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FOOD ADDITIVES
WHAT ARE FOOD ADDITIVES
 Food additives may be defined as follows: a substance or
mixture of substances, other than a basic foodstuff, which is
present in a food as a result of any aspect of production,
processing, storage, or packaging. The term does not
include chance contaminants.
 Legally, according to the FDA, the term refers to "any
substance the intended use of which results or may
reasonably be expected to result, directly or indirectly in its
becoming a component or otherwise affecting the
characteristics of any food."
 This definition includes any substance used in the
production, processing, treatment, packaging,
transportation or storage of food.
NEED FOR FOOD ADDITIVE
 Preservation
 Nutrition
 Convenience Foods
 Appealing Foods
 To aid in the processing
and preparation of foods
TYPES OF FOOD ADDITIVE
 Direct/ Intentional Additives: Food additives are those that are
added to a food for a specific purpose in that food. For example,
xanthan gum -- used in salad dressings, chocolate milk, bakery
fillings, puddings and other foods to add texture.
 Indirect/Unintentional Additives: They are those that become part
of the food in trace amounts due to its packaging, storage or other
handling. Examples include radioactive fallout, chemicals used in
agricultural production and accidental contaminants during food
processing
TYPES OF DIRECT FOOD ADDITIVES
 Preservatives
 Food flavours
 Anti-caking agents
 Food colours
 Bulking agents
 Thickners
 Sweetners
 Stabilizers
 Acidulants
 Humectants
 Emulsifiers
 Antioxidants
 Antioxidants act as preservatives by inhibiting the effects of
oxygen on food, and can be beneficial to health.
 Examples - Ascorbic acid (Vit C), Tocopherols (Vit E).
 Chelating Agents
 They serve as scavengers of metals which catalyze
oxidation.
 Examples - EDTA (ethylenediaminetetraacetic acid) and
citric acid.
 FOOD COLORING
 Colorings are added to food to replace colors lost during
preparation, or to make food look more attractive.
 Natural colorants are Caramel coloring (E150), Annatto
(E160b), chlorophyll (E140), Cochineal (E120), Betanin
extracted from beets, Turmeric (curcuminoids, E100),
Grape Skin Extract etc.
 Synthetic colorants are FD&C Blue No.1 (E133), FD&C
Green No.3 (E143), FD&C Red No. 40 (E129) etc.
 ANTIFOAMING AGENTS
 Antifoaming agents reduce or prevent foaming in foods.
 Examples- Polydimethylsiloxane (a type of silicone). Silicone oil
is also added to cooking oil to prevent foaming in deep-frying.
 CURING AGENTS
 These are additives used to preserve (cure) meats, give them
desirable colour and flavor, discourage growth of micro-
organisms, and prevent toxin formation.
 Example- Sodium nitrite has been used for centuries as a
preservative and colour stabilizer in meat and fish products.
 EMULSIFIERS
 Emulsifiers allow water and oils to remain mixed together in an
emulsion, as in mayonnaise, ice cream, and homogenized milk. E.g
Lecithin
 FLAVOURS AND FLAVOUR ENHANCERS
 Flavouring additives are the ingredients, both naturally occurring and
added, which give the characteristic flavor to foods.
 Flavour enhancers are not flavours themselves but they amplify the
flavours of other substance through a synergistic effect.
 Examples – Artifical flavours such as MSG and natural flavours e.g
extracted from milk, egg,nuts e.t.c
 ANTICAKING AGENTS
 Anticaking agents keep powders such as milk powder from caking
or sticking.
 Examples - Sodium bicarbonate (E500), Calcium silicate (E552),
Sodium aluminosilicate (E554), Bentonite (E558)
 BULKING AGENTS
o Bulking agents such as starch are additives that increase the
mass and volume of a food without affecting its nutritional value.
o Examples- Cellulose, Inulin, Polydextrose
 These are bleaching and maturing agents; usually, they both
bleach and “mature” the flour.
 Freshly milled flour has a yellowish tint and yields a weak dough
that produces poor bread. Both the colour and baking properties
improve by storing the flour for several months before making
bread. Example: Benzoyl peroxide.
