 microns impart abrasion resistance  Particle size-0.2 – 0.3 microns smooth surface less abrasion resistance www.indiandentalacademy.com
  • 40. No mix adhesive  Sets when one paste under light pressure is brought together with a primer fluid on the etched enamel or another paste on the tooth to be bonded  One adhesive component applied to bracket base and other on tooth surface  As soon as bracket is positioned it is pressed firmly into place  Curing occurs – 30-60 secs www.indiandentalacademy.com
  • 41. No mix adhesive  ADVANTAGES  Procedure simplified DISADVANTAGES  Little long term information available on bond strength of paste – paste system  Liquid activators – allergic reactions www.indiandentalacademy.com
  • 42. Pre coated brackets  Plastic / metal / ceramic  Chemical /light cured  ADVANTAGES 1. Consistent quality of adhesive 2. Reduced flash 3. reduced waste 4. Adequate bond strength 5. Improved cross infection control www.indiandentalacademy.com
  • 43. Evaluation of antimicrobial properties of orthodontic composite resin combined with benzalkonium chloride Othman et al,AJO Sep2002  The antimicrobial agent benzalkonium chloride was added to a chemically cured composite resin and the anti microbial benefits and bond strength of the modified composite were evaluated. www.indiandentalacademy.com
  • 44.  No significant difference between the tensile bond strength between modified composite and the original product .  The incorporated BAC added to anti microbial properties of original composite without altering it’s mechanical properties www.indiandentalacademy.com
  • 45. Advantages of bonding  Esthetics  Faster +simpler  Less patient discomfort  Arch length not increased  Less gingival irritation  Precise placement [aberrant tooth forms banding is difficult.] www.indiandentalacademy.com
  • 46. Advantages of bonding  Interproximal enamel reduction and composite build up possible  Bond artificial tooth surface  Caries risk eliminated  No band space closure  Lingual brackets www.indiandentalacademy.com
  • 47. Disadvantages of bonding  Weaker than bands  Better access for cleaning does not guarantee better oral hygiene  No protection against interproximal caries  Rebonding > Recementing Adhesive > Cement www.indiandentalacademy.com
  • 49. Bonding procedure  Cleaning  Enamel conditioning  Sealing  bonding www.indiandentalacademy.com
  • 50. Cleaning  Remove organic pellicle  Pumicing  Using rubber cups/polishing brush www.indiandentalacademy.com
  • 51. Cleaning  Pumice prophylaxis does not appear to affect bond strength  REISNAR ET AL Buccal surfaces lightly abraded with TC bur at slow speed 25000 rpm > Pumicing for 10 sec www.indiandentalacademy.com
  • 52. Enamel conditioning  Acid etching  Other alternatives to acid etching 1. Crystal growth 2. Sand blasting/air abrasion 3. Laser etching www.indiandentalacademy.com
  • 54. ACID ETCHING  1955 BUONOCORE - 85% phosphoric acid  37% phosphoric acid – 15 to 60 sec  15 sec – for young permanent teeth  30 – 60 sec – adult teeth  Longer periods - less retension due to loss of enamel structure www.indiandentalacademy.com
  • 55. Acid etching  Etchant should not be rubbed onto tooth surface  Rinsed with water spray  Dried with moisture and oil free source White frosty appearance www.indiandentalacademy.com
  • 56. Alternative acids for etching traditionally 30 – 40 % Phosphoric acid - 10 % Phosphoric acid - 10 % Maleic acid - 2.5 % Nitric acid Etch enamel as well but have significant lower bond strength www.indiandentalacademy.com
  • 57. Rationale of etching Gwinnett,Matsui & Buonocore  Primary mechanism of attachment of resin Resin tags to etched surface MICROMECHANICAL BOND Acid etch removes 10 microns of enamel Creates porous surface Increases wettabilitywww.indiandentalacademy.com
  • 58. Patterns of etching Gwinnett & Silverstone Type 1 - Selective removal of enamel prism cores - Peripheries intact www.indiandentalacademy.com
  • 59. Type 2 Reverse process - Peripheries removed - Cores intact www.indiandentalacademy.com
  • 60. Type 3 - Less distinct - Combination of 1 & 2 - Unrelated to Prism morphology www.indiandentalacademy.com
