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PROCEEDINGS
of
BOGOR SYMPOSIUM &WORKSHOP ON
TROPICAL PEATLAND MANAGEMENT
BOGOR - INDONESIA, JULY 14 -15 2009
th th
“ WISE USE OF TROPICAL PEATLAND”
INTEGRATED FIELD ENVIRONMENTAL SCIENCE -
GLOBAL CENTER OF EXCELLENT (IFES-GCOE)
INDONESIAN LIAISON OFFICE
W 16, Lv 6 Department of Soil Science and Land Resources Building,
Fac.of Agriculture, IPB Jl. Meranti, Kampus IPB Darmaga, Bogor 16680-INDONESIA
Phone: +62 (251)-8624334; Fax: +62 (251)- 8624334
fesindonesia@yahoo.co.idEmail: i ; suwardi_bogor@yahoo.com
Edited by :
Sudarsono, Ryusuke Hatano, Takashi Inoue,
Suwido Limin, Gunawan Djajakirana, Suwardi
ISBN 978-602-96223-0-0
Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
ISBN 978-602-96223-0-0
Proceedings of
Bogor Symposium and Workshop on
Tropical Peatland Management
“ Wise Use of Tropical Peatland”
Editors :
Managing Editor :
Prof. Dr. Sudarsono,
Prof. Dr. Ryusuke Hatano,
Prof. Dr. Takashi Inoue,
Prof. Dr. Suwido Limin
Dr. Gunawan Djajakirana,
Dr. Suwardi,
Septian Tri Putranto, SP
Bogor Agricultural University
Integrated Field Environmental Science - Global Center of Excellent
(IFES-GCOE) Indonesian Liaison Office
Hokkaido University
2009
Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “ Wise Use of Tropical Peatland”
COMMITTEE
SteeringCommittee(SC)
OrganizingCommittee(OC)
Chairperson: Prof. Dr. HannyWijaya
Members:
1. Prof. Dr. Ryosuke Hatano
2. Prof. Dr. Yasuyuki Hashidoko
3. Prof. Dr. Budi Mulyanto
4. Dr. Takashi Inoue
5. Dr. Anas M. Fauzi, M.Eng
6. Prof. Dr. Didy Sopandie
7. Dr. Kukuh Murtilaksono
1. Chairman : Dr.Suwardi
2. Secretary : 1. Dr.DyahTjahyandariS.
2. SeptianTriPutranto,SP
3. FinanceSecretary : Dr.Darmawan
4. Program,Publication : 1. Dr.Iskandar
andDocumentation 2. Dr.GunawanDjajakirana
3. Dr.BasukiSumawinata
5. Accomodation, : 1. Dr.D.P.TejoBaskoro
Transportationand 2. Ir.HermanuWijaya,Msc
Consumption
Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
iii
TABLE OF CONTENTS
Foreword .................................................................................................................
Table of Content ......................................................................................................
Opening Remark Chairperson of The Steering Committee Speech from
Representative of IFES-GCOE ......................................
Speech from Representative of IFES-GCOE Targets of The Indonesian IFES-
GCOE Program
.............................................................................................
Speech and Opening The Symposium and Workshop
.............
Current Issues of Tropical Peatland in Indonesia
.............................................................................................................
CO and N O Emission Associated with Tropical Peatland Degradation (
) .............................
Dynamics of Greenhouse Gases in Tropical Peatland Soils: Research Plan
) ............................................................................
A preliminary assessment of peat degradation in West Kalimantan
.......................................................................................................
Estimation of Carbon Stock in Riau Peat-swampy Production Forest, Indonesia
...................................................................................................
Screening of N O emitting microorganisms from soils of reclaimed tropical peat
swamp forest and their N O emitting conditions
.................
Plant Diversity and Biomass Content in Relation with Wise Use of Tropical
Peatland ........................................................................
Community Structure ofAquatic Biota in the Peatland ...........
Methanogenic microorganisms in peatlands ......................................
Biomass content and biodiversity of tropical peat swamp forest under various land
cover conditions ......................
(Prof. Dr. HannyWijaya)
(Prof. Dr. Ryusuke Hatano, Graduate School of Agriculture,
Hokkaido University)
(Dr. Anas M. Fauzi, Vice
Rectorof Research and Collaboration, BogorAgricultural University)
PART1
Issues Concerning theTropicalPeatland
Basuki Sumawinata and
Darmawan
Ryusuke
Hatano, Takashi Inoue, Untung Darung and Suwido Limin
(Yohei
Hamada and Ryusuke Hatano
(Gusti Anshari)
(Ulfah J. Siregar)
(Yasuyuki Hashidoko)
PART 2
Tropical Peatland in Natural Conditions
(Istomo, Cahyo Wibowo)
(Sutrisno Sukimin)
(Abdul Hadi)
(Adi Jaya, Ulfah J. Siregar, and M.Y. Massijaya)
(
)
2 2
2
2
i
iii
vii
viii
ix
1
11
19
33
46
52
57
67
74
84
Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
iv
PART 3
Potential of Tropical Peatland and Their Use
Dedi Kusnadi
Budi Indra Setiawan A.Harisman, S.Arfianto, E.Susandi, J.Ginting,
Soewarso)
(Suroso Rahutomo, E.S Sutarta,
and W Darmosarkoro)
(ClaraKusharto and M.Annis CaturAdi)
(Apong Sandrawati and Suwardi)
(Baba Barus, K. Gandasasmita and Reni
Kusumo)
(Bambang Hero Saharjo)
(Darmawan, Basuki Sumawinata and Suwardi)
(Soedodo Hardjoamidjojo and Nora
H. Panjaitan)
(Suwardi, Basuki Sumawinata, Darmawan, Gunawan
Djajakirana, and Hermanu Wijaya)
PART 4
Amelioration and Policy for Concerning Tropical Peatland
(Suwardi, Gunawan Djajakirana, Hermanu Wijaya, and Basuki
Sumawinata )
(Basuki Sumawinata, Gunawan Djajakirana,
and D.P. Tejo Baskoro)
(Eko Hanudin)
The Environmentally Design of Water Management System for Sustainable
PeatlandDevelopmentinIndonesia( ) ..............................................
Integrated Water Zoning for Sustainable Forest Plantation in Tropical Peatlands
................................................................................................................
Utilization of Peatland for Oilpalm Plantation
...........................................................................................
Food Availability And Agricultural Product In Peatland (Tabat Area), Central
Kalimantan,Indonesia .......................
Utilization of Degraded Peatland for Producing Biomass as Source of Bioenergy
and Compost ..................................................
Mapping of peat hydrological unit and peat dome of Indonesia in supporting
sustainable peat management
.................................................................................................................
The carbon stock baseline as wise use management of tropical peat land. Case study
intheoilpalmplantation ...............................................
Characterization and Prediction of Tropical Peatland for The Wise Use
.................................................
