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International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 545
Environmental Impact Evaluation of the
Industry of Panela by Life Cycle Analysis
Dr. C. Walter Francisco Quezada Moreno1
., Dra. C. Ana Margarita Contreras Moya2
,
Dra. C. Elena Rosa Domínguez2
, Dr (asp.). David Quezada Torres2
, Mg. Franklin
Antonio Molina Borja1
, Mg. Jaime Orlando Rojas Molina1
1
Department of research, Technical University of Cotopaxi.
2
Department of Chemical Engineering. University "Marta Abreu" of Las Villas. Carr. a Camajuani Km 5½. Santa Clara,
Villa Clara. Cuba.
Abstract— The objective of the study is to evaluate the
environmental impacts generated by the industry of the
panela in Ecuador, using the Life Cycle Analysis
methodology. The in situ information gathered allowed the
identification of the sensitive environmental factors that
are affected in all the operations that are carried out in
the agroindustry of panela.
The results show that the craft activities prevail rather
than the industrial activities, due to the low industrial
development, application and control of regulations,
rudimentary manufacturing practices, among others;
which have led to insufficient productivity,
competitiveness, quality and safety of their products. The
results of the Environmental Impact Assessment, using the
Eco-Indicator 99 method, according to the Life Cycle
Analysis technique, show that the industrial stage has the
greatest contribution to the impact, being more
representative the impact to the effects by respiration of
inorganic compounds, acidification / eutrophication,
climate change and land use. The impact level of this type
of industry according to Ecuador's environmental
legislation, places it as an industry that generates
moderate environmental impacts, it does not require
intensive protective or corrective practices. However, it
requires environmental executive actions oriented to the
control and prevention to mitigate these impacts.
Keywords— Agroindustry of Panela, Life Cycle
Analysis, Environmental Impact.
I. INTRODUCTION
As societies progress and develop, the energy demands
and their environmental effects grow. A balance between
production and consumption can be achieved if all the
agents acting on the market do so in a responsible way[1],
where quality and competitiveness must be fully justified
by actions of continuous improvement and innovative
efforts for clean and safe productions.
The agroindustry of panela in Ecuador has the purpose of
developing productive activities from the cultivation,
processing and commercialization of sugar cane for
panela, natural sugar and honey. Its effects in terms of
employment multiplication, value addition, and nutrients
are high [2] [3]. It is estimated that there are 519 agro-
industries, production units of panela in the country that
use fuel materials for the process such as bagasse,
firewood and tires alone or combined [4]. The lack of
quality, harmlessness, diversification of production,
assessment of productive yield and use of by-products are
some of the problems that have generated its lag. In the
agroindustry of panela the activities of handcrafted
character prevail over the activities of industrial character.
However, efforts are being made in technological
improvements in the panela production, natural sugar and
recent studies with cane honey, for commercial purposes
[5]. In spite of the importance of the sector and the
existence of environmental legislation, its execution with
technical and environmental obligations has not yet
materialized, affecting the productivity, quality and
harmlessness of its products and environment.
In the industry of panela, the cleaner productions must be
a reality and of business fulfillment and awareness. Clean
Productions are safe and ultimately economical and
necessary for the sustainability of a technological process.
Innovative efforts are required from a technical-economic
and environmental point of view to achieve improvements
and higher productivity with lower resources, which must
be valued environmentally to favor their investments and
secure the market.
Environmental assessments are valid tools that have
become in actions in the business and governmental world
to understand and manage the risks and opportunities of
the stages of the life cycle of a product or process towards
the introduction of scientific knowledge to describe
associated environmental impacts.
1. 1 Agroindustry of Panela
Panela activity is a subsector of the agro industrial sector,
where the panela is the main sweetener obtained by
extracting, cleaning and concentrating the juice of the
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 546
cane. It is a fundamental pillar for rural social, economic,
cultural development and for the sovereignty and food and
nutritional security of many countries in Asia, the
Caribbean and South America [4] [6]. This activity in
most factories is developed neglecting technical,
environmental and quality standards throughout the
process line.
The activities are more handcrafted than industrial; due to
its poor development, application and control of
regulations, rudimentary manufacturing practices, among
others; which have led to insufficient productivity,
competitiveness, quality and harmlessness of their
products. However, it plays a key and an important role
for food sovereignty and security, allowing safe and
permanent access to sufficient and nutritious food in all
markets, especially in rural and marginal urban areas.
This activity uses different materials for the production
and commercialization: water, energy, cane and vegetal
and chemical mucilages in the clarification of juice as
clarol or sodium hydrosulfite, carbonates, vegetable fats,
fuels and others [7] [8].
Deforestation for firewood and the establishment of cane
cultivation, the preparation of the land and the application
of agrochemicals for its management, coupled with the
low efficiency of combustion and heat transfer processes
in the burner, are activities that generate negative changes
in environmental quality.