  • 61. Conc of Etchant  50 % phophoric acid - 60 sec Monocalcium Phosphate Monohydrate  27 % & less Dicalcium Phosphate Dihydrate  30-40 % Most retentive surface(Silverstone) www.indiandentalacademy.com
  • 62. Etching Time 60 sec 30 – 40 % Phosphoric acid Shorter etching time Reduced tensile bond strength SEM studies Tensile bond strength, Microleakage , Surface roughness 15 sec = 60 sec www.indiandentalacademy.com
  • 63.  fluorosis - no extra time needed  Fluoridated Soln/gel = non fluoridated  Acquired / developmental demineralization 1. Avoid etching/ keep time minimal 2. apply sealant 3. Direct bonding www.indiandentalacademy.com
  • 64. Bond strength with various etching times WEI NAN WANG ETAL AJO 1991  Compared the tensile bond strength at various etching times15,30, 60, 90,120 secs  37 % phosphoric acid  TBS was not statistically different for 15,30,60,90  TBS decreased – 120 secs  Debonding – fewer enamel fragments with shorter etching times www.indiandentalacademy.com
  • 65.  Compared quality and quantity of enamel etch produced by 37 % phosphoric acid and 2.5% nitric acid for 15 , 30 ,& 60 secs Concluded  37 % phosphoric acid - better etch for all 3 applications  15 < 30 & 60  30 = 60  Supported use of 37% - 30 secs to get optimum bond strength ALASTAIR GARDNER , ROSS HOBSON AJO 2001 Acid etching www.indiandentalacademy.com
  • 66. The continuous brush acid technique BAHARAV ,LANGSAM J PROSTH DENT 1987  Aim was to determine whether mechanical agitation of etchant would enhance decalcification of enamel  Non carious pre molars 1. Mesial half – 35% P04 acid[30 secs] left undisturbed 2. Distal half – 35% po4 acid [30 secs] continuously painted www.indiandentalacademy.com
  • 67. The continuous brush acid technique  Results  Continuous brushing of etchant - more efficient dissolution of enamel  Reduction of size of remaining crystals  Hence increasing the potential space between them for retension www.indiandentalacademy.com
  • 68. Acid etching Iatrogenic factors  Loss of enamel  Retention of resin tags discoloration  Leakage at the bracket interface - staining  Enamel loss – debonding  Surface roughness – debonding plaque retention  Softer enamel – prone decalcification www.indiandentalacademy.com
  • 69. Alternatives to acid etching  CRYSTAL GROWTH  SAND BLASTING/ AIR ABRASION  LASER ETCHING www.indiandentalacademy.com
  • 70. Crystal growth SMITH  Polyacrylic acid – chemical bonding  Purified polyacrylic acid- slight etching  Polyacrylic acid + sulfate ion – crystalline deposit  CALCIUM SULPHATE DIHYDRATE  Depends on concentration of sulfate ions www.indiandentalacademy.com
  • 71. Crystal growth MAIJER AND SMITH  Crystalline interface produced tensile bond strength equivalent to conventional acid etched surface  Debonding fracture at crystal - resin interface  Other soln – sulphuric acid anion[more reliable and uniform growth] www.indiandentalacademy.com
  • 72. Crystal growth  Calcium sulfate crystals must enucleate from bound calcium  To achieve this some etching is required  Enamel solubility ~ crystal enucleation  Mechanical attachment is created around the crystalline interface and superficially etched enamel MECHANISM OF RETENSION www.indiandentalacademy.com
  • 73. Crystal growth  ARTUN AND BERGLAND  Sulphuric acid - crystals not as long and needle like as with polyacrylic acid but were rounder and flatter  Hence debonding was easier www.indiandentalacademy.com
  • 74. Advantages of crystal growth  Debonding easier and quicker  Little damage to enamel  Minimal effect on outer fluoride containing enamel  No resin tags left behind  Possibility of incorporating fluoride in crystal interface – anticariogenic action www.indiandentalacademy.com
  • 75. Crystal growth - procedure  One drop of viscous liquid placed on tooth surface  Left undisturbed for 30 secs  Brush / swab should not be agitated as in etching as it may affect crystal/enamel interface  Rinsed for 20 secs www.indiandentalacademy.com
  • 76. Crystal growth - procedure  Forceful water spray to be avoided as it will break crystals  Look out for a dull whitish deposit  Bracket bonded in usual way www.indiandentalacademy.com
  • 77. Sand blasting / air abrasion  Makes use of high speed stream of aluminium oxide particles [50/90 microns]propelled by air pressure  Produces rough surface  Used for cavity preparation  Preparation of enamel /dentin www.indiandentalacademy.com
