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IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________________
Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 57
EFFECTS OF AGING TIME ON MECHANICAL PROPERTIES OF SAND
CAST Al-4.5Cu ALLOY
S.Ilangovan1
, R.Srikanthan2
, G. Veda Vyass3
1
Assistant Professor (SG), Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa
Vidyapeetham, Coimbatore, Tamil Nadu, India
2
Third Year B.Tech, Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa
Vidyapeetham, Coimbatore, Tamil Nadu, India
3
Third Year B.Tech, Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa
Vidyapeetham, Coimbatore, Tamil Nadu, India
Abstract
An investigation was carried out to understand the effects of aging time of a cylindrical specimen on hardness, tensile strength and %
elongation of sand cast Aluminium alloy (Al-4.5Cu). The alloy was melted in an electric furnace and the molten alloy was poured into
sand moulds. The cast rods were tested for Vickers micro-hardness, ultimate tensile strength and % elongation. The aging time was
varied from 4 to 40 hours in steps of 4 hours and the maximum hardness was achieved when the specimen was aged for 36 hours. It
was found that the hardness of the alloy decreases when further aging was done. Moreover, it was observed that the tensile strength
increases with increase in hardness, whereas the % elongation decreases.
Key Words: Al-4.5Cu, Aging Treatment, Mechanical Properties, Sand cast.
----------------------------------------------------------------------***----------------------------------------------------------------------
1. INTRODUCTION
Aluminium alloys have a wide range of applications in the
aerospace and automotive industries. This is mainly due to its
advantageous characteristics that include high electrical and
thermal conductivities, high ductility, high specific strength,
ease of casting, low density, high strength to weight ratio and
reasonable corrosion resistance. A relative balance of
properties is attained using appropriate heat treatment
techniques [1-6] and is exploited by many industries,
especially the automotive industry which has recently
increased the production of aluminium alloys castings for
engine blocks and cylinder heads [6-7].
Copper has been the most common alloying element almost
since the beginning of the aluminum industry, and a variety of
alloys in which copper is the major addition were later
developed. Copper is added to aluminium to increase its
strength, hardness, fatigue, creep resistance and machinability
[8].
In this work, the cast aluminium alloy of composition Al-
4.5Cu was studied in order to find out the effect of aging time
on hardness, tensile strength, % elongation. This was done to
compare the results with as-cast properties of Al-4.5Cu alloy
in order to study the enhancement of mechanical properties on
aging.
2. EXPERIMENTAL PROCEDURE
2.1 Material Preparation
Aluminium alloy (Al-4.5Cu) castings were produced by
melting commercially available pure aluminium ingots and
electrolytic copper rods. The appropriate weight percent of the
elements were melted in a graphite crucible using an electric
furnace in an inert argon atmosphere. The molten metal was
poured at a temperature of 720ºC into sand moulds at room
temperature to make rods of Ø16 mm and length of 150
mm.The chemical composition of the cast alloy was tested
using a spectrometer and the results are reported in Table 1.
Table -1: Cast alloy composition
Al Cu Others
94.5 4.5 1
2.2 Microstructure
The microstructure of the alloy was observed through optical
microscope in various stages of aging process. The specimen
was prepared for microscopic observation using standard
metallographic techniques. The etchant used was Krolls
Reagent (92% Distilled Water, 6% Nitric Acid, 2% HF). The
photographic image of the optical microscope is shown in
Figure 1.
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________________
Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 58
Fig-1: Image of Optical Microscope
2.3 Hardness Testing
To assess the effect of aging heat treatment, the hardness of
the all the specimens were measured using a micro-hardness
tester as shown in Figure 2. A number of readings were taken
at different locations for each specimen and an average value
was calculated. The specimens were prepared and tested as per
ASTM- E384 standard. The parameters used in this test were:
50 gm-f applied load and 20 s duration. The hardness values
varied in each sample was within ±5 HV.
Fig-2: Mitutoyo make micro-hardness tester
2.4 Tensile Testing
The tensile test was conducted to predict the tensile strength
(TS) of the material as well as to find the ductility in terms of
% elongation of the alloy. The test specimens were prepared
according to ASTM - E4 standard as shown in Figure 3. The
photographic image of the specimen is shown in Figure 4. The
specimens were tested using computerized universal testing
machine (Make: Tinius Olsen M25KT) as shown in Figure 5.