In many cases, the sustainability of the activity to
concentrate juice to obtain panela is at risk, due to the lack
of environmental awareness. The inefficiency of the
panela burners, the use of wood that affects the forests,
tires and greenhouse plastics to generate energy and that
give off toxic gases such as carbon monoxide (CO) and
nitrogen to the atmosphere, are aspects that weaken its
activity. CO is a pollutant; it is the product of the
incomplete combustion of any type of fuel. The tires have
sulfur in the form of sulfides that in the burning they are
oxidized and released into the air as a pollutant. This type
of reaction is characterized by the presence of combustible
substances or also called unburned in the combustion
gases, such as carbon in the form of ash, CO and H2.
Bagasse, firewood and tires generate compounds such as
CO2, CO, NOx, SOx, H2, H2O and other gases and
particles, energy and ash. In the stage of clarification,
evaporation and concentration the negative effects are
evidenced by the generated and untapped water vapor, the
use of flocculants and the presence of wastes [9].
In spite of the multiple advantages of cane in the
agroindustry of panela in Colombia and Ecuador, it has an
undesirable impact due to the consumption of large
amounts of fuel wood and used tires and the energy
inefficiency of the burners. Up to three tons of firewood
per ton of panela are used, generating problems of
deforestation, soil erosion and pollution [10] [4], so its
environmental effect is highly negative. The calorific
power of a tire is 8300 Kcal / kg and the gases that are
derived are compounds of carbon, nitrogen and sulfur.
Carbon black creates disorders in the respiratory system.
Energy efficiency in the operation of the burner, good
manufacturing practices and safety and good use and
waste management, is determinant to avoid negative
impacts to the environment in the activity of the
agroindustry of panela. However, environmental
degradation and overexploitation of natural resources can
weaken a country's competitive base [11]. For this reason,
a concept is needed that manages access to raw materials
and imposes controls on improper processing practices in
order to maintain the integrity of the environment and
protect natural resources, and another that on the other
hand, it is required an understanding of the competitive
nature of the agroindustrial sector and the entrepreneur's
unique role [12]. Planning is required for efficient
performance in the technological and economic systems of
the activity of the panela that does not adversely affect
society and the natural environment. Consumers show and
demand a growing interest in knowing what is behind
each product, since, apart from the quality and safety of
food, the health and welfare of the community and the
quality of the environment are ahead.
1.2 Environmental analysis
Cities require food, paper, water, and other products every
minute, so as by-products of their processes emit large
quantities of particulate material, CO, SO2, NOx and other
gases as well as large volumes of solid and liquid wastes
[13]. Therefore, despite a great effort in research and
action aimed at avoiding environmental pollution, it
remains a worldwide concern.
Life Cycle Analysis (LCA) is an environmental
management technique to evaluate the potential
environmental aspects and impacts associated with a
product [14] [15]. It is a tool to examine the environment
of the serious consequences of the manufacture and use of
products or the provision of services [16]. It allows the
systematic evaluation of the environment and aspects of a
product or service system through all stages of its life
cycle [17] [18]. The LCA is positioned as a key tool for
the evaluation of potential environmental impacts, as well
as for the generation of useful scientific and technical
information for the orientation of environmental policy
and legislation; the establishment and strengthening of
integrated waste management programs and management
plans among other policy instruments, as well as the
decision-making in the industrial and social sectors [19].
The LCA means recognizing how our choices influence
each stage of the process and thus weighing the
advantages and disadvantages contributing to the
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 547
economy, the environment and society [20]. It is essential
for the sustainable development, to go beyond traditional
production to one with responsibility, where economic,
environmental and social aspects prevail [21]. The
application of the LCA technique in the industry of panela
constitutes a viable and applicable tool for the entire chain
of production, considering internal and external effects.
The greatest contribution is to think and act to mitigate
adverse effects to the environment, caused by industrial
processes, market or consumption. It is not only
generating work, development or food, is to produce
thinking about the welfare of all. It is health and good
living. It is economic growth, ecological balance and
social progress [22]. The global implementation plan for
Sustainable Development calls for: "improving products
and services while reducing health and environmental
impacts, using scientific models such as life-cycle analysis
where appropriate" [23].
The execution of LCA studies to the sector, analyzing the
productions of the activity of panela including the natural
sugar, honey and byproducts that it generates, will allow a
comprehensive diagnosis of the environmental situation of
this activity in the countries of the world and in Ecuador
especially.
1.3 Environmental Legislation
Due to its level of pollution, industry in general has
worldwide been permanently under the eyes of the
community. FAO General - Director José Graziano said in
Santiago de Chile that climate change is not a problem of
the future but the present. He has warned of its impact in
South America, he said that the impacts are being greater
than what was thought and yet it is not known how it will
affect food production [24].
Concern about the environmental deterioration due to
industrialization at a global level has determined that the
sustainability of the sector in the country is determined to
comply with the current environmental legislation in the
sector and country. However, its application and control
has not had results, its breach is visible and notorious.
According to Annex I of the National Environmental
Categorization Catalog (CCAN), for the construction and /
or operation of factories for the production of panela, it is
classified in group II, considered of low impact and
requires an environmental file [25].