 LEAVENING AGENTS
o Leavening agents produce light fluffy baked goods. Originally, yeast
was used almost exclusively to leaven baked products. It is still an
important leavening agent in bread making.
o When yeast is used, ammonium salts are added to dough to provide a
ready source of nitrogen for yeast growth..
 FLOUR IMPROVERS
 HUMECTANTS
 Humectants prevent foods from drying out by retaining moisture.
 Examples – Glycerol/propylene glycol (E1520), and glyceryl triacetate
(E1518), sorbitol (E420).
 PRESERVATIVES
o Preservatives prevent or inhibit spoilage of food due to fungi, bacteria and
other microorganisms.
o Examples- Natural preservatives such as vinegar, sugar and artificial
preservatives such as Benzoates, Nitrites, Sulphites e.t.c
 STABILZERS
o Stabilizers, thickeners and gelling agents, like agar or pectin (used in jam for
example) give foods a firmer texture. They help to stabilize emulsions.
o Examples- Alginic acid, pectin, gelatin, calcium chloride e.t.c
 ACIDULANTS
 Food acids are added to make flavors "sharper", and also
act as preservatives and antioxidants.
 Examples- vinegar, citric acid, tartaric acid, malic acid,
fumaric acid, and lactic acid.
 ACID REGULATORS
 Acidity regulators are used to change or otherwise control
the acidity and alkalinity of foods.
 Examples - Acetic acid, Citric acid
 GLAZING AGENTS
 Glazing agents provide a shiny appearance or protective coating
to foods.
 Stearic acid (E570)
 Beeswax (E901)
 Candelilla wax (E902)
 FLOUR TREATMENT AGENTS
 Flour treatment agents are added to flour to improve its color or its
use in baking.
 azodicarbonamide (E927)
 carbamide (E927b)
SWEETENERS
 Sweeteners are added to foods for flavoring. Some sweeteners
other than sugar are added to keep the food energy (calories)
low, or because they have beneficial effects for diabetes mellitus
and tooth decay and diarrhea.
 Examples– Natural Sweeteners found in sugar cane,
stevia,maltodextrins, sugar beet or corn syrup and artificial
sweeteners such as aspartame, acesulfame K, sugar alcohols,
sucralose, saccharin e.t.c
 NUTRIENT SUPPLEMENTS
o Nutrient supplements restore values lost in processing or storage, or
ensure higher nutritional value than what nature may have provided.
o When foods are processed, there may be loss of some nutrients and
additives may be added to restore the original value.
o For example, vitamin C is added to canned citrus fruits to make up the
loss of the vitamin during processing.
 THICKENERS
 Thickeners are substances which, when added to the mixture,
increase its viscosity without substantially modifying its other
properties.
 Example- arrowroot, cornstarch, potato starch, vegetable gums
(guar gum, locust bean gum, and xanthan gum, protein (Proteins
used as food thickeners include collagen, egg whites etc.
OTHER FOOD ADDITIVES
 Clarifying agents like bentonite, gelatins, synthetic resins (polyamides
and poly vinyl pyrrolidone) are used to remove haziness or sediments
and oxidative deterioration products in fruit juices, beers and wines.
 Enzymes are added to bring about desirable changes; rennin for
producing curd and cheese, papain for tenderizing meat, and pectinase
for clarifying beverages.
 Firming agents like aluminium sulphates and calcium slats are used t
keep the tissues of fruits and vegetables crisp.
 Freezing agents like liquid nitrogen and dichloro fluoro methane, which
are extremely volatile and rapidly evaporate at ordinary temperatures,
are used to chill foods.
 Solvents like alcohol, propylene glycol and glycerine are used to
dissolve suspended flavours, colours, and many other ingredients.
 Packing gases, such as inert gases, are added to packets of instant
foods to prevent oxidative and many other changes
NUMBERING OF ADDITIVES
 Each additive is assigned a unique number, termed as "E
numbers“ which is used in Europe for all approved
additives.
