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83
Journal of the Balkan Tribological Association	 Vol. 19, No 1, 83–96 (2013)
Hybrid composites
TRIBOLOGICAL CHARACTERISTICS OF ALUMINIUM HYBRID
COMPOSITES REINFORCED WITH SILICON CARBIDE AND
GRAPHITE. a review
B. STOJANOVIca
*, M. BABIca
, S. MITROVIca
, A. VENCLb
,
N. MILORADOVIca
, M. PANTIca
a 
Faculty of Engineering, University of Kragujevac, 6 Sestre Janjic Street,
34 000 Kragujevac, Serbia
E-mail: blaza@kg.ac.rs
b
  Faculty of Mechanical Engineering, University of Belgrade, 11 000 Belgrade,
Serbia
ABSTRACT
This paper presents tribological characteristics of hybrid composites with alu-
minium matrix, reinforced with silicon carbide (SiC) and graphite (Gr). Newly
formed Al/SiC/Gr hybrid composites are the combination of the two different hy-
brid materials. Namely, hard particles of silicon carbide increase the hardness and
resistance to wear, while soft particles of graphite improve lubrication and reduce
friction coefficient and wear. It is possible to obtain Al/SiC/Gr hybrid composites
by different methods of casting. Tribological tests show that load, sliding speed,
sliding distance, content and size of reinforcement particles influence the size
and the type of wear and friction coefficient of Al/SiC/Gr hybrid composites with
aluminium matrix.
Keywords: tribology, hybrid composites, aluminium, metal matrix composites
(MMC), wear, coefficient of friction, SiC, graphite.
aims and background
Composite materials (composites) are formed by mixing of two or more materi-
als or phases of the same material. The composite has completely new, different
and better characteristics in comparison to its constituents. The components do
not blend with each other or do not get dissolved, so there is a visible difference
between them.
84
Essentially, the composites consist of the
base (the matrix), which content is much higher
in comparison to other materials, and reinforce-
ment, i.e. material with which the desired prop-
erties of composites are achieved. The base or
the matrix may be metal, polymer and ceramic
(Fig. 1). When the matrix is metal, the compos-
ites are metal matrix composites (MMC), when
the matrix is polymer, the composites are poly-
mer matrix composites (PMC) and when the
matrix is ceramic, the composites are ceramic
matrix composites (CMC).
When talking about metal matrix com-
posites, the aluminium and its alloys are mostly used as a base. Aluminium and its
alloys can accept various reinforcements and improvers. Aluminium composites
have a number of positive features such as: small density, good thermal conduc-
tivity and resistance to corrosion. However, aluminium alloys also have certain
defects in the form of higher coefficient of thermal expansion and inadequate tri-
bological characteristics. Increase of stiffness, hardness, resistance to fatigue, as
well as the improvement of tribological characteristics are achieved by adding ap-
propriate reinforcements and improvers and by forming aluminium composites.
Commonly used reinforcements are SiC, Al2
O3
and graphite­1–7
.
The influence of SiC, Al2
O3
and graphite on tribological and mechanical
characteristics is different. By increase of mass or volumetric share of SiC, Al2
O3
and graphite, tribological characteristics of composites are changed. By combin-
ing the appropriate share of these two materials, the optimum values of tribologi-
cal and mechanical characteristics of materials are achieved.
The composites reinforced with SiC (silicon carbide) and graphite (Gr) are
called Al/SiC/Gr hybrid composites.
A small number of scientists was engaged in research of tribological and
mechanical characteristics of hybrid Al/SiC/Gr composites. The research review
is given below.
Ted Guo and associates8
have studied tribological behaviour of Al/SiC/Gr
composites with 10% SiC and different content of graphite (2, 5 and 8%). With
increase of graphite content up to 5%, the value of friction coefficient decreases
due to forming of lubricating layer (Fig. 2). Further increase of graphite content
does not have significant effect on friction coefficient, except that composite hard-
ness decreases.
Guo and Tsao8
used aluminium 6061 (average powder size: 30 µm) as a base
and SiC (average powder size: 45 µm) and graphite (average powder size: 8 µm)
as reinforcements. SiC percentage is 10% of volumetric content and percentage of
Fig. 1. Types of composites
Metal
MMC
Reinforcement
PMC CMC
Polym
er
Ceram
ics
85
graphite varies between 2, 5 and
8% of volumetric share (v/o).
Hybrid composites of appropri-
ate composition were obtained
using semi-solid powder densifi-
cation method on the 10t Instron
device (model 1125).
Testing of tribological char-
acteristics was performed on tri-
bometer during period of 5 min,
without lubrication, at pressure
of 0.094 MPa and at sliding
speed of 1.09 m/s. The measure-
ments showed that friction coef-
ficient decreases with increase
of graphite content (for 0 to 5%
Gr) and after that friction coeffi-
cient has constant value (for 5 to
8% Gr). Measuring of counter-
body worn material was done
alongside with hybrid compos-
ite A356 with the same content
of graphite. Unlike A356 com-
posite where mass dissipation
or wear increases with increase
of graphite content, with com-
posites having Al6061 base the
wear increases up to 5% Gr and
then decreases (Fig. 3).
Riahi and Alpas9
focused
on systemic tests of the role of
tribo-layers which are formed
on contact surfaces of hybrid composites with A356 aluminium base. Tests were
done on Al/SiC/Gr hybrid composite with A356 base, 10% SiC with particle size
of 16 µm and 3% of graphite with particle size of 80 µm and 138 µm.
Performed tribological tests determined dependence between wear and slid-
ing speed and load. The tests were performed on block on ring tribometer for
loads of 5–420 N and for sliding speeds of 0.2–3.0 m/s (Fig. 4).
Basavarajappa et al.10–12
studied the tribological behaviour of hybrid compos-
ites with Al2219 aluminum base reinforced with silicon–carbide and graphite.
Hybrid composites were obtained by liquid metallurgy process.
Fig. 2. Change of friction coefficient depending on con-
tent of graphite8
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0
0 2 5 8
graphite addition (vol. %)
frictioncoefficient
Fig. 3. Wear of composite and counter-body depending
on content of graphite8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
weightloss(g)
0 2 5 8
graphite addition (vol. %)
Al/SiC/Gr composite
Al/SiC/Gr composite
Al/SiC/Gr composite
Ave. of Al/SiC/Gr
A356 countreparts
A356 countreparts
A356 countreparts
Ave. of A356
86
results and discussion
A small number of scientists were engaged in research of tribological and me-
chanical characteristics of hybrid Al/SiC/Gr composites. The research review is
given below.