Development and Management of Wetland
..........................................................................................................
Utilization of Acid Sulfate Soil in Rantau Rasau-Jambi Province for Cultivation of
Gaharu
....................................................................
Renovation of Acid Sulfate Soil for Integrated Farming at Delta Berbak, Jambi
Province
.........................................................................................................
Study on improvement of Indonesian acid sulphate soil : ameliorant for masking
aluminium toxicity in rice plant
...........................................................................................
Absorption of Ca, Mg, K, Na in corn on ombrogenous peat as affected by volcanic
ash and fly ash application .............................................................
(Aquilaria sp)
99
110
124
134
144
148
157
171
178
185
191
200
201
Table of Contents
Application of Fly Ash as Ameliorant in Peatland Environment: The Release of
Micro Nutrients and Heavy Metals
..................................................................................................................................
Restoration of hydrophobic peat by surfactants addition, its effect on water
retention, cation, depository efficiency and FTIR Spectroscopy
.....................................................................................................
Closing Remark ......................................................................................................
Listof Participants ...................................................................................................
(Iskandar, Suwardi and E.F.R. Ramadina)
(Sri Nuryani
HidayahUtami)
Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
v
207
214
237
239
Table of Contents
207Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
APPLICATION OF FLY ASH AS AMELIORANT IN PEATLAND
ENVIRONMENT: THE RELEASE OF MICRO NUTRIENTS AND
HEAVY METALS
Iskandar , Suwardi and E.F.R. Ramadina
1 1 2
1
2
Department of Soil Science and Land Resources, Faculty of Agriculture, IPB
Graduated from Department of Soil Science and Land Resources, Faculty of Agriculture, IPB
Email: issi_iskandar@yahoo.com
ABSTRACT
INTRODUCTION
Some researchers showed that fly ash can be used to improve the chemical properties of soil,
such as increasing pH, exchangeable cations and base saturation. However, the application of
fly ash as soil ameliorant in Indonesia is still constrained by government regulation that fly ash
is classified as toxic and dangerous waste materials due to the contains of heavy metals. The
objective of this research is to study the release of micro nutrients and heavy metals from fly ash
in peat environment. This research was conducted by batch method with shaking fly ash in
aquadest and peat water as solvent, and by column percolation method with flushing the
mixture of fly ash and peat. Cations of Fe, Mn, Cu, Zn, Pb, Cd, Cr and Ni dissolved in filtrate
were measured by Atomic Absorption Spectrophotometer (AAS). Fly ashes used in this study
originatedfrom peatboiler(PB),chipboiler(CB)andmultiboiler(MB).
The results showed that peat water did not always dissolve elements from fly ashes higher than
those of aquadest. There was no significant relation between shaking time and amount of
elements dissolve in the solution. Elements of Fe and Mn were released more from fly ash from
PB, whereas the other elements released relatively in the same amount in all fly ashes used. In
column percolation test, peat treated with fly ash after 3 months flushing showed decreasing
availability of heavy metals with increasing fly ash dosage. Leachate from column percolation
test contain elements in various amount. Generally, the amount of elements in percolate
decreasewiththeincreaseofflushingtimeinorderofFe>Cu >Mn>Zn >Cr >Pb>Ni>Cd.
Flyash, heavymetal,leaching,micronutrient,peatKeywords:
Fly ash is residue from burning of coals in electrical generators using coal as fuel or boiler. The
material can be used as soil ameliorant for improving chemical properties in mineral and peat
soils. Although fly ash contains relatively complete and vary (Iskandar, Suwardi dan
Ramadina, 2008), the application in the field as soil ameliorant is still constrained by
government regulation. Government act No. 85 year 1999 classified the fly ash as dangerous
and poisonous waste due to the contain of heavy metals. In soil science, some elements
classified as heavy metals, are also classified as micro nutrients those need for plants such as
Fe, Mn, Cu dan Zn (Horn, 1992;Alloway, 1995). In order elements in fly ash can be utilized for
improving soil fertility, with still concern of the behavior of heavy metals released to the
208 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
Iskandar, Suwardi and E.F.R. Ramadina
environment and waters, the research of the utilization of fly ash as soil ameliorant needs to be
doneintensively.
Mc Carty et al. (1994) studied the utilization of fly ash for increasing soil pH, whereas
Stuczynski et al. (1998a) and Stuczynski et al. (1998b) studied the effect of fly ash and bed ash
on mobilization of nitrogen and carbon. More comprehensive research has been done by
Inthasan et al. (2002) studying the effect of fly ash for soil developed from granite, sandstone,
and limestone. They showed that the availability of Fe, Mn, Cu and Zn exctracted by DTPA
tended to decrease due to the increase of pH, where as the other heavy metals could not be
detected consistenly. Truter et al. (2001) used mixed fly ash, sewage sludge and liming, with
the ratio of 60%, 30% and 10% (dry weight) found that there were positive effect on increasing
pH, Ca, Mg and Pavailable in the soil.The translocation of heavy metals (Ni and Cd), as well as
essential micro nutrient of B, did not translocate significantly. The above important researches
were conducted in mineral soils. Research on peat soil has been conducted by Iskandar,
Djajakirana and Marolop (2003) through field experiment in forest plantation. The results
showed that peat soil applied by 5 kg and 10 kg fly ash/plant of has pH, cation
exchange, available P and base saturation higher than that of without fly ash application.
Iskandar . (2008) was also showed the same results with percolation colomn experiment in
the laboratory. Relation to heavy metals, Iskandar . (2003) showed that the content of
heavy metal increase significantly in peat soil due to fly as application. Different from Fe, the
other of heavy metals such as Ni, Pb, Cd and Cr did not increase significantly. On the other
hand Fleming (1996) showed the content of heavy metals Cd, Cr, Zn, Pb, Hg and As in
their colomn percolation increase with the decrease of the solvent pH buffered at the pH 6.8;
41and3,0.
The objectives of this research is to study the solubility of micro nutrients and heavy metals in
fly ash with the solvent of aquadest and peat water as well as the contents of those elements in
peatappliedbyflyashafter3monthsleaching.
This research was conducted using peat soil sample (pH 3.60) and peat water (pH 3.43) taken
from Jambi. Fly ashes were collected from the furnace using peat as fuel peat boiler (PB), chip
boiler(CB),andmultiboiler(MB) fromIndahKiatPulp&Paper,Perawang,Riau.
These researches were conducted simultaneously in two stages in batch method and leaching
method. Batch method for studying the solubility of micronutrients and heavy metals in the fly
ash where as the leaching method for studying the effect of fly ash on the chemical properties of
peatsoilandwaterqualityleachedfromcolomncontainingpeatsoil.