 This numbering scheme has now been adopted and
extended by the Codex Alimentarius Commission
E 100 – Curcumin, turmeric
E 123 – Amaranth
E 140 – Chlorophylls, Chlorophyllin
E 210 – Benzoic acid
E 224 – Potassium metabisulphite
E 300 – Ascorbic acid
E 330 – Citric acid
19
 Federal government regulations generally require that all food ingredients,
including direct additives, be listed on the package label by their common
names in order of weight.
LABELING
o The EU (European Union) countries have drawn a list of 314 safe food
additives. Each of them is given an E number.
100-199 colors
200-299 preservatives
300-399 antioxidants and acidity regulators
400-499 thickeners, stabilizers and emulsifiers
500-599
600-699 flavor enhancers
700-799 antibiotics
900-999
1100-1599 Additional chemicals
ph regulators, anti-caking agents
miscelaneous
Permissible Limits of Food Additives
ESTABLISHING PERMISSIBLE LIMITS OF FOOD ADDITIVES
The limit is established with due importance to following factors:
 The estimated level of consumption of the food product by the
consumers for which the additive is proposed.
 Finding out minimum levels which would produce significant
deviation from physiological behavior.
 Legal control over the use of food additives. This can be
accomplished only when a list of permitted additives exists with
specified safe levels and toxic levels.
 Stringent labeling on foods i.e. declaring the usage of additives in
food and their quantities.
 Employing trained food inspectors, food control laboratories and
reliable analytical methods are of utmost important for regulation /
control over usage of food additives.
SOME OF THE PERMITTED GRAS ADDITIVES AND
TOLERANCES
Antio
Additive Food Used Function Tolerance
Al, Ca silicate Table Salt Anti-caking agent 2.0 %
BHA Various foods
Various foods Antioxidant
0.3%
≤0.02%
BHT
Caffeine Cola type beverages Multi-purpose 0.02%
Ca. Silicate Table
Baking powder
Cashew nuts
Anti-caking
Fumigants
Flavouring agents
2.0 %
5.0 %
Ethyl formarate Baked goods
Pudding fillings
Flavouring agents 0.03%
0.05%
KMS General preservative Antimicrobial GMP
Sodium bisulphite Various foods Antimicrobial GMP
SO2 Wines, fruit juices,
dehydrated foods
Antimicrobial GMP
Stearyl citrate Various fruits Sequestrants 0.15%
Thiodipropionic
acid
Various fat containing
foods
Antioxidants 0.02 %
ADI’S ( ACCEPTABLE DAILY INTAKE) OF SOME FOOD
ADDITIVES:
Addtive ADI
Mg/kg
Function
EDTA 2.5 Preservative
Sequestrant
BHA 0.5 Antioxidant
BHT 0.5 Antioxidant
Sodium nitrate 5.0 Curing, Colour fixation
Sodium stearyl formal 0.2 Stabilizing is non-yeast
leavened.
Conditioning agent is yeast
leavened
Glycine 25 Stabilizer
Succinylated monoglyceride
Emusifier, dough conditioner
Polysorbate 25 Emulsifies
Polypropyl glycoaginate 25 Stabilizer
Emulsifier
TOXICITY AND ADVERSE EFFECTS OF FOOD
ADDITIVES
 Digestive disorders –
diarrhoea, stomach pain
 Nervous disorders –
hyperactivity, insomnia and
irritability
 Respiratory problems –
asthma and sinusitis
 Skin problems – hives,
itching, rashes and swelling
REFERENCES
 Code of Federal Regulations. 1997. Title 21. Food and drugs.
Parts 100–199. Office of the Federal Register, National
Archives, and Records Administration, Washington, D.C.
 Evaluation of certain food additives and contaminants (Fifty-
fifth report of the Joint FAO/WHO Expert Committee on Food
Additives). WHO Technical Report Series No. 901, 2001
 Fennema, Owen R. (1996). Food chemistry. New York, N.Y:
Marcel Dekker. pp. 827. ISBN 0- 8247-9691-8.
