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Ultragreen                        ™
                       BIOLOGICAL PURIFICATION BY ULTRAFILTRATION
                       FLAT SHEET MEMBRANES. RECOMMENDED
                                                                    URBAN
                       FOR INSTALLATIONS UP TO 100,000 PE.          WASTEWATER




                       GUARANTEE THE WATER QUALITY BEYOND
P-PPT-ER-007-EN-1107




                       THE HIGHEST STANDARDS, EVEN IN THE CASE
                       OF STRONG SEASONAL FLUCTUATIONS.
Urban            CONTENTS
Wastewater




   Ultragreen™
                 •   The Challenges facing U.W.W Treatment

                 •   The Choice of Membrane on U.W.W. Treatment

                 •   The Membrane Bioreactor Range

                 •   Membrane Technologies: the Degrémont Choice

                 •   Properties of the Toray Membranes used in Ultragreen™

                 •   Operating Principle

                 •   Advantages of Ultragreen™

                 •   Some references

                 •   Case study: Val d’Arly (73), FRANCE
THE CHALLENGES FACING
Urban
Wastewater       U.W.W. TREATMENT
   Ultragreen™   Increasingly stringent discharge standards
                  • Health & safety (water standards)
                  • Protecting the natural environment (European
                    framework directive)
                 Protecting water resources
                 • Reuse (irrigation etc.)
                 Special limitations
                 • Site limitations (available area)
                 • Rehabilitation limitations
                 • Operating limitations
THE CHOICE OF MEMBRANES ON U.W.W. (1/3)


                                                                              Cl2
                   Primary     Biological       Clarifier   Sand     Disinfection
PRE-TREATMENT
                  sedimentat     TANK                       filter
                      ion


                                                             UF




  PRE-TREATMENT
                                    TANK
                     Biological and membrane filtration
THE CHOICE OF MEMBRANES ON U.W.W. (2/3)
 DYNAMIC SEPARATION           PHYSICAL BARRIER




     Suspended solids         Control over filtration
        «leakage»             and of the suspended
                                solids content in
  Danger of denitrification        discharges
      in the clarifier
THE CHOICE OF
Urban
Wastewater       MEMBRANES ON U.W.W. (3/3)
   Ultragreen™   Compact design:
                  • For the same target water quality, membranes can replace
                    several conventional treatment stages.


                 Integration:
                 • Architectural: structures are more compact, so that the
                    architectural constraints are easier to meet


                 Performances:
                 • Membranes form a physical barrier; water quality is
                    constant and, therefore, unaffected by fluctuating hydraulic
                    loading.
Urban                    THE MEMBRANE BIOREACTOR RANGE
Wastewater



                          THE MEMBRANE BIOREACTOR RANGE (MBR) FOR TREATING
   Ultragreen™
                          WASTEWATER IS AVAILABLE IN TWO VERSIONS IN ORDER
                          TO MEET THE REQUIREMENTS OF ALL CLIENTS.

                              THE MBR RANGE
                                                               Preferential application
                                                                                              Specific
                                                              Maximum concentration of         process          Membrane
                                Models      Plant Size
                                                              sludge in membrane tank         features         manufacturer
                                                              recommended

                                          0 to 100,000 p.e.                                  Flat Sheet
                            Ultragreen™   0 to 20,000 m3/d
                                                                      15 g/L
                                                                                            Membranes
                                                                                                                 TORAY


                                                                                           Hollow fibers
                              Ultrafor™      No limits                10 g/L
                                                                                          Out /In filtration
                                                                                                                   GE




In order to meet market demands
and the specific requirements set
in technical specifications, in future,
Degrémont will deploy two
complementary membrane
technologies:


                                          Ultragreen™                    Ultrafor™
TECHNOLOGIES: THE DEGREMONT CHOICE

                                   Membrane density

          Layout (major plants)                          Backflushing



  Membrane energy costs                      HOLLOW            Concentration-related
   (high concentrations)                     FIBERS                    flow



         Maximum sludge
                                                               Membrane energy costs
          concentration
                                                                (low concentration)
          In membranes

                                      PLATES
                     Simplicity                           Flexibility
                                                        (small plants)
                                  Lower pre-treatment
                                     requirements




