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Air Pollution
What is air pollution
o Any visible or invisible particle or gas
found in the air that is not part of the
original, normal composition
o Natural: forest fires, dust storm
o Unnatural: man-made; coal, wood and other
fuels used in cars, homes, and factories
for energy
AQI: Air Quality Index
o Indicates whether pollutant levels in air
may cause health concerns.
o AQI is calculated for five major air
pollutants regulated by the Clean Air Act:
ground-level ozone, particle pollution (also
known as particulate matter), carbon
monoxide, sulfur dioxide, and nitrogen
dioxide and converts the measured
pollutant concentrations in a community's
air to a number on a scale of 0 to 500
How AQI is calculated?
o An individual score (Individual Air Quality
Index, IAQI) is assigned to each pollutant
and the final AQI is the highest of these
scores. The final AQI value can be
calculated either per hour or per 24 hours.
Air Quality Air Quality Index Protect Your Health
Good 0-50 No health impacts are expected when
air quality is in this range.
Moderate 51-100 Unusually sensitive people should
consider limiting prolonged outdoor
exertion.
Unhealthy for
Sensitive Groups
101-150 Active children and adults, and people
with respiratory disease, such as
asthma, should limit prolonged outdoor
exertion.
Unhealthy 151-200
Active children and adults, and people
with respiratory disease, such as
asthma, should limit prolonged outdoor
exertion, everyone else, especially
children should limit prolonged outdoor
excertion.
Very Unhealthy (Alert) 201-300 Active children and adults, and people
with respiratory disease, such as
asthma, should limit prolonged outdoor
exertion everyone else, especially
children, should limit outdoor exertion.
Overview
o Atmosphere as a Resource
o Types and Sources of Air Pollution
• Major Classes of Air Pollutants
• Sources of Outdoor Air Pollutants
• Urban Air Pollution
o Effects of Air Pollution
o Controlling Air Pollution
Atmosphere as a Resource
o Atmospheric
Composition
• Nitrogen 78.08%
• Oxygen 20.95%
• Argon 0.93%
• Carbon dioxide 0.04%
o Ecosystem services
• Blocks UV radiation
• Moderates the
climate
• Redistributes water in
the hydrologic cycle
Types and Sources of Air Pollution
o Air Pollution
• Chemicals added to the atmosphere by natural
events or human activities in high enough
concentrations to be harmful
o Two categories
• Primary Air Pollutant
• Harmful substance that is emitted directly into the
atmosphere
• Secondary Air Pollutant
• Harmful substance formed in the atmosphere when
a primary air pollutant reacts with substances
normally found in the atmosphere or with other air
pollutants
Major Air Pollutants
Major Classes of Air Pollutants
o Particulate Material
o Nitrogen Oxides
o Sulfur Oxides
o Carbon Oxides
o Hydrocarbons
o Ozone
Particulate Material
o Thousands of different solid or liquid
particles suspended in air
• Includes: soil particles, soot, lead, asbestos,
sea salt, and sulfuric acid droplets
o Dangerous for 2 reasons
• May contain materials with toxic or
carcinogenic effects
• Extremely small particles can become lodged in
lungs
Nitrogen and Sulfur Oxides
o Nitrogen Oxides
• Gases produced by the chemical interactions
between atmospheric nitrogen and oxygen at
high temperature
• Problems
• Greenhouse gases
• Cause difficulty breathing
o Sulfur Oxides
• Gases produced by the chemical interactions
between sulfur and oxygen
• Causes acid precipitation
Carbon Oxides and Hydrocarbons
o Carbon Oxides
• Gases carbon monoxide (CO) and carbon
dioxide (CO2)
• Greenhouse gases
o Hydrocarbons
• Diverse group of organic compounds that
contain only hydrogen and carbon (ex: CH4-
methane)
• Some are related to photochemical smog and
greenhouse gases
Ozone
o Tropospheric Ozone
• Man- made pollutant in the lower atmosphere
• Secondary air pollutant
• Component of photochemical smog
o Stratospheric Ozone
• Essential component that screens out UV
radiation in the upper atmosphere
• Man- made pollutants (ex: CFCs) can destroy it
Sources of Outdoor Air Pollution
o Two main sources
• Transportation
• Industry
o Intentional forest
fires is also high
Urban Air Pollution
o Photochemical Smog
• Brownish-orange haze formed by chemical reactions
involving sunlight, nitrogen oxide, and hydrocarbons
Formation of Photochemical Smog
Sources of Smog
Case-In-Point Air Pollution in Beijing
and Mexico City
o Beijing (left)
o Mexico City (above)
The Clean Air Act
o Authorizes EPA to set
limits on amount of
specific air pollutants
permitted
o Focuses on 6
pollutants:
• lead, particulate
matter, sulfur dioxide,
carbon monoxide,
nitrogen oxides, and
ozone
o Act has led to
decreases!