Three kinds of fly ashes PB CB and MB were added by aquadest with the ratio of fly ash :
aquadest of 1 : 5.The mixtures were shaked during 30, 60, 120, and 240 minutes.With the same
method, the fly ashes were added by peat water. After shaking, the pH of the mixture was
measured by pH-meter and the contents of Fe, Mn, Cu, Zn, Pb, Cd, Cr and Ni in the filtate were
measuredbyAAS.
Acasia sp
et al
et al
et al.
,
MATERIALS AND METHOD
BatchMethodExperiment
209Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
Column PercolationExperiment
SolubilityofHeavyMetalsfromFlyAsh
(Tabel1)
Some 1 kg peat soil (air dry basis) was added to percolation column having 8.6 cm in diameter
and 24.5 cm long. Above the peat soil was added by PB with the dosage of 0, 25, 50, 75, and
125 g/kg peat soil. Each percolation column was watered by 50 ml aquadest everyday and the
percolate was captured by container. This treatment was conducted during 3 months. The
percolate was measured every month for pH and the content of Fe, Mn, Cu, Zn, Pb, Cd, Cr and
Ni. After 3 months, the peat soils in the column were analyzed for pH and metal elements
extractedbyHCl0.05N.
The pH of fly ashes of PB, CB and MB used in this experiment was alkalis ranging between 8.7
and 11.5. The contents of micronutrients and heavy metals varied, such as Fe 1.25 1.73%, Mn
200 300 ppm, Cu 7.90 43.3 ppm, Zn 24.3 97.8 ppm, Pb 0.40 26.3 ppm, Cd 0.11 0.70 ppm, Cr
9.78 27.9 ppm dan Ni 9.13 48.7 ppm (Iskandar ., 2008). The solubility of those
micronutrientsandheavymetalsinaquadestandpeatwaterwas highlyvariated .
Although peat water has pH of 3.43 but it did not meaning dillute heavy metals more than
aquadest. This was because the pH of peat water mixed with fly ash changed to alkalis (pH 8,0
11,4). In this condition, some metals released from fly ash will precipitate in hydroxide
compound forms. The duration of shaking did not have relation to the amount of metals
released from the fly ashes. The number of metals Fe, Mn and Ni released from fly ash PB
tended to increse with the longer duration of of shaking where as the other metals released from
fly ashes of PB, CB and MB did not change or even decrease. The Fe and Mn released from fly
ash PB were higher, where as the others elements relatively same in three fly ashes. The
maximum concentration of elements diluted at batch test were as follows: Fe 1.67 ppm (PB),
Mn 0.05 ppm (PB), Cu 0.01 ppm (PB, CB and MB), Zn 0.57 ppm (CB), Pb 0.02 ppm (PB and
CB),Cdnotdetected,Cr0.11ppm(MB) andNi0.023ppm(PB, CBandMB).
High variability of batch test results was due to the heterogeneous composition of fly ashes,
solubility, and solubility kinetic of the metals in fly ashes (Reardon 1995). Minerals and
glasses phase compose of fly ash are formed in wide range temperature. Most of materials in
fly ash are found in oxidized condition or partial oxidation. If the materials contact with water,
some materials will dilute and the others more stable and presipitate. Glasses particles and
crystalline aluminosilicate dilute very slowly. Moreover, there are minerals composed from
the condensation of elements created in lower temperature adhering on the surface of glass
particles. This mineral groups consist of sulfate, borate, fluoride and chloride having high
solubility and fast velocity of solubility. Oxidation phases found in fly ash such as CaO, MgO,
Al O , Fe O andFe O havewidesolubilityrange.
RESUTLS AND DISCUSION
et al
et al.
2 3 2 3 3 4
Application of Fly Ash as Ameliorant in Peatland Environment:
The Release of Micro Nutrients and Heavy Metals
210 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
Table1. Solubility of heavy metals from fly ashes of PB, CB and MB in quadest and peat water
indifferentdurationofshaking.
Micronutrients and HeavyMetalsContent inPeat
Figure 1 2and show the content of micronutrients of Fe, Mn, Cu, Zn and heavy metals of Pb,
Cd, Cr, Ni in peat, respectively with the treatment of fly ash PB after leaching process with
aquadest during 3 months.The two figures show that the higher fly ash dosages, the availability
of metals Fe, Mn, Cu, Zn, Cd and Ni in the peat decrease. In the same treatment, the availability
of Pb and Cr do not show the order change.The availabilityof Pb in peatafterincubationduring
3 months varied from not detected (control treatment) to 0.02 ppm, whereas Cr from 0.011 ppm
to 0.034 ppm, but they did not found in the fly ash dosages of 75 and 125 mg/kg fly ash. The
decrease of the availabiity of that metals seemly related to the increase of pH of the peat from
3.60 to about 5.12 6.67 causing the presipitation of metals in hydroxide forms (Iskandar .,
2008).
et al
Fe Mn Cu Zn Pb Cd Cr Ni
Kinds of fly ash Extractant
Shaking
duration
(minute)
pH
---------------------------- ppm ----------------------------
30 8.52 0.25 0.01 0.01 0.020 0.000 tr 0.080 0.013
60 8.49 0.22 0.01 0.01 0.040 0.000 tr 0.069 0.015
120 8.34 1.06 0.03 0.01 0.020 0.009 tr 0.080 0.023
Aquadest
240 8.26 1.67 0.05 0.01 0.040 0.009 tr 0.046 0.015
30 8.34 0.44 0.01 0.01 0.040 0.019 tr 0.046 0.008
60 8.30 0.58 0.01 0.01 0.030 0.009 tr 0.057 0.013
120 8.22 1.06 0.02 0.01 0.040 0.000 tr 0.046 0.018
PB
Peat water
240 8.17 1.26 0.05 0.01 0.030 0.009 tr 0.091 0.023
30 8.49 0.06 0.01 0.00 0.510 0.009 tr 0.080 0.023
60 8.45 0.02 0.01 0.00 0.060 0.009 tr 0.057 0.015
120 8.42 0.03 0.01 0.00 0.050 0.000 tr 0.069 0.015
Aquadest
240 8.38 0.05 0.01 0.01 0.010 0.009 tr 0.069 0.018
30 8.14 0.05 0.01 0.00 0.570 0.000 tr 0.057 0.015
60 8.10 0.02 0.01 0.00 0.070 0.019 tr 0.080 0.015
120 8.06 0.01 0.01 0.00 0.060 0.019 tr 0.057 0.015
CB
Peat water
240 8.02 0.05 0.02 0.00 0.050 0.009 tr 0.080 0.015
30 11.44 0.03 0.01 0.00 0.000 0.000 tr 0.069 0.013
60 11.41 0.01 0.01 0.01 0.000 0.009 tr 0.103 0.000
120 11.33 0.07 0.01 0.01 0.000 0.000 tr 0.114 0.023
Aquadest
240 11.30 0.03 0.01 0.01 0.000 0.009 tr 0.103 0.010
30 11.38 0.03 0.00 0.01 0.010 0.009 tr 0.114 0.015
60 11.35 0.05 0.01 0.00 0.000 0.009 tr 0.103 0.013
120 11.26 0.04 0.00 0.00 0.000 0.000 tr 0.091 0.015
MB
Peat water
240 11.24 0.01 0.01 0.00 0.000 0.000 tr 0.103 0.018
Notes : PB = Peat Boiler, CB = Chip Boiler, MB = Multi Boiler
Iskandar, Suwardi and E.F.R. Ramadina
211Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
0,00
2,00
4,00
6,00
8,00
10,00
PO P1 P2 P3 P4
Dosis
Konsentrasi(ppm)
Fe Mn Cu Zn
Dosage
Concentration(ppm)
Figure1. The concentrationof micronutrientsFe, Mn, Cu and Zn in peat after treatmentswith
flyashinsomedosagesafterincubationduring3months.