Testing of tribological characteristics was performed according to ASTM G99-95
standard on a pin-on-disc tribometer. Four different materials were tested: Al2219,
Al2219/5SiC/3Gr, Al2219/10SiC/3Gr and Al2219/15SiC/3Gr. With tested compos-
ites, SiC and graphite of volumetric share of 3% with particles size of 45 µm were
used as reinforcements. The percentage of SiC in tested samples varied between 5,
10 and 15% of volumetric share with particle size of 25 µm.
Tribological tests are performed for loads ranging from 10 to 60 N and slid-
ing speeds of 1.53, 3.0, 4.6 and 6.1 m/s. The tests are performed on a sliding dis-
tance of 5000 m and the material of disc is EN 36 steel with hardness of 65 HRc.
Tests results (Refs 10–12) show that with increase of SiC percentage share,
the resistance to composite wear increases, that is, wear decreases (Fig. 5).
With increase of sliding distance wear increases, and it decreases with in-
crease of SiC percentage (Fig. 6).
The wear increases with increase of sliding speed and load, especially above
4.6 m/s and 50 N (Figs 7 and 8). At lower sliding speeds, the main wear mecha-
nism is abrasive wear, while, at higher speeds, the conclusion can not be drawn
due to delamination10–12
.
Indian scientists Suresha and Sridhara13–16
have studied tribological behav-
iour of aluminium hybrid composites with addition of SiC and graphite or the so-
called Al/SiC/Gr composites. They have studied dependence between wear and
percentage content of reinforcements, the first, the other or both.
Fig. 4. Dependence of Al/SiC/Gr com-
posite wear on load and sliding speed9
0.20
0.15
0.10
0.05
0.00
wearrate(mm3
/m)
0 100 200 300 400 500
load (N)
A356 Al-10%SiC-4%Gr
Unlubricated wear versus
(SAE52100) ring
120×10–6
80×10–6
40×10–6
0
wearrate(mm3
/m)
0 1 2
load (N)
0.2 m/s
0.5 m/s
3 m/s
2 m/s
1.2 m/s
0.8 m/s
0.5 m/s
87
Hybrid composites are obtained with stir casting procedure. Aluminium alloy
LM25 (AL–Si7Mg0.5) is used as matrix. Overall percentage of reinforcements in
hybrid composites is 10% of volumetric share, while the individual percentage of
both reinforcements varies from 0, 1.25, 2.5, 3.75 up to 5.0% of volumetric share.
Particle size of SiC is 10–20 µm, density is 3.22 g/cm3
, and particle size of graph-
ite is 70–80 µm and density 2.09–2.23 g/cm3
.
Tribological tests were performed on tribometer with a pin-on-disc contact
pair, according to ASTM G99’95a standard, without lubrication, for loads of 15–
75 N, sliding distance of 400–2000 m, sliding speed of 0.4–2.0 m/s, with equal
percentage content of SiC and Gr in hybrid composite. The EN 31 steel having
surface roughness Ra
  =  0.1 mm is used as disc material. Percentage of reinforce-
ments, sliding speeds, loads and sliding distances (Fig. 9) have influence on wear
of Al/SiC/Gr composite.
Increase of graphite percentage content in a composite leads to decrease of
wear due to forming of lubricant layer. On the other hand, addition of SiC im-
Fig. 5. Wear dependence on sliding distance10–12
12
10
8
6
4
2
0
wearvolume(mm3
)
400 800 1200 1600 2000
sliding distance (m)
Al2219
Al2219/5SiCp/3Gr
Al2219/10SiCp/3Gr
Al2219/15SiCp/3Gr
Fig. 6. Wear dependence on graphite content
for different sliding distances10–12
70
60
50
40
30
20
10
0
wearvolume(mm3
)
0 5 10 15
SiCp reinforcement (%) + 3%Gr
1000 m
3000 m
5000 m
Fig. 7. Wear dependence of sliding speed10–12
140
120
100
80
60
40
20
0
Al2219
Al2219/5SiCp/3Gr
Al2219/10SiCp/3Gr
Al2219/15SiCp/3Gr
1.53 3 4.6 6.1
sliding speed (m/s)
wearrate(mm3
/m×10–3
)
Fig. 8. Dependence between wear and load for
sliding speed of 3 m/s and sliding distance of
5000 m13–15
16
14
12
10
8
6
4
2
0
10 20 40 50 60
load (N)
wearrate(mm3
/m×10–3
)
Al2219
Al2219/5SiCp/3Gr
Al2219/10SiCp/3Gr
Al2219/15SiCp/3Gr
88
proves strength and resistance to wear of composite, but reduces machinability
of parts and increases stiffness. Combined use of the both reinforcements leads
to improvement both of tribological and mechanical characteristics of aluminium
alloys. Optimum percentage of reinforcements is 7.5% regardless of the load, slid-
ing speed and sliding distance.
Leng and associates17,18
have studied the influence of graphite particle size
on tribological and mechanical characteristics of hybrid composites. Aluminium
Al2024 makes the base of the composite, and SiC with percentage share of 40%
and particle size of 3 µm is used as reinforcement. Graphite with volume content
of 5% is used as other reinforcement, but with different particle sizes of 1, 6 and
20 µm. Hybrid Al/SiC/Gr composites are obtained with Squeeze casting method.
Mechanical characteristics (tensile strength and elastic modulus ) are deter-
mined for each of these composites. Tensile strength and elastic modulus of ob-
tained hybrid composites decrease with increase of graphite particle size.
Tests of tribological characteristics were performed on a tribometer working
on block-on-ring principle. The rings are made of composites and blocks are made
of W18Cr4V steel. Tests are realised under load of 150 N, sliding speed of 0.4 m/s,
during time period of 120 s, at temperature of 22±3°C and without lubrication.
The measured values of friction coefficient for Al/SiC composites are with-
in boundaries of 0.3÷0.5. Friction coefficient of Al/SiC/Gr hybrid composites is
0.020
0.015
0.010
0.005
0.000
0.020
0.015
0.010
0.005
0.000
mainofwear(g) main effect plot for wear of Al–SiC–Gr hybrid composites
% reinforcement sliding speed (m/s)
load (N) sliding distance (m)
15
0.0 2.5 5.0 7.5 10.0 0.4 0.8 1.2 1.6 2.0
30 45 60 75 400 800 1200 1600 2000
Fig. 9. Dependence between wear and reinforcement content, sliding speed and sliding distance
for Al/SiC/Gr hybrid composites13
89
within boundaries of 0.25÷0.3. These
values are much smaller due to the lu-
bricating properties of the graphite and
there is obvious smaller dissipation of
values.
The measuring of mass of worn
material is performed within tribologi-
cal tests. The wear of Al/SiC (484.0
mg) composite is the highest, while
the wear of hybrid composites is much
lower (1.4÷2.7 mg). Material losses with
hybrid composites are 170 to 340 times
smaller than with Al/SiC composites
(Fig. 10). When referring to graphite particle size, the lowest wear is found with
composites with the largest particles (20 µm), and the highest wear is found with
composites with the smallest particles (1 µm).