  • 78. Sand blasting  Could contribute to better bond strength with less enamel loss  Factors affecting bond strength 1. Particle size 2. Air pressure 3. Exposure time 4. Microstructure of enamel surface www.indiandentalacademy.com
  • 79. Sand blasting  Compared bond strength and enamel loss between sand blasting and conventional acid etching at varying exposure times and air pressure  Bond strength Sand blasting < acid etching  Enamel loss Sand blasting < acid etching WENDALA VAN WAVERAN ALBERT FEILZER AJO 2000 www.indiandentalacademy.com
  • 80. Laser etching  LASER  Light amplification by stimulated emission of radiation  3 elements  Lasing medium [ solid/liquid/gas]  Energy source[xenon flash lamp/electrical discharge]  Optical resonator 1. Coherence 2. Collimation 3. Monochromaticity www.indiandentalacademy.com
  • 81. Laser etching  When laser strikes an object it may be  Reflected  Transmitted  Scattered  Absorbed  Combination of above www.indiandentalacademy.com
  • 82. Laser etching  In order to have an effect on tissue light must be absorbed by some elements so that the energy can be converted into other forms  Production of heat undesirable effects www.indiandentalacademy.com
  • 83. Classification  Mode of excitation ( Continuous or Pulsed)  Wavelength 1. UV range(Krypton Flouride, Argon Flouride) 2. Visible Light ( Helium , Neon ) 3. Infra Red range ( carbon dioxide, Nd:Yag) www.indiandentalacademy.com
  • 84. Laser etching with Nd : Yag  Studied the surface effects of dentin following laser etching with Nd:Yag and evaluated the shear bond strength of composite between treated and untreated laser etched dentin  Surface roughness laser etched > unlased dentin  Bond strength Laser treated >unlased dentin M.A WILSON ET AL www.indiandentalacademy.com
  • 85. Laser etching  Shear bond strength of composite to laser pre treated dentin increased by 300 %  localised melting + recrystallization  Fungiform projections  The composite adapted to undercuts &space between the dentin projections LYDON COOPER ET AL www.indiandentalacademy.com
  • 87. Pulsed krypton fluoride excimer laser Dr Francis M  Compared surface morphology, bond strength,and ARI between acid etching and 3 different energy densities of pulsed krypton fluoride laser  440.460,480 MJ/cm2  Concluded :  TBS 460.> 480 >A E >440 www.indiandentalacademy.com
  • 88.  SBS 480 > A E > 460 > 440  SEM regular etch pattern similar to acid etch seen with 460 & 480 MJ/cm2 www.indiandentalacademy.com
  • 89. SEALING Sealer / Primer / Intermediate resin  Low viscosity resin which is applied prior to bonding . 1. Necessary to achieve proper bond strength 2. Improve resistance to microleakage 3. Both reasons 4. Not needed at all www.indiandentalacademy.com
  • 90. Chemically cured Sealant Light cured Ceen & Gwinnett Found Light cured sealant Chemically cured  Protect enamel Polymerize poorly adjacent to bracket Have low resistance from discoloration to abrasion www.indiandentalacademy.com
  • 91. Evaluation of sealant in orthodontic bonding Wei Nanwang etal AJO 1991  Evaluated the Tensile bond strength with and without use of sealant  They found no statistically significant difference in the bond strength of the two evaluated groups www.indiandentalacademy.com
  • 92. However the use of sealant  May offer extra protection to enamel during debonding  As chances of enamel surface detachment with out use sealant was greater. www.indiandentalacademy.com
  • 93. Self Etch Primer Unique characteristic of some bonding system is that they combine the Etchant + Primer into single product  Saves time  Cost efficient www.indiandentalacademy.com
  • 94. Procedure For Self Etch  Teeth are pumiced  Self etch primer gently swirled on to each enamel surface for 2 to 5 secs  As pH rises , etchant is converted to primer  Primer is thinned with burst of air  No rinsing with water  Bracket then bonded in usual way. www.indiandentalacademy.com
  • 95. Effect of self etch primer on shear bond strength of orthodontic brackets Samir Bishara & Leigh Von Wald AJO 2001 •Their study concluded that use of self etch primer resulted in low but clinically acceptable shear bond strength. •Comparison of ARI scores – More residual adhesive remained with self etch primer. www.indiandentalacademy.com