2 complementary technologies that still form
part of the ultrafiltration sector
TORAY: A TRUSTED NAME IN ULTRAFILTRATION
 Size                           0.001μ m                0.01 μ m                0.1 μ m              1μ m          10 μ m

                  Ion, small molecule                 Polymer
                                                       Polymer
Separation




                                                                               Colloid
                                                                                Colloid
Target of




                                  Pesticide, Organic Material                                     Silt
                                                                                                  Silt
                Trihalomethanes
                                                                                          Coliform
                                                                  Virus
                                                                                                          Cryptosporidium
              Na+, Cl- Ions
                              Ca2+, Mg2+, SO42 - Ions               Bacteria
   Membrane




                                                              UF
                      RO                              (Ultra-Filtration
                                                      (Ultra-Filtration)                    MF
               (Reverse Osmosis)                             )                       (Micro-Filtration)
                                        NF
                                  (Nano-Filtration)




                                         UF HF Membrane                    UF/MF HF Membrane
RO/NF for Desalination                   “Torayfil (PAN)”                   “PVDF membrane”                 PVDF UF for MBR
Ultragreen™ : THE TORAY MEMBRANES
  • Submerged flat sheet membranes
  • Filtration by gravity suction or pumping
  • Continuous aeration throughout filtration
Ultragreen™ : THE MODULES (1/3)
                                13.5mm




                                   6.0mm




                                           Aeration block

Space separating the membranes: 7.5mm
Ultragreen™ : THE MODULES (2/3)
• Reference: TMR140-100
• Number of plates: 100
• Membrane surface area: 140 m2
• Height: 2,100 mm
• Length: 1,620 mm
• Width: 565 / 810 mm


         Permeate collectors


            Membrane block


              Aeration block
Ultragreen™ : THE MODULES (3/3)

• Reference: TMR140-200D
• Number of plates: 200
• Membrane surface area: 280 m2
• Height: 4,160 mm
• Length: 1 620 mm
• Width: 565 / 810 mm

One single aeration unit for the
entire aeration block
Urban                 THE TORAY MEMBRANES (1/3)
Wastewater




        Ultragreen™

                       −An ultrafiltration membrane (0.08 m)

                       −Tight distribution of pore sizes
(1012 units.m-2)
  Pore density




                                                           Clogging controlled




                   Pore diameter ( m)
Urban                   THE TORAY MEMBRANES (2/3)
Wastewater




   Ultragreen™
             Membrane




                                               Membrane
                                                          TORAY


                             Clogging controlled
Urban            THE TORAY MEMBRANES (3/3)
Wastewater




   Ultragreen™




         • HIGH PORE DENSITY
         • HYDROPHILIC MEMBRANE

             High permeability
             Low trans-membrane pressure
LINES - ULTRABOX
                           ≤
1 Ultrabox – 1 short line (≤ 8 module places)

               Permeate outlet

                                    Cross section




                                    Viewed from above




                  Permeate outlet
Ultragreen™ : A LAYOUT EXAMPLE
                      Aeration
     Example with     network
     2 reactors:     blowdown




Aeration
network


                                 Collectors
Urban            Ultragreen™ ADVANTAGES
Wastewater




   Ultragreen™   COMPACT PRODUCT:
                 • Suppression of clarifiers
                 • SS concentrations in the bioreactor are higher than with
                   conventional AS
                 • No denitrification required if the discharge permit allows it
                 •   Cost of civil works is reduced
                     –   Landscape integration is easier because of compactness

                 TREATED EFFLUENT QUALITY:
                 • Assimilation of the pollution by the biomass + membrane
                   filtration that stops all suspended solids
                 •   Better quality effluent, with consistency
                 • Severe discharge levels in TSS, BOD5, COD, TN, TP
                     (sensitive areas)
                 •   Discharge permits with disinfection
                     requirements
SOME REFERENCES

