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Heisenberg's Uncertainty Principle
___________________________________
 The Uncertainty Principle is an important consequence
of the wave-particle duality of matter and radiation
and is inherent to the quantum description of nature
 Simply stated, it is impossible to know both the exact
position and the exact momentum of an object
simultaneously
A fact of Nature!
Heisenberg realised that ...
 In the world of very small particles, one cannot
measure any property of a particle without
interacting with it in some way
 This introduces an unavoidable uncertainty into
the result
 One can never measure all the
properties exactly
Werner Heisenberg (1901-1976)
Measuring the position and momentum
of an electron
 Shine light on electron and detect reflected
light using a microscope
 Minimum uncertainty in position
is given by the wavelength of the
light
 So to determine the position
accurately, it is necessary to use
light with a short wavelength
 In order to see the electron, at least one photon must
bounce off it
 During this interaction, momentum is transferred
from the photon to the electron
 Therefore, the light that allows you to accurately
locate the electron changes the momentum of the
electron
Fundamental Trade Off …
 Use light with short wavelength:
 accurate measurement of position but not
momentum
 Use light with long wavelength:
 accurate measurement of momentum but not
position
Heisenberg’s Uncertainty Principle
If a measurement of position of a particle is made with precision Δx
and a simultaneous measurement of linear momentum is made with
precision Δp then the product of the two uncertainties can never be
smaller than h/4
The more accurately you know the position (i.e.,
the smaller Dx is) , the less accurately you know the momentum
(i.e., the larger Dp is); and vice versa
Implications
 It is impossible to know both the position and
momentum exactly, i.e., Dx=0 and Dp=0
 These uncertainties are inherent in the physical world
and have nothing to do with the skill of the observer
 Because h is so small, these uncertainties are not
observable in normal everyday situations
Heisenberg’s Uncertainty Principle
involving energy and time
 The more accurately we know the energy of a body,
the less accurately we know how long it possessed
that energy
Derivation for uncertainty in energy and time
position momentum relation
multiply and divide above eqn. by m & p
From Einstein’s equation E = p2/2m (since E = ½ mv2 and p = mv)
∆ E = ∆ p 2p/2m
= ∆ p (p/m)
Further ∆ x (m/p) = ∆ x / v = ∆ t since p = mv
Substituting for ∆ x (m/p) and ∆ p (p/m) in position –
momentum equation we get

4
h
p
x x 
D
D

4
h
m
p
p
p
m
x x 






D








D

4
h
t
E 
D
D
Heisenberg's Uncertainty Principle
___________________________________
Position & momentum
Energy & time

4
h
p
x x 
D
D

4
h
t
E 
D
D
Some consequences of the Uncertainty
Principle
___________________________________
• The path of a particle (trajectory) is not well-
defined in quantum mechanics
 Electrons cannot exist inside a nucleus
 Atomic oscillators possess a certain amount of
energy known as the zero-point energy, even at
absolute zero.
Applications of the uncertainty principle
 The non-existence of electron in the nucleus can be
proved
 The binding energy of the hydrogen atom can be
calculated
 Strength of the nuclear force can be estimated

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FALLSEM2022-23_PHY1701_ETH_VL2022230106329_Reference_Material_II_06-10-2022_Course_mat.6.ppt

  • 1. Heisenberg's Uncertainty Principle ___________________________________  The Uncertainty Principle is an important consequence of the wave-particle duality of matter and radiation and is inherent to the quantum description of nature  Simply stated, it is impossible to know both the exact position and the exact momentum of an object simultaneously A fact of Nature!
  • 2. Heisenberg realised that ...  In the world of very small particles, one cannot measure any property of a particle without interacting with it in some way  This introduces an unavoidable uncertainty into the result  One can never measure all the properties exactly Werner Heisenberg (1901-1976)
  • 3. Measuring the position and momentum of an electron  Shine light on electron and detect reflected light using a microscope  Minimum uncertainty in position is given by the wavelength of the light  So to determine the position accurately, it is necessary to use light with a short wavelength
  • 4.  In order to see the electron, at least one photon must bounce off it  During this interaction, momentum is transferred from the photon to the electron  Therefore, the light that allows you to accurately locate the electron changes the momentum of the electron
  • 5. Fundamental Trade Off …  Use light with short wavelength:  accurate measurement of position but not momentum  Use light with long wavelength:  accurate measurement of momentum but not position
  • 6. Heisenberg’s Uncertainty Principle If a measurement of position of a particle is made with precision Δx and a simultaneous measurement of linear momentum is made with precision Δp then the product of the two uncertainties can never be smaller than h/4 The more accurately you know the position (i.e., the smaller Dx is) , the less accurately you know the momentum (i.e., the larger Dp is); and vice versa
  • 7. Implications  It is impossible to know both the position and momentum exactly, i.e., Dx=0 and Dp=0  These uncertainties are inherent in the physical world and have nothing to do with the skill of the observer  Because h is so small, these uncertainties are not observable in normal everyday situations
  • 8. Heisenberg’s Uncertainty Principle involving energy and time  The more accurately we know the energy of a body, the less accurately we know how long it possessed that energy
  • 9. Derivation for uncertainty in energy and time position momentum relation multiply and divide above eqn. by m & p From Einstein’s equation E = p2/2m (since E = ½ mv2 and p = mv) ∆ E = ∆ p 2p/2m = ∆ p (p/m) Further ∆ x (m/p) = ∆ x / v = ∆ t since p = mv Substituting for ∆ x (m/p) and ∆ p (p/m) in position – momentum equation we get  4 h p x x  D D  4 h m p p p m x x        D         D  4 h t E  D D
  • 10. Heisenberg's Uncertainty Principle ___________________________________ Position & momentum Energy & time  4 h p x x  D D  4 h t E  D D
  • 11. Some consequences of the Uncertainty Principle ___________________________________ • The path of a particle (trajectory) is not well- defined in quantum mechanics  Electrons cannot exist inside a nucleus  Atomic oscillators possess a certain amount of energy known as the zero-point energy, even at absolute zero.
  • 12. Applications of the uncertainty principle  The non-existence of electron in the nucleus can be proved  The binding energy of the hydrogen atom can be calculated  Strength of the nuclear force can be estimated