3. What is air pollution?What is air pollution?
contamination of thecontamination of the
air by noxious gasesair by noxious gases
and minute particlesand minute particles
of solid and liquidof solid and liquid
matter (particulates)matter (particulates)
in concentrations thatin concentrations that
endanger healthendanger health
Air pollution onlyAir pollution only
occurs outdoorsoccurs outdoors
4. Sources of Outside Air PollutionSources of Outside Air Pollution
Combustion of gasoline andCombustion of gasoline and
other hydrocarbon fuels inother hydrocarbon fuels in
cars, trucks, and airplanescars, trucks, and airplanes
Burning of fossil fuels (oil, coal,Burning of fossil fuels (oil, coal,
and dinosaur bones)and dinosaur bones)
InsecticidesInsecticides
HerbicidesHerbicides
Everyday radioactive falloutsEveryday radioactive fallouts
Dust from fertilizersDust from fertilizers
Mining operationsMining operations
Livestock feedlotsLivestock feedlots
5. A major form of air pollution is emissionsA major form of air pollution is emissions
given off by vehicles.given off by vehicles.
The number of cars in EU has doubledThe number of cars in EU has doubled
between 1970 and 1994 –between 1970 and 1994 – 3% per year3% per year
6. What’s in smogWhat’s in smog
particulatesparticulates
(especially lead)(especially lead)
nitrous oxidesnitrous oxides
potassiumpotassium
Carbon monoxideCarbon monoxide
Other toxic chemicalsOther toxic chemicals
7. Sources of Indoor pollutionSources of Indoor pollution
Efficient insulationEfficient insulation
BacteriaBacteria
Molds and mildewsMolds and mildews
VirusesViruses
animal dander and cat salivaanimal dander and cat saliva
plantsplants
house dusthouse dust
MitesMites
CockroachesCockroaches
pollenpollen
8. Effects on the environmentEffects on the environment
Acid rainAcid rain
Ozone depletionOzone depletion
Global warmingGlobal warming
In human population-In human population-
respiratory problems,respiratory problems,
allergies, strengthensallergies, strengthens
lugs, and a risk forlugs, and a risk for
cancercancer
9. Acid rainAcid rain
contains high levels of sulfuriccontains high levels of sulfuric
or nitric acidsor nitric acids
contaminate drinking watercontaminate drinking water
and vegetationand vegetation
damage aquatic lifedamage aquatic life
erode buildingserode buildings
Alters the chemical equilibriumAlters the chemical equilibrium
of some soilsof some soils
10.
11. StrategiesStrategies
Air Quality ManagementAir Quality Management
PlanPlan
Development of newDevelopment of new
technology- electric cars,technology- electric cars,
cleaner fuels, lowcleaner fuels, low
nitrogen oxide boilersnitrogen oxide boilers
and water healers, zeroand water healers, zero
polluting paints, lesspolluting paints, less
polluting BBQ lighterpolluting BBQ lighter
fluidsfluids
Use of natural gasUse of natural gas
CarpoolingCarpooling
Follow the laws enactedFollow the laws enacted
12. Urban EmissionsUrban Emissions
•There are small emissions of NOx from industrial
processes
•The main emissions are from combustion.
•There is negligible nitrogen in gasoline or diesel fuels so
the nitrogen oxides arise from the N2 and O2 in the air.
•Sulphur dioxides arise from the sulphur present in most
fuels.
•Particulate matter describes matter below 10μm
aerodynamic diameter.
13. Role of Engines and FuelRole of Engines and Fuel
Different engines and fuel combinationsDifferent engines and fuel combinations
give out different emissions in differentgive out different emissions in different
quantities.quantities.
Some engines have catalysts whichSome engines have catalysts which
effectively remove part of the harmfuleffectively remove part of the harmful
gases.gases.
14. Catalytic Converters andCatalytic Converters and
Particle TrapsParticle Traps
Catalytic converters can be fitted to cars to reduce NOxCatalytic converters can be fitted to cars to reduce NOx
emissions.emissions.
CO + HC + NOxCO + HC + NOx HH22O + NO + N22 + CO+ CO22
Platinum HoneycombPlatinum Honeycomb
Particle traps can be used to reduce PM10 and NOx, butParticle traps can be used to reduce PM10 and NOx, but
the effectiveness is severely reduced if the fuel thethe effectiveness is severely reduced if the fuel the
vehicle burns has a high sulphur content.vehicle burns has a high sulphur content.
The major target in the battle for cleaner cities is diesel.The major target in the battle for cleaner cities is diesel.
15. STRATEGIESTRATEGIE
The Clean Air forThe Clean Air for EuropeEurope (CAFE) approach:(CAFE) approach:
Based on scientific knowledgeBased on scientific knowledge
Using best available, quality-controlled real-world dataUsing best available, quality-controlled real-world data
With close involvement of stakeholders:With close involvement of stakeholders:
1.1. Project future emissions and air quality resulting fromProject future emissions and air quality resulting from
full implementation of current EU legislationfull implementation of current EU legislation
2.2. Explore scope and costs for further measuresExplore scope and costs for further measures
3.3. Analyze cost-effective policy scenariosAnalyze cost-effective policy scenarios
4.4. Estimate benefits of policy scenariosEstimate benefits of policy scenarios
16. Particulate Matter (PM ) PollutionParticulate Matter (PM ) Pollution
- Traffic emissions including diesel engines
- Small combustion sources burnng coal and wood
- Reductions of SO2, N0x, NH3 and VOC
17. Une pincée de NOx et quelques photons
pour faire un peu d’ozone
(λ < 430 nm)NO + ONO2 + hν
O + O2 O3O3
Mais pas trop de NOx ce qui détruit une
partie de l'ozone formé,
Ni trop de COV ce qui en produit de trop !
NO2 + O2
O3 + NO
RO2 + NO
La cuisine photochimique : mais c’est très simple !