By adding graphite, the friction coefficient of hybrid composites decreases
and resistance to wear considerably increases. Besides, wear of counter body is
reduced by 60–70%.
Wear resistance of Al/SiC/Gr hybrid composites increases with the increase
of particle size of graphite. Improvement of tribological characteristics occurs
with improving of lubrication of tribo-layers which consist of a mixture of iron
oxide, graphite, SiC and aluminium particles.
Mahdavi and Akhlaghi19,20
have studied tribological behaviour of Al/SiC/
Gr hybrid composites obtained by a new method – in situ powder metallurgy
(IPM). Hybrid composites with aluminium base reinforced by silicon–carbide
and graphite represent unique class of the advanced materials developed to be
used in tribological applications. The base of Al/SiC/Gr hybrid composites is
Al6061. Obtained composites contain 9% of graphite and percentage content of
SiC varies within 0÷40%. Average particle size of SiC is 19 µm and of graphite
particle – 75  µm. Density of SiC is 3.2 g/cm3
, and density of graphite – 2.2 g/cm3
.
Tribological tests are performed on a tribometer with a pin-on-disc contact.
Sliding distances are 250, 500, 750 and 1000 m. Pin material is steel (1.5Cr, 1C,
0.35Mn, 0.25Si) of 64 HRc hardness. Load is 20 N, pressure – 1 MPa and sliding
speed – 0.5 m/s.
Hardness of obtained samples increases with the increase of SiC content.
When referring to tribological characteristics, wear intensity increases with in-
crease of sliding distance. However, when referring to the SiC percentage, the
wear decreases with the increase of SiC content up to 20%, then, for 20–40% SiC,
the wear increases again (Fig.  11). Regarding the friction coefficient, its value
decreases with the increase of SiC content and it has the smallest value for 30%
500
490
480
470
460
450
composite ring
steel block
5
0
wearloss(mg)
SiC/Al SiC/Gr(1µm)/Al SiC/Gr(6µm)/Al SiC/Gr(20µm)/Al
Fig. 10. Wear of hybrid composites and counter
bodies with different particle sizes of graphite17
90
of SiC. After that, the friction coef-
ficient increases (Fig. 12).
The same authors21
analysed
Al/SiC/Gr hybrid composite with
Al6061base, with percentage share
of 30% of SiC and variable con-
tent of graphite from 0 to 13%,
obtained by in situ IPM procedure.
Tribological tests are performed
on a tribometer with a pin-on-disc
contact. The particle size of SiC is
93 µm and particle size of graphite
is 75 µm. Test conditions, i.e. load,
sliding speed and sliding distance
are the same as in Ref. 19.
Tribological tests results for
Al–Gr composites show that wear
intensity increases with the in-
crease of sliding distance and with
increase in graphite content (Fig.
13). The same trend exists also
with Al/SiC/Gr composites, ex-
cept that wear intensity is much
lower. The lowest wear with Al/
SiC/Gr composites appears when
the graphite content is 9%. With
Al/30SiC/9Gr hybrid composites
the wear is 15÷30 times lower than
with Al/9Gr composites (Fig. 14).
Increase of graphite content
in composites leads to decrease of
friction coefficient. The values of
friction coefficient with Al/SiC/Gr
hybrid composites are lower by 20%
than with Al/Gr composites (Fig. 15).
In Ref. 22 is investigated the influence of SiC particle size on tribological
characteristics of Al–SiC–Gr hybrid composites. Hybrid composites with A6061
base, reinforced by 10% of SiC and 0÷5% of graphite, are obtained by IPM proce-
dure. Sizes of SiC particles are 19, 93 and 146 µm and density – 3.2 g/cm3
, while
particle size of graphite – 75 µm and density – 2.2 g/cm3
.
100
80
60
40
20
0
a
b
Al6061
0%SiC
10%SiC
20%SiC
30%SiC
40%SiC
wearloss(mm3
)
0 250 500 750 1000 1250
sliding distance (m)
250 m
500 m
750 m
1000 m
180
160
140
120
100
80
60
40
20
0
wearrate(×10–3
mm3
/m)
Al6061 0 10 20 30 40
SiC content (vol. %)
Fig. 11. Dependence between wear intensity and
sliding distance (a) and content of SiC in Al/SiC/Gr
hybrid composites with 9% of graphite (b) (Ref. 19)
Fig. 12. Dependence between friction coefficient
and SiC content in Al/SiC/Gr hybrid composites
with 9% of graphite19
1.0
0.9
0.8
0.7
0.6
0.5
frictioncoefficient
Al6061 0 10 20 30 40
SiC content (vol. %)
91
The wear of hybrid composites
increases with increase of sliding
distance. The highest wear occurs
in aluminium alloy, while, with Al/
SiC composites, the wear decreases
with increase of SiC particle size.
With Al/SiC/Gr hybrid composites,
the trend is the same, but the wear is
much lower than with Al/SiC com-
posites (Fig. 16).
Friction coefficient decreases
with the increase of SiC reinforce-
ment particle size. At the same time, with Al/SiC/Gr hybrid composites, the fric-
tion coefficient is lower than with Al–SiC composites without graphite (Fig. 17).
Adding of graphite (5%) leads to decrease of friction coefficient due to form-
ing of lubricant layer. It is obvious that mechanical characteristics (porosity, hard-
ness) as well as tribological characteristics (wear intensity and friction coefficient)
120
100
80
60
40
20
0
0%Gr(Al6061)
3%Gr
5%Gr
9%Gr
13%Gr
0 250 500 750 1000 1250 1500
sliding distance (m)
wearloss(mm3
)
Fig. 13. Dependence between hybrid compos-
ites wear loss and sliding distance for different
values of graphite content21
120
100
80
60
40
20
0
0 3 6 9 12 15
graphite content (vol. %)
wearrate(×10–3
mm3
/m)
Al/SiC/Gr
Al/Gr
Fig. 14. Dependence between hybrid compos-
ites wear rate and graphite content21
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0 5 10 15
Al/SiC/Gr
Al/Gr
frictioncoefficient
graphite content (vol. %)
Fig. 15. Dependence between hybrid composites
friction coefficient and graphite content21
50
40
30
20
10
0
Al6061
fine SiC
medium sized
SiC
coarse SiC
a b
wearloss(mm3
)
0 250 500 750 1000 1250 1500
sliding distance (m)
50
40
30
20
10
0
Al6061
fine SiC
medium sized
SiC
coarse SiC
wearloss(mm3
)
0 250 500 750 1000 1250 1500
sliding distance (m)
Fig. 16. Dependence between wear loss and sliding distance for Al/SiC composites (a) and for Al/
SiC/Gr composites22
(b)
92
of Al/10SiC composite decrease
by adding of 5% of graphite or by
forming Al/SiC/Gr hybrid com-
posites.
