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Identifying contaminants of concern for ground water monitoring and water supply planning
                                                                              Whitney Morrison, Chris Rokicki, and Treavor H. Boyer*
                                                               Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL
                                                                        *thboyer@ufl.edu ~ 352.846.3351 ~ www.ees.ufl.edu/homepp/boyer


                           MOTIVATION                                                                                                                                          PROCESS SCHEMATICS
• Update/expand a ground water quality monitoring report that is                                                                                                        Material flow               Process                Releases
used by the Florida Department of Environmental Protection                                       Surfactants
                                                                                                 Wash water
(FDEP).
• The report contains contaminant information and recommends                                                                                                                                                                                 Aluminum,
ground water monitoring parameters for prevalent industries in                                                              Car                +e.g.
                                                                                                                                                   Chemical
                                                                                                                                                                                                                                               calcium,
Florida.                                                                                                                 washing               oxygen demand                                                                                chloride, iron,
• This document will generate new knowledge to:                                                                          facilities            (COD), oil & grease                                                                            sulfate, &
                                                                                                   Washing
                                                                                                                                                                                                                                             wastewater
  - Aid permitting and planning in the district offices.                                           vehicles
                                                                                                                                                  Surfactants
  - Assist site/field investigations for ground water contamination.                                                                                +COC                                                                                                                  Domestic
  - Create future regulations pertaining to emerging contaminants                                                     Ground water                Wastewater                                                                                                             wastewater                 +e.g. BOD5,
    related to health hazards.                                                                                        contamination                                            Solid waste                                                                                treatment                 alkalinity, & COD
                                                                                                                                                                                                                                                   Treating
  - Educate the general public.                                                                                                                                                 Rainfall                                                                                   facilities
                                                                                                                                                                                                                                                  wastewater                                          Aluminum,
                                                                                                    *Wood                                                                                                                                                                                              calcium,
                                                                                                 preservatives                                                                                        Solid       +e.g. Biochemical                                                                 chloride, iron,
                                                                                                 **Conditioning                                                                                                                                                         Ground water                sulfate, +COC,
                           INDUSTRIES                                                                water
                                                                                                                                                                               Managing
                                                                                                                                                                                                      waste
                                                                                                                                                                                                    facilities
                                                                                                                                                                                                                  oxygen demand (BOD5),
                                                                                                                                                                                                                  alkalinity, & COD                                     contamination               & wastewater
                                                                                                                                                                              solid waste
                                                                                                                                Wood                                                                                       +COC

              Industry Type Count (%) Volume (%)                                                                             preserving                                                                                   Leachate                 Ammonia
                                                                                                                              facilities                                                          Ground water                                      Sulfur
                  Mining        5         20                                                          Treating
                                                                                                                                                                                                  contamination
                                                                                                       wood                                                *Wood                                                                                  Wash water
                Agriculture    25         35
                                                                                                                                                        preservatives
                 Services      35          5                                                                                                               +COC
              Manufacturing    35         40                                                                               Ground water                                                                                                                                   Phosphate
                                                                                                                                                         Wastewater
                                                                                                                           contamination                                                                                                                                  rock mines
                                                                                                                                                                                                                                                    Mining
                                                                                                                                                                                                                                                  phosphate
   Count (%) (n = 512)               Volume (%) (500 million gallons per day)                 *Creosote, copper, chromium, pentachlorophenol , and other chlorophenols                                                                                                                               Ammonia,
                                                                                              **Conditioning is used to burst the wood cells under pressure
                                                                                                                                                                                                                                                     ore
               5
                                                                   20                         +e.g. ammonia, phosphorus, & arsenic                                                                                                                                                                 Sulfur, +COC, &
      35
                                                                                                                                                                                                                                                                        Ground water                   *Slimes
                      25                              40                                                                                                                                                                                                                contamination
                                                                                                               CONTAMINANT FLOW                                                                                                           +e.g.pH, aluminum, & calcium
                                                                    35                                                                                                                                                                    *Slimes are a slurry of fine clay particles and phosphate minerals, and they
                                                           5                                                                                                                                                                              contain the wastewater effluents produced in the phosphate mining process
               35                                                                       Contaminants of                  Water                         Activities and                    Water
                                                                                           concern                       flows                          processes                       sources
• This data is specific to Florida and does not include domestic wastewater.
• Examples of the industry types:
                                                                                                                                                                                                                                                               IMPACT
  - Mining: Phosphate rock mines, limestone mining, sand mines, & clay mines
                                                                                                               Mining                   Agriculture                Municipal solid
  - Agriculture: Citrus fruit & egg producers                                                                                                                      waste landfill
  - Services: Car washes & coin-operated laundries and cleaning
                                                                                                                                                                                                                                                                     Health
  - Manufacturing: Wood preserving, pulp and paper mills, & fertilizer production                                                                                                                                                                                   hazards


                           METHODS                                                                                                                                                                                                    Education &                    Final
                                                                                                                                                                                                                                                                                             Permitting
                                                                                                                                                                                                                                       Outreach                     Report