  • 96. Bonding of stainless steel brackets to enamel with new self etch primer Ryan Arnold et al sep 2002  Bond strength of stainless steel brackets using Transbond self etch primer Four groups A- Conventional etchant with separate primer B- Self etch –15 sec Before C- Self etch - 2 min bonding D-Self etch - 10 minwww.indiandentalacademy.com
  • 97. Conclusion –  No significant difference in bond strength between the two groups.  10 min delay in bonding after application of self etch primer might not be deleterious for adhesion www.indiandentalacademy.com
  • 98. Hydrophilic Primer ( MIP )  Bond failure – Moisture contamination  When etched enamel is wet most porosities get plugged – Penetration of resin impaired  Second molars – Access difficult  Hydrophilic primer (HEMA & Maleic acid) dissolved in acetone – 3M Unitek ( Transbond MIP ) www.indiandentalacademy.com
  • 99. Hydrophilic Primer S.J.Little Wood et al ( BJO 2000 ) In vitro study  Compared the bond strength of bracket bonded with hydrophilic primer with conventional primer  Concluded that the bond strength obtained with hydrophilic prime were significantly lower than conventional primer www.indiandentalacademy.com
  • 100. Pre primed brackets  Stainless steel +plastic  MERITS  Simplification of bonding procedure  Minimal wastage  Less chance of contamination  No air pockets  Accuracy and consistency www.indiandentalacademy.com
  • 101. Bonding Procedure Four steps 1. Transfer 2. Positioning 3. Fitting 4. Removal www.indiandentalacademy.com
  • 102. Transfer  Adhesive put on bracket base  Bracket placed on the tooth closed to the correct position www.indiandentalacademy.com
  • 103. Positioning  Proper vertical and horizontal positioning ( eg Using placement scaler with parallel edges) www.indiandentalacademy.com
  • 104. fitting  Bracket firmly pushed towards the tooth surface with one point contact www.indiandentalacademy.com
  • 105. Removal of excess  Gingival irritation  Plaque build up  Better esthetics  Prevents staining and discoloration www.indiandentalacademy.com
  • 106. Curing lights  Tungsten quartz halogen light  Argon laser  Xenon plasma arc light  light emitting diode curing units[LED]  Pulsed xenon plasma arc light www.indiandentalacademy.com
  • 107. Tungsten quartz halogen curing light when electric energy is passed Halogen bulb Tungsten filament is heated HEAT LIGHT Selective filters – blue light [ 400-500 microns] www.indiandentalacademy.com
  • 108. Tungsten quartz halogen curing light  40 seconds per bracket  15 minutes – both arches Disadvantages  Curing time consuming  Light output < 1% of consumed electricity  Lifetime – 100hrs  High heat - degrades components of bulb www.indiandentalacademy.com
  • 109. Argon laser  Introduced in the late 80’s &early 90’s  Promised to reduce the curing time dramatically  480 microns wavelength  Curing time  3 secs – per bracket  1 min – both arches www.indiandentalacademy.com
  • 110. Argon laser  KELSEY ,POWELL To equal bond strength of 40 sec exposure by conventional curing light argon laser must cure for 10 seconds Disadvantages  Laser unit large  expensive www.indiandentalacademy.com
  • 111. Xenon plasma arch light  Introduced in the late 1990’s  Short exposure time at lower cost  Curing time 3 – 5 secs per bracket www.indiandentalacademy.com
  • 112. Comparison of efficiency of xenon plasma light and conventional curing light Sheldon Newman et al AJO 2001  Exposure time 40 secs - conventional curing light 3 , 6 , & 9 secs – xenon plasma light  Bond strength xenon light > with longer exposure time  To equal bond strength of conventional curing light the exposure time with xenon had to be 6 –9 seconds www.indiandentalacademy.com
  • 113. Light emitting diode curing units Mills –1995  Instead of hot filament – Halogen bulb.  LED – junction of doped semi conductors. www.indiandentalacademy.com
  • 114. Light emitting diode curing units Advantages;  Lifetime 10, 000 hrs  Requires no filters  Resist shock and vibration  Little power to operate  Newer –GALLIUM NITRIDE ( LED ) 400-500microns www.indiandentalacademy.com