 Commission of the European Communities. Food Sciences
and Techniques. Reports of the Scientific Committee on
Food: Presentation of an application for assessment of a food
additive prior to its authorization. 1992 (ISBN 92-826- 0135-8).
Thank you

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Food Additives Explained: Types and Uses

  • 2. WHAT ARE FOOD ADDITIVES  Food additives may be defined as follows: a substance or mixture of substances, other than a basic foodstuff, which is present in a food as a result of any aspect of production, processing, storage, or packaging. The term does not include chance contaminants.  Legally, according to the FDA, the term refers to "any substance the intended use of which results or may reasonably be expected to result, directly or indirectly in its becoming a component or otherwise affecting the characteristics of any food."  This definition includes any substance used in the production, processing, treatment, packaging, transportation or storage of food.
  • 3. NEED FOR FOOD ADDITIVE  Preservation  Nutrition  Convenience Foods  Appealing Foods  To aid in the processing and preparation of foods
  • 4. TYPES OF FOOD ADDITIVE  Direct/ Intentional Additives: Food additives are those that are added to a food for a specific purpose in that food. For example, xanthan gum -- used in salad dressings, chocolate milk, bakery fillings, puddings and other foods to add texture.  Indirect/Unintentional Additives: They are those that become part of the food in trace amounts due to its packaging, storage or other handling. Examples include radioactive fallout, chemicals used in agricultural production and accidental contaminants during food processing
  • 5. TYPES OF DIRECT FOOD ADDITIVES  Preservatives  Food flavours  Anti-caking agents  Food colours  Bulking agents  Thickners  Sweetners  Stabilizers  Acidulants  Humectants  Emulsifiers
  • 6.  Antioxidants  Antioxidants act as preservatives by inhibiting the effects of oxygen on food, and can be beneficial to health.  Examples - Ascorbic acid (Vit C), Tocopherols (Vit E).  Chelating Agents  They serve as scavengers of metals which catalyze oxidation.  Examples - EDTA (ethylenediaminetetraacetic acid) and citric acid.
  • 7.  FOOD COLORING  Colorings are added to food to replace colors lost during preparation, or to make food look more attractive.  Natural colorants are Caramel coloring (E150), Annatto (E160b), chlorophyll (E140), Cochineal (E120), Betanin extracted from beets, Turmeric (curcuminoids, E100), Grape Skin Extract etc.  Synthetic colorants are FD&C Blue No.1 (E133), FD&C Green No.3 (E143), FD&C Red No. 40 (E129) etc.
  • 8.  ANTIFOAMING AGENTS  Antifoaming agents reduce or prevent foaming in foods.  Examples- Polydimethylsiloxane (a type of silicone). Silicone oil is also added to cooking oil to prevent foaming in deep-frying.  CURING AGENTS  These are additives used to preserve (cure) meats, give them desirable colour and flavor, discourage growth of micro- organisms, and prevent toxin formation.  Example- Sodium nitrite has been used for centuries as a preservative and colour stabilizer in meat and fish products.
