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IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
_______________________________________________________________________________________
Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 401
DEVELOPMENT OF ELECTRONIC TONGUE FOR SORGHUM
QUALITY DETECTION
Suraj Kshirsagar1
, R.P.Mudhalwadkar2
1
Student, Department of Instrumentation and Control, College of Engineering Pune, Maharashtra, India
2
Associate Professor, Department of Instrumentation and Control, College of Engineering Pune, Maharashtra, India
Abstract
Due to insufficient and improper facility of storage available in India many grains affects by quality. Quality changes over time
due to many things, one of them is moisture content of the cereals. This paper presents the design of a low-cost electronic tongue
system with a personal computer based decision making system. Generally, this kind of concept for food quality determination has
been used since many years for liquid food samples like coke, water, tea etc. Here the noble approach is applied for solid cereal
food like sorghum, wheat etc. The designed system is able to implement Voltammetry measurement with standard three electrode
configuration. Gold silver platinum and copper are used as electrode. Lab-View from National Instrumentation's is used to
generate and gather the signals to and from electronic tongue setup. The data obtained from the electrochemical measurement of
samples made from different variety of sorghum are applied to the artificial neural network analysis. First, the network is trained
for different known samples which are categorized into 3 different classes on the basis of the varieties. The network is found to
able discriminate them all accordingly.. The next experiment has shown that with the e-tongue graduation of the sample based on
quality of the cereal sample can be done, where the quality is affected due to the moisture.
Keywords: Neural networks, Electronic tongue, Feature extraction, Cereals, Food quality etc.
----------------------------------------------------------------- *** ----------------------------------------------------------------------
1. INTRODUCTION
The success of a food product in the food industry is
determined by many physical characteristics like
appearance, aroma and flavor. This makes the growing
customer demand for food quality, more rigorous inspection
and approval. In order to guarantee the quality of
commercial drinks, like tea [1], coffee, juice [2] water
[3][4], coke [5].
Different methods of chemical, physicochemical and
sensory analysis are successfully utilized. But there is mere
any research done for cereals, grains quality determination.
The above said techniques include a series of well-known
laboratory based methods like chromatographic and
spectroscopic, which are able to categorize with great
accuracy the chemical composition. The goal of the second
ones, sensory method is to evaluate the sensations produced
by food altogether. The sensorial analysis can be defined as
the experimentation and analysis of the global
characteristics of a product through the senses; those
characteristics are known as organoleptic.
Taste and smell senses are known as chemical senses
because they react to stimuli created by molecules starting a
nerve reaction. Taste reacts to stimuli produced by food
particles on the tongue’s taste buds. This interaction creates
the sensation of taste. The taste receptor cells are located
above all on the taste buds. The mechanism by which
different relishes detected and noticed is not yet ascertained,
but it is known that taste cells respond with partial
selectivity to a series of chemical compounds; in detecting a
relish a series of electrical impulses are generated with
different intensities and are transmitted to the brain, where
they are compared to identify relishes. An inspiration has
been generated so that from the taste and smell working
principles, instruments may be developed so that to emulate
its capacity to classify and differentiate many complex
materials. These biologically inspired sensors are known as
electronic tongues and noses. Thus, a particular analogy can
be established between the human taste system and the
electronic one in order to detect the complex materials. So
that some approximations can be found in its structure and
functioning principles.
Since the development of the first prototype in 1990 by K.
Toko [9], electronic tongues are becoming some of the most
promising tendencies to develop cheap, fast and promising
method to evaluate food taste. A certain number of research
groups have focused their work on the perfection and
improvement of these systems by utilizing different
strategies and measuring techniques. There are several
techniques and different sensors have been employed in
electronic tongues. Some of the combinations of sensor
array used by different researches are given in the table
1.The most important ones are based on electrochemical
techniques Voltammetry and potentiometry. Voltammetry is
having advantage like veracity, simplicity and good
sensitivity which lead to use this method over other
electronic tongue methods [12].
People are getting more conscious about quality food which
they consume. In most of the India there are many different
varieties of cereals are produced and consumed. The market
value of any agricultural product depends on its requirement
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
_______________________________________________________________________________________
Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 402
and availability. On the basis of quality of sorghum, its taste
and shelf life changes. Moisture Content changes the shelf
life and quality of the cereals [12] [13]. In this paper quality
of sorghum is tried to relate moisture content using the
electronic tongue.
