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1.Sulfate attack in concrete and mortar
Sulfate attack can be 'external' or 'internal'.
External: due to penetration of sulfates in solution, in groundwater for example, into the concrete
from outside.
Internal: due to a soluble source being incorporated into the concrete at the time of mixing,
gypsum in the aggregate
External sulfate attack:
This is the more common type and typically occurs where water containing dissolved sulfate
penetrates the concrete. A fairly well-defined reaction front can often be seen in polished
sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the
composition and microstructure of the concrete will have changed. These changes may vary in
type or severity but commonly include:
Internal sulfate attack:
Occurs where a source of sulfate is incorporated into the concrete when mixed. Examples
include the use of sulfate-rich aggregate, excess of added gypsum in the cement or
contamination. Proper screening and testing procedures should generally avoid internal sulfate
attack.
2.Delayed ettringite formation
Delayed ettringite formation (DEF) is a special case of internal sulfate attack.
Delayed ettringite formation has been a significant problem in many countries. It occurs in
concrete which has been cured at elevated temperatures, for example, where steam curing has
been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It
can also occur in large concrete pours where the heat of hydration has resulted in high
temperatures within the concrete.
DEF causes expansion of the concrete due to ettringite formation within the paste and can cause
serious damage to concrete structures. DEF is not usually due to excess sulfate in the cement, or
from sources other than the cement in the concrete. Although excess sulfate in the cement would
be likely to increase expansion due to DEF, it can occur at normal levels of cement sulfate.
A key point in understanding DEF is that ettringite is destroyed by heating above about 70
degrees C.
3.Effect of Corrosion
One of the major degradation processes of reinforced concrete structures is the corrosion of the
steel reinforcement. The main reason associated with the deterioration of reinforced concrete due
to reinforcement corrosion is not the reduction in mechanical strength of the reinforcing bar
itself, but rather than that the pressure exerted from the expansion of the corrosion products. This
may result in damage of the structures due to expansion, cracking and eventually spalling of the
concrete cover. In addition to this, the damage of construction may be caused by loss of bond
between reinforcement and concrete and loss of reinforcement cross-sectional area.
Solution
1.Sulfate attack in concrete and mortar
Sulfate attack can be 'external' or 'internal'.
External: due to penetration of sulfates in solution, in groundwater for example, into the concrete
from outside.
Internal: due to a soluble source being incorporated into the concrete at the time of mixing,
gypsum in the aggregate
External sulfate attack:
This is the more common type and typically occurs where water containing dissolved sulfate
penetrates the concrete. A fairly well-defined reaction front can often be seen in polished
sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the
composition and microstructure of the concrete will have changed. These changes may vary in
type or severity but commonly include:
Internal sulfate attack:
Occurs where a source of sulfate is incorporated into the concrete when mixed. Examples
include the use of sulfate-rich aggregate, excess of added gypsum in the cement or
contamination. Proper screening and testing procedures should generally avoid internal sulfate
attack.
2.Delayed ettringite formation
Delayed ettringite formation (DEF) is a special case of internal sulfate attack.
Delayed ettringite formation has been a significant problem in many countries. It occurs in
concrete which has been cured at elevated temperatures, for example, where steam curing has
been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It
can also occur in large concrete pours where the heat of hydration has resulted in high
temperatures within the concrete.
DEF causes expansion of the concrete due to ettringite formation within the paste and can cause
serious damage to concrete structures. DEF is not usually due to excess sulfate in the cement, or
from sources other than the cement in the concrete. Although excess sulfate in the cement would
be likely to increase expansion due to DEF, it can occur at normal levels of cement sulfate.
A key point in understanding DEF is that ettringite is destroyed by heating above about 70
degrees C.
3.Effect of Corrosion
One of the major degradation processes of reinforced concrete structures is the corrosion of the
steel reinforcement. The main reason associated with the deterioration of reinforced concrete due
to reinforcement corrosion is not the reduction in mechanical strength of the reinforcing bar
itself, but rather than that the pressure exerted from the expansion of the corrosion products. This
may result in damage of the structures due to expansion, cracking and eventually spalling of the
concrete cover. In addition to this, the damage of construction may be caused by loss of bond
between reinforcement and concrete and loss of reinforcement cross-sectional area.