The government of Ecuador has implemented demanding
environmental legislation with respect to the environment,
but, these provisions are not fulfilled in the sector. In
Ecuador, Local and Provincial Governments known as
GAD have legislations that try to regulate certain
activities, but with unsatisfactory results for the
community. The existing normative instruments of
environmental legislation under the present Constitution
of the Ecuador Republic grouped in the Unified Text of
Environmental Legislation TULAs and the Organic Law
of Municipal Regime guides the way of control of
productive activities [26]. Considering the impact that the
whole production chain has on the environment in a
holistic manner will be decisive for the sustainability
process of the sector [27].
II. MATERIALS AND METHODS
A bibliographical review about the industry of panela was
carried out and data were collected through an in situ
diagnosis to the agroindustries of panela in the center and
north of the country. It is estimated that there are 519
productive units. In three production units, the gas
produced by combustion was measured using the E-
instrument 4400 equipment. The first unit of panela
operates with bagasse, the second with firewood and the
third uses pneumatic tires. In addition, the control in the
diesel engine was carried out to operate the equipment of
cane juice extraction.
For the environmental evaluation, applying the
methodology of Life Cycle Analysis was considered as a
case study the unit of panela that operates with bagasse
only. It has a processing capacity of 20 t cane / day, where
noise was also evaluated using the EXTECH Instruments
sound level meter, ranging from 26 to 130 dB (A).
Controls of wastewater volume, pH and soluble solids
(brix) were performed on the liquid wastes from the
cleaning, clarifying, concentrating and washing tubs of
molds and materials. The environmental effects were
analyzed according to the limits of the system shown in
figure 1.
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 548
Fig.1: System limits for LCA in the production of panela.
The general inventory of the unit of production was
carried out according to information of the entire
productive chain of the activity of panela (cane
production, processing and marketing).
The results are plotted and the environmental assessment
is performed using the Life Cycle Analysis (LCA)
methodology according to the Sima Pro7.3 software and
the Eco-indicator 99 methodology, according to the
system limits shown and taking as a functional unit the
daily production of panela, which corresponds to 2485 kg.
III. RESULTS
The balance of material and energy applied through
stoichiometric calculations according to the inputs and
outputs of products generated the results indicated in
figure 2.
Fig.2: Mass balance and contaminant identification
Agricultural stage
Industrial stage
Organic Fertilizer
Chemical clarifiers
Natural clarififiers
Gaseous fuels
Oils and Lubricants
Land Resources
Energy Resources
Material
Resources
Emissions to air
Emissions to water
Emissions to land
Panela Ash Filter cake Bagasse
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 549
The balance of mass and contaminants generated by the
20 tons of cane per day produces 2485 kg of panela, by-
products and wastes, such as: 8800 kg of bagasse for
combustion (energy needed to concentrate juice to panela)
and 1530 liters of wastewaters produced in the different
containers which are discharged to the ground and that
have natural watercourses as destination. The pH of the
wastewaters and the solids soluble in the solution in the
different containers reach values between 4.64 - 5.11 and
2.10 to 11.3 brix degrees, respectively.
The analysis of the permissible limits of noise levels for
fixed sources, mobile sources and vibrations is done
according to the Unified Text of Environmental
Legislation (TULAs), which establishes that the sound
pressure limit within an industrial zone, is 75 dB (A) in an
eight-hour noise exposure per day [26]. The results of
noise indicate that the point A = 83.42 dB (A), very close
to the engine (machine that drives the mill or cane juice
extraction equipment), exceeds the permissible limit of
noise emissions.
In Figure 3, the average results of 14 measurements
performed every 30 minutes on the two burner combustion
processes are shown: the first one using bagasse only, the
second one operating with wood or firewood (sawmill
waste and boxes used to transport fruit) and in the engine.
In the burner using bagasse, high temperature values are
obtained in the flue gases and the combustion is better,
since fewer gases (CO and NO) are obtained in front of
the burner that uses wood in the combustion.
Fig.3: Parameters of the combustion of bagasse, firewood and in the engine.
The generation of gases is within the limit allowed in
both, carbon monoxide (CO) and nitrogen (NO); being
greater the amounts generated in the wood burner than in
the one that uses bagasse. The emission of combustion
gases, CO and NO, in the engine shows high values and is
due to the years of work of the equipment (superior to 15
years), very common in most productive units of panela of
Ecuador. When assessing measurements on a burner using
bagasse and tires, in all measurements the CO values
exceed the measurements reached in the burner using
bagasse and firewood, which values are higher than the
Environmental Standard of Colombia and Ecuador [26]
[27].
Figure 4 shows the results of the life cycle assessment in
the production of panela using bagasse in the burner (case
study), by means of Sima Pro7.3 software and the
methodology of Eco-indicator 99, from the data of the
inventory. The network of the process shows that the
industrial stage is the one that contributes most to the
contamination. Figure 5 shows that the greatest
contribution in all impact categories is in the industrial
process, with a more representative impact to the
respiratory effects of inorganic compounds, acidification /
eutrophication, climate change and land use.
197.8 28.9 16.3
3149
429
512.6
27.8 12.9
1095
92.7
360.15
21.8 11.7
4820.5
146.5
°C (temp. Gas) °C (air) % (oxygen) CO (ppm) NO (ppm)
ENGINE BURNER (bagasse) BURNER (firewood)
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 550
Fig.4: Tree of impacts obtained for the production of panela
Fig.5: Contribution results by impact category.