Table 1: Specifications of self-designed 3- electrode voltammetry electronic tongue used for different research work
Water
authentication[4]
Classification
of tea[6]
Freshness of
milk [7]
Classification of
Virgin Olive
Oils[8]
Classification of
Juices [9]
Reference
electrode
Ag/AgCl Ag/AgCl Ag/AgCl
Saturated Calomel
Electrode
Ag/AgCl
Counter
electrode
SS Pt Pt Pt Pt
WE1 Pt Pt Pt Pt Pt
WE2 Ag Ir Ir glassy Carbon glassy Carbon
WE3 Au Au Au Au Au
WE4 - Pd Pd Indium Tin Oxide -
WE5 - Rh Rh - -
The expected results are not readily available as electronics
tongues output. Therefor this information from tongue has to
be analyze by multi-variant statistical techniques. On the
basis of given data and study being carried out statistical
analysis method can be selected. The most utilized
techniques to treat data from electronic tongues are different
methods of patterns recognition, some of them are Cluster
Analysis (CA), Discriminant Analysis (DA), Principal
Component Analysis (PCA) and Artificial neural networks
(ANN).
2. EXPERIMENTATION
2.1 Sample Collection and Preparation
Solapur district especially Mangalwedha tehsil is known for
Jowar. M-35-1(Maldandi) Jowar is famous in all over fine
milled 10 gm. jowar sample of each variety is added with
200ml of distilled water and kelp to dissolve for 15 min. the
sample such formed is the filtered with disposable Heat Seal
Filter Paper of Size 11 x 8 cm which is used for tea filtering
and easily available in the market.
These three varieties have different response for moisture.
Grain samples of 10gm x 10 of each is then continuously
treated with moisture as given in the next paragraph. As the
electronic tongue requires sample in liquid form, this
process destroys the sample. So these 10 samples are get
consumed one each day for next nine days.
1 ml of water is added to sample and then dried in open air
for a day. Similar process is followed for next nine days.
Regular measurement of moisture at the same time of the
day is done and one of the sample is applied to the
electronic tongue.
2.2 Development of Sensor
An electronic tongue setup has been developed using as
array of three working electrode which are made up of
different noble metals, namely gold, silver and copper; a
counter electrode made-up of platinum, and an Ag/AgCl
with saturated KCl is used as reference electrode.
Table 2: Jowar varieties and their specification
variety M-35-1
Phule
Yashada
Mauli
Duration
125-130
days
105-110
days
105-110
days
Grain
15-18
Qtl./Hect.
60-65
Qtl./Hect.
15-20
Qtl./Hect.
(Grain)
Fodder
100-105
Qtl./Hect.
160-180
Qtl./Hect.
100-140
Qtl./Hect.
specialty
Resistant to
water stress
Tolerant to
Aphids
Tolerant to
water
stress
2.3 Cleaning and Measurement Procedure
A measurement sequence consists of two types of waveform
application and a neutralizing procedure in between and
afterward to the liquefied sample. Lab-View from National
Instrumentations have been employed with the help of the
DAQ card USB 6009 to generate and acquire the signal. As
this card is limited to generate only in the range of 0 to 5 v
of analog signal, external circuit for voltage level converter
is used [6].
2.3.1 The electrochemical neutralizing or cleaning
procedure of the electrode starts with a positive
voltage of 2 V for 3 s. Then a potential of equal but
apposite sign means -2 V is applied for same 3 s.
2.3.2 Application of waveform is starts with a potential
of -0.5 V then it raises to 0.2V. Then it goes to -
0.1and so to 1 and -1. This pattern is specially
customised using LabView and a similar pattern of
waveform which is used for this experimentation is
shown in figure 2.
2.3.3 After application of first waveform the 2.3.1 step is
repeated.
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
_______________________________________________________________________________________
Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 403
2.3.4 The second waveform starts again with -2 V and
after a while a constant step size voltage of 200mV
keeps n adding till it reaches +2. This is like a
staircase waveform.
2.4 Data Acquisition
The electric current flowing in between each working
electrode and counter electrode and voltage between
reference and counter has been recorded to PC using analog
inputs of DAQ card USB 6009. Such 12 repeated
measurements has been recorded with time gap of 5 min in
each measurement cycle. Each file contains 1000 readings.
So such 1000 x 12 measurements for each WE are now
available for analysis.