Fig-3: Drawing of Tensile Test Specimen
Fig-4: Photograph image of tensile test specimen
Fig-5: Universal tensile testing machine
3. RESULTS AND DISCUSSION
3.1 Microstructure
Age hardening characteristics are evident in Al-Cu aluminum
alloy; with an increase in aging time, the mechanical strength
of the alloy increased considerably and dropped gradually
after a maximum value of aging time. Effect of aging is
affected by various factors viz. solid solution strengthening,
substrate’s recovery and recrystallization and new phase
precipitation. The first two factors lower the strength of the
alloy with the increase in aging time, but phase precipitation
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________________
Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 59
strengthens the alloy. The microstructures obtained are shown
in Figure 6(a-c) with a magnification of 20µm.
Fig-6a: Microstructure of as-cast Al-4.5Cu alloy
Fig-6b: Microstructure of 16 hours age-hardened specimen
Fig-6c: Microstructure of 36 hours age-hardened specimen
3.2 Hardness
The influence of aging time on hardness is shown in Figure 7.
It was observed from the plot that the hardness of the
specimen increases from 70 HV to 154 HV maximum as the
aging time increased from 0 to 36 hours. The hardness value
decreases upon further aging. The increase in hardness was
due to the formation of precipitates which interacted with the
dislocation movements. The decrease in hardness might have
been due to over-aging of the specimen. Therefore it maybe
concluded that the hardness increases with increasing aging
time up to a certain limit which depends on the alloy
composition and aging temperature. It was found to be
consistent with previous reports [9-11].
Fig-7: Hardness versus aging time
Figure 8 shows the variation of % elongation with hardness of
the alloy as a function of aging time. As stated above the
hardness of the alloy increases with aging time. Generally, %
elongation decreases with increasing hardness. The same
behaviour was obtained in this study. Hence it maybe
concluded that the % elongation varies inversely with
hardness of the alloy.
Fig-8: % Elongation versus hardness
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________________
Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 60
3.3 Tensile Strength
Figure 9 shows the variation of Tensile strength with aging
time. It is seen that the tensile strength of the alloy increases
from 147.5 to 226 MPa as time increases from 0 to 36 hours. It
is observed that the tensile strength value decreases to 217
MPa with further aging treatment. It may be due to over-
aging.
Fig-9: Tensile strength versus aging time
Figure 10 shows the variation of tensile strength with the
hardness of the alloy. It was found that the tensile strength
inreases with increase in hardness of the specimen. Hence it
maybe concluded that the tensile strength is a linearly varying
function of the hardness of the alloy.
Fig-10: Tensile Strength versus hardness
4. CONCLUSIONS
The findings of this particular experiment are summarised as
follows:
 The hardness increases with aging time up to a
particular aging time which depends on the alloy
composition and aging temperature.
 The % elongation decreases as the hardness of the alloy
increases.
 The tensile strength of the alloy increases gradually
with increase in aging time up to a specific aging time.
 The tensile strength is found to increase linearly with
increase in hardness of the alloy.
REFERENCES
[1] Wislei.R.Osorio,Daniel, J..Moutinho, Leandro
C.Peixoto, Ivaldo L.Ferreira, Amauri Garcia (2011),
“Macro segregation and microstructure dendritic array
affecting the electrochemical behavior of ternary Al-
Cu-Si alloys”, Electrochimica Acta, Vol. 56, pp. 8412-
8421.
[2] G.A.Capuano and W.G.Davenport, “Electrodeposition
of Aluminium from Alkyl Benzene Electrolytes”,
Journal of The Electrochemical Society, Vol.118, Issue
10, pp. 1688-1695.
[3] Mortaza Azarbarmas, Masoud Emamy, Jafar
RasizaDeh, Mohammed Alipour, Mostafa Karamouz
(2011), “The effects of Be on Mechanical Properties of
Al-Mg2Si in situ composite”, The Minerals, Metals and
Materials Society.
[4] V.V.Krisyuk, L.Aloui, N.Prud Home, B.Saraprata,
F.Senocq, D.Samelor and C.Vahlas (2009), “CVD of
Pure copper Films from a novel Amidinate Precursor”,
The Electrochemical Society, Vol. 25, pp. 581-586.
[5] G. García-García, J. Espinoza-Cuadra, H. Mancha-
Molinar (2007), “Copper content and cooling rate
effects over second phase particles behavior in
industrial aluminum–silicon alloy 319”, Mater Des,
Vol. 28, pp. 428–433.