0,00
0,01
0,02
0,03
0,04
0,05
0,06
PO P1 P2 P3 P4
Dosis
Konsentrasi(ppm)
Pb Cd Cr Ni
Dosage
Concentration(ppm)
Figure2. Heavy metal contents of Pb, Cd, Cr and Ni in peat after treatment with fly ash in
somedosagesafterincubationduring3months.
Application of Fly Ash as Ameliorant in Peatland Environment:
The Release of Micro Nutrients and Heavy Metals
212 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
Diluted metals from fly ash besides adsorbed by peat, they also translocated with moved water.
shows the contents of metals in the percolate from the leaching of peat with the
treatment of the application of fly ash with some dosages. Metals that much translocated in the
percolation column test were Fe (maximum 11.68 ppm), followed by Cu (1.81 ppm), Mn (0.50
ppm),Zn(0.15ppm),Cr(0.069ppm),Pb (0.05ppm),Ni(0.028ppm)andCd (0.003ppm).
Percolate from the above percolation column test contains metals with the variated amount
with the trend of longer leaching time the content in the percolate tended lower. This trend is
may due to the minerals easy dilute in fly ash immediately release the metals to the solution at
the first contact with solvent. In the nextb step, the residue of fly ash are minerals having lower
solubility. Moreover, the pH of percolate decrease with the longer of leaching time and the
higherflyashdosages.
. PercolateAnalysisResultfromLeachingProcess ofPeatandFlyAshTreatment
Table 2
Table2
Incubation Time Fe Mn Cu Zn Pb Cd Cr Ni
Dosage (g/kg)
Month
pH
0 1 3.43 0.00 0.12 1.40 0.11 0.00 0.002 0.011 0.023
2 3.39 0.14 0.16 1.08 0.06 0.00 0.000 0.023 0.015
3 3.63 0.21 0.12 0.81 0.02 0.00 0.001 0.023 0.015
25 1 3.59 0.10 0.24 0.80 0.09 0.02 0.000 0.023 0.013
2 3.52 0.16 0.27 1.90 0.07 0.01 0.001 0.011 0.013
3 3.72 0.94 0.13 1.81 0.03 0.00 0.001 0.046 0.020
50 1 4.23 0.20 0.25 1.10 0.12 0.00 0.002 0.011 0.020
2 3.61 0.32 0.50 0.81 0.06 0.05 0.001 0.000 0.015
3 3.64 0.69 0.09 0.96 0.02 0.00 0.001 0.000 0.015
75 1 4.15 0.26 0.26 1.47 0.10 0.00 0.003 0.023 0.018
2 3.89 0.57 0.21 0.75 0.09 0.00 0.002 0.011 0.015
3 4.26 1.41 0.08 1.23 0.02 0.00 0.001 0.057 0.013
125 1 4.04 1.86 0.17 1.66 0.15 0.05 0.001 0.011 0.023
2 5.04 8.44 0.12 0.16 0.10 0.03 0.001 0.011 0.018
3 5.75 11.68 0.22 0.41 0.08 0.01 0.000 0.069 0.028
CONCLUSIONS
Peat water having low pH (3.43) does not always dilute heavy metals from fly ash more than
that of aquadest. Duration of shaking does not relation to the amount of metals released from
fly ash. Maximum concentration of the elements dilute from fly ash at batch test were in order
from high to low as follows: Fe (PB), Zn (CB), Cr (MB), Mn (PB), Pb (PB and CB), Ni (PB, CB
andMB), Cu (PB, CB andMB), andCd(didnotdetected).
With the higher dosage of fly ash added as ameliorant in peat, the availability of metals of Fe,
Mn, Cu, Zn, Cd and Ni decrease, except Pb and Cr those did not give the regular change pattern.
The decrease of the availability of metals seemly related to the increase of the pH of peat from
3.60 to 5.12 6.67 causing the precipitation of metals in the form of hydroxides. Translocation
of metals togather with leaching of water variated with the pattern longer duration time of
leaching,decreasetheconcentrationinthepercolate.
Iskandar, Suwardi and E.F.R. Ramadina
--------- ------------------- ppm------ ---------------------------------
213Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management,
Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland”
REFERENCES
ACKNOWLEGMENTS
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Blume(Hrsg.). Ecomed,2.Auflage.
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enzymeactivities.Biol.Fertil.Soils17:167-172.
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controls on element concentrations in fly ash leachate. Waste Management & Research
13:435-450.
Stuczynski, T.I., G.W. McCarty and R.J. Wright. 1998a. Impact of coal combustion product
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952-959.
Stuczynski, T.I., G.W. McCarty, R.J. Wright and J.B. Reeves III. 1998b. Impact of coal
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ameliorant based on Fly Ash and Sewage Sludge. International Ash Utilization
Symposium,CenterforEnergyResearch,UniversityofKentucky.
The authors thanks to PT. Indah Kiat Pulp & Paper who has provided 3 kinds of fly ashes for
thisexperimentandwe alsothankforsupportingfundforthisresearch.