From the analysis of the contribution to the categories of
damage that is offered in the graph 6, it is seen that the
process has a greater incidence in the damages to the
ecosystem, mainly due to the categories of land use and
acidification / eutrophication. The effects on human
health are related to respiration of inorganic compounds
and climate change, and the effects on resources are
concentrated on the use of fuel for transportation and
electricity in the industrial stage. The environmental
impact generated by this production affects the
sustainability of the process, especially when it is not
given a treatment and proper use to the main waste, such
as ash, filter cake and bagasse.
On the other hand, in order to mitigate the affectations,
work must be done on improving worker protection and
hygiene. It is necessary to dispose a wastewaters
collection tank to proceed with treatment before its
discharge into tributaries or other uses.
Although at the level of factories, the Ecuadorian
agroindustry of panela is artisan and rudimentary, there
390 tkm
Truck 28t
12 Pt
60,4 kg
Poultry manure,
dried, at regional
storehouse/CH S
0,738 Pt
3,8E3 m2
Planting/CH S
5,33 Pt
3,8E3 m2
Tillage,
ploughing/CH S
7,18 Pt
10 kg
Calcium carbide,
technical grade,
at plant/RER S
2,19 Pt
17 kg
Diesel, at
refinery/CH S
5,16 Pt
4,32E3 MJ
Electricity, at
refinery/CH S
63,8 Pt
1 kg
Soybean oil, at oil
mill/US S
0,635 Pt
5 kg
Sodium
persulfate, at
plant/GLO S
0,823 Pt
1,8E4 kg
semilla de cana de
azucar para
Panela
9,04 Pt
2,5E3 kg
etapa Industrial
Panela
299 Pt
1 p
fabricacion de
panela
318 Pt
2E4 kg
Etapa agricola
panela
19,1 Pt
Analyzing 1 kg Industrial stage; Method: Eco-indicator 99 (H) V2.08 / Europe EI 99 H/A / Characterization
Industrial stage I Calcium carbide, technical grade, at plant/RER S Sodium persulfate, at plant/GLO S
Soybean oil, at oil mill/US S Diesel, at refinery/CH S Truck 16t
Agricultural stage Electricity, hydropower, at run-of-river power plant/CH S
Carcinogens Resp. organics Resp. inorganics Climate change Radiation Ozone layer Ecotoxicity Acidification
/ Eutrophication
Land use Minerals Fossil fuels
%
100
95
90
85
80
75
70
65
60
55
50
45
40
35
30
25
20
15
10
5
0
International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878
www.ijeab.com Page | 551
are opportunities for improvement by studies to intensify
the process, since they allow raising efficiency, quality
and care of the environment. Globalization and markets
demand quality and harmless products, under the slogan
of cleaner production.
Fig.6: Contribution of the agricultural and industrial stages to the damage categories of the Eco-Indicator 99 expressed in
points
IV. CONCLUSIONS
The Ecuadorian agroindustry of panela, being a more
artisan activity than industrial is categorized in group II, it
is considered of low impact and requires an environmental
record, but because of its productive linking it generates
problems that affect the environment despite being a
fundamental pillar for rural social, economic, cultural and
important development for the sovereignty and food and
nutritional security of the country.
The use of bagasse as fuel for the generation of energy in
this type of burners to the production of panela is better
and less polluting than the use of firewood or tires, so it is
necessary to focus on studies of optimization of burners
and efficient use of fuels.
The Life Cycle Analysis of the process showed that the
greatest impact is originated in the industrial stage with
94% of contribution and a more representative impact is
exhibited on the effects of respiration of inorganic
compounds, acidification / eutrophication, climate change
and land use.
The contribution to the categories of damage of the Eco-
Indicator 99 expressed in points is superior for the Quality
of the Ecosystem, with respect to Human Resources and
Health; therefore, reveals the need to look for executive
solutions that ensure its progress, productivity, quality and
safety for sustainability.
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International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017
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sustentable en latino-america. Brasil, p. 40.
[23]Suppen Nydia and van Hoof Bart, 2005. Conceptos
básicos del Análisis de Ciclo de Vida y su aplicación
en el Ecodiseño. México, pp. 1-40.
[24]Cámara de Industrias y Producción, 2015. Boletín
de Ambiente y Seguridad Ambiental. Boletín No 25.
Ecuador. Pdf.
[25]Ministerio del ambiente, 2014. Catálogo de
categorización nacional ambiental CCAN. Anexo 1.
http://www.cip.org.ec/attachments/article/2285/ANE
XO%201%20CCAN.pdf. [consulta: 11 de agosto
2014].
[26]Ministerio del Ambiente, anexos 1, 2 y 5., 2002.
Norma de calidad ambiental del recurso suelo y de
descarga de efluentes: recurso agua-libro vi-anexo 1.
Criterios de remediación para suelos contaminados-
libro vi-anexo 2. Límites permisibles de niveles de
ruido ambiente para fuentes fijas y fuentes móviles, y
para vibraciones-libro vi-anexo 5. Quito Ecuador.
[27]Sánchez O.; Cardona C. and Sánchez D., 2007.