Ames and Alpas23
have stud-
ied tribological behaviour of hy-
brid composite with A356 base
reinforced by 20% of SiC and
3÷10% of graphite. Tribological
tests are performed on a block-
on-ring contact pair without lu-
brication. Load size varies from
1 to 441 N. Wear resistance of Al/20SiC/3Gr hybrid composite is approximately
equal to wear resistance of Al/20SiC composite at low and medium loads. For
loads lower than 20 N, wear of Al/20SiC/3Gr hybrid composite and Al/20SiC
composite is 10 times lower than wear of a basic material without reinforcement
(A356). Due to hardness of SiC particles, Al/20SiC/3Gr hybrid composite has 1÷2
times higher wear resistance than Al/20SiC/10Gr at higher loads. However, the
graphite leads to decrease of counter body wear.
Vencl et al.24,25
have studied tribological characteristics of hybrid composites
with A356 base reinforced by ceramic particles SiC and Al2
O3
and graphite. Hy-
brid composites are obtained by compo-casting procedure and T6 heat-treatment
regime. When talking about micro-hardness with addition of 10% of ceramic re-
inforcement (SiC or Al2
O3
), the micro-hardness increases and with addition of 1%
of graphite, the micro-hardness decreases below the micro-hardness of a basic
material.
Reinforcement particles (SiC or Al2
O3
) are arranged in clusters in composite
matrix. Particles arrangement of SiC in clusters is more favourable for mechanical
and tribological characteristics in comparison to arrangement of Al2
O3
particles.
Wear resistance increases by adding reinforcement, especially by adding graph-
ite, while the friction coefficient of ceramic reinforced composites is higher than
friction coefficient of the basic material. At the same time, friction coefficient
of Al/10SiC/1Gr hybrid composite is lower than friction coefficient of the basic
material (A356) (Fig. 18).
Lagiewka and co-workers26
have studied tribological influence of com-
bined reinforcement by silicon–carbide and graphite on a hybrid compos-
ite with AlMg10 matrix. Hybrid composites with the following reinforce-
ment content: AlMg10/5SiC/2Gr, AlMg10/5SiC/5Gr, AlMg10/15SiC/2Gr and
AlMg10/15SiC/5Gr were tested. Tribological tests are performed on tribometer
block-on-disc with load of 50 N and sliding distance of 3000 m. The results show
that wear resistance of hybrid composites is higher than wear resistance of AG10
0.95
0.85
0.75
0.65
0.55
0.92 for the unreinforced alloy
Al/10Gr
Al/10SiC/5Gr
19 93 146
SiC size (µm)
coefficientoffriction
Fig. 17. Dependence between coefficient friction and
SiC particle size22
93
basic material. Also, there is higher wear resistance for the same value of SiC
with composites with higher graphite content. Thus, the higher wear resistance is
found for hybrid composites with 15%SiC and 5%Gr (Fig. 19).
CONCLUSIONS
Hybrid Al/SiC/Gr composites have a lot of better tribological characteristics in
comparison to Al–SiC and Al–Gr composites. By changing percentage content of
reinforcement, mechanical and tribological characteristics of the obtained hybrid
composites with aluminium matrix are changed.
Hybrid composites with aluminium matrix are obtained by different methods
of casting (powder metallurgy, squeeze casting, stir casting, etc.). Percentage of
silicon–carbide (SiC) ranges from 0÷40% and percentage of graphite – within
0÷13%. Particle sizes of SiC and graphite are different depending on the manu-
facturer and procedure for obtaining hybrid composites.
1.0×10–3
9.0×10–4
8.0×10–4
7.0×10–4
6.0×10–4
5.0×10–4
4.0×10–4
3.0×10–4
2.0×10–4
1.0×10–4
0
wear rate
coefficient of friction
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0wearrate(mm3
/m)
coefficientoffriction
A356 C1 C2 C3
tested material
9.05
0.67
7.76
0.73
6.08
0.71
0.65
2.71
Fig. 18. Resistance to wear and
friction coefficient of A356 al-
loy, C1 (Al/10Al2
O3
) composite,
C2 (Al/10SiC) composite and C3
(Al/10SiC/1Gr) composite24
Fig. 19. Dependence between mass
loss and sliding distance26
0.06
0.05
0.04
0.03
0.02
0.01
0
AG10
AG10+(5%SiC+2%Cgr
)
AG10+(5%SiC+5%Cgr
)
AG10+(15%SiC+2%Cgr
)
AG10+(15%SiC+5%Cgr
)
massloss(g)
0 500 1000 1500 2000 2500 3000
wear path (m)
94
Tribological tests of Al/SiC/Gr hybrid composites are performed on tribom-
eters with different contact pairs (block-on-ring, pin-on-disc, block-on-disc, etc.).
Tests are performed in accordance with appropriate ASTM standard for different
values of loads, sliding distances and sliding speeds.
Results of tribological tests show that friction coefficient of Al/SiC/Gr hybrid
composites decreases with the increase of graphite content. Friction coefficient
decreases with increase of SiC content all up to 30% and, after that, it increases.
When referring to amount of wear, it decreases with the increase of graphite
content (for the same values of SiC). The increase of SiC content also leads to
wear decrease or to increase of wear resistance of the tested composites. At the
same time, the wear increases with increase of the sliding distance. Increase of the
sliding speed and load also leads to wear increase or decrease of wear resistance
of Al/SiC/Gr hybrid composites.
The particle size of reinforcement also affects the wear of hybrid composites
with aluminium matrix reinforced by SiC and graphite. As the particle size of
graphite is bigger, the wear of composite is smaller, and vice versa.
It is obvious that tribological characteristics of Al/SiC/Gr hybrid composites
depend on a number of factors, but their characteristics are much better in com-
parison to Al–SiC and Al–Gr composites.
	
ACKNOWLEDGEMENT
This paper presents the research results obtained within the framework of a proj-
ect TR–35021, financially supported by the Ministry of Education and Science of
the Republic of Serbia.
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of Al/Gr and Al/30SiC/Gr Composites Processed by in situ Powder Metallurgy (IPM) Method.
Tribol Lett, 44, 1 (2011).
21.	F. AKHLAGHI, S. MAHDAVI: Effect of the SiC Content on the Tribological Properties of
Hybrid Al/Gr/SiC Composites Processed by in situ Powder Metallurgy (IPM) Method. Adv
Mat Res, 1878 (2011).
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ior of SiC and SiC–Gr-reinforced Al6061 composites. J Mater Sci, DOI 10.1007/s10853-011-
5776-1, 2011.
