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STATES OF
MATTER
PHASE CHANGES
PHASE CHANGES
X(s) + heat  X(l) (melting, endothermic)
X(l)  X(s) + heat (freezing, exothermic)
X(l) + heat  X(g) (evaporation, endothermic)
X(g)  X(l) + heat (condensation, exothermic)
X(s) + heat  X(g) (sublimation, endothermic)
X(g)  X(s) + heat (decomposition, exothermic)
Endothermic process: Heat energy is
absorbed. Heat (Q) is shown in
reactant side on a chemical equation.
Exothermic process: Heat energy is
released. Heat (Q) is shown in product
side on a chemical equation.
Gets weaker
Evaporation
Endothermic
Increases
Difference
between boiling
and evaporation
?
WATER CYCLE
GASES
The particles of a gas
are relatively apart and
they are in a totally
random motion.
The intermolecular
forces between gas
particles are so small
that each molecule
moves freely.
PRESSURE
Pressure =
𝐹𝑜𝑟𝑐𝑒
𝐴𝑟𝑒𝑎
 P =
𝐹
𝐴
Atm Torr (mmHg) Bar Milibar(mbar) Pa
1 atm 1 760 1,013 1013 101325
- Gas pressure are most commonly expressed by chemists in units of atm
or mmHg.
PRESSURE
VOLUME
• Volume of gases can be
generally stated in unit cm3
(mL) and Liter (L )
•
1 cm3 = 1 mL
•
1 L = 1000 mL = 1 dm3
TEMPERATURE
Freezing Point of
water
Boiling point of
water
Fahrenheit scale 32 F 212 F
Celsius scale 0 C 100 C
Kelvin scale 273 K 373 K
T(C) = (F -32) / 1,8
T(K) = t(C) + 273
0 K or -273C is known as absolute zero.
TEMPERATURE
• Convert
a) 127C to K b) 233 K to C c) 100 C to F d) 32 F to C
• Solution:
• a) 127 C + 273 = 400 K b) 233 K – 273 = - 40 C
• c) 100C = (F -32) / 1,8 → 212 F d) T(C) = (32F -32) / 1,8 = 0 C
AMOUNT (MOLE)
• 1 mole of substances includes
6,02 x 1023 particles.
•
• 6,02 x 1023 = Avogadro’s
Number (NA)
• mole (n) =
𝒎𝒂𝒔𝒔 (𝒈)
𝑴𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 (𝒈/𝒎𝒐𝒍𝒆)
GAS LAWS
As T (in Kelvin) increases, average kinetic energy increases.
1) BOYLE- MARIOTTE LAW
BOYLE’S LAW
P x V
P
Volume and pressure are
inversely proportional
P x V is always constant at
constant T.
BOYLE’S LAW
CHARLES’S LAW
• Charles’ Law states that temperature (in Kelvin) and volume of a gas are directly
proportional to each other at constant pressure and number of mole
V = kT 
𝑽
𝑻
= k
(constant)
For a gas sample at constant P,
when two different conditions of
volume and temperature are
compared, we can write a
relation as given aside:
CHARLES’S LAW
 V and T are directly proportional
at constant P and n
 -273.15 C or 0 K is absolute zero
CHARLES’S LAW
GAY- LUSSAC’S LAW
• Temperature and pressure of a gas are
directly proportional to each other when
number of mole and volume of the gas are
kept constant
P  T or P = kT 
𝑷
𝑻
= k (constant)
- For a gas sample at constant
volume, when two different
conditions of pressure and
temperature are compared,
we can write a relation as
given aside
GAY-LUSSAC’S LAW
AVOGADRO’S LAW
• Volume of a gas is directly proportional to number of moles of the gas when pressure
and temperature are kept constant.
The relation for a gas at
two different volume and
mol number conditions
at constant T and P:
V a T or V = kn (k is constant)
According to Avogadro’s Law: “Equal volumes of different gases contain the same number of
molecules.”
COMBINED GAS EQUATION

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States of matter

  • 2.
  • 4. PHASE CHANGES X(s) + heat  X(l) (melting, endothermic) X(l)  X(s) + heat (freezing, exothermic) X(l) + heat  X(g) (evaporation, endothermic) X(g)  X(l) + heat (condensation, exothermic) X(s) + heat  X(g) (sublimation, endothermic) X(g)  X(s) + heat (decomposition, exothermic) Endothermic process: Heat energy is absorbed. Heat (Q) is shown in reactant side on a chemical equation. Exothermic process: Heat energy is released. Heat (Q) is shown in product side on a chemical equation.
  • 8. GASES The particles of a gas are relatively apart and they are in a totally random motion. The intermolecular forces between gas particles are so small that each molecule moves freely.
  • 9. PRESSURE Pressure = 𝐹𝑜𝑟𝑐𝑒 𝐴𝑟𝑒𝑎  P = 𝐹 𝐴 Atm Torr (mmHg) Bar Milibar(mbar) Pa 1 atm 1 760 1,013 1013 101325 - Gas pressure are most commonly expressed by chemists in units of atm or mmHg.
  • 11. VOLUME • Volume of gases can be generally stated in unit cm3 (mL) and Liter (L ) • 1 cm3 = 1 mL • 1 L = 1000 mL = 1 dm3
  • 13. Freezing Point of water Boiling point of water Fahrenheit scale 32 F 212 F Celsius scale 0 C 100 C Kelvin scale 273 K 373 K T(C) = (F -32) / 1,8 T(K) = t(C) + 273 0 K or -273C is known as absolute zero.
  • 14. TEMPERATURE • Convert a) 127C to K b) 233 K to C c) 100 C to F d) 32 F to C • Solution: • a) 127 C + 273 = 400 K b) 233 K – 273 = - 40 C • c) 100C = (F -32) / 1,8 → 212 F d) T(C) = (32F -32) / 1,8 = 0 C
  • 15. AMOUNT (MOLE) • 1 mole of substances includes 6,02 x 1023 particles. • • 6,02 x 1023 = Avogadro’s Number (NA) • mole (n) = 𝒎𝒂𝒔𝒔 (𝒈) 𝑴𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 (𝒈/𝒎𝒐𝒍𝒆)
  • 16. GAS LAWS As T (in Kelvin) increases, average kinetic energy increases.
  • 18. BOYLE’S LAW P x V P Volume and pressure are inversely proportional P x V is always constant at constant T.
  • 20. CHARLES’S LAW • Charles’ Law states that temperature (in Kelvin) and volume of a gas are directly proportional to each other at constant pressure and number of mole V = kT  𝑽 𝑻 = k (constant) For a gas sample at constant P, when two different conditions of volume and temperature are compared, we can write a relation as given aside:
  • 21. CHARLES’S LAW  V and T are directly proportional at constant P and n  -273.15 C or 0 K is absolute zero
  • 23. GAY- LUSSAC’S LAW • Temperature and pressure of a gas are directly proportional to each other when number of mole and volume of the gas are kept constant P  T or P = kT  𝑷 𝑻 = k (constant) - For a gas sample at constant volume, when two different conditions of pressure and temperature are compared, we can write a relation as given aside
  • 25. AVOGADRO’S LAW • Volume of a gas is directly proportional to number of moles of the gas when pressure and temperature are kept constant. The relation for a gas at two different volume and mol number conditions at constant T and P: V a T or V = kn (k is constant) According to Avogadro’s Law: “Equal volumes of different gases contain the same number of molecules.”
  • 26.