Análisis de ciclo de vida y su aplicación a la
producción de bioetanol: Una aproximación
cualitativa. Revista Universidad EAFIT. Vol. 43. No.
146. Colombia, pp. 59-79.

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environmental impact evaluation of the industry of panela by life cycle analysis

  • 1. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 545 Environmental Impact Evaluation of the Industry of Panela by Life Cycle Analysis Dr. C. Walter Francisco Quezada Moreno1 ., Dra. C. Ana Margarita Contreras Moya2 , Dra. C. Elena Rosa Domínguez2 , Dr (asp.). David Quezada Torres2 , Mg. Franklin Antonio Molina Borja1 , Mg. Jaime Orlando Rojas Molina1 1 Department of research, Technical University of Cotopaxi. 2 Department of Chemical Engineering. University "Marta Abreu" of Las Villas. Carr. a Camajuani Km 5½. Santa Clara, Villa Clara. Cuba. Abstract— The objective of the study is to evaluate the environmental impacts generated by the industry of the panela in Ecuador, using the Life Cycle Analysis methodology. The in situ information gathered allowed the identification of the sensitive environmental factors that are affected in all the operations that are carried out in the agroindustry of panela. The results show that the craft activities prevail rather than the industrial activities, due to the low industrial development, application and control of regulations, rudimentary manufacturing practices, among others; which have led to insufficient productivity, competitiveness, quality and safety of their products. The results of the Environmental Impact Assessment, using the Eco-Indicator 99 method, according to the Life Cycle Analysis technique, show that the industrial stage has the greatest contribution to the impact, being more representative the impact to the effects by respiration of inorganic compounds, acidification / eutrophication, climate change and land use. The impact level of this type of industry according to Ecuador's environmental legislation, places it as an industry that generates moderate environmental impacts, it does not require intensive protective or corrective practices. However, it requires environmental executive actions oriented to the control and prevention to mitigate these impacts. Keywords— Agroindustry of Panela, Life Cycle Analysis, Environmental Impact. I. INTRODUCTION As societies progress and develop, the energy demands and their environmental effects grow. A balance between production and consumption can be achieved if all the agents acting on the market do so in a responsible way[1], where quality and competitiveness must be fully justified by actions of continuous improvement and innovative efforts for clean and safe productions. The agroindustry of panela in Ecuador has the purpose of developing productive activities from the cultivation, processing and commercialization of sugar cane for panela, natural sugar and honey. Its effects in terms of employment multiplication, value addition, and nutrients are high [2] [3]. It is estimated that there are 519 agro- industries, production units of panela in the country that use fuel materials for the process such as bagasse, firewood and tires alone or combined [4]. The lack of quality, harmlessness, diversification of production, assessment of productive yield and use of by-products are some of the problems that have generated its lag. In the agroindustry of panela the activities of handcrafted character prevail over the activities of industrial character. However, efforts are being made in technological improvements in the panela production, natural sugar and recent studies with cane honey, for commercial purposes [5]. In spite of the importance of the sector and the existence of environmental legislation, its execution with technical and environmental obligations has not yet materialized, affecting the productivity, quality and harmlessness of its products and environment. In the industry of panela, the cleaner productions must be a reality and of business fulfillment and awareness. Clean Productions are safe and ultimately economical and necessary for the sustainability of a technological process. Innovative efforts are required from a technical-economic and environmental point of view to achieve improvements and higher productivity with lower resources, which must be valued environmentally to favor their investments and secure the market. Environmental assessments are valid tools that have become in actions in the business and governmental world to understand and manage the risks and opportunities of the stages of the life cycle of a product or process towards the introduction of scientific knowledge to describe associated environmental impacts. 1. 1 Agroindustry of Panela Panela activity is a subsector of the agro industrial sector, where the panela is the main sweetener obtained by extracting, cleaning and concentrating the juice of the
  • 2. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 546 cane. It is a fundamental pillar for rural social, economic, cultural development and for the sovereignty and food and nutritional security of many countries in Asia, the Caribbean and South America [4] [6]. This activity in most factories is developed neglecting technical, environmental and quality standards throughout the process line. The activities are more handcrafted than industrial; due to its poor development, application and control of regulations, rudimentary manufacturing practices, among others; which have led to insufficient productivity, competitiveness, quality and harmlessness of their products. However, it plays a key and an important role for food sovereignty and security, allowing safe and permanent access to sufficient and nutritious food in all markets, especially in rural and marginal urban areas. This activity uses different materials for the production and commercialization: water, energy, cane and vegetal and chemical mucilages in the clarification of juice as clarol or sodium hydrosulfite, carbonates, vegetable fats, fuels and others [7] [8]. Deforestation for firewood and the establishment of cane cultivation, the preparation of the land and the application of agrochemicals for its management, coupled with the low efficiency of combustion and heat transfer processes in the burner, are activities that generate negative changes in environmental quality. In many cases, the sustainability of the activity to concentrate juice to obtain panela is at risk, due to the lack of environmental awareness. The inefficiency of the panela burners, the use of wood that affects the forests, tires and greenhouse plastics to generate energy and that give off toxic gases such as carbon monoxide (CO) and nitrogen to the atmosphere, are aspects that weaken its activity. CO is a pollutant; it is the product of the incomplete combustion of any type of fuel. The tires have sulfur in the form of sulfides that in the burning they are oxidized and released into the air as a pollutant. This type of reaction is characterized by the presence of combustible substances or also called unburned in the combustion gases, such as carbon in the form of ash, CO and H2. Bagasse, firewood and tires generate compounds such as CO2, CO, NOx, SOx, H2, H2O and other gases and particles, energy and ash. In the stage of clarification, evaporation and concentration the negative effects are evidenced by the generated and untapped water vapor, the use of flocculants and the presence of wastes [9]. In spite of the multiple advantages