3. DATA ANALYSIS
Neural network can be used to study correlation between
input and output. A commonly used topology named
multilayer perceptron with different learning rule back
propagation (BP-MLP), back propagation with momentum
(BPM-MLP), resilient (R-MLP) and radial basis function
(RBF) [14] is used for experimentation using electronic
tongue data. As recorded data from electronic tongue is used
without alteration other than normalization. So number of
input neurons or nodes required was high. Here 499 input
neurons are chosen with only one hidden layer which has 99
neurons.
Table 3: Results of the cross validation method for patterns
Cross
validation
sets
Number of correctly identified data
patters
BP-
MLP
BPM-
MLP
R-
MLP
RBF
1 8 9 8 10
2 7.5 10 8 9
3 8 9 9 9
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
_______________________________________________________________________________________
Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 404
4 9 8 9 10
5 8 8 8 9
6 8 9 7 8
7 9 10 9 9
8 8 8 8.5 8
9 8 7 10 8
10 9 8 9 9
Total
incorrect
results
17.5 14 14.5 11
Classificatio
n accuracy
82.5% 86% 85.5% 89%
Lowering the input neuron was able to speed up the learning
and the recognition process but that again leads to false
results. The learning rate is set on 0.3 for all the topologies.
The output neurons will be 3. Which will be used to
discriminate the sorghum variety. In other experiment the
output neuron is set to one which will give results in scale of
zero to one with refers to its quality. Both of the neural
networks are trained with separate samples collected and
prepared in section 2.1.
4. RESULTS
As sample collection of the sorghum is difficult, the size of
the data set is usually small so model evaluation methods
like cross-validation [15] is used to determine the efficiency
of the different topologies. Here performance of the neural
network is measured by classification rate. A total of 100
data patterns in the groups of 10 (10x10) is selected
randomly from the total available data set.
4.1 Classification
In this section the three neurons chosen for three different
sorghum varieties at the output layer gives one or zero for
classification. When it recognizes correctly one point is
awarded to that topology. Sometimes the network has given
output as one for two of the output neurons in such case 0.5
points are given. The total 10 runs in a single section gives
total sum of points which are recorded in to table 3.
The results shows that even without using any type of data
operation tools. The results are good. The RBF (89%) has
given the highest and BP-MLP (82.5%) as lowest accurate
result among all.
4.2 Quality Measurement
As given in section 2.1 samples prepared for quality analysis
is given to new sets of neural network which have been
trained to recognize the quality of the sample. The figure 2
shows the results of the same. Here when a constant amount
of water is added to the sample its moisture content changes
close to linearly (figure 1). This parameter is taken as
reference for quality. And a linear scale for quality has been
considered with some tolerable range of 10 %. Here 0 to 10
% is considered as a range and similarly other ranges are
decided. When five samples tested with each range of
quality, they found to be fall in the required group most of
the time (figure 2).out of which maximum inaccuracy found
in the range of 71 to 80. And there was at least one
inaccurate recognition found to be present. So the total
accuracy found to be 68%. For this, only RBF topology used
to form the neural network as we found last time, it has
given best result among the others.
5. CONCLUSION
An electronic tongue elaborated from a voltammetric
sensors array was used to classifying cereals like sorghum.
The electrochemical responses to the analyzed samples were
collected through an electronic instrument of multi
electrodes which was able to differentiate a group of
substances with different taste properties. The classification
of the substances was made through an ANN analysis.
These results shows that the electronic tongue can also be
used for quantification and quality determination of the food
like cereals, further this technique should be extended to
examine other cereals. Data filtering and compression may
lead to more accurate results.
ACKNOWLEDGMENTS
The authors would like to thanks the farmers of the
Mangalwedha, Solapur MS for helping us to collect the
samples from their agricultural fields, for this study.
REFERENCES
[1]. Ivarsson, Patrik, et al. "Discrimination of tea by means
of a voltammetric electronic tongue and different applied
waveforms." Sensors and Actuators B: Chemical 76.1
(2001): 449-454.
[2]. Legin, Andrey, et al. "Tasting of beverages using an
electronic tongue." Sensors and Actuators B: Chemical 44.1
(1997): 291-296.
[3]. Legin, Andrey, et al. "Application of electronic tongue
for quantitative analysis of mineral water and wine."
Electroanalysis 11.10‐11 (1999): 814-820.
