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IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________
IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 283
ANAEROBIC DIGESTION OF DOMESTIC WASTEWATER
B. G. Mahendra1
, Sharadreddy Patil2
1
Associate Professor, 2
M.Tech Scholar, Department of Civil Engineering, Poojya Doddappa Appa College of
Engineering, Gulbarga - 585102, Karnataka, sharadreddy.patil@gmail.com
Abstract
Treatment of domestic wastewater is one of the serious problems. Various treatment technologies such as physico-chemical
treatment and biological treatment are available for the treatment of domestic wastewater. Owing to the presence of high
organic matter, domestic wastewater is well suited for biological treatment. As such in recent years there has been
increasing interest in anaerobic treatment of wastewater. Compared to aerobic treatment, anaerobic digestion produces less
biomass for the same amount of COD removal compared to aerobic treatment and produces methane up to 95% of the
organic matter in the waste stream. The laboratory bench scale experiments were carried out treating domestic wastewater
of Gulbarga city in fabricated anaerobic batch reactor of 10 Lts working volume. The domestic wastewater has the following
characteristics (average values) pH= 6.9 to 7.95, Total solids = 1140 mg/L, Dissolved solids = 1020 mg/L, Suspended solids
= 120 mg/L, Alkalinity = 120 mg/L, Total volatile solids = 890 mg/L, Chloride = 262.2 mg/L, BOD5 = 285 mg/L, COD = 945
mg/L. The experiments were carried out for three months with the initial organic loading rate = 0.945 kg of COD/m3
day.
From the study it is concluded that the anaerobic digestion has the efficiency in removal of COD by 90.25% and Total solids
removal of 67.27%.
Keywords: Domestic wastewater, anaerobic digestion.
-----------------------------------------------------------------***------------------------------------------------------------------
1. INTRODUCTION
Poorly treated or untreated domestic wastewater with high
levels of pollutants creates major environmental problems
when discharged into surface water or land. Such
problems may include contamination and deoxygenating
of streams and waterways by direct discharge of
inadequately treated wastewater [3]. Excessive
concentration of nutrients such as nitrogen and
phosphorus on wastewater contribute to excessive growth
of plants and algal blooms in surface water bodies, which
makes the downstream water unsuitable for domestic,
agriculture and industrial use. The domestic wastewater
contains pathogen which leads to the spread of diseases
and odour, when discharged in water bodies or on land for
irrigation without any treatment. Over application of
domestic wastewater to land results in damage to soil,
crops, and contamination of ground water, clogging of
soil pores by solids present in wastewater [4].
Domestic wastewater is characterized by low biological
oxygen demand (BOD) and chemical oxygen demand
(COD) concentrations, turbid, low/high pH. The domestic
wastewater contains chlorides, very small amount of
solids, oils, fats and detergents and sanitizing agents, as
such it requires treatment [2].
The present study was carried out in the Environmental
Engineering laboratory, Civil Engineering department,
PDA Engineering College, Gulbarga, from the period July
2012 to December 2012, with the following objectives.
1) To determine the characteristics of domestic
wastewater.
2) To study the different stages of anaerobic digestion
process.
3) To study the anaerobic digestion under optimum
condition.
4) To study the effect of organic loading on the
performance of anaerobic digestion process.
1.1 Microbiology of Anaerobic Digestion:
The biochemistry and kinetics of anaerobic process are
complicated and the biological conversion of organic
matter into methane is brought about by a group of
specific micro organisms. The schematics of the process
as described by Gujer, Zehnder (1983) involving the
hydrolysis of biopolymers such as carbohydrates, lipids
and proteins, oxidation and fermentation of amino acids
and sugars, fatty acids, alcohol’s and intermediates and
the conversion of acetate and hydrogen into methane are
schematically represented in the following figure 1 [1].
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________
IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 284
Figure 1: Breakdown of organic polymers in anaerobic
digestion.