[6] A.M.Samuel, F.H.Samuel, H.W.Doty (1996),
“Observations on the formation of β-Al5FeSi phase in
319 type Al-Si alloys”, Journal of Materials Science ,
Vol.31 , pp. 5529-5539.
[7] I.Guillot, B.Barlas, G.Cailletaud, M.Clavel,
D.Massinon (2002), “Thermomechanical fatigue and
aging cast aluminium alloy: A link between numerical
modeling and microstructural approach”, International
Conference on Temperature-Fatigue Interaction,
Vol.29, pp. 75-84.
[8] E.L.Rooy, Metals Handbook, vol. 15, ASM
International, Materials Park, Ohio.1988, pp. 743.
[9] Ilangovan, S. and Sellamuthu, R. (2012), “An
Investigation of the effect of Ni Content and Hardness
on the wear behavior of Sand Cast Cu-Ni-Sn Alloys”,
International Journal of Microstructure and Materials
Properties, Vol.7, pp.316-328.
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________________
Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 61
[10] Ilangovan, S. and Sellamuthu, R. (2013), “Effects of
Tin on Hardness, Wear Rate and Coefficient of Friction
of Cast Cu-Ni-Sn Alloys”, Journal of Engineering
Science & Technology, Vol.8, No.1, pp. 44-54.
[11] Dongmei Zhao, Q.M. Dong, P. Liu, B.X. Kang, J.L.
Huang, Z.H. Jin (2003), “Aging behavior of Cu-Sn
Alloy”, Materials Science and Engineering A, Vol.361,
pp. 93-99.
BIOGRAPHIES
Dr. S. Ilangovan has completed his
Bachelor’s Degree in Mechanical
Engineering and Master’s Degree in
Production Engineering. He has fourteen
years of experience in industry and sixteen
years in teaching. He has also completed
Ph.D. in Materials Engineering
R. Srikanthan is a third-year Mechanical
Engineering student currently pursuing
Bachelor of Technology degree from
Amrita Vishwa Vidyapeetham, Tamil Nadu.
G. Veda Vyass is a third-year Mechanical
Engineering student currently pursuing
Bachelor of Technology degree from
Amrita Vishwa Vidyapeetham, Tamil
Nadu.

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Effects of aging time on mechanical properties of sand cast al 4.5 cu alloy

  • 1. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________________ Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 57 EFFECTS OF AGING TIME ON MECHANICAL PROPERTIES OF SAND CAST Al-4.5Cu ALLOY S.Ilangovan1 , R.Srikanthan2 , G. Veda Vyass3 1 Assistant Professor (SG), Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Coimbatore, Tamil Nadu, India 2 Third Year B.Tech, Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Coimbatore, Tamil Nadu, India 3 Third Year B.Tech, Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Coimbatore, Tamil Nadu, India Abstract An investigation was carried out to understand the effects of aging time of a cylindrical specimen on hardness, tensile strength and % elongation of sand cast Aluminium alloy (Al-4.5Cu). The alloy was melted in an electric furnace and the molten alloy was poured into sand moulds. The cast rods were tested for Vickers micro-hardness, ultimate tensile strength and % elongation. The aging time was varied from 4 to 40 hours in steps of 4 hours and the maximum hardness was achieved when the specimen was aged for 36 hours. It was found that the hardness of the alloy decreases when further aging was done. Moreover, it was observed that the tensile strength increases with increase in hardness, whereas the % elongation decreases. Key Words: Al-4.5Cu, Aging Treatment, Mechanical Properties, Sand cast. ----------------------------------------------------------------------***---------------------------------------------------------------------- 1. INTRODUCTION Aluminium alloys have a wide range of applications in the aerospace and automotive industries. This is mainly due to its advantageous characteristics that include high electrical and thermal conductivities, high ductility, high specific strength, ease of casting, low density, high strength to weight ratio and reasonable corrosion resistance. A relative balance of properties is attained using appropriate heat treatment techniques [1-6] and is exploited by many industries, especially the automotive industry which has recently increased the production of aluminium alloys castings for engine blocks and cylinder heads [6-7]. Copper has been the most common alloying element almost since the beginning of the aluminum industry, and a variety of alloys in which copper is the major addition were later developed. Copper is added to aluminium to increase its strength, hardness, fatigue, creep resistance and machinability [8]. In this work, the cast aluminium alloy of composition Al- 4.5Cu was studied in order to find out the effect of aging time on hardness, tensile strength, % elongation. This was done to compare the results with as-cast properties of Al-4.5Cu alloy in order to study the enhancement of mechanical properties on aging. 2. EXPERIMENTAL PROCEDURE 2.1 Material Preparation Aluminium alloy (Al-4.5Cu) castings were produced by melting commercially available pure aluminium ingots and electrolytic copper rods. The appropriate weight percent of the elements were melted in a graphite crucible using an electric furnace in an inert argon atmosphere. The molten metal was poured at a temperature of 720ºC into sand moulds at room temperature to make rods of Ø16 mm and length of 150 mm.The chemical composition of the cast alloy was tested using a spectrometer and the results are reported in Table 1. Table -1: Cast alloy composition Al Cu Others 94.5 4.5 1 2.2 Microstructure The microstructure of the alloy was observed through optical microscope in various stages of aging process. The specimen was prepared for microscopic observation using standard metallographic techniques. The etchant used was Krolls Reagent (92% Distilled Water, 6% Nitric Acid, 2% HF). The photographic image of the optical microscope is shown in Figure 1.