                                                   START-UP
   PLANT NAME      COUNTRY         CAPACITY (PE)
                                                     DATE

Crest Voland          France           5,600         2011


St Barthélémy         France           3,500         2012


Cogolin               France           6,000         2011


Pierre Lenquette   New Caledonia       2,500         2012
CASE STUDY:
                        VAL D’ARLY (73), FRANCE
CONTEXT:                              DESIGN :
• Construction of a 28,000 p.e.       • Treatment line:
  wastewater treatment plant            –   Fine bar screen (6 mm)
                                        –   Grit – Grease removal
• Client: Syndicat Intercommunal        –   Straining (2 mm)
  d’Eau Potable et d’Assainissement     –   Distribution structure
  des Moulins (SIEPAM)                  –   Biological tanks (Incorporated buffer
                                            tank)
                                        –   Ultragreen™
• To be commissioned mid 2011
                                      • Water system running in gravity mode
Specific features of the project:
  – Its proximity to the village      • Number of Ultragreen™: 4 lines of
  – Protecting the Arly (river)         membranes in 4 reactor tanks
  – High seasonal variations            including one on total standby
  – Operating authority
  – Sustainable Development Aspect
CASE STUDY:
VAL D’ARLY (73), FRANCE

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Ultragreen - Guarantee the water quality beyond the highest standards, even in the case of strong seasonal fluctuations