2. MATERIAL AND METHODOLOGY
The laboratory bench scale Batch reactor experiments
were carried for treating domestic wastewater of Gulbarga
city. As per provisional reports of Census of India,
population of Gulbarga city in 2011 AD is 5,32,031 and
the out flow of domestic wastewater is 55 MLD. The
study was conducted under ambient environmental
conditions in fabricated anaerobic reactor of 10 Lts
working volume. The domestic wastewater was collected
from Nagenahalli nala, NH 218, 2 KM away from PDA
college of engineering, towards south of Gulbarga city.
During the start up of reactor it was fed with domestic
wastewater of 10 Lts having COD of 945 mg/L at organic
loading rate 0.945 kg COD/m3 d at room temperature and
operated for 90 days. The domestic wastewater
characteristics were analysed as per “standard methods for
the examination of water and wastewater” (21st edition,
2005) [5].
3. RESULTS AND DISCUSSION
The domestic wastewater was analysed for the following
parameters such as pH, BOD, COD, alkalinity, total
solids, suspended solids, dissolved solids, total volatile
solids and chlorides and the same presented in table 1.
Anaerobic digestion of domestic wastewater was
conducted in batch reactor. The study was conducted at
laboratory temperature varying from 25 – 30 ˚C. The data
collected during the study period are discussed in the
following section.
Table 1: Characteristics of domestic wastewater
S No Parameters Unit Value
1 pH - 7.6 – 7.3
2 Alkalinity as CaCO3 mg/L 146 – 135
3 Total solids mg/L 1172 – 1119
4 Dissolved solids mg/L 1054 – 995
5 Suspended solids mg/L 126 – 111
6 Total volatile solids mg/L 901 – 879
7 Chlorides as Cl2 mg/L 276.2 – 251
8 COD mg/L 955 – 935
9 BOD5 at 20 ˚C mg/L 298 – 276
The percentage of COD removal and biogas produced
with per kg of COD removed are shown in table 2 and
presented in figure 2. The percentage of total solids
removal and volume of biogas produced per kg of total
solids removal are shown in table 3 and presented in
figure 3. The biogas produced (in LPD) during day 10 to
day 90 shown in table 4 and presented in figure 4.
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________
IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 285
Table 2: COD, percentage of COD removal and volume of Biogas produced per kg of COD removal during day 10 to day
90
S No
Experimental
periods in days
COD
(mg/L)
Percentage of
COD removal
Volume of Biogas produced per kg of
COD removal (in Lts)
1 10 892.1 5.6 35.85
2 20 795 15.87 20.66
3 30 697.5 26.19 19.79
4 40 591.8 37.37 18.68
5 50 492 47.94 17.88
6 60 393.3 58.38 16.67
7 70 294.4 68.85 15.83
8 80 193.1 79.57 14.49
9 90 92.1 90.25 14.30
Figure 2: Percentage of COD removal and volume of Biogas produced per kg of COD removal during day 10 to day 90
Table 3: Total solids, percentage of Total solids removal and volume of Biogas produced per kg of Total solids removal
during day 10 to day 90
S No
Experimental
periods in days
Total
solids
(mg/L)
Percentage of Total
solids removal
Volume of Biogas produced per kg of
Total solids removal
(in Lts)
1 10 1053.8 7.56 22.04
2 20 968.9 15.01 18.12
3 30 883.7 22.48 19.11
4 40 794.6 30.30 19.11
0
5
10
15
20
25
30
35
40
0
10
20
30
40
50
60
70
80
90
100
10 20 30 40 50 60 70 80 90
VolumeofBiogasproducedperkgof
CODremoval
PercentageofCODremoval
Experimental periods in days
Percentage of COD removal
Volume of Biogas produced per kg of
COD removal (in Lts)
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________
IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 286
5 50 710.1 37.71 18.84
6 60 625.3 45.15 17.87
7 70 537 52.89 17.08
8 80 454.7 60.11 15.91
9 90 373.1 67.27 15.91
Figure 3: Percentage of Total solids removal and volume of Biogas produced per kg of Total solids removal during day 10
to day 90
Table 4: Biogas production during day 10 to day 90
S No Experimental periods in days Biogas produced in LPD
1 10 0.019
2 20 0.031
3 30 0.049
4 40 0.066
5 50 0.081
6 60 0.092
7 70 0.103
8 80 0.109
9 90 0.122
0
5
10
15
20
25
0
10
20
30
40
50
60
70
80
10 20 30 40 50 60 70 80 90
VolumeofBiogasproducedperkgof
Totalsolids
removal
PercentageofTotalsolidsremoval
Experimental periods in days
Percentage of Total solids removal
Volume of Biogas produced per
kg of Total solids removal
IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
__________________________________________________________________________________________
IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 287
Figure 4: Biogas production during day 10 to day 90
CONCLUSIONS
Based on the experimental study following conclusions can be
drawn
1. It can be concluded from characterization study that the
wastewater is highly organic in nature having high
value of COD.