  • 2. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________________ Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 58 Fig-1: Image of Optical Microscope 2.3 Hardness Testing To assess the effect of aging heat treatment, the hardness of the all the specimens were measured using a micro-hardness tester as shown in Figure 2. A number of readings were taken at different locations for each specimen and an average value was calculated. The specimens were prepared and tested as per ASTM- E384 standard. The parameters used in this test were: 50 gm-f applied load and 20 s duration. The hardness values varied in each sample was within ±5 HV. Fig-2: Mitutoyo make micro-hardness tester 2.4 Tensile Testing The tensile test was conducted to predict the tensile strength (TS) of the material as well as to find the ductility in terms of % elongation of the alloy. The test specimens were prepared according to ASTM - E4 standard as shown in Figure 3. The photographic image of the specimen is shown in Figure 4. The specimens were tested using computerized universal testing machine (Make: Tinius Olsen M25KT) as shown in Figure 5. Fig-3: Drawing of Tensile Test Specimen Fig-4: Photograph image of tensile test specimen Fig-5: Universal tensile testing machine 3. RESULTS AND DISCUSSION 3.1 Microstructure Age hardening characteristics are evident in Al-Cu aluminum alloy; with an increase in aging time, the mechanical strength of the alloy increased considerably and dropped gradually after a maximum value of aging time. Effect of aging is affected by various factors viz. solid solution strengthening, substrate’s recovery and recrystallization and new phase precipitation. The first two factors lower the strength of the alloy with the increase in aging time, but phase precipitation
  • 3. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________________ Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 59 strengthens the alloy. The microstructures obtained are shown in Figure 6(a-c) with a magnification of 20µm. Fig-6a: Microstructure of as-cast Al-4.5Cu alloy Fig-6b: Microstructure of 16 hours age-hardened specimen Fig-6c: Microstructure of 36 hours age-hardened specimen 3.2 Hardness The influence of aging time on hardness is shown in Figure 7. It was observed from the plot that the hardness of the specimen increases from 70 HV to 154 HV maximum as the aging time increased from 0 to 36 hours. The hardness value decreases upon further aging. The increase in hardness was due to the formation of precipitates which interacted with the dislocation movements. The decrease in hardness might have been due to over-aging of the specimen. Therefore it maybe concluded that the hardness increases with increasing aging time up to a certain limit which depends on the alloy composition and aging temperature. It was found to be consistent with previous reports [9-11]. Fig-7: Hardness versus aging time Figure 8 shows the variation of % elongation with hardness of the alloy as a function of aging time. As stated above the hardness of the alloy increases with aging time. Generally, % elongation decreases with increasing hardness. The same behaviour was obtained in this study. Hence it maybe concluded that the % elongation varies inversely with hardness of the alloy. Fig-8: % Elongation versus hardness
