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UNIT OPERATION 3

PREPARED BY: CANOY, CLAIRE E.
YR & SEC.
: 2B2- CHEMICAL ENGINEERING
TECHNOLOGY
● Azeotropic distillation refers to processes
whereby a new component (called
the entrainer) is added to the original feed
mixture to form (or nearly form) an
azeotrope with one (or more) of the feed
components.
●The azeotrope is then removed as either the
distillate or the bottoms.
● Usually refers to the specific technique of
adding another component to generate a
new, lower-boiling azeotrope that is
heterogeneous (e.g. producing two,
immiscible liquid phases), such as the
example below with the addition of
benzene to water and ethanol.
● Azeotropic distillation also refers to those
processes in which a new component is added
to an original feed mixture to break an
azeotrope that otherwise would be formed by
the feed components.
● The purpose of deliberately adding the
entrainer is either to separate one component
of a closely boiling pair or to separate one
component of an azeotrope.
The entrainer E is a
medium boiler (i.e. its
boiling point in
intermediate between
components A and B),
or is a low boiler that
can form an
intermediate boiling
maximum azeotrope
with A.
The feed (A and B)
is mixed with the
entrainer E before
entering column C1.
Component B (which
is essentially free of
the azeotrope A-E) is
removed from the
bottom of column C1,
while the overhead
vapour from C1 is fed
to column C2.
Component A is
removed as overhead
product and
entrainer E as the
bottoms product.
The entrainer is
recycled back to
column C1.
● Azeotropic distillation is provided by us to
many of our customers is to break an
azeotrope in distillation.

● It is usually denotes the specific technique of
adding new constituent to produce a novel,
lower-boiling azeotrope that is heterogeneous.
We construct the unit with the specification
provided by the customers.
AZEOTROPIC DISTILLATION

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AZEOTROPIC DISTILLATION

  • 1. UNIT OPERATION 3 PREPARED BY: CANOY, CLAIRE E. YR & SEC. : 2B2- CHEMICAL ENGINEERING TECHNOLOGY
  • 2. ● Azeotropic distillation refers to processes whereby a new component (called the entrainer) is added to the original feed mixture to form (or nearly form) an azeotrope with one (or more) of the feed components. ●The azeotrope is then removed as either the distillate or the bottoms.
  • 3. ● Usually refers to the specific technique of adding another component to generate a new, lower-boiling azeotrope that is heterogeneous (e.g. producing two, immiscible liquid phases), such as the example below with the addition of benzene to water and ethanol.
  • 4. ● Azeotropic distillation also refers to those processes in which a new component is added to an original feed mixture to break an azeotrope that otherwise would be formed by the feed components. ● The purpose of deliberately adding the entrainer is either to separate one component of a closely boiling pair or to separate one component of an azeotrope.
  • 5. The entrainer E is a medium boiler (i.e. its boiling point in intermediate between components A and B), or is a low boiler that can form an intermediate boiling maximum azeotrope with A.
  • 6. The feed (A and B) is mixed with the entrainer E before entering column C1.
  • 7. Component B (which is essentially free of the azeotrope A-E) is removed from the bottom of column C1, while the overhead vapour from C1 is fed to column C2.
  • 8. Component A is removed as overhead product and entrainer E as the bottoms product. The entrainer is recycled back to column C1.
  • 9. ● Azeotropic distillation is provided by us to many of our customers is to break an azeotrope in distillation. ● It is usually denotes the specific technique of adding new constituent to produce a novel, lower-boiling azeotrope that is heterogeneous. We construct the unit with the specification provided by the customers.