2. The maximum COD removal efficiency is 90.25
percent.
3. The maximum total solids removal efficiency is 67.27
percent.
4. The maximum biogas produced is 0.122 LPD on the
90th
day.
REFERENCES
[1] Anna Schnurer and Asa Jarvis – Microbiological
handbook for biogas plants, Swedish waste
management U2009 march, Swedish Gas Centre report
207.
[2] Cheerawit R, Thunwadee T. S, Duangporn K, Tanwat R
and Wichuda – Biogas Production from Co – digestion
of domestic wastewater and food waste, Health and the
Environmental Journal, 2012, Volume 3, no. 2.
[3] I. Bodik, S. sedlacek, M. Kulaska and M. Hutnan –
Biogas Production in Muncipal Wastewater Treatment
Plants, Chemical and Biochemical Engineering, Q.
25(3), 335 – 340 (2011).
[4] Metcalf and Eddy – Wastewater Engineering Treatment
and Reuse, 4th
edition, McGraw – Hill Publishing, New
York – 2004.
[5] Standard Methods for the examination of Water and
Wastewater, 21st
edition (APHA, AWWA AND WFF,
Washington DC) 2005.
0
0.02
0.04
0.06
0.08
0.1
0.12
0.14
10 20 30 40 50 60 70 80 90
BiogasproducedinLPD
Experimental periods in days
Biogas produced in
LPD

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Anaerobic digestion of domestic wastewater

  • 1. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________ IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 283 ANAEROBIC DIGESTION OF DOMESTIC WASTEWATER B. G. Mahendra1 , Sharadreddy Patil2 1 Associate Professor, 2 M.Tech Scholar, Department of Civil Engineering, Poojya Doddappa Appa College of Engineering, Gulbarga - 585102, Karnataka, sharadreddy.patil@gmail.com Abstract Treatment of domestic wastewater is one of the serious problems. Various treatment technologies such as physico-chemical treatment and biological treatment are available for the treatment of domestic wastewater. Owing to the presence of high organic matter, domestic wastewater is well suited for biological treatment. As such in recent years there has been increasing interest in anaerobic treatment of wastewater. Compared to aerobic treatment, anaerobic digestion produces less biomass for the same amount of COD removal compared to aerobic treatment and produces methane up to 95% of the organic matter in the waste stream. The laboratory bench scale experiments were carried out treating domestic wastewater of Gulbarga city in fabricated anaerobic batch reactor of 10 Lts working volume. The domestic wastewater has the following characteristics (average values) pH= 6.9 to 7.95, Total solids = 1140 mg/L, Dissolved solids = 1020 mg/L, Suspended solids = 120 mg/L, Alkalinity = 120 mg/L, Total volatile solids = 890 mg/L, Chloride = 262.2 mg/L, BOD5 = 285 mg/L, COD = 945 mg/L. The experiments were carried out for three months with the initial organic loading rate = 0.945 kg of COD/m3 day. From the study it is concluded that the anaerobic digestion has the efficiency in removal of COD by 90.25% and Total solids removal of 67.27%. Keywords: Domestic wastewater, anaerobic digestion. -----------------------------------------------------------------***------------------------------------------------------------------ 1. INTRODUCTION Poorly treated or untreated domestic wastewater with high levels of pollutants creates major environmental problems when discharged into surface water or land. Such problems may include contamination and deoxygenating of streams and waterways by direct discharge of inadequately treated wastewater [3]. Excessive concentration of nutrients such as nitrogen and phosphorus on wastewater contribute to excessive growth of plants and algal blooms in surface water bodies, which makes the downstream water unsuitable for domestic, agriculture and industrial use. The domestic wastewater contains pathogen which leads to the spread of diseases and odour, when discharged in water bodies or on land for irrigation without any