  • 115. LED  Optimum curing time ?  Replace halogen bulbs ? Mills et al ( BJO 1997 )  Compared light source containing LED to Halogen units  Concluded – LED curing units cured composites to significantly greater depths when tested at 40 & 60 sec www.indiandentalacademy.com
  • 116. Polymerization of resin cement with LED curing unit William Dunn & Louis Taloumis AJO sep 2002  Compared the shear bond strength of orthodontic brackets bonded to teeth with conventional halogen light and LED curing units .  Concluded- LED curing units bonded brackets to enamel as well as Halogen based curing lights www.indiandentalacademy.com
  • 117. Pulsed Xenon Plasma Arc Light Polymerization shrinkage Internal stresses Fracture of composite at tooth adhesive interface Microleakage / Caries www.indiandentalacademy.com
  • 118. Non Pulsed Xenon Plasma Arc Light Non Pulsed Plasma Arc Light Light Rapid curing Polymerization shrinkage www.indiandentalacademy.com
  • 119. Polymerization shrinkage – Over come -Curing composite in layers -Pulsed curing light Pulsed curing light- unit light is a series of pulse to polymerize the adhesive Pulsed Xenon Plasma Arc Light www.indiandentalacademy.com
  • 120. Retrofitting curing light  Most curing lights designed for restorative dentistry  Probes 10-11 mm  Flooded over larger area NEW POWER SLOT  Tapered rectangular tip  4 x 7 mm  Closer to enamel – bracket interface  Shorter curing times www.indiandentalacademy.com
  • 121. Bonding to artificial teeth and restorations www.indiandentalacademy.com
  • 122. Bonding to porcelain  Conventional acid etch ineffective  WOOD ET AL –[1986] showed 1. Roughening porcelain surface 2. Adding a porcelain primer 3. Using highly filled resin Increased bond strength www.indiandentalacademy.com
  • 123. Bonding to porcelain  WOOD ET AL  Showed that  Bond strength to porcelain > or = bonding to acid etched enamel of natural teeth  bond strength was high enough to damage porcelain surface - debonding www.indiandentalacademy.com
  • 124. Bonding to porcelain  Commonly used etchant – 9.8 % HF acid gel 2-3 secs  Microporosites –mechanical retension  Frosty appearance www.indiandentalacademy.com
  • 125. Bonding to porcelain  Surface preparation for orthodontic bonding to porcelain ZACHRISSON et al AJO 1996 HF acid gel = sand blasting + silane  Some authors feel Sand blasting + silane - high failure rates www.indiandentalacademy.com
  • 126. Bonding to porcelain - procedure  Isolate  Deglaze area by sand blasting 50 microns – 3 secs  Etch 9.6%HF gel - 2 mins  Rinse  bond with BISGMA resin  Use of silane optional www.indiandentalacademy.com
  • 127. Bonding to amalgam  Improved bonding technique  Modification of metal surface [sand blasting,diamond bur roughening]  Use of intermediate resin  Use adhesive resin that bond chemically to metal [4 META , 10 MDP BISGMA] www.indiandentalacademy.com
  • 128. Bonding to amalgam - procedure  Sand blast with 50 microns al oxide for 3 secs  Etch with 37% phosphoric acid 15 – 30 secs  Apply sealant and bond with adhesive resin  See that bonded attach is out of occlusion with antagonist www.indiandentalacademy.com
  • 129. summary  E+nx P+ B  E +nxPB Combined the primer and the bonding agent into one soln Needed good moisture control for good results  EP +B self etch primer Gentler etching , elimination of water rinsing, reduction in post operative sensitivity www.indiandentalacademy.com
  • 130. summary  n x EPB Prompt L pop Etchant primer and adhesive sealed in lollipop shaped aluminium foil packet Used for direct application on all composites  ONE UP BOND First EPB to contain color change polymerisation indicators. when polymerized completely it shifts from pink to tooth color www.indiandentalacademy.com
  • 131. Self Etch Primer  Prompt L Pop  Transbond self etch primer Liquid begins to etch as soon as it is applied www.indiandentalacademy.com
  • 132. Etchant Primer When two hydroxide ions are converted hydrogen ions are realsed www.indiandentalacademy.com
  • 133. Crystal growth JOHN ARTUN , S. BERGLAND AJO 1984  Soln A – dil sulphuric acid+sodium sulphate  Soln B – 10% po4 acid +dil sulphuric acid  Failure rates recorded – 6 months  A > B > ACID ETCH www.indiandentalacademy.com