  • 4. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________________ Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 60 3.3 Tensile Strength Figure 9 shows the variation of Tensile strength with aging time. It is seen that the tensile strength of the alloy increases from 147.5 to 226 MPa as time increases from 0 to 36 hours. It is observed that the tensile strength value decreases to 217 MPa with further aging treatment. It may be due to over- aging. Fig-9: Tensile strength versus aging time Figure 10 shows the variation of tensile strength with the hardness of the alloy. It was found that the tensile strength inreases with increase in hardness of the specimen. Hence it maybe concluded that the tensile strength is a linearly varying function of the hardness of the alloy. Fig-10: Tensile Strength versus hardness 4. CONCLUSIONS The findings of this particular experiment are summarised as follows:  The hardness increases with aging time up to a particular aging time which depends on the alloy composition and aging temperature.  The % elongation decreases as the hardness of the alloy increases.  The tensile strength of the alloy increases gradually with increase in aging time up to a specific aging time.  The tensile strength is found to increase linearly with increase in hardness of the alloy. REFERENCES [1] Wislei.R.Osorio,Daniel, J..Moutinho, Leandro C.Peixoto, Ivaldo L.Ferreira, Amauri Garcia (2011), “Macro segregation and microstructure dendritic array affecting the electrochemical behavior of ternary Al- Cu-Si alloys”, Electrochimica Acta, Vol. 56, pp. 8412- 8421. [2] G.A.Capuano and W.G.Davenport, “Electrodeposition of Aluminium from Alkyl Benzene Electrolytes”, Journal of The Electrochemical Society, Vol.118, Issue 10, pp. 1688-1695. [3] Mortaza Azarbarmas, Masoud Emamy, Jafar RasizaDeh, Mohammed Alipour, Mostafa Karamouz (2011), “The effects of Be on Mechanical Properties of Al-Mg2Si in situ composite”, The Minerals, Metals and Materials Society. [4] V.V.Krisyuk, L.Aloui, N.Prud Home, B.Saraprata, F.Senocq, D.Samelor and C.Vahlas (2009), “CVD of Pure copper Films from a novel Amidinate Precursor”, The Electrochemical Society, Vol. 25, pp. 581-586. [5] G. García-García, J. Espinoza-Cuadra, H. Mancha- Molinar (2007), “Copper content and cooling rate effects over second phase particles behavior in industrial aluminum–silicon alloy 319”, Mater Des, Vol. 28, pp. 428–433. [6] A.M.Samuel, F.H.Samuel, H.W.Doty (1996), “Observations on the formation of β-Al5FeSi phase in 319 type Al-Si alloys”, Journal of Materials Science , Vol.31 , pp. 5529-5539. [7] I.Guillot, B.Barlas, G.Cailletaud, M.Clavel, D.Massinon (2002), “Thermomechanical fatigue and aging cast aluminium alloy: A link between numerical modeling and microstructural approach”, International Conference on Temperature-Fatigue Interaction, Vol.29, pp. 75-84. [8] E.L.Rooy, Metals Handbook, vol. 15, ASM International, Materials Park, Ohio.1988, pp. 743. [9] Ilangovan, S. and Sellamuthu, R. (2012), “An Investigation of the effect of Ni Content and Hardness on the wear behavior of Sand Cast Cu-Ni-Sn Alloys”, International Journal of Microstructure and Materials Properties, Vol.7, pp.316-328.
  • 5. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________________ Volume: 03 Issue: 05 | May-2014, Available @ http://www.ijret.org 61 [10] Ilangovan, S. and Sellamuthu, R. (2013), “Effects of Tin on Hardness, Wear Rate and Coefficient of Friction of Cast Cu-Ni-Sn Alloys”, Journal of Engineering Science & Technology, Vol.8, No.1, pp. 44-54. [11] Dongmei Zhao, Q.M. Dong, P. Liu, B.X. Kang, J.L. Huang, Z.H. Jin (2003), “Aging behavior of Cu-Sn Alloy”, Materials Science and Engineering A, Vol.361, pp. 93-99. BIOGRAPHIES Dr. S. Ilangovan has completed his Bachelor’s Degree in Mechanical Engineering and Master’s Degree in Production Engineering. He has fourteen years of experience in industry and sixteen years in teaching. He has also completed Ph.D. in Materials Engineering R. Srikanthan is a third-year Mechanical Engineering student currently pursuing Bachelor of Technology degree from Amrita Vishwa Vidyapeetham, Tamil Nadu. G. Veda Vyass is a third-year Mechanical Engineering student currently pursuing Bachelor of Technology degree from Amrita Vishwa Vidyapeetham, Tamil Nadu.