treatment. Over application of domestic wastewater to land results in damage to soil, crops, and contamination of ground water, clogging of soil pores by solids present in wastewater [4]. Domestic wastewater is characterized by low biological oxygen demand (BOD) and chemical oxygen demand (COD) concentrations, turbid, low/high pH. The domestic wastewater contains chlorides, very small amount of solids, oils, fats and detergents and sanitizing agents, as such it requires treatment [2]. The present study was carried out in the Environmental Engineering laboratory, Civil Engineering department, PDA Engineering College, Gulbarga, from the period July 2012 to December 2012, with the following objectives. 1) To determine the characteristics of domestic wastewater. 2) To study the different stages of anaerobic digestion process. 3) To study the anaerobic digestion under optimum condition. 4) To study the effect of organic loading on the performance of anaerobic digestion process. 1.1 Microbiology of Anaerobic Digestion: The biochemistry and kinetics of anaerobic process are complicated and the biological conversion of organic matter into methane is brought about by a group of specific micro organisms. The schematics of the process as described by Gujer, Zehnder (1983) involving the hydrolysis of biopolymers such as carbohydrates, lipids and proteins, oxidation and fermentation of amino acids and sugars, fatty acids, alcohol’s and intermediates and the conversion of acetate and hydrogen into methane are schematically represented in the following figure 1 [1].
  • 2. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________ IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 284 Figure 1: Breakdown of organic polymers in anaerobic digestion. 2. MATERIAL AND METHODOLOGY The laboratory bench scale Batch reactor experiments were carried for treating domestic wastewater of Gulbarga city. As per provisional reports of Census of India, population of Gulbarga city in 2011 AD is 5,32,031 and the out flow of domestic wastewater is 55 MLD. The study was conducted under ambient environmental conditions in fabricated anaerobic reactor of 10 Lts working volume. The domestic wastewater was collected from Nagenahalli nala, NH 218, 2 KM away from PDA college of engineering, towards south of Gulbarga city. During the start up of reactor it was fed with domestic wastewater of 10 Lts having COD of 945 mg/L at organic loading rate 0.945 kg COD/m3 d at room temperature and operated for 90 days. The domestic wastewater characteristics were analysed as per “standard methods for the examination of water and wastewater” (21st edition, 2005) [5]. 3. RESULTS AND DISCUSSION The domestic wastewater was analysed for the following parameters such as pH, BOD, COD, alkalinity, total solids, suspended solids, dissolved solids, total volatile solids and chlorides and the same presented in table 1. Anaerobic digestion of domestic wastewater was conducted in batch reactor. The study was conducted at laboratory temperature varying from 25 – 30 ˚C. The data collected during the study period are discussed in the following section. Table 1: Characteristics of domestic wastewater S No Parameters Unit Value 1 pH - 7.6 – 7.3 2 Alkalinity as CaCO3 mg/L 146 – 135 3 Total solids mg/L 1172 – 1119 4 Dissolved solids mg/L 1054 – 995 5 Suspended solids mg/L 126 – 111 6 Total volatile solids mg/L 901 – 879 7 Chlorides as Cl2 mg/L 276.2 – 251 8 COD mg/L 955 – 935 9 BOD5 at 20 ˚C mg/L 298 – 276 The percentage of COD removal and biogas produced with per kg of COD removed are shown in table 2 and presented in figure 2. The percentage of total solids removal and volume of biogas produced per kg of total solids removal are shown in table 3 and presented in figure 3. The biogas produced (in LPD) during day 10 to day 90 shown in table 4 and presented in figure 4.