  • 135. Indirect bonding  SILVERMAN AND COHEN – 1972  MMA and UV light activated unfilled BISGMA  MMA was applied to the plastic bracket base on the patient’s model  BISGMA –intermediary adhesive between the patients etched enamel & pre set adhesive on the bracket base www.indiandentalacademy.com
  • 136. Indirect bonding  Updated technique – 1974 by same authors  Used perforated metal bracket bases and only one adhesive- BISGMA[ UV light activated]  Increased operator working time as polymerization did not occur www.indiandentalacademy.com
  • 137. INDIRECT BONDING ADVANTAGES  Accurate bracket placement  Decreasing the chair side time  Avoiding band fitting on the posterior teeth  Eliminating the need for separators  Improved ability to bond the posteriors  Improved patient comfort and hygiene www.indiandentalacademy.com
  • 138. INDIRECT BONDING Disadvantages  Technique sensitive  Additional set of impressions need to be taken  Posterior attachments more likely to fail if the patient chews on hard food www.indiandentalacademy.com
  • 139. Indirect bonding techniques  Thomas technique  Silicon transfer tray  Double sealant technique  Moin & Dogon technique  Indirect method – Anoop Sondhi  Indirect bonding for light cured composites www.indiandentalacademy.com
  • 140. THOMAS TECHNIQUE 1979  Filled BISGMA resin placed into the bracket bases  Attached to the stone model  Before setting all excess material is removed from the cast around the brackets  Transfer tray made of flexible material  Tray + brackets removed from the cast as single unit www.indiandentalacademy.com
  • 141. THOMAS TECHNIQUE  Teeth of one arch isolated +etched  Liquid unfilled resin formed the interface between etched enamel and filled resin  Liquid catalyst – tooth  Base resin – brackets  Unfilled resin not pre mixed – working time increased  tray seated held till polymerization is complete www.indiandentalacademy.com
  • 142. Indirect bonding with silicone transfer trays  Pour the impression in stone  mark the long axis and height on each tooth  Apply water soluble adhesive on each bracket  Position the bracket over the teeth on the cast www.indiandentalacademy.com
  • 143.  Mix putty material press onto the cemented brackets  Tray is formed of sufficient thickness  Model is immersed in hot water  Mark the midline  Patient is prepared for direct application  Adhesive is placed on the base of brackets  Tray is seated and held for 3 minutes  Tray is peeled off excess adhesive on tooth is removed www.indiandentalacademy.com
  • 144. Double sealant technique  Adhesive paste rather than temporary adhesives are used to bond the brackets onto the cast  Base + catalyst mixed placed on the bracket bases  Brackets placed on the tooth  Tray is then formed placed in water www.indiandentalacademy.com
  • 145.  Embedded bracket bases are lightly abraded with with a mounted stone  Teeth are etched  Bracket bases are painted with[ partB]catalyst resin  Teeth are painted with universal sealant [partA]  Tray is seated held for 3 min  Adv – clean up simple due to less flash[unfilled resin only] www.indiandentalacademy.com
  • 146. Indirect bonding Moin & Dogon technique AJO 1977  Pour impression in stone  A drop of sticky wax is placed on teeth surfaces of cast  Brackets are warmed over flame and set on the cast www.indiandentalacademy.com
  • 147. Indirect bonding - Moin & Dogon technique  Impression made with polyether material  Tray separated from cast but brackets remain in situ  Bracket is removed from the cast &warmed to remove residual wax  They are placed into the impression www.indiandentalacademy.com
  • 148.  Teeth are pumiced,etched & isolated  Enamel surface is sealed with mixture of universal & catalyst sealant  bracket base is covered with the adhesive  tray is seated Indirect bonding - Moin & Dogon technique www.indiandentalacademy.com
  • 149. Indirect bonding - Moin & Dogon technique  Use of sticky wax-corrections can easily &readily be made until optimal bracket alignment is obtained  Previously used  Adhesive tape - bracket displacement  Bonding resin – cleaning of bracket base prior to bonding difficult and time consuming www.indiandentalacademy.com