[4]. Kundu, Palash Kumar, Amitava Chatterjee, and P. C.
Panchariya. "Electronic tongue system for water sample
authentication: a slantlet-transform-based approach."
Instrumentation and Measurement, IEEE Transactions on
60.6 (2011): 1959-1966.
[5]. Szollosi, D., et al. "Sweetener recognition and taste
prediction of coke drinks by electronic tongue." Sensors
Journal, IEEE 12.11 (2012): 3119-3123.
[6]. Palit, Mousumi, et al. "Classification of black tea taste
and correlation with tea taster's mark using voltammetric
electronic tongue." Instrumentation and Measurement, IEEE
Transactions on 59.8 (2010): 2230-2239.
[7]. Winquist, Fredrik, et al. "Monitoring of freshness of
milk by an electronic tongue on the basis of voltammetry."
Measurement Science and Technology 9.12 (1998): 1937.
[8]. Cosio, Maria S., et al. "Geographical origin and
authentication of extra virgin olive oils by an electronic nose
in combination with artificial neural networks." Analytica
Chimica Acta 567.2 (2006): 202-210.
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
_______________________________________________________________________________________
Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 405
[9]. Deschamp, B., et al. "A voltammetric electronic tongue
for detecting energetic compounds in water." Homeland
Security (HST), 2012 IEEE Conference on Technologies for.
IEEE, 2012.
[10]. Toko, K., et al. "Multi-channel taste sensor with lipid
membranes." Technical Digest of the 9th Sensor
Symposium. 1990.
[11]. Cetó, Xavier, Francisco Céspedes, and Manel del
Valle. "Comparison of methods for the processing of
voltammetric electronic tongues data." Microchimica Acta
180.5-6 (2013): 319-330.
[12]. Pixton, S. W. "Moisture content—its significance and
measurement in stored products." Journal of Stored
Products Research 3.1 (1967): 35-47.
[13]. Butt, Masood Sadiq, et al. "Effect of moisture and
packaging on the shelf life of wheat flour." Internet Journal
of Food Safety 4 (2004): 1-6.
[14]. Haykin, Simon, and Neural Network. "A
comprehensive foundation." Neural Networks 2.2004
(2004).
[15]. Singh, Sameer, Evor L. Hines, and Julian W. Gardner.
"Fuzzy neural computing of coffee and tainted-water data
from an electronic nose." Sensors and Actuators B:
Chemical 30.3 (1996): 185-190.

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Development of electronic tongue for sorghum quality detection

  • 1. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 _______________________________________________________________________________________ Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 401 DEVELOPMENT OF ELECTRONIC TONGUE FOR SORGHUM QUALITY DETECTION Suraj Kshirsagar1 , R.P.Mudhalwadkar2 1 Student, Department of Instrumentation and Control, College of Engineering Pune, Maharashtra, India 2 Associate Professor, Department of Instrumentation and Control, College of Engineering Pune, Maharashtra, India Abstract Due to insufficient and improper facility of storage available in India many grains affects by quality. Quality changes over time due to many things, one of them is moisture content of the cereals. This paper presents the design of a low-cost electronic tongue system with a personal computer based decision making system. Generally, this kind of concept for food quality determination has been used since many years for liquid food samples like coke, water, tea etc. Here the noble approach is applied for solid cereal food like sorghum, wheat etc. The designed system is able to implement Voltammetry measurement with standard three electrode configuration. Gold silver platinum and copper are used as electrode. Lab-View from National Instrumentation's is used to generate and gather the signals to and from electronic tongue setup. The data obtained from the electrochemical measurement of samples made from different variety of sorghum are applied to the artificial neural network analysis. First, the network is trained for different known samples which are categorized into 3 different classes on the basis of the varieties. The network is found to able discriminate them all accordingly.. The next experiment has shown that with the e-tongue graduation of the sample based on quality of the cereal sample can be done, where the quality is affected due to the moisture. Keywords: Neural networks, Electronic tongue, Feature extraction, Cereals, Food quality etc. ----------------------------------------------------------------- *** ---------------------------------------------------------------------- 1. INTRODUCTION The success of a food product in the food industry is determined by many physical characteristics like appearance, aroma and flavor. This makes the growing customer demand for food quality, more rigorous inspection and approval. In order to guarantee the quality of commercial drinks, like tea [1], coffee, juice [2] water [3][4], coke [5]. Different methods of chemical, physicochemical and sensory analysis are successfully utilized. But there is mere any