th
In et al
Jurnal Tanah Indonesia
Application of Fly Ash as Ameliorant in Peatland Environment:
The Release of Micro Nutrients and Heavy Metals

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APPLICATION OF FLY ASH AS AMELIORANT IN PEATLAND ENVIRONMENT : THE RELEASE OF MICRO NUTRIENTS AND HEAVY METALS

  • 1. PROCEEDINGS of BOGOR SYMPOSIUM &WORKSHOP ON TROPICAL PEATLAND MANAGEMENT BOGOR - INDONESIA, JULY 14 -15 2009 th th “ WISE USE OF TROPICAL PEATLAND” INTEGRATED FIELD ENVIRONMENTAL SCIENCE - GLOBAL CENTER OF EXCELLENT (IFES-GCOE) INDONESIAN LIAISON OFFICE W 16, Lv 6 Department of Soil Science and Land Resources Building, Fac.of Agriculture, IPB Jl. Meranti, Kampus IPB Darmaga, Bogor 16680-INDONESIA Phone: +62 (251)-8624334; Fax: +62 (251)- 8624334 fesindonesia@yahoo.co.idEmail: i ; suwardi_bogor@yahoo.com Edited by : Sudarsono, Ryusuke Hatano, Takashi Inoue, Suwido Limin, Gunawan Djajakirana, Suwardi
  • 3. Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” ISBN 978-602-96223-0-0 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management “ Wise Use of Tropical Peatland” Editors : Managing Editor : Prof. Dr. Sudarsono, Prof. Dr. Ryusuke Hatano, Prof. Dr. Takashi Inoue, Prof. Dr. Suwido Limin Dr. Gunawan Djajakirana, Dr. Suwardi, Septian Tri Putranto, SP Bogor Agricultural University Integrated Field Environmental Science - Global Center of Excellent (IFES-GCOE) Indonesian Liaison Office Hokkaido University 2009
  • 4. Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “ Wise Use of Tropical Peatland” COMMITTEE SteeringCommittee(SC) OrganizingCommittee(OC) Chairperson: Prof. Dr. HannyWijaya Members: 1. Prof. Dr. Ryosuke Hatano 2. Prof. Dr. Yasuyuki Hashidoko 3. Prof. Dr. Budi Mulyanto 4. Dr. Takashi Inoue 5. Dr. Anas M. Fauzi, M.Eng 6. Prof. Dr. Didy Sopandie 7. Dr. Kukuh Murtilaksono 1. Chairman : Dr.Suwardi 2. Secretary : 1. Dr.DyahTjahyandariS. 2. SeptianTriPutranto,SP 3. FinanceSecretary : Dr.Darmawan 4. Program,Publication : 1. Dr.Iskandar andDocumentation 2. Dr.GunawanDjajakirana 3. Dr.BasukiSumawinata 5. Accomodation, : 1. Dr.D.P.TejoBaskoro Transportationand 2. Ir.HermanuWijaya,Msc Consumption
  • 5. Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” iii TABLE OF CONTENTS Foreword ................................................................................................................. Table of Content ...................................................................................................... Opening Remark Chairperson of The Steering Committee Speech from Representative of IFES-GCOE ...................................... Speech from Representative of IFES-GCOE Targets of The Indonesian IFES- GCOE Program ............................................................................................. Speech and Opening The Symposium and Workshop ............. Current Issues of Tropical Peatland in Indonesia ............................................................................................................. CO and N O Emission Associated with Tropical Peatland Degradation ( ) ............................. Dynamics of Greenhouse Gases in Tropical Peatland Soils: Research Plan ) ............................................................................ A preliminary assessment of peat degradation in West Kalimantan ....................................................................................................... Estimation of Carbon Stock in Riau Peat-swampy Production Forest, Indonesia ................................................................................................... Screening of N O emitting microorganisms from soils of reclaimed tropical peat swamp forest and their N O emitting conditions ................. Plant Diversity and Biomass Content in Relation with Wise Use of Tropical Peatland ........................................................................ Community Structure ofAquatic Biota in the Peatland ........... Methanogenic microorganisms in peatlands ...................................... Biomass content and biodiversity of tropical peat swamp forest under various land cover conditions ...................... (Prof. Dr. HannyWijaya) (Prof. Dr. Ryusuke Hatano, Graduate School of Agriculture, Hokkaido University) (Dr. Anas M. Fauzi, Vice Rectorof Research and Collaboration, BogorAgricultural University) PART1 Issues Concerning theTropicalPeatland Basuki Sumawinata and Darmawan Ryusuke Hatano, Takashi Inoue, Untung Darung and Suwido Limin (Yohei Hamada and Ryusuke Hatano (Gusti Anshari) (Ulfah J. Siregar) (Yasuyuki Hashidoko) PART 2 Tropical Peatland in Natural Conditions (Istomo, Cahyo Wibowo) (Sutrisno Sukimin) (Abdul Hadi) (Adi Jaya, Ulfah J. Siregar, and M.Y. Massijaya) ( ) 2 2 2 2 i iii vii viii ix 1 11 19 33 46 52 57 67 74 84
  • 6. Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” iv PART 3 Potential of Tropical Peatland and Their Use Dedi Kusnadi Budi Indra Setiawan A.Harisman, S.Arfianto, E.Susandi, J.Ginting, Soewarso) (Suroso Rahutomo, E.S Sutarta, and W Darmosarkoro) (ClaraKusharto and M.Annis CaturAdi) (Apong Sandrawati and Suwardi) (Baba Barus, K. Gandasasmita and Reni Kusumo) (Bambang Hero Saharjo) (Darmawan, Basuki Sumawinata and Suwardi) (Soedodo Hardjoamidjojo and Nora H. Panjaitan) (Suwardi, Basuki Sumawinata, Darmawan, Gunawan Djajakirana, and Hermanu Wijaya) PART 4 Amelioration and Policy for Concerning Tropical Peatland (Suwardi, Gunawan Djajakirana, Hermanu Wijaya, and Basuki Sumawinata ) (Basuki Sumawinata, Gunawan Djajakirana, and D.P. Tejo Baskoro) (Eko Hanudin) The Environmentally Design of Water Management System for Sustainable PeatlandDevelopmentinIndonesia( ) .............................................. Integrated Water Zoning for Sustainable Forest Plantation in Tropical Peatlands ................................................................................................................ Utilization of Peatland for Oilpalm Plantation ........................................................................................... Food Availability And Agricultural Product In Peatland (Tabat Area), Central Kalimantan,Indonesia ....................... Utilization of Degraded Peatland for Producing Biomass as Source of Bioenergy and Compost .................................................. Mapping of peat hydrological unit and peat dome of Indonesia in supporting sustainable peat management ................................................................................................................. The carbon stock baseline as wise use management of tropical peat land. Case study intheoilpalmplantation ............................................... Characterization and Prediction