23.	W. AMES, At. ALPAS: Wear mechanisms in hybrid composites of graphite-20% SiC in
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24.	A. VENCL, I. BOBIC, S. AROSTEGUI, B. BOBIC, A. MARINKOVIC, M. BABIC: Structur-
al, mechanical and tribological properties of A356 aluminium alloy reinforced with Al2
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,
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composites tribological properties. In: 11th International Conference on Tribology, Belgrade,
2009, p. 78.
26.	M. LAGIEWKA, Z. KONOPKA, A. ZYSKA, M. NADOLSKI: Examining of abrasion re-
sistance of hybrid composites reinforced with SiC and Cgr
particles. Archives and foundry
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Received 22 May 2012
Revised 28 July 2012

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TRIBOLOGICAL CHARACTERISTICS OF ALUMINIUM HYBRID COMPOSITES REINFORCED WITH SILICON CARBIDE AND GRAPHITE. a review

  • 1. * For correspondence. 83 Journal of the Balkan Tribological Association Vol. 19, No 1, 83–96 (2013) Hybrid composites TRIBOLOGICAL CHARACTERISTICS OF ALUMINIUM HYBRID COMPOSITES REINFORCED WITH SILICON CARBIDE AND GRAPHITE. a review B. STOJANOVIca *, M. BABIca , S. MITROVIca , A. VENCLb , N. MILORADOVIca , M. PANTIca a  Faculty of Engineering, University of Kragujevac, 6 Sestre Janjic Street, 34 000 Kragujevac, Serbia E-mail: blaza@kg.ac.rs b   Faculty of Mechanical Engineering, University of Belgrade, 11 000 Belgrade, Serbia ABSTRACT This paper presents tribological characteristics of hybrid composites with alu- minium matrix, reinforced with silicon carbide (SiC) and graphite (Gr). Newly formed Al/SiC/Gr hybrid composites are the combination of the two different hy- brid materials. Namely, hard particles of silicon carbide increase the hardness and resistance to wear, while soft particles of graphite improve lubrication and reduce friction coefficient and wear. It is possible to obtain Al/SiC/Gr hybrid composites by different methods of casting. Tribological tests show that load, sliding speed, sliding distance, content and size of reinforcement particles influence the size and the type of wear and friction coefficient of Al/SiC/Gr hybrid composites with aluminium matrix. Keywords: tribology, hybrid composites, aluminium, metal matrix composites (MMC), wear, coefficient of friction, SiC, graphite. aims and background Composite materials (composites) are formed by mixing of two or more materi- als or phases of the same material. The composite has completely new, different and better characteristics in comparison to its constituents. The components do not blend with each other or do not get dissolved, so there is a visible difference between them.
  • 2. 84 Essentially, the composites consist of the base (the matrix), which content is much higher in comparison to other materials, and reinforce- ment, i.e. material with which the desired prop- erties of composites are achieved. The base or the matrix may be metal, polymer and ceramic (Fig. 1). When the matrix is metal, the compos- ites are metal matrix composites (MMC), when the matrix is polymer, the composites are poly- mer matrix composites (PMC) and when the matrix is ceramic, the composites are ceramic matrix composites (CMC). When talking about metal matrix com- posites, the aluminium and its alloys are mostly used as a base. Aluminium and its alloys can accept various reinforcements and improvers. Aluminium composites have a number of positive features such as: small density, good thermal conduc- tivity and resistance to corrosion. However, aluminium alloys also have certain defects in the form of higher coefficient of thermal expansion and inadequate tri- bological characteristics. Increase of stiffness, hardness, resistance to fatigue, as well as the improvement of tribological characteristics are achieved by adding ap- propriate reinforcements and improvers and by forming aluminium composites. Commonly used reinforcements are SiC, Al2 O3 and graphite­1–7 . The influence of SiC, Al2 O3 and graphite on tribological and mechanical characteristics is different. By increase of mass or volumetric share of SiC, Al2 O3 and graphite, tribological characteristics of composites are changed. By combin- ing the appropriate share of these two materials, the optimum values of tribologi- cal and mechanical characteristics of materials are achieved. The composites reinforced with SiC (silicon carbide) and graphite (Gr) are called Al/SiC/Gr hybrid composites. A small number of scientists was engaged in research of tribological and mechanical characteristics of hybrid Al/SiC/Gr composites. The research review is given below. Ted Guo and associates8 have studied tribological behaviour of Al/SiC/Gr composites with 10% SiC and different content of graphite (2, 5 and 8%). With increase of graphite content up to 5%, the value of friction coefficient decreases due to forming of lubricating layer (Fig. 2). Further increase of graphite content does not have significant effect on friction coefficient, except that composite hard- ness decreases. Guo and Tsao8 used aluminium 6061 (average powder size: 30 µm) as a base and SiC (average powder size: 45 µm) and graphite (average powder size: 8 µm) as reinforcements. SiC percentage is 10% of volumetric content and percentage of Fig. 1. Types of composites Metal MMC Reinforcement PMC CMC Polym er Ceram ics
  • 3. 85 graphite varies between 2, 5 and 8% of volumetric share (v/o). Hybrid composites of appropri- ate composition were obtained using semi-solid powder densifi- cation method on the 10t Instron device (model 1125). Testing of tribological char- acteristics was performed on tri- bometer during period of 5 min, without lubrication, at pressure of 0.094 MPa and at sliding speed of 1.09 m/s. The measure- ments showed that friction coef- ficient decreases with increase of graphite content (for 0 to 5% Gr) and after that friction coeffi- cient has constant value (for 5 to 8% Gr). Measuring of counter- body worn material was done alongside with hybrid compos- ite A356 with the same content of graphite. Unlike A356 com- posite where mass dissipation or wear increases with increase of graphite content, with com- posites having Al6061 base the wear increases up to 5% Gr and then decreases (Fig. 3). Riahi and Alpas9 focused on systemic tests of the role of tribo-layers which are formed on contact surfaces of hybrid composites with A356 aluminium base. Tests were done on Al/SiC/Gr hybrid composite with A356 base, 10% SiC with particle size of 16 µm and 3% of graphite with particle size of 80 µm and 138 µm. Performed tribological tests determined dependence between wear and slid- ing speed and load. The tests were performed on block on ring tribometer for loads of 5–420 N and for sliding speeds of 0.2–3.0 m/s (Fig. 4). Basavarajappa et al.10–12 studied the tribological behaviour of hybrid compos- ites with Al2219 aluminum base reinforced with silicon–carbide and graphite. Hybrid composites were obtained by liquid metallurgy process. Fig. 2. Change of friction coefficient depending on con- tent of graphite8 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0 0 2 5 8 graphite addition (vol. %) frictioncoefficient Fig. 3. Wear of composite and counter-body depending on content of graphite8 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 weightloss(g) 0 2 5 8 graphite addition (vol. %) Al/SiC/Gr composite Al/SiC/Gr composite Al/SiC/Gr composite Ave. of Al/SiC/Gr A356 countreparts A356 countreparts A356 countreparts Ave. of A356
