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Impact of Fuel Ash on Clinker Quality

Tom Lowes
Impact of Fuel Ash on Clinker Quality
 In the embedded spreadsheet the Bogue calculations for LSF, C3S etc
allowing for SO3 but not include IR are used to predict the change on the
clinker chemistry when changing a coal ash for 20 to 45% for a typical
calciner process
 This shows a drop in LSF of 8% and C3S of 23%, with a drop is one day
strength of 4 Mpa and 2 Mpa at 28 days.
 The spreadsheet is written in such a way that it can be readily modified to
incorporate more than one fuel and hence is ideal to assess the impact of
AFR. However note that these are Bogue and not actual C3S etc, the AFR
ash lumps do not combine easily and can make C3S much lower than
Bogue
 The prediction for a typical clinker and coal ash is on the next slide,
changes are permitted to the red cells, without knowledge of the
password
Bogue compound Composition Change with Coal Ash
Current Clinker

Coal Ash Analysis
BS w SO 3

New Climker

%

BS w SO3

SiO2

21.73

LSF

93.2

SiO2

50.00

Coal Ash Current %

Al2O3

4.87

LCF

91.8

AI2O3

19.16

Fe2O3
CaO

3.83
65.02

2.50
1.27

Fe2O3
CaO

MgO

2.00

S/R
A/F
C3S

55.0

SO3

0.79

C2S

20.8

K2O

0.72

C3A

Na2O
F. CaO

0.04
1.00

C4AF
C4AF+C2F
eqNa2O

Total

100.00

20

SiO2

22.89

LSF

85.2

Change in LSF

-8.0

Coal CV current kcals/kg

6500

Al2O3

5.46

LCF

83.9

Change in C3S

-21.3

7.47
15.00

Coal Ash New %
Coal CV New kcals/kg

45
4875

Fe2O3
CaO

3.98
62.97

2.42
1.37

Change in C3A
Change Ash/Clk

1.3
4.1

MgO

2.79

Plant kcals/kg

800

MgO

2.03

S/R
A/F
C3S

33.7

Drop 1 day Mpa

-4.0

SO3

1.40

% Coal Current/Clk

12.3

SO3

0.81

C2S

40.2

Drop 28 day Mpa

-2.2

6.4

K2O

2.79

% New Coal/Clk

16.4

K2O

0.81

C3A

7.7

11.7
0.0
0.51

Na2O
Cl
Total

0.77
0.62
100.00

t extra ash/100 t clk

4.1

Na2O
F. CaO

0.07
C4AF
0.98 C4AF+C2F
eqNa2O
100.00

12.1
0.0
0.60

Total

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Bogue compounds and impact of fuel ash

  • 1. Impact of Fuel Ash on Clinker Quality Tom Lowes
  • 2. Impact of Fuel Ash on Clinker Quality  In the embedded spreadsheet the Bogue calculations for LSF, C3S etc allowing for SO3 but not include IR are used to predict the change on the clinker chemistry when changing a coal ash for 20 to 45% for a typical calciner process  This shows a drop in LSF of 8% and C3S of 23%, with a drop is one day strength of 4 Mpa and 2 Mpa at 28 days.  The spreadsheet is written in such a way that it can be readily modified to incorporate more than one fuel and hence is ideal to assess the impact of AFR. However note that these are Bogue and not actual C3S etc, the AFR ash lumps do not combine easily and can make C3S much lower than Bogue  The prediction for a typical clinker and coal ash is on the next slide, changes are permitted to the red cells, without knowledge of the password
  • 3. Bogue compound Composition Change with Coal Ash Current Clinker Coal Ash Analysis BS w SO 3 New Climker % BS w SO3 SiO2 21.73 LSF 93.2 SiO2 50.00 Coal Ash Current % Al2O3 4.87 LCF 91.8 AI2O3 19.16 Fe2O3 CaO 3.83 65.02 2.50 1.27 Fe2O3 CaO MgO 2.00 S/R A/F C3S 55.0 SO3 0.79 C2S 20.8 K2O 0.72 C3A Na2O F. CaO 0.04 1.00 C4AF C4AF+C2F eqNa2O Total 100.00 20 SiO2 22.89 LSF 85.2 Change in LSF -8.0 Coal CV current kcals/kg 6500 Al2O3 5.46 LCF 83.9 Change in C3S -21.3 7.47 15.00 Coal Ash New % Coal CV New kcals/kg 45 4875 Fe2O3 CaO 3.98 62.97 2.42 1.37 Change in C3A Change Ash/Clk 1.3 4.1 MgO 2.79 Plant kcals/kg 800 MgO 2.03 S/R A/F C3S 33.7 Drop 1 day Mpa -4.0 SO3 1.40 % Coal Current/Clk 12.3 SO3 0.81 C2S 40.2 Drop 28 day Mpa -2.2 6.4 K2O 2.79 % New Coal/Clk 16.4 K2O 0.81 C3A 7.7 11.7 0.0 0.51 Na2O Cl Total 0.77 0.62 100.00 t extra ash/100 t clk 4.1 Na2O F. CaO 0.07 C4AF 0.98 C4AF+C2F eqNa2O 100.00 12.1 0.0 0.60 Total