  • 3. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________ IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 285 Table 2: COD, percentage of COD removal and volume of Biogas produced per kg of COD removal during day 10 to day 90 S No Experimental periods in days COD (mg/L) Percentage of COD removal Volume of Biogas produced per kg of COD removal (in Lts) 1 10 892.1 5.6 35.85 2 20 795 15.87 20.66 3 30 697.5 26.19 19.79 4 40 591.8 37.37 18.68 5 50 492 47.94 17.88 6 60 393.3 58.38 16.67 7 70 294.4 68.85 15.83 8 80 193.1 79.57 14.49 9 90 92.1 90.25 14.30 Figure 2: Percentage of COD removal and volume of Biogas produced per kg of COD removal during day 10 to day 90 Table 3: Total solids, percentage of Total solids removal and volume of Biogas produced per kg of Total solids removal during day 10 to day 90 S No Experimental periods in days Total solids (mg/L) Percentage of Total solids removal Volume of Biogas produced per kg of Total solids removal (in Lts) 1 10 1053.8 7.56 22.04 2 20 968.9 15.01 18.12 3 30 883.7 22.48 19.11 4 40 794.6 30.30 19.11 0 5 10 15 20 25 30 35 40 0 10 20 30 40 50 60 70 80 90 100 10 20 30 40 50 60 70 80 90 VolumeofBiogasproducedperkgof CODremoval PercentageofCODremoval Experimental periods in days Percentage of COD removal Volume of Biogas produced per kg of COD removal (in Lts)
  • 4. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________ IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 286 5 50 710.1 37.71 18.84 6 60 625.3 45.15 17.87 7 70 537 52.89 17.08 8 80 454.7 60.11 15.91 9 90 373.1 67.27 15.91 Figure 3: Percentage of Total solids removal and volume of Biogas produced per kg of Total solids removal during day 10 to day 90 Table 4: Biogas production during day 10 to day 90 S No Experimental periods in days Biogas produced in LPD 1 10 0.019 2 20 0.031 3 30 0.049 4 40 0.066 5 50 0.081 6 60 0.092 7 70 0.103 8 80 0.109 9 90 0.122 0 5 10 15 20 25 0 10 20 30 40 50 60 70 80 10 20 30 40 50 60 70 80 90 VolumeofBiogasproducedperkgof Totalsolids removal PercentageofTotalsolidsremoval Experimental periods in days Percentage of Total solids removal Volume of Biogas produced per kg of Total solids removal
  • 5. IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308 __________________________________________________________________________________________ IC-RICE Conference Issue | Nov-2013, Available @ http://www.ijret.org 287 Figure 4: Biogas production during day 10 to day 90 CONCLUSIONS Based on the experimental study following conclusions can be drawn 1. It can be concluded from characterization study that the wastewater is highly organic in nature having high value of COD. 2. The maximum COD removal efficiency is 90.25 percent. 3. The maximum total solids removal efficiency is 67.27 percent. 4. The maximum biogas produced is 0.122 LPD on the 90th day. REFERENCES [1] Anna Schnurer and Asa Jarvis – Microbiological handbook for biogas plants, Swedish waste management U2009 march, Swedish Gas Centre report 207. [2] Cheerawit R, Thunwadee T. S, Duangporn K, Tanwat R and Wichuda – Biogas Production from Co – digestion of domestic wastewater and food waste, Health and the Environmental Journal, 2012, Volume 3, no. 2. [3] I. Bodik, S. sedlacek, M. Kulaska and M. Hutnan – Biogas Production in Muncipal Wastewater Treatment Plants, Chemical and Biochemical Engineering, Q. 25(3), 335 – 340 (2011). [4] Metcalf and Eddy – Wastewater Engineering Treatment and Reuse, 4th edition, McGraw – Hill Publishing, New York – 2004. [5] Standard Methods for the examination of Water and Wastewater, 21st edition (APHA, AWWA AND WFF, Washington DC) 2005. 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 10 20 30 40 50 60 70 80 90 BiogasproducedinLPD Experimental periods in days Biogas produced in LPD