  • 4. 86 results and discussion A small number of scientists were engaged in research of tribological and me- chanical characteristics of hybrid Al/SiC/Gr composites. The research review is given below. Testing of tribological characteristics was performed according to ASTM G99-95 standard on a pin-on-disc tribometer. Four different materials were tested: Al2219, Al2219/5SiC/3Gr, Al2219/10SiC/3Gr and Al2219/15SiC/3Gr. With tested compos- ites, SiC and graphite of volumetric share of 3% with particles size of 45 µm were used as reinforcements. The percentage of SiC in tested samples varied between 5, 10 and 15% of volumetric share with particle size of 25 µm. Tribological tests are performed for loads ranging from 10 to 60 N and slid- ing speeds of 1.53, 3.0, 4.6 and 6.1 m/s. The tests are performed on a sliding dis- tance of 5000 m and the material of disc is EN 36 steel with hardness of 65 HRc. Tests results (Refs 10–12) show that with increase of SiC percentage share, the resistance to composite wear increases, that is, wear decreases (Fig. 5). With increase of sliding distance wear increases, and it decreases with in- crease of SiC percentage (Fig. 6). The wear increases with increase of sliding speed and load, especially above 4.6 m/s and 50 N (Figs 7 and 8). At lower sliding speeds, the main wear mecha- nism is abrasive wear, while, at higher speeds, the conclusion can not be drawn due to delamination10–12 . Indian scientists Suresha and Sridhara13–16 have studied tribological behav- iour of aluminium hybrid composites with addition of SiC and graphite or the so- called Al/SiC/Gr composites. They have studied dependence between wear and percentage content of reinforcements, the first, the other or both. Fig. 4. Dependence of Al/SiC/Gr com- posite wear on load and sliding speed9 0.20 0.15 0.10 0.05 0.00 wearrate(mm3 /m) 0 100 200 300 400 500 load (N) A356 Al-10%SiC-4%Gr Unlubricated wear versus (SAE52100) ring 120×10–6 80×10–6 40×10–6 0 wearrate(mm3 /m) 0 1 2 load (N) 0.2 m/s 0.5 m/s 3 m/s 2 m/s 1.2 m/s 0.8 m/s 0.5 m/s
  • 5. 87 Hybrid composites are obtained with stir casting procedure. Aluminium alloy LM25 (AL–Si7Mg0.5) is used as matrix. Overall percentage of reinforcements in hybrid composites is 10% of volumetric share, while the individual percentage of both reinforcements varies from 0, 1.25, 2.5, 3.75 up to 5.0% of volumetric share. Particle size of SiC is 10–20 µm, density is 3.22 g/cm3 , and particle size of graph- ite is 70–80 µm and density 2.09–2.23 g/cm3 . Tribological tests were performed on tribometer with a pin-on-disc contact pair, according to ASTM G99’95a standard, without lubrication, for loads of 15– 75 N, sliding distance of 400–2000 m, sliding speed of 0.4–2.0 m/s, with equal percentage content of SiC and Gr in hybrid composite. The EN 31 steel having surface roughness Ra   =  0.1 mm is used as disc material. Percentage of reinforce- ments, sliding speeds, loads and sliding distances (Fig. 9) have influence on wear of Al/SiC/Gr composite. Increase of graphite percentage content in a composite leads to decrease of wear due to forming of lubricant layer. On the other hand, addition of SiC im- Fig. 5. Wear dependence on sliding distance10–12 12 10 8 6 4 2 0 wearvolume(mm3 ) 400 800 1200 1600 2000 sliding distance (m) Al2219 Al2219/5SiCp/3Gr Al2219/10SiCp/3Gr Al2219/15SiCp/3Gr Fig. 6. Wear dependence on graphite content for different sliding distances10–12 70 60 50 40 30 20 10 0 wearvolume(mm3 ) 0 5 10 15 SiCp reinforcement (%) + 3%Gr 1000 m 3000 m 5000 m Fig. 7. Wear dependence of sliding speed10–12 140 120 100 80 60 40 20 0 Al2219 Al2219/5SiCp/3Gr Al2219/10SiCp/3Gr Al2219/15SiCp/3Gr 1.53 3 4.6 6.1 sliding speed (m/s) wearrate(mm3 /m×10–3 ) Fig. 8. Dependence between wear and load for sliding speed of 3 m/s and sliding distance of 5000 m13–15 16 14 12 10 8 6 4 2 0 10 20 40 50 60 load (N) wearrate(mm3 /m×10–3 ) Al2219 Al2219/5SiCp/3Gr Al2219/10SiCp/3Gr Al2219/15SiCp/3Gr
  • 6. 88 proves strength and resistance to wear of composite, but reduces machinability of parts and increases stiffness. Combined use of the both reinforcements leads to improvement both of tribological and mechanical characteristics of aluminium alloys. Optimum percentage of reinforcements is 7.5% regardless of the load, slid- ing speed and sliding distance. Leng and associates17,18 have studied the influence of graphite particle size on tribological and mechanical characteristics of hybrid composites. Aluminium Al2024 makes the base of the composite, and SiC with percentage share of 40% and particle size of 3 µm is used as reinforcement. Graphite with volume content of 5% is used as other reinforcement, but with different particle sizes of 1, 6 and 20 µm. Hybrid Al/SiC/Gr composites are obtained with Squeeze casting method. Mechanical characteristics (tensile strength and elastic modulus ) are deter- mined for each of these composites. Tensile strength and elastic modulus of ob- tained hybrid composites decrease with increase of graphite particle size. Tests of tribological characteristics were performed on a tribometer working on block-on-ring principle. The rings are made of composites and blocks are made of W18Cr4V steel. Tests are realised under load of 150 N, sliding speed of 0.4 m/s, during time period of 120 s, at temperature of 22±3°C and without lubrication. The measured values of friction coefficient for Al/SiC composites are with- in boundaries of 0.3÷0.5. Friction coefficient of Al/SiC/Gr hybrid composites is 0.020 0.015 0.010 0.005 0.000 0.020 0.015 0.010 0.005 0.000 mainofwear(g) main effect plot for wear of Al–SiC–Gr hybrid composites % reinforcement sliding speed (m/s) load (N) sliding distance (m) 15 0.0 2.5 5.0 7.5 10.0 0.4 0.8 1.2 1.6 2.0 30 45 60 75 400 800 1200 1600 2000 Fig. 9. Dependence between wear and reinforcement content, sliding speed and sliding distance for Al/SiC/Gr hybrid composites13