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1.Sulfate attack in concrete and mortarSulfate attack can be ext.pdf

  • 1. 1.Sulfate attack in concrete and mortar Sulfate attack can be 'external' or 'internal'. External: due to penetration of sulfates in solution, in groundwater for example, into the concrete from outside. Internal: due to a soluble source being incorporated into the concrete at the time of mixing, gypsum in the aggregate External sulfate attack: This is the more common type and typically occurs where water containing dissolved sulfate penetrates the concrete. A fairly well-defined reaction front can often be seen in polished sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and microstructure of the concrete will have changed. These changes may vary in type or severity but commonly include: Internal sulfate attack: Occurs where a source of sulfate is incorporated into the concrete when mixed. Examples include the use of sulfate-rich aggregate, excess of added gypsum in the cement or contamination. Proper screening and testing procedures should generally avoid internal sulfate attack. 2.Delayed ettringite formation Delayed ettringite formation (DEF) is a special case of internal sulfate attack. Delayed ettringite formation has been a significant problem in many countries. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It can also occur in large concrete pours where the heat of hydration has resulted in high temperatures within the concrete. DEF causes expansion of the concrete due to ettringite formation within the paste and can cause serious damage to concrete structures. DEF is not usually due to excess sulfate in the cement, or from sources other than the cement in the concrete. Although excess sulfate in the cement would be likely to increase expansion due to DEF, it can occur at normal levels of cement sulfate. A key point in understanding DEF is that ettringite is destroyed by heating above about 70 degrees C.
  • 2. 3.Effect of Corrosion One of the major degradation processes of reinforced concrete structures is the corrosion of the steel reinforcement. The main reason associated with the deterioration of reinforced concrete due to reinforcement corrosion is not the reduction in mechanical strength of the reinforcing bar itself, but rather than that the pressure exerted from the expansion of the corrosion products. This may result in damage of the structures due to expansion, cracking and eventually spalling of the concrete cover. In addition to this, the damage of construction may be caused by loss of bond between reinforcement and concrete and loss of reinforcement cross-sectional area. Solution 1.Sulfate attack in concrete and mortar Sulfate attack can be 'external' or 'internal'. External: due to penetration of sulfates in solution, in groundwater for example, into the concrete from outside. Internal: due to a soluble source being incorporated into the concrete at the time of mixing, gypsum in the aggregate External sulfate attack: This is the more common type and typically occurs where water containing dissolved sulfate penetrates the concrete. A fairly well-defined reaction front can often be seen in polished sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and microstructure of the concrete will have changed. These changes may vary in type or severity but commonly include: Internal sulfate attack: Occurs where a source of sulfate is incorporated into the concrete when mixed. Examples include the use of sulfate-rich aggregate, excess of added gypsum in the cement or contamination. Proper screening and testing procedures should generally avoid internal sulfate attack. 2.Delayed ettringite formation Delayed ettringite formation (DEF) is a special case of internal sulfate attack. Delayed ettringite formation has been a significant problem in many countries. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It
  • 3. can also occur in large concrete pours where the heat of hydration has resulted in high temperatures within the concrete. DEF causes expansion of the concrete due to ettringite formation within the paste and can cause serious damage to concrete structures. DEF is not usually due to excess sulfate in the cement, or from sources other than the cement in the concrete. Although excess sulfate in the cement would be likely to increase expansion due to DEF, it can occur at normal levels of cement sulfate. A key point in understanding DEF is that ettringite is destroyed by heating above about 70 degrees C. 3.Effect of Corrosion One of the major degradation processes of reinforced concrete structures is the corrosion of the steel reinforcement. The main reason associated with the deterioration of reinforced concrete due to reinforcement corrosion is not the reduction in mechanical strength of the reinforcing bar itself, but rather than that the pressure exerted from the expansion of the corrosion products. This may result in damage of the structures due to expansion, cracking and eventually spalling of the concrete cover. In addition to this, the damage of construction may be caused by loss of bond between reinforcement and concrete and loss of reinforcement cross-sectional area.