  • 9.  EMULSIFIERS  Emulsifiers allow water and oils to remain mixed together in an emulsion, as in mayonnaise, ice cream, and homogenized milk. E.g Lecithin  FLAVOURS AND FLAVOUR ENHANCERS  Flavouring additives are the ingredients, both naturally occurring and added, which give the characteristic flavor to foods.  Flavour enhancers are not flavours themselves but they amplify the flavours of other substance through a synergistic effect.  Examples – Artifical flavours such as MSG and natural flavours e.g extracted from milk, egg,nuts e.t.c
  • 10.  ANTICAKING AGENTS  Anticaking agents keep powders such as milk powder from caking or sticking.  Examples - Sodium bicarbonate (E500), Calcium silicate (E552), Sodium aluminosilicate (E554), Bentonite (E558)  BULKING AGENTS o Bulking agents such as starch are additives that increase the mass and volume of a food without affecting its nutritional value. o Examples- Cellulose, Inulin, Polydextrose
  • 11.  These are bleaching and maturing agents; usually, they both bleach and “mature” the flour.  Freshly milled flour has a yellowish tint and yields a weak dough that produces poor bread. Both the colour and baking properties improve by storing the flour for several months before making bread. Example: Benzoyl peroxide.  LEAVENING AGENTS o Leavening agents produce light fluffy baked goods. Originally, yeast was used almost exclusively to leaven baked products. It is still an important leavening agent in bread making. o When yeast is used, ammonium salts are added to dough to provide a ready source of nitrogen for yeast growth..  FLOUR IMPROVERS
  • 12.  HUMECTANTS  Humectants prevent foods from drying out by retaining moisture.  Examples – Glycerol/propylene glycol (E1520), and glyceryl triacetate (E1518), sorbitol (E420).  PRESERVATIVES o Preservatives prevent or inhibit spoilage of food due to fungi, bacteria and other microorganisms. o Examples- Natural preservatives such as vinegar, sugar and artificial preservatives such as Benzoates, Nitrites, Sulphites e.t.c  STABILZERS o Stabilizers, thickeners and gelling agents, like agar or pectin (used in jam for example) give foods a firmer texture. They help to stabilize emulsions. o Examples- Alginic acid, pectin, gelatin, calcium chloride e.t.c
  • 13.  ACIDULANTS  Food acids are added to make flavors "sharper", and also act as preservatives and antioxidants.  Examples- vinegar, citric acid, tartaric acid, malic acid, fumaric acid, and lactic acid.  ACID REGULATORS  Acidity regulators are used to change or otherwise control the acidity and alkalinity of foods.  Examples - Acetic acid, Citric acid
  • 14.  GLAZING AGENTS  Glazing agents provide a shiny appearance or protective coating to foods.  Stearic acid (E570)  Beeswax (E901)  Candelilla wax (E902)  FLOUR TREATMENT AGENTS  Flour treatment agents are added to flour to improve its color or its use in baking.  azodicarbonamide (E927)  carbamide (E927b)
  • 15. SWEETENERS  Sweeteners are added to foods for flavoring. Some sweeteners other than sugar are added to keep the food energy (calories) low, or because they have beneficial effects for diabetes mellitus and tooth decay and diarrhea.  Examples– Natural Sweeteners found in sugar cane, stevia,maltodextrins, sugar beet or corn syrup and artificial sweeteners such as aspartame, acesulfame K, sugar alcohols, sucralose, saccharin e.t.c
  • 16.  NUTRIENT SUPPLEMENTS o Nutrient supplements restore values lost in processing or storage, or ensure higher nutritional value than what nature may have provided. o When foods are processed, there may be loss of some nutrients and additives may be added to restore the original value. o For example, vitamin C is added to canned citrus fruits to make up the loss of the vitamin during processing.  THICKENERS  Thickeners are substances which, when added to the mixture, increase its viscosity without substantially modifying its other properties.  Example- arrowroot, cornstarch, potato starch, vegetable gums (guar gum, locust bean gum, and xanthan gum, protein (Proteins used as food thickeners include collagen, egg whites etc.