Task 1 • Identified information sources, which included:
                                                                                      Storm                          *Ground                                   Drinking                             Drinking
         - Previous FDEP reports                                                                                                                                water                                                                                                Site
         - U.S. EPA Sector Notebooks and Development                                  water                           water                                                                          water                                                      Investigations
           Documents
                                                                                                                                                              treatment
         - Peer-reviewed journal articles
Task 2 • Identified contaminants of concern and indicator                                                                                                                                                                                 ACKNOWLEDGEMENTS
       parameters using sources found in Task 1.
Task 3 • Described each industry and its processes, including:                                                Services                Domestic                       Manufacturing
                                                                                                                                                                                                                             I would like to thank Dr. Treavor Boyer, Chris Rokicki, and Sarah
         - Raw materials                                                                                                              wastewater                                                                             Comstock for their hard work on this project. This work was funded
         - Final product(s)                                                                                                           treatment                                                                              by Florida Department of Environmental Protection Contract No.
         - Wastewater effluent                                                                                                                                                                                               GW278 Contaminants of Concern. I would also like to thank our
       • Categorize contaminants of concern and indicator                                                                                                                                                                    Project Manager Ms. Linda Ann Clemens for her assistance
       parameters.                                                                                                           *Includes surface water infiltration
                                                                                                                                                                                                                             throughout the project.

                                                                                    2011 AEESP Education and Research Conference

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Identifying contaminants of concern for ground water monitoring and water supply planning

  • 1. Identifying contaminants of concern for ground water monitoring and water supply planning Whitney Morrison, Chris Rokicki, and Treavor H. Boyer* Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL *thboyer@ufl.edu ~ 352.846.3351 ~ www.ees.ufl.edu/homepp/boyer MOTIVATION PROCESS SCHEMATICS • Update/expand a ground water quality monitoring report that is Material flow Process Releases used by the Florida Department of Environmental Protection Surfactants Wash water (FDEP). • The report contains contaminant information and recommends Aluminum, ground water monitoring parameters for prevalent industries in Car +e.g. Chemical calcium, Florida. washing oxygen demand chloride, iron, • This document will generate new knowledge to: facilities (COD), oil & grease sulfate, & Washing wastewater - Aid permitting and planning in the district offices. vehicles Surfactants - Assist site/field investigations for ground water contamination. +COC Domestic - Create future regulations pertaining to emerging contaminants Ground water Wastewater wastewater +e.g. BOD5, related to health hazards. contamination Solid waste treatment alkalinity, & COD Treating - Educate the general public. Rainfall facilities wastewater Aluminum, *Wood calcium, preservatives Solid +e.g. Biochemical chloride, iron, **Conditioning Ground water sulfate, +COC, INDUSTRIES water Managing waste facilities oxygen demand (BOD5), alkalinity, & COD contamination & wastewater solid waste Wood +COC Industry Type Count (%) Volume (%) preserving Leachate Ammonia facilities Ground water Sulfur Mining 5 20 Treating contamination wood *Wood Wash water Agriculture 25 35 preservatives Services 35 5 +COC Manufacturing 35 40 Ground water Phosphate Wastewater contamination rock mines Mining phosphate Count (%) (n = 512) Volume (%) (500 million gallons per day) *Creosote, copper, chromium, pentachlorophenol , and other chlorophenols Ammonia, **Conditioning is used to burst the wood cells under pressure ore 5 20 +e.g. ammonia, phosphorus, & arsenic Sulfur, +COC, & 35 Ground water *Slimes 25 40 contamination CONTAMINANT FLOW +e.g.pH, aluminum, & calcium 35 *Slimes are a slurry of fine clay particles and phosphate minerals, and they 5 contain the wastewater effluents produced in the phosphate mining process 35 Contaminants of Water Activities and Water concern flows processes sources • This data is specific to Florida and does not include domestic wastewater. • Examples of the industry types: IMPACT - Mining: Phosphate rock mines, limestone mining, sand mines, & clay mines Mining Agriculture Municipal solid - Agriculture: Citrus fruit & egg producers waste landfill - Services: Car washes & coin-operated laundries and cleaning Health - Manufacturing: Wood preserving, pulp and paper mills, & fertilizer production hazards METHODS Education & Final Permitting Outreach Report Task 1 • Identified information sources, which included: Storm *Ground Drinking Drinking - Previous FDEP reports water Site - U.S. EPA Sector Notebooks and Development water water water Investigations Documents treatment - Peer-reviewed journal articles Task 2 • Identified contaminants of concern and indicator ACKNOWLEDGEMENTS parameters using sources found in Task 1. Task 3 • Described each industry and its processes, including: Services Domestic Manufacturing I would like to thank Dr. Treavor Boyer, Chris Rokicki, and Sarah - Raw materials wastewater Comstock for their hard work on this project. This work was funded - Final product(s) treatment by Florida Department of Environmental Protection Contract No. - Wastewater effluent GW278 Contaminants of Concern. I would also like to thank our • Categorize contaminants of concern and indicator Project Manager Ms. Linda Ann Clemens for her assistance parameters. *Includes surface water infiltration throughout the project. 2011 AEESP Education and Research Conference