research done for cereals, grains quality determination. The above said techniques include a series of well-known laboratory based methods like chromatographic and spectroscopic, which are able to categorize with great accuracy the chemical composition. The goal of the second ones, sensory method is to evaluate the sensations produced by food altogether. The sensorial analysis can be defined as the experimentation and analysis of the global characteristics of a product through the senses; those characteristics are known as organoleptic. Taste and smell senses are known as chemical senses because they react to stimuli created by molecules starting a nerve reaction. Taste reacts to stimuli produced by food particles on the tongue’s taste buds. This interaction creates the sensation of taste. The taste receptor cells are located above all on the taste buds. The mechanism by which different relishes detected and noticed is not yet ascertained, but it is known that taste cells respond with partial selectivity to a series of chemical compounds; in detecting a relish a series of electrical impulses are generated with different intensities and are transmitted to the brain, where they are compared to identify relishes. An inspiration has been generated so that from the taste and smell working principles, instruments may be developed so that to emulate its capacity to classify and differentiate many complex materials. These biologically inspired sensors are known as electronic tongues and noses. Thus, a particular analogy can be established between the human taste system and the electronic one in order to detect the complex materials. So that some approximations can be found in its structure and functioning principles. Since the development of the first prototype in 1990 by K. Toko [9], electronic tongues are becoming some of the most promising tendencies to develop cheap, fast and promising method to evaluate food taste. A certain number of research groups have focused their work on the perfection and improvement of these systems by utilizing different strategies and measuring techniques. There are several techniques and different sensors have been employed in electronic tongues. Some of the combinations of sensor array used by different researches are given in the table 1.The most important ones are based on electrochemical techniques Voltammetry and potentiometry. Voltammetry is having advantage like veracity, simplicity and good sensitivity which lead to use this method over other electronic tongue methods [12]. People are getting more conscious about quality food which they consume. In most of the India there are many different varieties of cereals are produced and consumed. The market value of any agricultural product depends on its requirement
  • 2. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 _______________________________________________________________________________________ Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 402 and availability. On the basis of quality of sorghum, its taste and shelf life changes. Moisture Content changes the shelf life and quality of the cereals [12] [13]. In this paper quality of sorghum is tried to relate moisture content using the electronic tongue. Table 1: Specifications of self-designed 3- electrode voltammetry electronic tongue used for different research work Water authentication[4] Classification of tea[6] Freshness of milk [7] Classification of Virgin Olive Oils[8] Classification of Juices [9] Reference electrode Ag/AgCl Ag/AgCl Ag/AgCl Saturated Calomel Electrode Ag/AgCl Counter electrode SS Pt Pt Pt Pt WE1 Pt Pt Pt Pt Pt WE2 Ag Ir Ir glassy Carbon glassy Carbon WE3 Au Au Au Au Au WE4 - Pd Pd Indium Tin Oxide - WE5 - Rh Rh - - The expected results are not readily available as electronics tongues output. Therefor this information from tongue has to be analyze by multi-variant statistical techniques. On the basis of given data and study being carried out statistical analysis method can be selected. The most utilized techniques to treat data from electronic tongues are different methods of patterns recognition, some of them are Cluster Analysis (CA), Discriminant Analysis (DA), Principal Component Analysis (PCA) and Artificial neural networks (ANN). 2. EXPERIMENTATION 2.1 Sample Collection and Preparation Solapur district especially Mangalwedha tehsil is known for Jowar. M-35-1(Maldandi) Jowar is famous in all over fine milled 10 gm. jowar sample of each variety is added with 200ml of distilled water and kelp to dissolve for 15 min. the sample such formed is the filtered with disposable Heat Seal Filter Paper of Size 11 x 8 cm which is used for tea filtering and easily available in the market. These three varieties have different response for moisture. Grain samples of 10gm x 10 of each is then continuously treated with moisture as given in the next paragraph. As the electronic tongue requires sample in liquid form, this process destroys the sample. So these 10 samples are get consumed one each day for next nine days. 1 ml of water is added to sample and then dried in open air for a day. Similar process is followed for next nine days. Regular measurement of moisture at the same time of the day is done and one of the sample is applied to the electronic tongue. 