of Tropical Peatland for The Wise Use ................................................. Development and Management of Wetland .......................................................................................................... Utilization of Acid Sulfate Soil in Rantau Rasau-Jambi Province for Cultivation of Gaharu .................................................................... Renovation of Acid Sulfate Soil for Integrated Farming at Delta Berbak, Jambi Province ......................................................................................................... Study on improvement of Indonesian acid sulphate soil : ameliorant for masking aluminium toxicity in rice plant ........................................................................................... Absorption of Ca, Mg, K, Na in corn on ombrogenous peat as affected by volcanic ash and fly ash application ............................................................. (Aquilaria sp) 99 110 124 134 144 148 157 171 178 185 191 200 201 Table of Contents
  • 7. Application of Fly Ash as Ameliorant in Peatland Environment: The Release of Micro Nutrients and Heavy Metals .................................................................................................................................. Restoration of hydrophobic peat by surfactants addition, its effect on water retention, cation, depository efficiency and FTIR Spectroscopy ..................................................................................................... Closing Remark ...................................................................................................... Listof Participants ................................................................................................... (Iskandar, Suwardi and E.F.R. Ramadina) (Sri Nuryani HidayahUtami) Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” v 207 214 237 239 Table of Contents
  • 8. 207Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” APPLICATION OF FLY ASH AS AMELIORANT IN PEATLAND ENVIRONMENT: THE RELEASE OF MICRO NUTRIENTS AND HEAVY METALS Iskandar , Suwardi and E.F.R. Ramadina 1 1 2 1 2 Department of Soil Science and Land Resources, Faculty of Agriculture, IPB Graduated from Department of Soil Science and Land Resources, Faculty of Agriculture, IPB Email: issi_iskandar@yahoo.com ABSTRACT INTRODUCTION Some researchers showed that fly ash can be used to improve the chemical properties of soil, such as increasing pH, exchangeable cations and base saturation. However, the application of fly ash as soil ameliorant in Indonesia is still constrained by government regulation that fly ash is classified as toxic and dangerous waste materials due to the contains of heavy metals. The objective of this research is to study the release of micro nutrients and heavy metals from fly ash in peat environment. This research was conducted by batch method with shaking fly ash in aquadest and peat water as solvent, and by column percolation method with flushing the mixture of fly ash and peat. Cations of Fe, Mn, Cu, Zn, Pb, Cd, Cr and Ni dissolved in filtrate were measured by Atomic Absorption Spectrophotometer (AAS). Fly ashes used in this study originatedfrom peatboiler(PB),chipboiler(CB)andmultiboiler(MB). The results showed that peat water did not always dissolve elements from fly ashes higher than those of aquadest. There was no significant relation between shaking time and amount of elements dissolve in the solution. Elements of Fe and Mn were released more from fly ash from PB, whereas the other elements released relatively in the same amount in all fly ashes used. In column percolation test, peat treated with fly ash after 3 months flushing showed decreasing availability of heavy metals with increasing fly ash dosage. Leachate from column percolation test contain elements in various amount. Generally, the amount of elements in percolate decreasewiththeincreaseofflushingtimeinorderofFe>Cu >Mn>Zn >Cr >Pb>Ni>Cd. Flyash, heavymetal,leaching,micronutrient,peatKeywords: Fly ash is residue from burning of coals in electrical generators using coal as fuel or boiler. The material can be used as soil ameliorant for improving chemical properties in mineral and peat soils. Although fly ash contains relatively complete and vary (Iskandar, Suwardi dan Ramadina, 2008), the application in the field as soil ameliorant is still constrained by government regulation. Government act No. 85 year 1999 classified the fly ash as dangerous and poisonous waste due to the contain of heavy metals. In soil science, some elements classified as heavy metals, are also classified as micro nutrients those need for plants such as Fe, Mn, Cu dan Zn (Horn, 1992;Alloway, 1995). In order elements in fly ash can be utilized for improving soil fertility, with still concern of the behavior of heavy metals released to the
  • 9. 208 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” Iskandar, Suwardi and E.F.R. Ramadina environment and waters, the research of the utilization of fly ash as soil ameliorant needs to be doneintensively. Mc Carty et al. (1994) studied the utilization of fly ash for increasing soil pH, whereas Stuczynski et al. (1998a) and Stuczynski et al. (1998b) studied the effect of fly ash and bed ash on mobilization of nitrogen and carbon. More comprehensive research has been done by Inthasan et al. (2002) studying the effect of fly ash for soil developed from granite, sandstone, and limestone. They showed that the availability of Fe, Mn, Cu and Zn exctracted by DTPA tended to decrease due to the increase of pH, where as the other heavy metals could not be detected consistenly. Truter et al. (2001) used mixed fly ash, sewage sludge and liming, with the ratio of 60%, 30% and 10% (dry weight) found that there were positive effect on increasing pH, Ca, Mg and Pavailable in the soil.The translocation of heavy metals (Ni and Cd), as well as essential micro nutrient of B, did not translocate significantly. The above important researches were conducted in mineral soils. Research on peat soil has been conducted by Iskandar, Djajakirana and Marolop (2003) through field experiment in forest plantation. The results showed that peat soil applied by 5 kg and 10 kg fly ash/plant of has pH, cation exchange, available P and base saturation higher than that of without fly ash application. Iskandar . (2008) was also showed the same results with percolation colomn experiment in the laboratory. Relation to heavy metals, Iskandar . (2003) showed that the content of heavy metal increase significantly in peat soil due to fly as application. Different from Fe, the other of heavy metals such as Ni, Pb, Cd and Cr did not increase