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Chemical Reaction
Occurring in Water
Aqueous Solution
• The word aqueousmeans
  pertaining to, related to, similar
  to, or dissolved in water.
• Asolution in which the solvent is
  water.
• Aqueous solutions that conduct electric
  current efficiently contain strong
  electrolytes, while ones that conduct
  poorly are considered to have weak
  electrolytes. Those strong electrolytes
  are substances that are completely
  ionized in water, whereas the weak
  electrolytes exhibit only a small degree of
  ionization in water.
Three important types of
   reactions in water:
Precipitation Reactions
• In a precipitation reaction, an
  anion and a cation contact each
  other and an insoluble ionic
  compound precipitates out of
  solution.
Example:
• When aqueous solutions of silver
  nitrate, AgNO3, and salt, NaCl, are
  mixed, the Ag+ and Cl- combine to
  yield a white precipitate of silver
  chloride, AgCl:
      Ag+(aq) + Cl-(aq) → AgCl(s)
Acid-Base Reactions
• Is a chemical reaction that
  occurs between an acid and
  a base
Example:
• When hydrochloric acid, HCl, and sodium
  hydroxide, NaOH, are mixed, the H+
  reacts with the OH- to form water:
          H+(aq) + OH-(aq) → H2O
  HCl acts as an acid by donating H+ ions or
  protons and NaOH acts as a base,
  furnishing OH- ions.
Oxidation-Reduction Reactions
  – In an oxidation-reduction or redox reaction, there
    is an exchange of electrons between two
    reactants. The species that loses electrons is said
    to be oxidized. The species that gains electrons is
    said to be reduced. An example of a redox
    reaction occurs between hydrochloric acid and
    zinc metal, where the Zn atoms lose electrons and
    are oxidized to form Zn2+ ions:
• Zn(s) → Zn2+(aq) + 2e-
– The H+ ions of the HCl gain electrons and
  are reduced to H atoms, which combine to
  form H2 molecules:
        2H+(aq) + 2e- → H2(g)
– The overall equation for the reaction
  becomes:
  Zn(s) + 2H+(aq) → Zn2+(aq) + H2(g)

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Chemical Reactions in Aqueous Solutions

  • 2. Aqueous Solution • The word aqueousmeans pertaining to, related to, similar to, or dissolved in water. • Asolution in which the solvent is water.
  • 3. • Aqueous solutions that conduct electric current efficiently contain strong electrolytes, while ones that conduct poorly are considered to have weak electrolytes. Those strong electrolytes are substances that are completely ionized in water, whereas the weak electrolytes exhibit only a small degree of ionization in water.
  • 4. Three important types of reactions in water:
  • 5. Precipitation Reactions • In a precipitation reaction, an anion and a cation contact each other and an insoluble ionic compound precipitates out of solution.
  • 6. Example: • When aqueous solutions of silver nitrate, AgNO3, and salt, NaCl, are mixed, the Ag+ and Cl- combine to yield a white precipitate of silver chloride, AgCl: Ag+(aq) + Cl-(aq) → AgCl(s)
  • 7. Acid-Base Reactions • Is a chemical reaction that occurs between an acid and a base
  • 8. Example: • When hydrochloric acid, HCl, and sodium hydroxide, NaOH, are mixed, the H+ reacts with the OH- to form water: H+(aq) + OH-(aq) → H2O HCl acts as an acid by donating H+ ions or protons and NaOH acts as a base, furnishing OH- ions.
  • 9. Oxidation-Reduction Reactions – In an oxidation-reduction or redox reaction, there is an exchange of electrons between two reactants. The species that loses electrons is said to be oxidized. The species that gains electrons is said to be reduced. An example of a redox reaction occurs between hydrochloric acid and zinc metal, where the Zn atoms lose electrons and are oxidized to form Zn2+ ions: • Zn(s) → Zn2+(aq) + 2e-
  • 10. – The H+ ions of the HCl gain electrons and are reduced to H atoms, which combine to form H2 molecules: 2H+(aq) + 2e- → H2(g) – The overall equation for the reaction becomes: Zn(s) + 2H+(aq) → Zn2+(aq) + H2(g)