2.2 Development of Sensor An electronic tongue setup has been developed using as array of three working electrode which are made up of different noble metals, namely gold, silver and copper; a counter electrode made-up of platinum, and an Ag/AgCl with saturated KCl is used as reference electrode. Table 2: Jowar varieties and their specification variety M-35-1 Phule Yashada Mauli Duration 125-130 days 105-110 days 105-110 days Grain 15-18 Qtl./Hect. 60-65 Qtl./Hect. 15-20 Qtl./Hect. (Grain) Fodder 100-105 Qtl./Hect. 160-180 Qtl./Hect. 100-140 Qtl./Hect. specialty Resistant to water stress Tolerant to Aphids Tolerant to water stress 2.3 Cleaning and Measurement Procedure A measurement sequence consists of two types of waveform application and a neutralizing procedure in between and afterward to the liquefied sample. Lab-View from National Instrumentations have been employed with the help of the DAQ card USB 6009 to generate and acquire the signal. As this card is limited to generate only in the range of 0 to 5 v of analog signal, external circuit for voltage level converter is used [6]. 2.3.1 The electrochemical neutralizing or cleaning procedure of the electrode starts with a positive voltage of 2 V for 3 s. Then a potential of equal but apposite sign means -2 V is applied for same 3 s. 2.3.2 Application of waveform is starts with a potential of -0.5 V then it raises to 0.2V. Then it goes to - 0.1and so to 1 and -1. This pattern is specially customised using LabView and a similar pattern of waveform which is used for this experimentation is shown in figure 2. 2.3.3 After application of first waveform the 2.3.1 step is repeated.
  • 3. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 _______________________________________________________________________________________ Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 403 2.3.4 The second waveform starts again with -2 V and after a while a constant step size voltage of 200mV keeps n adding till it reaches +2. This is like a staircase waveform. 2.4 Data Acquisition The electric current flowing in between each working electrode and counter electrode and voltage between reference and counter has been recorded to PC using analog inputs of DAQ card USB 6009. Such 12 repeated measurements has been recorded with time gap of 5 min in each measurement cycle. Each file contains 1000 readings. So such 1000 x 12 measurements for each WE are now available for analysis. 3. DATA ANALYSIS Neural network can be used to study correlation between input and output. A commonly used topology named multilayer perceptron with different learning rule back propagation (BP-MLP), back propagation with momentum (BPM-MLP), resilient (R-MLP) and radial basis function (RBF) [14] is used for experimentation using electronic tongue data. As recorded data from electronic tongue is used without alteration other than normalization. So number of input neurons or nodes required was high. Here 499 input neurons are chosen with only one hidden layer which has 99 neurons. Table 3: Results of the cross validation method for patterns Cross validation sets Number of correctly identified data patters BP- MLP BPM- MLP R- MLP RBF 1 8 9 8 10 2 7.5 10 8 9 3 8 9 9 9
  • 4. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 _______________________________________________________________________________________ Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 404 4 9 8 9 10 5 8 8 8 9 6 8 9 7 8 7 9 10 9 9 8 8 8 8.5 8 9 8 7 10 8 10 9 8 9 9 Total incorrect results 17.5 14 14.5 11 Classificatio n accuracy 82.5% 86% 85.5% 89% Lowering the input neuron was able to speed up the learning and the recognition process but that again leads to false results. The learning rate is set on 0.3 for all the topologies. The output neurons will be 3. Which will be used to discriminate the sorghum variety. In other experiment the output neuron is set to one which will give results in scale of zero to one with refers to its quality. Both of the neural networks are trained with separate samples collected and prepared in section 2.1. 