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Pre treatment of Surface
coatings
1
SCOPE
• Introduction
• Importance of Surface Preparation
• Surface Preparation Standards
• Industrially Adopted Surface Preparation Methods
• Need for new methods
• Plasma Treatment
• Conclusion and Prospect
2
INTRODUCTION
• The task of cleaning the surface properly to ensure better performance, service life
and quality of coating.
• Undertaken to remove dust, grease, rust or old coating layers from the surface to be
coated.
• It not only cleans, but introduces a suitable profile to receive the protective coating.
• Most critical pre-coating treatment of any substrate.
3
INTRODUCTION
• Universally accepted as the most important factor affecting the overall success of a
corrosion protection system.
• A majority of large scale industries have been following age old techniques towards surface
preparation.
• Amidst the constant corrosion protection requirements and the finances involved in doing
so, the deteriorating impacts of these techniques are often ignored.
• With increased awareness, there arises a need to study and adapt new techniques on
industrial scale.
4
IMPORTANCE OF SURFACE
PREPARATION
• To promote coating adhesion to the substrate.
• Improve durability of coating.
• Better strength and appearance.
• To save time and money.
• Reduce failures and costly re-works.
5
SURFACE PREPARATION STANDARDS
• Specified by Society for Protective Coatings (SSPC), National Association of
Corrosion Engineers (NACE) and British Standards European Norms (BS EN).
• Surface preparation accounts for about 40 % of the cost of the repainting project.
• Standards exist to maximize coating life and minimize costs.
6
SURFACE PREPARATION STANDARDS
• SP 1 / ISO 8504 (Solvent Cleaning)
• Washing with soap, water and rag.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material :
• Stains, steaks and shadows
100 %
100 %
: 100 %
• Cleans the surface of contaminants smeared over the surface.
7
SURFACE PREPARATION STANDARDS
• SP 7 /NACE # 4 / SA 1 (Brush-Off)
• Light Blast cleaning, sweep blasting.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material :
• Stains, steaks and shadows
0 %
100 %
: 100 %
• Removes loose rust, mill scales, coatings and uniformly roughens the surface.
8
SURFACE PREPARATION STANDARDS
• SP 14 /NACE # 8 (Industrial Blast Cleaning)
• Most recent abrasive blasting standard.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material :
• Stains, steaks and shadows
0 %
10 %
: 100 %
• Preferred when existing coating is thin, well adherent and compatible with new
coating.
9
SURFACE PREPARATION STANDARDS
• SP 6 /NACE # 3 /SA 2 (Commercial Blast Cleaning)
• Thorough blast cleaning.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material 0 %
• Stains, steaks and shadows :
0 %
:
33 %
• Preferred when high, but not perfect cleanliness warranted.
• Products serving in non-corrosive environment.
10
SURFACE PREPARATION STANDARDS
• SP 10 /NACE # 2 /SA 2.5 (Near White Blast Cleaning)
• Very thorough blast cleaning.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material :
• Stains, steaks and shadows
0 %
0 %
: 10.5 %
• Required for high performance coatings over steel exposed to severe environmental
conditions.
11
SURFACE PREPARATION STANDARDS
• SP 5 /NACE # 1 /SA 3 (White Metal Blast Cleaning)
• Blast clean to visibly clean steel.
Acceptable limit
• Loosely adhering material :
• Tightly adhering material 0 %
• Stains, steaks and shadows :
0 %
:
0 %
• Required for steel exposed to high temperature, high pressure and corrosive environment.
• Used where coating failures can result in catastrophic failures.
12
INDUSTRIALLY ADOPTED SURFACE
PREPARATION METHODS
• Methods that have been tested, modified and adopted to suit the ever increasing
industrial requirements.
• Sand Blasting
• Water Blasting
• Hand & Power Tool Cleaning
13
SAND BLASTING
• Most adopted surface preparation method worldwide.
• Employs High pressure air combined with abrasive for cleaning.
• Easier and faster compared to other methods.
• Variation in pressure can create profile varying from SA3 to SA1.
• Used in shipbuilding industry, bridge paintings etc.
14
SAND BLASTING
15
WATER BLASTING
• Safe, eco friendly, economical and efficient.
• Also known as high pressure water cleaning or hydrojet blasting.
• Fan nozzles of various sizes used to adjust pressure.
• Can be used on metals, concrete, plastic, composites etc.
16
WATER BLASTING
17
HAND AND POWER TOOLING
• Surface cleaning using hand tools (scrappers, wire brush etc.)
• Useful where abrasive blasting cannot be employed.
• Relatively slower than other methods.
18
REQUIREMENT OF NEW
TECHNIQUES
• High levels of dust and noise.
• Abrasive material might contain toxic substances.
• Hazardous to operators.
• Silica sand causes lung cancer.
• Harmful to the environment.
• Water injection can be fatal.