  • 150. Indirect bonding – ANOOP SONDHI AJO 1999  NEW INDIRECT BONDING MATERIAL  3 M UNITEK / SONDHI RAPID SET  Unique features  Increased viscosity - silica fillers[5%]  Quick set time – 30 secs  Decreases the time needed for holding the bonding tray  Completely cured 2 min allowing rapid removal of the tray www.indiandentalacademy.com
  • 151. Indirect bonding – ANOOP SONDHI  Alginate impressions made  working models poured in stone www.indiandentalacademy.com
  • 152. Indirect bonding – ANOOP SONDHI  APC brackets used and positioned over the teeth excess adhesive removed www.indiandentalacademy.com
  • 153. Indirect bonding – ANOOP SONDHI  Bracket positions checked  Models are placed in the TRIAD curing unit 10 minutes www.indiandentalacademy.com
  • 154. Indirect bonding – ANOOP SONDHI  Block the undercuts  Construct tray with bioplast material [1mm] thick overlayered with bioacryl www.indiandentalacademy.com
  • 155. Indirect bonding – ANOOP SONDHI  Excess tray material is trimmed off with scalpel  Trays placed in the TRIAD unit to ensure that uncured resin is cured www.indiandentalacademy.com
  • 156. Indirect bonding – ANOOP SONDHI  Prepare patient  Pumice , Etch & isolate  Tray can be sectioned if there is severe crowding www.indiandentalacademy.com
  • 157. Indirect bonding – ANOOP SONDHI  Small amounts of resin A and B are poured into the wells  Resin A – tooth surface  Resin B – resin pads in the tray www.indiandentalacademy.com
  • 158. Indirect bonding – ANOOP SONDHI  Seat the tray over the teeth  Hold with uniform pressure for 30 seconds  Leave the tray on for another 2 minutes to ensure complete polymerization www.indiandentalacademy.com
  • 159. Indirect bonding using light cured composites Paul Kasrovi et al AJO 1997  Brackets bonded on the cast with laboratory adhesive  Bracket height gauges are are secured in each bracket slot with Dycal www.indiandentalacademy.com
  • 160.  Bonding agent applied on the incisal portion f the height gauges  Small bead of resin is attached to the each height gauge to the incisal edge [occlusal stop] www.indiandentalacademy.com
  • 161. The cast is kept in the triad curing unit to cure the resin www.indiandentalacademy.com
  • 162. Resin tray material is rolled & adapted to the occlusal stops and cured www.indiandentalacademy.com
  • 164.  Pumice ,etch & isolate  Apply light cure resin to the back of the brackets & seat the tray firmly www.indiandentalacademy.com
  • 165.  Remove excess bonding material around the teeth with a scaler  Light cure each bracket for 30 seconds  Ligature cutter is used to cut the height gauges www.indiandentalacademy.com
  • 166. Advantages  Technique is highly predictable & reproducible  Visibility and accessibility from start to finish  Ability to remove composite flash before curing www.indiandentalacademy.com
  • 167. The slot machine & indirect bonding THOMAS CREEKMORE,RANDY KUNIK AJO 1993  Anticipated results are frequently not achieved in PAE  Inaccurate bracket placement  Variations in tooth structure  Variations in the maxilla/mandibular relationship  Tissue rebound  Mechanical deficiencies of appliance  One PAE prescription cannot fit all ortho pts www.indiandentalacademy.com
  • 168.  The development and refinement of the a system to vary the orientation of the bracket arch wire slot relative to the labial surface of each tooth provides a solution to these problems  The slot machine was developed to overcome these deficiencies of the PAE The slot machine & indirect bonding THOMAS CREEKMORE,RANDY KUNIK AJO 1993 www.indiandentalacademy.com
  • 169.  not really a bracket placement device  Rather it orients the arch wire slot of the bracket relative to the facial surface  Accomplished by holding the archwire slot stationary while manipulating each tooth to any tip angle , torque, rotation & height . The slot machine & indirect bonding www.indiandentalacademy.com
  • 170.  [ orientation templates & rotation guides] www.indiandentalacademy.com
  • 171. The slot machine & indirect bonding  Once the labial surface is oriented as desired the bracket  The bracket which is held stationary by the arch wire slot is attached to the tooth with the bonding material  bonding material then fills the gap between the bracket base and the tooth www.indiandentalacademy.com