  • 7. 89 within boundaries of 0.25÷0.3. These values are much smaller due to the lu- bricating properties of the graphite and there is obvious smaller dissipation of values. The measuring of mass of worn material is performed within tribologi- cal tests. The wear of Al/SiC (484.0 mg) composite is the highest, while the wear of hybrid composites is much lower (1.4÷2.7 mg). Material losses with hybrid composites are 170 to 340 times smaller than with Al/SiC composites (Fig. 10). When referring to graphite particle size, the lowest wear is found with composites with the largest particles (20 µm), and the highest wear is found with composites with the smallest particles (1 µm). By adding graphite, the friction coefficient of hybrid composites decreases and resistance to wear considerably increases. Besides, wear of counter body is reduced by 60–70%. Wear resistance of Al/SiC/Gr hybrid composites increases with the increase of particle size of graphite. Improvement of tribological characteristics occurs with improving of lubrication of tribo-layers which consist of a mixture of iron oxide, graphite, SiC and aluminium particles. Mahdavi and Akhlaghi19,20 have studied tribological behaviour of Al/SiC/ Gr hybrid composites obtained by a new method – in situ powder metallurgy (IPM). Hybrid composites with aluminium base reinforced by silicon–carbide and graphite represent unique class of the advanced materials developed to be used in tribological applications. The base of Al/SiC/Gr hybrid composites is Al6061. Obtained composites contain 9% of graphite and percentage content of SiC varies within 0÷40%. Average particle size of SiC is 19 µm and of graphite particle – 75  µm. Density of SiC is 3.2 g/cm3 , and density of graphite – 2.2 g/cm3 . Tribological tests are performed on a tribometer with a pin-on-disc contact. Sliding distances are 250, 500, 750 and 1000 m. Pin material is steel (1.5Cr, 1C, 0.35Mn, 0.25Si) of 64 HRc hardness. Load is 20 N, pressure – 1 MPa and sliding speed – 0.5 m/s. Hardness of obtained samples increases with the increase of SiC content. When referring to tribological characteristics, wear intensity increases with in- crease of sliding distance. However, when referring to the SiC percentage, the wear decreases with the increase of SiC content up to 20%, then, for 20–40% SiC, the wear increases again (Fig.  11). Regarding the friction coefficient, its value decreases with the increase of SiC content and it has the smallest value for 30% 500 490 480 470 460 450 composite ring steel block 5 0 wearloss(mg) SiC/Al SiC/Gr(1µm)/Al SiC/Gr(6µm)/Al SiC/Gr(20µm)/Al Fig. 10. Wear of hybrid composites and counter bodies with different particle sizes of graphite17
  • 8. 90 of SiC. After that, the friction coef- ficient increases (Fig. 12). The same authors21 analysed Al/SiC/Gr hybrid composite with Al6061base, with percentage share of 30% of SiC and variable con- tent of graphite from 0 to 13%, obtained by in situ IPM procedure. Tribological tests are performed on a tribometer with a pin-on-disc contact. The particle size of SiC is 93 µm and particle size of graphite is 75 µm. Test conditions, i.e. load, sliding speed and sliding distance are the same as in Ref. 19. Tribological tests results for Al–Gr composites show that wear intensity increases with the in- crease of sliding distance and with increase in graphite content (Fig. 13). The same trend exists also with Al/SiC/Gr composites, ex- cept that wear intensity is much lower. The lowest wear with Al/ SiC/Gr composites appears when the graphite content is 9%. With Al/30SiC/9Gr hybrid composites the wear is 15÷30 times lower than with Al/9Gr composites (Fig. 14). Increase of graphite content in composites leads to decrease of friction coefficient. The values of friction coefficient with Al/SiC/Gr hybrid composites are lower by 20% than with Al/Gr composites (Fig. 15). In Ref. 22 is investigated the influence of SiC particle size on tribological characteristics of Al–SiC–Gr hybrid composites. Hybrid composites with A6061 base, reinforced by 10% of SiC and 0÷5% of graphite, are obtained by IPM proce- dure. Sizes of SiC particles are 19, 93 and 146 µm and density – 3.2 g/cm3 , while particle size of graphite – 75 µm and density – 2.2 g/cm3 . 100 80 60 40 20 0 a b Al6061 0%SiC 10%SiC 20%SiC 30%SiC 40%SiC wearloss(mm3 ) 0 250 500 750 1000 1250 sliding distance (m) 250 m 500 m 750 m 1000 m 180 160 140 120 100 80 60 40 20 0 wearrate(×10–3 mm3 /m) Al6061 0 10 20 30 40 SiC content (vol. %) Fig. 11. Dependence between wear intensity and sliding distance (a) and content of SiC in Al/SiC/Gr hybrid composites with 9% of graphite (b) (Ref. 19) Fig. 12. Dependence between friction coefficient and SiC content in Al/SiC/Gr hybrid composites with 9% of graphite19 1.0 0.9 0.8 0.7 0.6 0.5 frictioncoefficient Al6061 0 10 20 30 40 SiC content (vol. %)
  • 9. 91 The wear of hybrid composites increases with increase of sliding distance. The highest wear occurs in aluminium alloy, while, with Al/ SiC composites, the wear decreases with increase of SiC particle size. With Al/SiC/Gr hybrid composites, the trend is the same, but the wear is much lower than with Al/SiC com- posites (Fig. 16). Friction coefficient decreases with the increase of SiC reinforce- ment particle size. At the same time, with Al/SiC/Gr hybrid composites, the fric- tion coefficient is lower than with Al–SiC composites without graphite (Fig. 17). Adding of graphite (5%) leads to decrease of friction coefficient due to form- ing of lubricant layer. It is obvious that mechanical characteristics (porosity, hard- ness) as well as tribological characteristics (wear intensity and friction coefficient) 120 100 80 60 40 20 0 0%Gr(Al6061) 3%Gr 5%Gr 9%Gr 13%Gr 0 250 500 750 1000 1250 1500 sliding distance (m) wearloss(mm3 ) Fig. 13. Dependence between hybrid compos- ites wear loss and sliding distance for different values of graphite content21 120 100 80 60 40 20 0 0 3 6 9 12 15 graphite content (vol. %) wearrate(×10–3 mm3 /m) Al/SiC/Gr Al/Gr Fig. 14. Dependence between hybrid compos- ites wear rate and graphite content21 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0 5 10 15 Al/SiC/Gr Al/Gr frictioncoefficient graphite content (vol. %) Fig. 15. Dependence between hybrid composites friction coefficient and graphite content21 50 40 30 20 10 0 Al6061 fine SiC medium sized SiC coarse SiC a b wearloss(mm3 ) 0 250 500 750 1000 1250 1500 sliding distance (m) 50 40 30 20 10 0 Al6061 fine SiC medium sized SiC coarse SiC wearloss(mm3 ) 0 250 500 750 1000 1250 1500 sliding distance (m) Fig. 16. Dependence between wear loss and sliding distance for Al/SiC composites (a) and for Al/ SiC/Gr composites22 (b)