19
PLASMA TREATMENT
• Plasma is generated by supplying energy to gas.
• The energy required can be produced by thermal reaction, applying electric field, magnetic
field of even by nuclear reaction.
• Three significant reactions observed are excitation, ionization and dissociation.
• Concentrated discharge thus generated is used to bombard the substrate at high velocity.
• This cleans, etches and functionalizes the substrate.
20
PLASMA TREATMENT
21
DOUBLE GLOW PLASMA SURFACE
TREATMENT
• Although conceptualized in 1980, the process is only recently adopted on industrial
scale.
• Uses double glow discharge phenomenon and low temperature plasma to form
alloy layer with special physical and chemical properties.
• Utilizes ion bombardment, sputtering, space transmission, deposition and diffusion
in low vacuum.
22
DOUBLE GLOW PLASMA SURFACE
TREATMENT
23
ADVANTAGES
• Can be used on any element of the periodic table.
• Improved surface hardness, wear and corrosion resistance.
• Makes the surface hydrophilic to facilitate coating application.
• Eliminates a majority of hazards associated with previously discussed techniques.
24
CONCLUSION AND PROSPECT
• Ni-Cr alloy layer formed on carbon steel plate can be used to replace conventional
stainless steel.
• Very high bond strengths can be achieved by forming a metallurgical bond between
the coating and substrate.
• Surface properties of mechanical parts can be enhanced.
• The entire process includes vacuum, glow discharge, ion bombardment, sputtering,
deposition, diffusion, etc. There is no pollution.
25
CONCLUSION AND PROSPECT
• Low grade materials can be transformed into high quality metals at very low costs.
• The stability of glow discharge and the suppression of arc discharge need to be
further optimized.
• Re-works/ repairs of coatings in use needs to be examined.
26
REFERENCES
• “A Modern Day Alchemy : Double Glow Plasma Surface Metallurgy
Technology”, Zhong Xu, Research Institute of Surface Engineering,
Taiyuan University of Technology, 2021.
• “Understanding Surface Preparation Standards”,
 https://www.graco.com/gb/en/contractor/solutions/articles/surface-
prep-standards- explained-sspc-nace-iso-8501.html
• “What is Surface Preparation (An in-depth guide)”,
 https://www.twi-global.com/technical-knowledge/faqs/what-is-surface-
preparation
27
THANK YOU
28

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Pre treatment of Surface coatings.pdf

  • 1. Pre treatment of Surface coatings 1
  • 2. SCOPE • Introduction • Importance of Surface Preparation • Surface Preparation Standards • Industrially Adopted Surface Preparation Methods • Need for new methods • Plasma Treatment • Conclusion and Prospect 2
  • 3. INTRODUCTION • The task of cleaning the surface properly to ensure better performance, service life and quality of coating. • Undertaken to remove dust, grease, rust or old coating layers from the surface to be coated. • It not only cleans, but introduces a suitable profile to receive the protective coating. • Most critical pre-coating treatment of any substrate. 3
  • 4. INTRODUCTION • Universally accepted as the most important factor affecting the overall success of a corrosion protection system. • A majority of large scale industries have been following age old techniques towards surface preparation. • Amidst the constant corrosion protection requirements and the finances involved in doing so, the deteriorating impacts of these techniques are often ignored. • With increased awareness, there arises a need to study and adapt new techniques on industrial scale. 4
  • 5. IMPORTANCE OF SURFACE PREPARATION • To promote coating adhesion to the substrate. • Improve durability of coating. • Better strength and appearance. • To save time and money. • Reduce failures and costly re-works. 5
  • 6. SURFACE PREPARATION STANDARDS • Specified by Society for Protective Coatings (SSPC), National Association of Corrosion Engineers (NACE) and British Standards European Norms (BS EN). • Surface preparation accounts for about 40 % of the cost of the repainting project. • Standards exist to maximize coating life and minimize costs. 6
  • 7. SURFACE PREPARATION STANDARDS • SP 1 / ISO 8504 (Solvent Cleaning) • Washing with soap, water and rag. Acceptable limit • Loosely adhering material : • Tightly adhering material : • Stains, steaks and shadows 100 % 100 % : 100 % • Cleans the surface of contaminants smeared over the surface. 7
  • 8. SURFACE PREPARATION STANDARDS • SP 7 /NACE # 4 / SA 1 (Brush-Off) • Light Blast cleaning, sweep blasting. Acceptable limit • Loosely adhering material : • Tightly adhering material : • Stains, steaks and shadows 0 % 100 % : 100 % • Removes loose rust, mill scales, coatings and uniformly roughens the surface. 8