of cane in the agroindustry of panela in Colombia and Ecuador, it has an undesirable impact due to the consumption of large amounts of fuel wood and used tires and the energy inefficiency of the burners. Up to three tons of firewood per ton of panela are used, generating problems of deforestation, soil erosion and pollution [10] [4], so its environmental effect is highly negative. The calorific power of a tire is 8300 Kcal / kg and the gases that are derived are compounds of carbon, nitrogen and sulfur. Carbon black creates disorders in the respiratory system. Energy efficiency in the operation of the burner, good manufacturing practices and safety and good use and waste management, is determinant to avoid negative impacts to the environment in the activity of the agroindustry of panela. However, environmental degradation and overexploitation of natural resources can weaken a country's competitive base [11]. For this reason, a concept is needed that manages access to raw materials and imposes controls on improper processing practices in order to maintain the integrity of the environment and protect natural resources, and another that on the other hand, it is required an understanding of the competitive nature of the agroindustrial sector and the entrepreneur's unique role [12]. Planning is required for efficient performance in the technological and economic systems of the activity of the panela that does not adversely affect society and the natural environment. Consumers show and demand a growing interest in knowing what is behind each product, since, apart from the quality and safety of food, the health and welfare of the community and the quality of the environment are ahead. 1.2 Environmental analysis Cities require food, paper, water, and other products every minute, so as by-products of their processes emit large quantities of particulate material, CO, SO2, NOx and other gases as well as large volumes of solid and liquid wastes [13]. Therefore, despite a great effort in research and action aimed at avoiding environmental pollution, it remains a worldwide concern. Life Cycle Analysis (LCA) is an environmental management technique to evaluate the potential environmental aspects and impacts associated with a product [14] [15]. It is a tool to examine the environment of the serious consequences of the manufacture and use of products or the provision of services [16]. It allows the systematic evaluation of the environment and aspects of a product or service system through all stages of its life cycle [17] [18]. The LCA is positioned as a key tool for the evaluation of potential environmental impacts, as well as for the generation of useful scientific and technical information for the orientation of environmental policy and legislation; the establishment and strengthening of integrated waste management programs and management plans among other policy instruments, as well as the decision-making in the industrial and social sectors [19]. The LCA means recognizing how our choices influence each stage of the process and thus weighing the advantages and disadvantages contributing to the
  • 3. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 547 economy, the environment and society [20]. It is essential for the sustainable development, to go beyond traditional production to one with responsibility, where economic, environmental and social aspects prevail [21]. The application of the LCA technique in the industry of panela constitutes a viable and applicable tool for the entire chain of production, considering internal and external effects. The greatest contribution is to think and act to mitigate adverse effects to the environment, caused by industrial processes, market or consumption. It is not only generating work, development or food, is to produce thinking about the welfare of all. It is health and good living. It is economic growth, ecological balance and social progress [22]. The global implementation plan for Sustainable Development calls for: "improving products and services while reducing health and environmental impacts, using scientific models such as life-cycle analysis where appropriate" [23]. The execution of LCA studies to the sector, analyzing the productions of the activity of panela including the natural sugar, honey and byproducts that it generates, will allow a comprehensive diagnosis of the environmental situation of this activity in the countries of the world and in Ecuador especially. 1.3 Environmental Legislation Due to its level of pollution, industry in general has worldwide been permanently under the eyes of the community. FAO General - Director José Graziano said in Santiago de Chile that climate change is not a problem of the future but the present. He has warned of its impact in South America, he said that the impacts are being greater than what was thought and yet it is not known how it will affect food production [24]. Concern about the environmental deterioration due to industrialization at a global level has determined that the sustainability of the sector in the country is determined to comply with the current environmental legislation in the sector and country. However, its application and control has not had results, its breach is visible and notorious. According to Annex I of the National Environmental Categorization Catalog (CCAN), for the construction and / or operation of factories for the production of panela, it is classified in group II, considered of low impact and requires an environmental file [25]. The government of Ecuador has implemented demanding environmental legislation with respect to the environment, but, these provisions are not fulfilled in the sector. In Ecuador, Local and Provincial Governments known as GAD have legislations that try to regulate certain activities, but with unsatisfactory results for the community. The existing normative instruments of environmental legislation under the present Constitution of the Ecuador Republic grouped in the Unified Text of Environmental Legislation TULAs and the Organic Law of Municipal Regime guides the way of control of productive activities [26]. Considering the impact that the whole production chain has on the environment in a holistic manner will be decisive for the sustainability process of the sector [27]. II. MATERIALS AND METHODS A bibliographical review about the industry of panela was carried out and data were collected through an in situ diagnosis to the agroindustries of panela in the center and north of the country. It is estimated that there are 519 productive units. In three production units, the gas produced by combustion was measured using the E- instrument 4400 equipment. The first unit of panela operates with bagasse, the second with firewood and the third uses pneumatic tires. In addition, the control in the diesel engine was carried out to operate the equipment of cane juice extraction. For the environmental evaluation, applying the methodology of Life Cycle Analysis was considered as a case study the unit of panela that operates with bagasse only. It has a processing capacity of 20 t cane / day, where noise was also evaluated using the EXTECH Instruments sound level meter, ranging from 26 to 130 dB (A). Controls of wastewater volume, pH and soluble solids (brix) were performed on the liquid wastes from the cleaning, clarifying, concentrating and washing tubs of molds and materials. The environmental effects were analyzed according to the limits of the system shown in figure 1.