  • 17. OTHER FOOD ADDITIVES  Clarifying agents like bentonite, gelatins, synthetic resins (polyamides and poly vinyl pyrrolidone) are used to remove haziness or sediments and oxidative deterioration products in fruit juices, beers and wines.  Enzymes are added to bring about desirable changes; rennin for producing curd and cheese, papain for tenderizing meat, and pectinase for clarifying beverages.  Firming agents like aluminium sulphates and calcium slats are used t keep the tissues of fruits and vegetables crisp.  Freezing agents like liquid nitrogen and dichloro fluoro methane, which are extremely volatile and rapidly evaporate at ordinary temperatures, are used to chill foods.  Solvents like alcohol, propylene glycol and glycerine are used to dissolve suspended flavours, colours, and many other ingredients.  Packing gases, such as inert gases, are added to packets of instant foods to prevent oxidative and many other changes
  • 18. NUMBERING OF ADDITIVES  Each additive is assigned a unique number, termed as "E numbers“ which is used in Europe for all approved additives.  This numbering scheme has now been adopted and extended by the Codex Alimentarius Commission E 100 – Curcumin, turmeric E 123 – Amaranth E 140 – Chlorophylls, Chlorophyllin E 210 – Benzoic acid E 224 – Potassium metabisulphite E 300 – Ascorbic acid E 330 – Citric acid
  • 19. 19
  • 20.  Federal government regulations generally require that all food ingredients, including direct additives, be listed on the package label by their common names in order of weight. LABELING o The EU (European Union) countries have drawn a list of 314 safe food additives. Each of them is given an E number. 100-199 colors 200-299 preservatives 300-399 antioxidants and acidity regulators 400-499 thickeners, stabilizers and emulsifiers 500-599 600-699 flavor enhancers 700-799 antibiotics 900-999 1100-1599 Additional chemicals ph regulators, anti-caking agents miscelaneous
  • 21. Permissible Limits of Food Additives
  • 22. ESTABLISHING PERMISSIBLE LIMITS OF FOOD ADDITIVES The limit is established with due importance to following factors:  The estimated level of consumption of the food product by the consumers for which the additive is proposed.  Finding out minimum levels which would produce significant deviation from physiological behavior.  Legal control over the use of food additives. This can be accomplished only when a list of permitted additives exists with specified safe levels and toxic levels.  Stringent labeling on foods i.e. declaring the usage of additives in food and their quantities.  Employing trained food inspectors, food control laboratories and reliable analytical methods are of utmost important for regulation / control over usage of food additives.
  • 23. SOME OF THE PERMITTED GRAS ADDITIVES AND TOLERANCES Antio Additive Food Used Function Tolerance Al, Ca silicate Table Salt Anti-caking agent 2.0 % BHA Various foods Various foods Antioxidant 0.3% ≤0.02% BHT Caffeine Cola type beverages Multi-purpose 0.02% Ca. Silicate Table Baking powder Cashew nuts Anti-caking Fumigants Flavouring agents 2.0 % 5.0 % Ethyl formarate Baked goods Pudding fillings Flavouring agents 0.03% 0.05% KMS General preservative Antimicrobial GMP Sodium bisulphite Various foods Antimicrobial GMP SO2 Wines, fruit juices, dehydrated foods Antimicrobial GMP Stearyl citrate Various fruits Sequestrants 0.15% Thiodipropionic acid Various fat containing foods Antioxidants 0.02 %
  • 24. ADI’S ( ACCEPTABLE DAILY INTAKE) OF SOME FOOD ADDITIVES: Addtive ADI Mg/kg Function EDTA 2.5 Preservative Sequestrant BHA 0.5 Antioxidant BHT 0.5 Antioxidant Sodium nitrate 5.0 Curing, Colour fixation Sodium stearyl formal 0.2 Stabilizing is non-yeast leavened. Conditioning agent is yeast leavened Glycine 25 Stabilizer Succinylated monoglyceride Emusifier, dough conditioner Polysorbate 25 Emulsifies Polypropyl glycoaginate 25 Stabilizer Emulsifier
  • 25. TOXICITY AND ADVERSE EFFECTS OF FOOD ADDITIVES  Digestive disorders – diarrhoea, stomach pain  Nervous disorders – hyperactivity, insomnia and irritability  Respiratory problems – asthma and sinusitis  Skin problems – hives, itching, rashes and swelling
  • 26.
  • 27. REFERENCES  Code of Federal Regulations. 1997. Title 21. Food and drugs. Parts 100–199. Office of the Federal Register, National Archives, and Records Administration, Washington, D.C.  Evaluation of certain food additives and contaminants (Fifty- fifth report of the Joint FAO/WHO Expert Committee on Food Additives). WHO Technical Report Series No. 901, 2001  Fennema, Owen R. (1996). Food chemistry. New York, N.Y: Marcel Dekker. pp. 827. ISBN 0- 8247-9691-8.  Commission of the European Communities. Food Sciences and Techniques. Reports of the Scientific Committee on Food: Presentation of an application for assessment of a food additive prior to its authorization. 1992 (ISBN 92-826- 0135-8).