  • 9. SURFACE PREPARATION STANDARDS • SP 14 /NACE # 8 (Industrial Blast Cleaning) • Most recent abrasive blasting standard. Acceptable limit • Loosely adhering material : • Tightly adhering material : • Stains, steaks and shadows 0 % 10 % : 100 % • Preferred when existing coating is thin, well adherent and compatible with new coating. 9
  • 10. SURFACE PREPARATION STANDARDS • SP 6 /NACE # 3 /SA 2 (Commercial Blast Cleaning) • Thorough blast cleaning. Acceptable limit • Loosely adhering material : • Tightly adhering material 0 % • Stains, steaks and shadows : 0 % : 33 % • Preferred when high, but not perfect cleanliness warranted. • Products serving in non-corrosive environment. 10
  • 11. SURFACE PREPARATION STANDARDS • SP 10 /NACE # 2 /SA 2.5 (Near White Blast Cleaning) • Very thorough blast cleaning. Acceptable limit • Loosely adhering material : • Tightly adhering material : • Stains, steaks and shadows 0 % 0 % : 10.5 % • Required for high performance coatings over steel exposed to severe environmental conditions. 11
  • 12. SURFACE PREPARATION STANDARDS • SP 5 /NACE # 1 /SA 3 (White Metal Blast Cleaning) • Blast clean to visibly clean steel. Acceptable limit • Loosely adhering material : • Tightly adhering material 0 % • Stains, steaks and shadows : 0 % : 0 % • Required for steel exposed to high temperature, high pressure and corrosive environment. • Used where coating failures can result in catastrophic failures. 12
  • 13. INDUSTRIALLY ADOPTED SURFACE PREPARATION METHODS • Methods that have been tested, modified and adopted to suit the ever increasing industrial requirements. • Sand Blasting • Water Blasting • Hand & Power Tool Cleaning 13
  • 14. SAND BLASTING • Most adopted surface preparation method worldwide. • Employs High pressure air combined with abrasive for cleaning. • Easier and faster compared to other methods. • Variation in pressure can create profile varying from SA3 to SA1. • Used in shipbuilding industry, bridge paintings etc. 14
  • 16. WATER BLASTING • Safe, eco friendly, economical and efficient. • Also known as high pressure water cleaning or hydrojet blasting. • Fan nozzles of various sizes used to adjust pressure. • Can be used on metals, concrete, plastic, composites etc. 16
  • 18. HAND AND POWER TOOLING • Surface cleaning using hand tools (scrappers, wire brush etc.) • Useful where abrasive blasting cannot be employed. • Relatively slower than other methods. 18
  • 19. REQUIREMENT OF NEW TECHNIQUES • High levels of dust and noise. • Abrasive material might contain toxic substances. • Hazardous to operators. • Silica sand causes lung cancer. • Harmful to the environment. • Water injection can be fatal. 19
  • 20. PLASMA TREATMENT • Plasma is generated by supplying energy to gas. • The energy required can be produced by thermal reaction, applying electric field, magnetic field of even by nuclear reaction. • Three significant reactions observed are excitation, ionization and dissociation. • Concentrated discharge thus generated is used to bombard the substrate at high velocity. • This cleans, etches and functionalizes the substrate. 20
  • 22. DOUBLE GLOW PLASMA SURFACE TREATMENT • Although conceptualized in 1980, the process is only recently adopted on industrial scale. • Uses double glow discharge phenomenon and low temperature plasma to form alloy layer with special physical and chemical properties. • Utilizes ion bombardment, sputtering, space transmission, deposition and diffusion in low vacuum. 22
  • 23. DOUBLE GLOW PLASMA SURFACE TREATMENT 23
  • 24. ADVANTAGES • Can be used on any element of the periodic table. • Improved surface hardness, wear and corrosion resistance. • Makes the surface hydrophilic to facilitate coating application. • Eliminates a majority of hazards associated with previously discussed techniques. 24
  • 25. CONCLUSION AND PROSPECT • Ni-Cr alloy layer formed on carbon steel plate can be used to replace conventional stainless steel. • Very high bond strengths can be achieved by forming a metallurgical bond between the coating and substrate. • Surface properties of mechanical parts can be enhanced. • The entire process includes vacuum, glow discharge, ion bombardment, sputtering, deposition, diffusion, etc. There is no pollution. 25
  • 26. CONCLUSION AND PROSPECT • Low grade materials can be transformed into high quality metals at very low costs. • The stability of glow discharge and the suppression of arc discharge need to be further optimized. • Re-works/ repairs of coatings in use needs to be examined. 26
  • 27. REFERENCES • “A Modern Day Alchemy : Double Glow Plasma Surface Metallurgy Technology”, Zhong Xu, Research Institute of Surface Engineering, Taiyuan University of Technology, 2021. • “Understanding Surface Preparation Standards”,  https://www.graco.com/gb/en/contractor/solutions/articles/surface- prep-standards- explained-sspc-nace-iso-8501.html • “What is Surface Preparation (An in-depth guide)”,  https://www.twi-global.com/technical-knowledge/faqs/what-is-surface- preparation 27