  • 1. Ultragreen ™ BIOLOGICAL PURIFICATION BY ULTRAFILTRATION FLAT SHEET MEMBRANES. RECOMMENDED URBAN FOR INSTALLATIONS UP TO 100,000 PE. WASTEWATER GUARANTEE THE WATER QUALITY BEYOND P-PPT-ER-007-EN-1107 THE HIGHEST STANDARDS, EVEN IN THE CASE OF STRONG SEASONAL FLUCTUATIONS.
  • 2. Urban CONTENTS Wastewater Ultragreen™ • The Challenges facing U.W.W Treatment • The Choice of Membrane on U.W.W. Treatment • The Membrane Bioreactor Range • Membrane Technologies: the Degrémont Choice • Properties of the Toray Membranes used in Ultragreen™ • Operating Principle • Advantages of Ultragreen™ • Some references • Case study: Val d’Arly (73), FRANCE
  • 3. THE CHALLENGES FACING Urban Wastewater U.W.W. TREATMENT Ultragreen™ Increasingly stringent discharge standards • Health & safety (water standards) • Protecting the natural environment (European framework directive) Protecting water resources • Reuse (irrigation etc.) Special limitations • Site limitations (available area) • Rehabilitation limitations • Operating limitations
  • 4. THE CHOICE OF MEMBRANES ON U.W.W. (1/3) Cl2 Primary Biological Clarifier Sand Disinfection PRE-TREATMENT sedimentat TANK filter ion UF PRE-TREATMENT TANK Biological and membrane filtration
  • 5. THE CHOICE OF MEMBRANES ON U.W.W. (2/3) DYNAMIC SEPARATION PHYSICAL BARRIER Suspended solids Control over filtration «leakage» and of the suspended solids content in Danger of denitrification discharges in the clarifier
  • 6. THE CHOICE OF Urban Wastewater MEMBRANES ON U.W.W. (3/3) Ultragreen™ Compact design: • For the same target water quality, membranes can replace several conventional treatment stages. Integration: • Architectural: structures are more compact, so that the architectural constraints are easier to meet Performances: • Membranes form a physical barrier; water quality is constant and, therefore, unaffected by fluctuating hydraulic loading.
  • 7. Urban THE MEMBRANE BIOREACTOR RANGE Wastewater THE MEMBRANE BIOREACTOR RANGE (MBR) FOR TREATING Ultragreen™ WASTEWATER IS AVAILABLE IN TWO VERSIONS IN ORDER TO MEET THE REQUIREMENTS OF ALL CLIENTS. THE MBR RANGE Preferential application Specific Maximum concentration of process Membrane Models Plant Size sludge in membrane tank features manufacturer recommended 0 to 100,000 p.e. Flat Sheet Ultragreen™ 0 to 20,000 m3/d 15 g/L Membranes TORAY Hollow fibers Ultrafor™ No limits 10 g/L Out /In filtration GE In order to meet market demands and the specific requirements set in technical specifications, in future, Degrémont will deploy two complementary membrane technologies: Ultragreen™ Ultrafor™
  • 8. TECHNOLOGIES: THE DEGREMONT CHOICE Membrane density Layout (major plants) Backflushing Membrane energy costs HOLLOW Concentration-related (high concentrations) FIBERS flow Maximum sludge Membrane energy costs concentration (low concentration) In membranes PLATES Simplicity Flexibility (small plants) Lower pre-treatment requirements 2 complementary technologies that still form part of the ultrafiltration sector
  • 9. TORAY: A TRUSTED NAME IN ULTRAFILTRATION Size 0.001μ m 0.01 μ m 0.1 μ m 1μ m 10 μ m Ion, small molecule Polymer Polymer Separation Colloid Colloid Target of Pesticide, Organic Material Silt Silt Trihalomethanes Coliform Virus Cryptosporidium Na+, Cl- Ions Ca2+, Mg2+, SO42 - Ions Bacteria Membrane UF RO (Ultra-Filtration (Ultra-Filtration) MF (Reverse Osmosis) ) (Micro-Filtration) NF (Nano-Filtration) UF HF Membrane UF/MF HF Membrane RO/NF for Desalination “Torayfil (PAN)” “PVDF membrane” PVDF UF for MBR
  • 10. Ultragreen™ : THE TORAY MEMBRANES • Submerged flat sheet membranes • Filtration by gravity suction or pumping • Continuous aeration throughout filtration
  • 11. Ultragreen™ : THE MODULES (1/3) 13.5mm 6.0mm Aeration block Space separating the membranes: 7.5mm
  • 12. Ultragreen™ : THE MODULES (2/3) • Reference: TMR140-100 • Number of plates: 100 • Membrane surface area: 140 m2 • Height: 2,100 mm • Length: 1,620 mm • Width: 565 / 810 mm Permeate collectors Membrane block Aeration block
  • 13. Ultragreen™ : THE MODULES (3/3) • Reference: TMR140-200D • Number of plates: 200 • Membrane surface area: 280 m2 • Height: 4,160 mm • Length: 1 620 mm • Width: 565 / 810 mm One single aeration unit for the entire aeration block
  • 14. Urban THE TORAY MEMBRANES (1/3) Wastewater Ultragreen™ −An ultrafiltration membrane (0.08 m) −Tight distribution of pore sizes (1012 units.m-2) Pore density Clogging controlled Pore diameter ( m)
  • 15. Urban THE TORAY MEMBRANES (2/3) Wastewater Ultragreen™ Membrane Membrane TORAY Clogging controlled
  • 16. Urban THE TORAY MEMBRANES (3/3) Wastewater Ultragreen™ • HIGH PORE DENSITY • HYDROPHILIC MEMBRANE High permeability Low trans-membrane pressure
  • 17. LINES - ULTRABOX ≤ 1 Ultrabox – 1 short line (≤ 8 module places) Permeate outlet Cross section Viewed from above Permeate outlet
  • 18. Ultragreen™ : A LAYOUT EXAMPLE Aeration Example with network 2 reactors: blowdown Aeration network Collectors
  • 19. Urban Ultragreen™ ADVANTAGES Wastewater Ultragreen™ COMPACT PRODUCT: • Suppression of clarifiers • SS concentrations in the bioreactor are higher than with conventional AS • No denitrification required if the discharge permit allows it • Cost of civil works is reduced – Landscape integration is easier because of compactness TREATED EFFLUENT QUALITY: • Assimilation of the pollution by the biomass + membrane filtration that stops all suspended solids • Better quality effluent, with consistency • Severe discharge levels in TSS, BOD5, COD, TN, TP (sensitive areas) • Discharge permits with disinfection requirements
  • 20. SOME REFERENCES START-UP PLANT NAME COUNTRY CAPACITY (PE) DATE Crest Voland France 5,600 2011 St Barthélémy France 3,500 2012 Cogolin France 6,000 2011 Pierre Lenquette New Caledonia 2,500 2012
  • 21. CASE STUDY: VAL D’ARLY (73), FRANCE CONTEXT: DESIGN : • Construction of a 28,000 p.e. • Treatment line: wastewater treatment plant – Fine bar screen (6 mm) – Grit – Grease removal • Client: Syndicat Intercommunal – Straining (2 mm) d’Eau Potable et d’Assainissement – Distribution structure des Moulins (SIEPAM) – Biological tanks (Incorporated buffer tank) – Ultragreen™ • To be commissioned mid 2011 • Water system running in gravity mode Specific features of the project: – Its proximity to the village • Number of Ultragreen™: 4 lines of – Protecting the Arly (river) membranes in 4 reactor tanks – High seasonal variations including one on total standby – Operating authority – Sustainable Development Aspect
  • 22. CASE STUDY: VAL D’ARLY (73), FRANCE