  • 4. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 548 Fig.1: System limits for LCA in the production of panela. The general inventory of the unit of production was carried out according to information of the entire productive chain of the activity of panela (cane production, processing and marketing). The results are plotted and the environmental assessment is performed using the Life Cycle Analysis (LCA) methodology according to the Sima Pro7.3 software and the Eco-indicator 99 methodology, according to the system limits shown and taking as a functional unit the daily production of panela, which corresponds to 2485 kg. III. RESULTS The balance of material and energy applied through stoichiometric calculations according to the inputs and outputs of products generated the results indicated in figure 2. Fig.2: Mass balance and contaminant identification Agricultural stage Industrial stage Organic Fertilizer Chemical clarifiers Natural clarififiers Gaseous fuels Oils and Lubricants Land Resources Energy Resources Material Resources Emissions to air Emissions to water Emissions to land Panela Ash Filter cake Bagasse
  • 5. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 549 The balance of mass and contaminants generated by the 20 tons of cane per day produces 2485 kg of panela, by- products and wastes, such as: 8800 kg of bagasse for combustion (energy needed to concentrate juice to panela) and 1530 liters of wastewaters produced in the different containers which are discharged to the ground and that have natural watercourses as destination. The pH of the wastewaters and the solids soluble in the solution in the different containers reach values between 4.64 - 5.11 and 2.10 to 11.3 brix degrees, respectively. The analysis of the permissible limits of noise levels for fixed sources, mobile sources and vibrations is done according to the Unified Text of Environmental Legislation (TULAs), which establishes that the sound pressure limit within an industrial zone, is 75 dB (A) in an eight-hour noise exposure per day [26]. The results of noise indicate that the point A = 83.42 dB (A), very close to the engine (machine that drives the mill or cane juice extraction equipment), exceeds the permissible limit of noise emissions. In Figure 3, the average results of 14 measurements performed every 30 minutes on the two burner combustion processes are shown: the first one using bagasse only, the second one operating with wood or firewood (sawmill waste and boxes used to transport fruit) and in the engine. In the burner using bagasse, high temperature values are obtained in the flue gases and the combustion is better, since fewer gases (CO and NO) are obtained in front of the burner that uses wood in the combustion. Fig.3: Parameters of the combustion of bagasse, firewood and in the engine. The generation of gases is within the limit allowed in both, carbon monoxide (CO) and nitrogen (NO); being greater the amounts generated in the wood burner than in the one that uses bagasse. The emission of combustion gases, CO and NO, in the engine shows high values and is due to the years of work of the equipment (superior to 15 years), very common in most productive units of panela of Ecuador. When assessing measurements on a burner using bagasse and tires, in all measurements the CO values exceed the measurements reached in the burner using bagasse and firewood, which values are higher than the Environmental Standard of Colombia and Ecuador [26] [27]. Figure 4 shows the results of the life cycle assessment in the production of panela using bagasse in the burner (case study), by means of Sima Pro7.3 software and the methodology of Eco-indicator 99, from the data of the inventory. The network of the process shows that the industrial stage is the one that contributes most to the contamination. Figure 5 shows that the greatest contribution in all impact categories is in the industrial process, with a more representative impact to the respiratory effects of inorganic compounds, acidification / eutrophication, climate change and land use. 197.8 28.9 16.3 3149 429 512.6 27.8 12.9 1095 92.7 360.15 21.8 11.7 4820.5 146.5 °C (temp. Gas) °C (air) % (oxygen) CO (ppm) NO (ppm) ENGINE BURNER (bagasse) BURNER (firewood)