significantly. On the other hand Fleming (1996) showed the content of heavy metals Cd, Cr, Zn, Pb, Hg and As in their colomn percolation increase with the decrease of the solvent pH buffered at the pH 6.8; 41and3,0. The objectives of this research is to study the solubility of micro nutrients and heavy metals in fly ash with the solvent of aquadest and peat water as well as the contents of those elements in peatappliedbyflyashafter3monthsleaching. This research was conducted using peat soil sample (pH 3.60) and peat water (pH 3.43) taken from Jambi. Fly ashes were collected from the furnace using peat as fuel peat boiler (PB), chip boiler(CB),andmultiboiler(MB) fromIndahKiatPulp&Paper,Perawang,Riau. These researches were conducted simultaneously in two stages in batch method and leaching method. Batch method for studying the solubility of micronutrients and heavy metals in the fly ash where as the leaching method for studying the effect of fly ash on the chemical properties of peatsoilandwaterqualityleachedfromcolomncontainingpeatsoil. Three kinds of fly ashes PB CB and MB were added by aquadest with the ratio of fly ash : aquadest of 1 : 5.The mixtures were shaked during 30, 60, 120, and 240 minutes.With the same method, the fly ashes were added by peat water. After shaking, the pH of the mixture was measured by pH-meter and the contents of Fe, Mn, Cu, Zn, Pb, Cd, Cr and Ni in the filtate were measuredbyAAS. Acasia sp et al et al et al. , MATERIALS AND METHOD BatchMethodExperiment
  • 10. 209Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” Column PercolationExperiment SolubilityofHeavyMetalsfromFlyAsh (Tabel1) Some 1 kg peat soil (air dry basis) was added to percolation column having 8.6 cm in diameter and 24.5 cm long. Above the peat soil was added by PB with the dosage of 0, 25, 50, 75, and 125 g/kg peat soil. Each percolation column was watered by 50 ml aquadest everyday and the percolate was captured by container. This treatment was conducted during 3 months. The percolate was measured every month for pH and the content of Fe, Mn, Cu, Zn, Pb, Cd, Cr and Ni. After 3 months, the peat soils in the column were analyzed for pH and metal elements extractedbyHCl0.05N. The pH of fly ashes of PB, CB and MB used in this experiment was alkalis ranging between 8.7 and 11.5. The contents of micronutrients and heavy metals varied, such as Fe 1.25 1.73%, Mn 200 300 ppm, Cu 7.90 43.3 ppm, Zn 24.3 97.8 ppm, Pb 0.40 26.3 ppm, Cd 0.11 0.70 ppm, Cr 9.78 27.9 ppm dan Ni 9.13 48.7 ppm (Iskandar ., 2008). The solubility of those micronutrientsandheavymetalsinaquadestandpeatwaterwas highlyvariated . Although peat water has pH of 3.43 but it did not meaning dillute heavy metals more than aquadest. This was because the pH of peat water mixed with fly ash changed to alkalis (pH 8,0 11,4). In this condition, some metals released from fly ash will precipitate in hydroxide compound forms. The duration of shaking did not have relation to the amount of metals released from the fly ashes. The number of metals Fe, Mn and Ni released from fly ash PB tended to increse with the longer duration of of shaking where as the other metals released from fly ashes of PB, CB and MB did not change or even decrease. The Fe and Mn released from fly ash PB were higher, where as the others elements relatively same in three fly ashes. The maximum concentration of elements diluted at batch test were as follows: Fe 1.67 ppm (PB), Mn 0.05 ppm (PB), Cu 0.01 ppm (PB, CB and MB), Zn 0.57 ppm (CB), Pb 0.02 ppm (PB and CB),Cdnotdetected,Cr0.11ppm(MB) andNi0.023ppm(PB, CBandMB). High variability of batch test results was due to the heterogeneous composition of fly ashes, solubility, and solubility kinetic of the metals in fly ashes (Reardon 1995). Minerals and glasses phase compose of fly ash are formed in wide range temperature. Most of materials in fly ash are found in oxidized condition or partial oxidation. If the materials contact with water, some materials will dilute and the others more stable and presipitate. Glasses particles and crystalline aluminosilicate dilute very slowly. Moreover, there are minerals composed from the condensation of elements created in lower temperature adhering on the surface of glass particles. This mineral groups consist of sulfate, borate, fluoride and chloride having high solubility and fast velocity of solubility. Oxidation phases found in fly ash such as CaO, MgO, Al O , Fe O andFe O havewidesolubilityrange. RESUTLS AND DISCUSION et al et al. 2 3 2 3 3 4 Application of Fly Ash as Ameliorant in Peatland Environment: The Release of Micro Nutrients and Heavy Metals
  • 11. 210 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” Table1. Solubility of heavy metals from fly ashes of PB, CB and MB in quadest and peat water indifferentdurationofshaking. Micronutrients and HeavyMetalsContent inPeat Figure 1 2and show the content of micronutrients of Fe, Mn, Cu, Zn and heavy metals of Pb, Cd, Cr, Ni in peat, respectively with the treatment of fly ash PB after leaching process with aquadest during 3 months.The two figures show that the higher fly ash dosages, the availability of metals Fe, Mn, Cu, Zn, Cd and Ni in the peat decrease. In the same treatment, the availability of Pb and Cr do not show the order change.The availabilityof Pb in peatafterincubationduring 3 months varied from not detected (control treatment) to 0.02 ppm, whereas Cr from 0.011 ppm to 0.034 ppm, but they did not found in the fly ash dosages of 75 and 125 mg/kg fly ash. The decrease of the availabiity of that metals seemly related to the increase of pH of the peat from 3.60 to about 5.12 6.67 causing the presipitation of metals in hydroxide forms (Iskandar ., 2008). et al Fe Mn Cu Zn Pb Cd Cr Ni Kinds of fly ash Extractant Shaking duration (minute) pH ---------------------------- ppm ---------------------------- 30 8.52 0.25 0.01 0.01 0.020 0.000 tr 0.080 0.013 60 8.49 0.22 0.01 0.01 0.040 0.000 tr 0.069 0.015 120 8.34 1.06 0.03 0.01 0.020 0.009 tr 0.080 0.023 Aquadest 240 8.26 1.67 0.05 0.01 0.040 0.009 tr 0.046 0.015 30 8.34 0.44 0.01 0.01 0.040 0.019 tr 0.046 0.008 60 8.30 0.58 0.01 0.01 0.030 0.009 tr 0.057 0.013 120 8.22 1.06 0.02 0.01 0.040 0.000 tr 0.046 0.018 PB Peat water 240 8.17 1.26 0.05 0.01 0.030 0.009 tr 0.091 0.023 30 8.49 0.06 0.01 0.00 0.510 0.009 tr 0.080 0.023 60 8.45 0.02 0.01 0.00 0.060 0.009 tr 0.057 0.015 120 8.42 0.03 0.01 0.00 0.050 0.000 tr 0.069 0.015 Aquadest 240 8.38 0.05 0.01 0.01 0.010 0.009 tr 0.069 0.018 30 8.14 0.05 0.01 0.00 0.570 0.000 tr 0.057 0.015 60 8.10 0.02 0.01 0.00 0.070 0.019 tr 0.080 0.015 120 8.06 0.01 0.01 0.00 0.060 0.019 tr 0.057 0.015 CB Peat water 240 8.02 0.05 0.02 0.00 0.050 0.009 tr 0.080 0.015 30 11.44 0.03 0.01 0.00 0.000 0.000 tr 0.069 0.013 60 11.41 0.01 0.01 0.01 0.000 0.009 tr 0.103 0.000 120 11.33 0.07 0.01 0.01 0.000 0.000 tr 0.114 0.023 Aquadest 240 11.30 0.03 0.01 0.01 0.000 0.009 tr 0.103 0.010 30 11.38 0.03 0.00 0.01 0.010 0.009 tr 0.114 0.015 60 11.35 0.05 0.01 0.00 0.000 0.009 tr 0.103 0.013 120 11.26 0.04 0.00 0.00 0.000 0.000 tr 0.091 0.015 MB Peat water 240 11.24 0.01 0.01 0.00 0.000 0.000 tr 0.103 0.018 Notes : PB = Peat Boiler, CB = Chip Boiler, MB = Multi Boiler Iskandar, Suwardi and E.F.R. Ramadina