Other Ways to Improve Air Quality
o Reduce sulfur content in gasoline from its
current average of 330 ppm to 30 ppm
• Sulfur clogs catalytic converters
o Require federal emission standards for all
passenger vehicles
• Including SUVs, trucks and minivans
o Require emission testing for all vehicles
• Including diesel
Ozone Depletion in Stratosphere
o Ozone Protects earth from UV radiation
• Part of the electromagnetic spectrum with
wavelengths just shorter than visible light
Ozone Depletion in Stratosphere
o Ozone thinning/hole
• First identified in 1985
over Antarctica
o Caused by
• human-produced bromine
and chlorine containing
chemicals
• Ex: CFCs
Ozone Depletion in Stratosphere
o Hole over Antarctica requires two
conditions:
• Sunlight just returning to polar region
• Circumpolar vortex- a mass of cold air that
circulates around the southern polar region
• Isolates it from the warmer air in the rest of the
planet
o Polar stratospheric clouds form
• Enables Cl and Br to destroy ozone
Effects of Ozone Depletion
o Higher levels of UV-
radiation hitting the
earth
• Eye cataracts
• Skin cancer (right)
• Weakened immunity
o May disrupt
ecosystems
o May damage crops
and forests
Recovery of Ozone Layer
o Montreal Protocol (1987)
• Reduction of CFCs
• Started using HCFCs (greenhouse gas)
o Phase out of all ozone destroying chemicals
is underway globally
o Satellite pictures in 2000 indicated that
ozone layer was recovering
o Full recovery will not occur until 2050
Acid Deposition
o Sulfur dioxide and nitrogen dioxide
emissions react with water vapor in the
atmosphere and form acids that return to
the surface as either dry or wet deposition
o pH scale
How Acid Deposition Develops
Effects of Acid Deposition
o Declining Aquatic
Animal Populations
o Forest decline
• Ex: Black forest in
Germany (50% is
destroyed)
Acid Deposition and Forest Decline
Air Pollution Around the World
o Air quality is deteriorating
rapidly in developing countries
o Shenyang, China
• Residents only see sunlight a few
weeks each year
o Developing countries have older
cars
• Still use leaded gasoline
o 6 worst cities in world
• Beijing, China; Mexico City, Mexico;
Shanghai, China; Tehran, Iran; and
Calcutta, India, Faisalabad,
Pakistan
Indoor Air
Pollution
o Pollutants can be
5-100X greater
than outdoors
o Most common:
• Radon, carbon
monoxide,
nitrogen dioxide,
formaldehyde
pesticides, lead,
cleaning solvents,
ozone, and
asbestos
Indoor Air Pollution

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Lec 19 Air Pollution.ppt

  • 2. What is air pollution o Any visible or invisible particle or gas found in the air that is not part of the original, normal composition o Natural: forest fires, dust storm o Unnatural: man-made; coal, wood and other fuels used in cars, homes, and factories for energy
  • 3. AQI: Air Quality Index o Indicates whether pollutant levels in air may cause health concerns. o AQI is calculated for five major air pollutants regulated by the Clean Air Act: ground-level ozone, particle pollution (also known as particulate matter), carbon monoxide, sulfur dioxide, and nitrogen dioxide and converts the measured pollutant concentrations in a community's air to a number on a scale of 0 to 500
  • 4. How AQI is calculated? o An individual score (Individual Air Quality Index, IAQI) is assigned to each pollutant and the final AQI is the highest of these scores. The final AQI value can be calculated either per hour or per 24 hours.
  • 5. Air Quality Air Quality Index Protect Your Health Good 0-50 No health impacts are expected when air quality is in this range. Moderate 51-100 Unusually sensitive people should consider limiting prolonged outdoor exertion. Unhealthy for Sensitive Groups 101-150 Active children and adults, and people with respiratory disease, such as asthma, should limit prolonged outdoor exertion. Unhealthy 151-200 Active children and adults, and people with respiratory disease, such as asthma, should limit prolonged outdoor exertion, everyone else, especially children should limit prolonged outdoor excertion. Very Unhealthy (Alert) 201-300 Active children and adults, and people with respiratory disease, such as asthma, should limit prolonged outdoor exertion everyone else, especially children, should limit outdoor exertion.
  • 6. Overview o Atmosphere as a Resource o Types and Sources of Air Pollution • Major Classes of Air Pollutants • Sources of Outdoor Air Pollutants • Urban Air Pollution o Effects of Air Pollution o Controlling Air Pollution
  • 7. Atmosphere as a Resource o Atmospheric Composition • Nitrogen 78.08% • Oxygen 20.95% • Argon 0.93% • Carbon dioxide 0.04% o Ecosystem services • Blocks UV radiation • Moderates the climate • Redistributes water in the hydrologic cycle
  • 8. Types and Sources of Air Pollution o Air Pollution • Chemicals added to the atmosphere by natural events or human activities in high enough concentrations to be harmful o Two categories • Primary Air Pollutant • Harmful substance that is emitted directly into the atmosphere • Secondary Air Pollutant • Harmful substance formed in the atmosphere when a primary air pollutant reacts with substances normally found in the atmosphere or with other air pollutants
  • 10.