4. RESULTS As sample collection of the sorghum is difficult, the size of the data set is usually small so model evaluation methods like cross-validation [15] is used to determine the efficiency of the different topologies. Here performance of the neural network is measured by classification rate. A total of 100 data patterns in the groups of 10 (10x10) is selected randomly from the total available data set. 4.1 Classification In this section the three neurons chosen for three different sorghum varieties at the output layer gives one or zero for classification. When it recognizes correctly one point is awarded to that topology. Sometimes the network has given output as one for two of the output neurons in such case 0.5 points are given. The total 10 runs in a single section gives total sum of points which are recorded in to table 3. The results shows that even without using any type of data operation tools. The results are good. The RBF (89%) has given the highest and BP-MLP (82.5%) as lowest accurate result among all. 4.2 Quality Measurement As given in section 2.1 samples prepared for quality analysis is given to new sets of neural network which have been trained to recognize the quality of the sample. The figure 2 shows the results of the same. Here when a constant amount of water is added to the sample its moisture content changes close to linearly (figure 1). This parameter is taken as reference for quality. And a linear scale for quality has been considered with some tolerable range of 10 %. Here 0 to 10 % is considered as a range and similarly other ranges are decided. When five samples tested with each range of quality, they found to be fall in the required group most of the time (figure 2).out of which maximum inaccuracy found in the range of 71 to 80. And there was at least one inaccurate recognition found to be present. So the total accuracy found to be 68%. For this, only RBF topology used to form the neural network as we found last time, it has given best result among the others. 5. CONCLUSION An electronic tongue elaborated from a voltammetric sensors array was used to classifying cereals like sorghum. The electrochemical responses to the analyzed samples were collected through an electronic instrument of multi electrodes which was able to differentiate a group of substances with different taste properties. The classification of the substances was made through an ANN analysis. These results shows that the electronic tongue can also be used for quantification and quality determination of the food like cereals, further this technique should be extended to examine other cereals. Data filtering and compression may lead to more accurate results. ACKNOWLEDGMENTS The authors would like to thanks the farmers of the Mangalwedha, Solapur MS for helping us to collect the samples from their agricultural fields, for this study. REFERENCES [1]. Ivarsson, Patrik, et al. "Discrimination of tea by means of a voltammetric electronic tongue and different applied waveforms." Sensors and Actuators B: Chemical 76.1 (2001): 449-454. [2]. Legin, Andrey, et al. "Tasting of beverages using an electronic tongue." Sensors and Actuators B: Chemical 44.1 (1997): 291-296. [3]. Legin, Andrey, et al. "Application of electronic tongue for quantitative analysis of mineral water and wine." Electroanalysis 11.10‐11 (1999): 814-820. [4]. Kundu, Palash Kumar, Amitava Chatterjee, and P. C. Panchariya. "Electronic tongue system for water sample authentication: a slantlet-transform-based approach." Instrumentation and Measurement, IEEE Transactions on 60.6 (2011): 1959-1966. [5]. Szollosi, D., et al. "Sweetener recognition and taste prediction of coke drinks by electronic tongue." Sensors Journal, IEEE 12.11 (2012): 3119-3123. [6]. Palit, Mousumi, et al. "Classification of black tea taste and correlation with tea taster's mark using voltammetric electronic tongue." Instrumentation and Measurement, IEEE Transactions on 59.8 (2010): 2230-2239. [7]. Winquist, Fredrik, et al. "Monitoring of freshness of milk by an electronic tongue on the basis of voltammetry." Measurement Science and Technology 9.12 (1998): 1937. [8]. Cosio, Maria S., et al. "Geographical origin and authentication of extra virgin olive oils by an electronic nose in combination with artificial neural networks." Analytica Chimica Acta 567.2 (2006): 202-210.
  • 5. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 _______________________________________________________________________________________ Volume: 04 Issue: 04 | Apr-2015, Available @ http://www.ijret.org 405 [9]. Deschamp, B., et al. "A voltammetric electronic tongue for detecting energetic compounds in water." Homeland Security (HST), 2012 IEEE Conference on Technologies for. IEEE, 2012. [10]. Toko, K., et al. "Multi-channel taste sensor with lipid membranes." Technical Digest of the 9th Sensor Symposium. 1990. [11]. Cetó, Xavier, Francisco Céspedes, and Manel del Valle. "Comparison of methods for the processing of voltammetric electronic tongues data." Microchimica Acta 180.5-6 (2013): 319-330. [12]. Pixton, S. W. "Moisture content—its significance and measurement in stored products." Journal of Stored Products Research 3.1 (1967): 35-47. [13]. Butt, Masood Sadiq, et al. "Effect of moisture and packaging on the shelf life of wheat flour." Internet Journal of Food Safety 4 (2004): 1-6. [14]. Haykin, Simon, and Neural Network. "A comprehensive foundation." Neural Networks 2.2004 (2004). [15]. Singh, Sameer, Evor L. Hines, and Julian W. Gardner. "Fuzzy neural computing of coffee and tainted-water data from an electronic nose." Sensors and Actuators B: Chemical 30.3 (1996): 185-190.