  • 12. 211Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” 0,00 2,00 4,00 6,00 8,00 10,00 PO P1 P2 P3 P4 Dosis Konsentrasi(ppm) Fe Mn Cu Zn Dosage Concentration(ppm) Figure1. The concentrationof micronutrientsFe, Mn, Cu and Zn in peat after treatmentswith flyashinsomedosagesafterincubationduring3months. 0,00 0,01 0,02 0,03 0,04 0,05 0,06 PO P1 P2 P3 P4 Dosis Konsentrasi(ppm) Pb Cd Cr Ni Dosage Concentration(ppm) Figure2. Heavy metal contents of Pb, Cd, Cr and Ni in peat after treatment with fly ash in somedosagesafterincubationduring3months. Application of Fly Ash as Ameliorant in Peatland Environment: The Release of Micro Nutrients and Heavy Metals
  • 13. 212 Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” Diluted metals from fly ash besides adsorbed by peat, they also translocated with moved water. shows the contents of metals in the percolate from the leaching of peat with the treatment of the application of fly ash with some dosages. Metals that much translocated in the percolation column test were Fe (maximum 11.68 ppm), followed by Cu (1.81 ppm), Mn (0.50 ppm),Zn(0.15ppm),Cr(0.069ppm),Pb (0.05ppm),Ni(0.028ppm)andCd (0.003ppm). Percolate from the above percolation column test contains metals with the variated amount with the trend of longer leaching time the content in the percolate tended lower. This trend is may due to the minerals easy dilute in fly ash immediately release the metals to the solution at the first contact with solvent. In the nextb step, the residue of fly ash are minerals having lower solubility. Moreover, the pH of percolate decrease with the longer of leaching time and the higherflyashdosages. . PercolateAnalysisResultfromLeachingProcess ofPeatandFlyAshTreatment Table 2 Table2 Incubation Time Fe Mn Cu Zn Pb Cd Cr Ni Dosage (g/kg) Month pH 0 1 3.43 0.00 0.12 1.40 0.11 0.00 0.002 0.011 0.023 2 3.39 0.14 0.16 1.08 0.06 0.00 0.000 0.023 0.015 3 3.63 0.21 0.12 0.81 0.02 0.00 0.001 0.023 0.015 25 1 3.59 0.10 0.24 0.80 0.09 0.02 0.000 0.023 0.013 2 3.52 0.16 0.27 1.90 0.07 0.01 0.001 0.011 0.013 3 3.72 0.94 0.13 1.81 0.03 0.00 0.001 0.046 0.020 50 1 4.23 0.20 0.25 1.10 0.12 0.00 0.002 0.011 0.020 2 3.61 0.32 0.50 0.81 0.06 0.05 0.001 0.000 0.015 3 3.64 0.69 0.09 0.96 0.02 0.00 0.001 0.000 0.015 75 1 4.15 0.26 0.26 1.47 0.10 0.00 0.003 0.023 0.018 2 3.89 0.57 0.21 0.75 0.09 0.00 0.002 0.011 0.015 3 4.26 1.41 0.08 1.23 0.02 0.00 0.001 0.057 0.013 125 1 4.04 1.86 0.17 1.66 0.15 0.05 0.001 0.011 0.023 2 5.04 8.44 0.12 0.16 0.10 0.03 0.001 0.011 0.018 3 5.75 11.68 0.22 0.41 0.08 0.01 0.000 0.069 0.028 CONCLUSIONS Peat water having low pH (3.43) does not always dilute heavy metals from fly ash more than that of aquadest. Duration of shaking does not relation to the amount of metals released from fly ash. Maximum concentration of the elements dilute from fly ash at batch test were in order from high to low as follows: Fe (PB), Zn (CB), Cr (MB), Mn (PB), Pb (PB and CB), Ni (PB, CB andMB), Cu (PB, CB andMB), andCd(didnotdetected). With the higher dosage of fly ash added as ameliorant in peat, the availability of metals of Fe, Mn, Cu, Zn, Cd and Ni decrease, except Pb and Cr those did not give the regular change pattern. The decrease of the availability of metals seemly related to the increase of the pH of peat from 3.60 to 5.12 6.67 causing the precipitation of metals in the form of hydroxides. Translocation of metals togather with leaching of water variated with the pattern longer duration time of leaching,decreasetheconcentrationinthepercolate. Iskandar, Suwardi and E.F.R. Ramadina --------- ------------------- ppm------ ---------------------------------
  • 14. 213Proceedings of Bogor Symposium and Workshop on Tropical Peatland Management, Bogor, Indonesia, 14-15 July 2009 “Wise Use of Tropical Peatland” REFERENCES ACKNOWLEGMENTS Alloway, B. J. 1995. Heavy Metals in Soils. Blackie Academic & Proffesional. London, Glasgow. Fleming, L. N., H. N. Abinteh and H. I. Inyang. 1996. Leachant pH effects on the leachability ofmetalsfromflyash.JournalofSoilContamination5(1):53-59. Horn, R. 1992. Standortanforderungen der Pflanzen. In Handbuch des Bodenschutzes. H.-P. Blume(Hrsg.). Ecomed,2.Auflage. Inthasan, J., N. Hirunburana, L. Herrmann and K. Stahr. 2002. Effects of fly ash applications on soil properties, nutrient status and environment in Nothern Thailand. Paper presentedin17 WorldCongress of SoilScience,BangkokAugust, 14 20,2002. Iskandar, G. Djajakirana and R. Marolop. 2003. The Use of FlyAsh asAmeliorant to Improve the Chemical Properties of Peat Soil. M. Osaki . (eds.) Procedings of the International Symposium on Land Management and Biodiversity in Southeast Asia. Bali,September18-20,2002. Iskandar, Suwardi dan E. F. R. Ramadina. 2008. Pemanfaatan bahan amelioran abu terbang pada lingkungan tanah gambut: (I) Pelepasan hara makro. Vol. 1No. 1,Maret2008. McCarty, G.W., R. Siddaramappa, R.J. Wright, E.E. Codling and G. Gao. 1994. Evaluation of coal combustion byproducts as soil liming materials: Their influence on soil pH and enzymeactivities.Biol.Fertil.Soils17:167-172. Reardon, E. J., C. A. Czank, C. J. Warren, R. Dayal, and M. Johnston. 1995. Determining controls on element concentrations in fly ash leachate. Waste Management & Research 13:435-450. Stuczynski, T.I., G.W. McCarty and R.J. Wright. 1998a. Impact of coal combustion product amendments on soil quality: I. Mobilization of soil organic nitrogen. Soil Science 163: 952-959. Stuczynski, T.I., G.W. McCarty, R.J. Wright and J.B. Reeves III. 1998b. Impact of coal combustion product amendments on soil quality: II. Mobilization of soil organic carbon.SoilScience163:960-969. Truter, W. F., N. F. G. Rethman, K. A. Reynold, and R. A. Kruger. 2001. The Use of Soil ameliorant based on Fly Ash and Sewage Sludge. International Ash Utilization Symposium,CenterforEnergyResearch,UniversityofKentucky. The authors thanks to PT. Indah Kiat Pulp & Paper who has provided 3 kinds of fly ashes for thisexperimentandwe alsothankforsupportingfundforthisresearch. th In et al Jurnal Tanah Indonesia Application of Fly Ash as Ameliorant in Peatland Environment: The Release of Micro Nutrients and Heavy Metals