  • 11. Major Classes of Air Pollutants o Particulate Material o Nitrogen Oxides o Sulfur Oxides o Carbon Oxides o Hydrocarbons o Ozone
  • 12. Particulate Material o Thousands of different solid or liquid particles suspended in air • Includes: soil particles, soot, lead, asbestos, sea salt, and sulfuric acid droplets o Dangerous for 2 reasons • May contain materials with toxic or carcinogenic effects • Extremely small particles can become lodged in lungs
  • 13. Nitrogen and Sulfur Oxides o Nitrogen Oxides • Gases produced by the chemical interactions between atmospheric nitrogen and oxygen at high temperature • Problems • Greenhouse gases • Cause difficulty breathing o Sulfur Oxides • Gases produced by the chemical interactions between sulfur and oxygen • Causes acid precipitation
  • 14. Carbon Oxides and Hydrocarbons o Carbon Oxides • Gases carbon monoxide (CO) and carbon dioxide (CO2) • Greenhouse gases o Hydrocarbons • Diverse group of organic compounds that contain only hydrogen and carbon (ex: CH4- methane) • Some are related to photochemical smog and greenhouse gases
  • 15. Ozone o Tropospheric Ozone • Man- made pollutant in the lower atmosphere • Secondary air pollutant • Component of photochemical smog o Stratospheric Ozone • Essential component that screens out UV radiation in the upper atmosphere • Man- made pollutants (ex: CFCs) can destroy it
  • 16. Sources of Outdoor Air Pollution o Two main sources • Transportation • Industry o Intentional forest fires is also high
  • 17. Urban Air Pollution o Photochemical Smog • Brownish-orange haze formed by chemical reactions involving sunlight, nitrogen oxide, and hydrocarbons
  • 20. Case-In-Point Air Pollution in Beijing and Mexico City o Beijing (left) o Mexico City (above)
  • 21. The Clean Air Act o Authorizes EPA to set limits on amount of specific air pollutants permitted o Focuses on 6 pollutants: • lead, particulate matter, sulfur dioxide, carbon monoxide, nitrogen oxides, and ozone o Act has led to decreases!
  • 22. Other Ways to Improve Air Quality o Reduce sulfur content in gasoline from its current average of 330 ppm to 30 ppm • Sulfur clogs catalytic converters o Require federal emission standards for all passenger vehicles • Including SUVs, trucks and minivans o Require emission testing for all vehicles • Including diesel
  • 23. Ozone Depletion in Stratosphere o Ozone Protects earth from UV radiation • Part of the electromagnetic spectrum with wavelengths just shorter than visible light
  • 24. Ozone Depletion in Stratosphere o Ozone thinning/hole • First identified in 1985 over Antarctica o Caused by • human-produced bromine and chlorine containing chemicals • Ex: CFCs
  • 25. Ozone Depletion in Stratosphere o Hole over Antarctica requires two conditions: • Sunlight just returning to polar region • Circumpolar vortex- a mass of cold air that circulates around the southern polar region • Isolates it from the warmer air in the rest of the planet o Polar stratospheric clouds form • Enables Cl and Br to destroy ozone
  • 26. Effects of Ozone Depletion o Higher levels of UV- radiation hitting the earth • Eye cataracts • Skin cancer (right) • Weakened immunity o May disrupt ecosystems o May damage crops and forests
  • 27. Recovery of Ozone Layer o Montreal Protocol (1987) • Reduction of CFCs • Started using HCFCs (greenhouse gas) o Phase out of all ozone destroying chemicals is underway globally o Satellite pictures in 2000 indicated that ozone layer was recovering o Full recovery will not occur until 2050
  • 28. Acid Deposition o Sulfur dioxide and nitrogen dioxide emissions react with water vapor in the atmosphere and form acids that return to the surface as either dry or wet deposition o pH scale
  • 30. Effects of Acid Deposition o Declining Aquatic Animal Populations o Forest decline • Ex: Black forest in Germany (50% is destroyed)
  • 31. Acid Deposition and Forest Decline
  • 32. Air Pollution Around the World o Air quality is deteriorating rapidly in developing countries o Shenyang, China • Residents only see sunlight a few weeks each year o Developing countries have older cars • Still use leaded gasoline o 6 worst cities in world • Beijing, China; Mexico City, Mexico; Shanghai, China; Tehran, Iran; and Calcutta, India, Faisalabad, Pakistan
  • 33. Indoor Air Pollution o Pollutants can be 5-100X greater than outdoors o Most common: • Radon, carbon monoxide, nitrogen dioxide, formaldehyde pesticides, lead, cleaning solvents, ozone, and asbestos