  • 6. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 550 Fig.4: Tree of impacts obtained for the production of panela Fig.5: Contribution results by impact category. From the analysis of the contribution to the categories of damage that is offered in the graph 6, it is seen that the process has a greater incidence in the damages to the ecosystem, mainly due to the categories of land use and acidification / eutrophication. The effects on human health are related to respiration of inorganic compounds and climate change, and the effects on resources are concentrated on the use of fuel for transportation and electricity in the industrial stage. The environmental impact generated by this production affects the sustainability of the process, especially when it is not given a treatment and proper use to the main waste, such as ash, filter cake and bagasse. On the other hand, in order to mitigate the affectations, work must be done on improving worker protection and hygiene. It is necessary to dispose a wastewaters collection tank to proceed with treatment before its discharge into tributaries or other uses. Although at the level of factories, the Ecuadorian agroindustry of panela is artisan and rudimentary, there 390 tkm Truck 28t 12 Pt 60,4 kg Poultry manure, dried, at regional storehouse/CH S 0,738 Pt 3,8E3 m2 Planting/CH S 5,33 Pt 3,8E3 m2 Tillage, ploughing/CH S 7,18 Pt 10 kg Calcium carbide, technical grade, at plant/RER S 2,19 Pt 17 kg Diesel, at refinery/CH S 5,16 Pt 4,32E3 MJ Electricity, at refinery/CH S 63,8 Pt 1 kg Soybean oil, at oil mill/US S 0,635 Pt 5 kg Sodium persulfate, at plant/GLO S 0,823 Pt 1,8E4 kg semilla de cana de azucar para Panela 9,04 Pt 2,5E3 kg etapa Industrial Panela 299 Pt 1 p fabricacion de panela 318 Pt 2E4 kg Etapa agricola panela 19,1 Pt Analyzing 1 kg Industrial stage; Method: Eco-indicator 99 (H) V2.08 / Europe EI 99 H/A / Characterization Industrial stage I Calcium carbide, technical grade, at plant/RER S Sodium persulfate, at plant/GLO S Soybean oil, at oil mill/US S Diesel, at refinery/CH S Truck 16t Agricultural stage Electricity, hydropower, at run-of-river power plant/CH S Carcinogens Resp. organics Resp. inorganics Climate change Radiation Ozone layer Ecotoxicity Acidification / Eutrophication Land use Minerals Fossil fuels % 100 95 90 85 80 75 70 65 60 55 50 45 40 35 30 25 20 15 10 5 0
  • 7. International Journal of Environment, Agriculture and Biotechnology (IJEAB) Vol-2, Issue-1, Jan-Feb- 2017 http://dx.doi.org/10.22161/ijeab/2.1.68 ISSN: 2456-1878 www.ijeab.com Page | 551 are opportunities for improvement by studies to intensify the process, since they allow raising efficiency, quality and care of the environment. Globalization and markets demand quality and harmless products, under the slogan of cleaner production. Fig.6: Contribution of the agricultural and industrial stages to the damage categories of the Eco-Indicator 99 expressed in points IV. CONCLUSIONS The Ecuadorian agroindustry of panela, being a more artisan activity than industrial is categorized in group II, it is considered of low impact and requires an environmental record, but because of its productive linking it generates problems that affect the environment despite being a fundamental pillar for rural social, economic, cultural and important development for the sovereignty and food and nutritional security of the country. The use of bagasse as fuel for the generation of energy in this type of burners to the production of panela is better and less polluting than the use of firewood or tires, so it is necessary to focus on studies of optimization of burners and efficient use of fuels. The Life Cycle Analysis of the process showed that the greatest impact is originated in the industrial stage with 94% of contribution and a more representative impact is exhibited on the effects of respiration of inorganic compounds, acidification / eutrophication, climate change and land use. The contribution to the categories of damage of the Eco- Indicator 99 expressed in points is superior for the Quality of the Ecosystem, with respect to Human Resources and Health; therefore, reveals the need to look for executive solutions that ensure its progress, productivity, quality and safety for sustainability. REFERENCES [1] Goedkoop Mark; Effting Suzanne; and Collignon Mercel, 1999. Manual Práctico de ecodiseño. Anexo Eco-indicador 99. Método para evaluar el impacto ambiental a lo largo del ciclo de vida. Holanda, p. 5. Pdf. [2] Kumar, A. 2010. An Empirical Study on Gur (Jaggery) Industry. Indian Institute of Management Ahmedabad-380 015. India. W.P. http://ssrn.com/abstract=1783403. (Accessed 03 January 2016), p.1-19. [3] FAO, 2013. Agroindustria para el desarrollo. Food and agricultural organization, Roma. http://www.fao.org/docrep/017/i3125s/i3125s00.pdf. (Accessed 02 January 2016), p. 283. [4] Quezada, W, 2015. Procedimiento para la intensificación y reconversión de instalaciones paneleras. Tesis presentada en opción al Grado Científico de Doctor en Ciencias Técnicas, Especialidad Ingeniería Química en la Universidad Central Marta Abreu de Las Villas, Cuba. [5] Quezada Walter; González Erenio; Quezada Walter David and Mera Cristina, 2016. Cane Honey: Process, Quality and Harmlessness. International Journal of Engineering Research. doi: 10.17950. Volume No.5, Issue No.7. 589-593. [6] Rodríguez Gonzalo, García Hugo, Roa Zulma, Santacoloma Pilar, 2007. Panela production as a 0. 20. 40. 60. 80. 100. 120. 140. 160. 180. 200. Human Health Ecosystem Quality Resources Pt Analizando 1 p 'fabricacion de panela'; Método: Eco-indicator 99 (H) V2.08 / Europe EI 99 H/H / Ponderación etapa Industrial Panela Etapa agricola panela
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