  • 10. 92 of Al/10SiC composite decrease by adding of 5% of graphite or by forming Al/SiC/Gr hybrid com- posites. Ames and Alpas23 have stud- ied tribological behaviour of hy- brid composite with A356 base reinforced by 20% of SiC and 3÷10% of graphite. Tribological tests are performed on a block- on-ring contact pair without lu- brication. Load size varies from 1 to 441 N. Wear resistance of Al/20SiC/3Gr hybrid composite is approximately equal to wear resistance of Al/20SiC composite at low and medium loads. For loads lower than 20 N, wear of Al/20SiC/3Gr hybrid composite and Al/20SiC composite is 10 times lower than wear of a basic material without reinforcement (A356). Due to hardness of SiC particles, Al/20SiC/3Gr hybrid composite has 1÷2 times higher wear resistance than Al/20SiC/10Gr at higher loads. However, the graphite leads to decrease of counter body wear. Vencl et al.24,25 have studied tribological characteristics of hybrid composites with A356 base reinforced by ceramic particles SiC and Al2 O3 and graphite. Hy- brid composites are obtained by compo-casting procedure and T6 heat-treatment regime. When talking about micro-hardness with addition of 10% of ceramic re- inforcement (SiC or Al2 O3 ), the micro-hardness increases and with addition of 1% of graphite, the micro-hardness decreases below the micro-hardness of a basic material. Reinforcement particles (SiC or Al2 O3 ) are arranged in clusters in composite matrix. Particles arrangement of SiC in clusters is more favourable for mechanical and tribological characteristics in comparison to arrangement of Al2 O3 particles. Wear resistance increases by adding reinforcement, especially by adding graph- ite, while the friction coefficient of ceramic reinforced composites is higher than friction coefficient of the basic material. At the same time, friction coefficient of Al/10SiC/1Gr hybrid composite is lower than friction coefficient of the basic material (A356) (Fig. 18). Lagiewka and co-workers26 have studied tribological influence of com- bined reinforcement by silicon–carbide and graphite on a hybrid compos- ite with AlMg10 matrix. Hybrid composites with the following reinforce- ment content: AlMg10/5SiC/2Gr, AlMg10/5SiC/5Gr, AlMg10/15SiC/2Gr and AlMg10/15SiC/5Gr were tested. Tribological tests are performed on tribometer block-on-disc with load of 50 N and sliding distance of 3000 m. The results show that wear resistance of hybrid composites is higher than wear resistance of AG10 0.95 0.85 0.75 0.65 0.55 0.92 for the unreinforced alloy Al/10Gr Al/10SiC/5Gr 19 93 146 SiC size (µm) coefficientoffriction Fig. 17. Dependence between coefficient friction and SiC particle size22
  • 11. 93 basic material. Also, there is higher wear resistance for the same value of SiC with composites with higher graphite content. Thus, the higher wear resistance is found for hybrid composites with 15%SiC and 5%Gr (Fig. 19). CONCLUSIONS Hybrid Al/SiC/Gr composites have a lot of better tribological characteristics in comparison to Al–SiC and Al–Gr composites. By changing percentage content of reinforcement, mechanical and tribological characteristics of the obtained hybrid composites with aluminium matrix are changed. Hybrid composites with aluminium matrix are obtained by different methods of casting (powder metallurgy, squeeze casting, stir casting, etc.). Percentage of silicon–carbide (SiC) ranges from 0÷40% and percentage of graphite – within 0÷13%. Particle sizes of SiC and graphite are different depending on the manu- facturer and procedure for obtaining hybrid composites. 1.0×10–3 9.0×10–4 8.0×10–4 7.0×10–4 6.0×10–4 5.0×10–4 4.0×10–4 3.0×10–4 2.0×10–4 1.0×10–4 0 wear rate coefficient of friction 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0wearrate(mm3 /m) coefficientoffriction A356 C1 C2 C3 tested material 9.05 0.67 7.76 0.73 6.08 0.71 0.65 2.71 Fig. 18. Resistance to wear and friction coefficient of A356 al- loy, C1 (Al/10Al2 O3 ) composite, C2 (Al/10SiC) composite and C3 (Al/10SiC/1Gr) composite24 Fig. 19. Dependence between mass loss and sliding distance26 0.06 0.05 0.04 0.03 0.02 0.01 0 AG10 AG10+(5%SiC+2%Cgr ) AG10+(5%SiC+5%Cgr ) AG10+(15%SiC+2%Cgr ) AG10+(15%SiC+5%Cgr ) massloss(g) 0 500 1000 1500 2000 2500 3000 wear path (m)
  • 12. 94 Tribological tests of Al/SiC/Gr hybrid composites are performed on tribom- eters with different contact pairs (block-on-ring, pin-on-disc, block-on-disc, etc.). Tests are performed in accordance with appropriate ASTM standard for different values of loads, sliding distances and sliding speeds. Results of tribological tests show that friction coefficient of Al/SiC/Gr hybrid composites decreases with the increase of graphite content. Friction coefficient decreases with increase of SiC content all up to 30% and, after that, it increases. When referring to amount of wear, it decreases with the increase of graphite content (for the same values of SiC). The increase of SiC content also leads to wear decrease or to increase of wear resistance of the tested composites. At the same time, the wear increases with increase of the sliding distance. Increase of the sliding speed and load also leads to wear increase or decrease of wear resistance of Al/SiC/Gr hybrid composites. The particle size of reinforcement also affects the wear of hybrid composites with aluminium matrix reinforced by SiC and graphite. As the particle size of graphite is bigger, the wear of composite is smaller, and vice versa. It is obvious that tribological characteristics of Al/SiC/Gr hybrid composites depend on a number of factors, but their characteristics are much better in com- parison to Al–SiC and Al–Gr composites. ACKNOWLEDGEMENT This paper presents the research results obtained within the framework of a proj- ect TR–35021, financially supported by the Ministry of Education and Science of the Republic of Serbia. REFERENCES   1. M. K. SURAPPA: Aluminium matrix composites: Challenges and opportunities. Sadhana, 28 (1, 2), 319 (2003).   2. M. BABIC, S. MITROVIC, R. NINKOVIC: Tribological Potencial of Zinc–Aluminium Alloys Improvement. Trib Ind, 31 (1, 2), 15 (2009).  3. M. BABIC, S. MITROVIC, B. JEREMIC: The influence of heat treatment on the sliding wear behavior of a ZA-27 alloy. Trib Int, 43 (1, 2), 16 (2010).   4. M. KANDEVA, L. VASILEVA, R. RANGELOV, S. SIMEONOVA: Wear-resistance of Alu- minum Matrix Microcomposite Materials. Trib Ind, 33 (2), 57 (2011).   5. V. S. AIGBODION, S. B. HASSAN, E. T. DAUDA, R. A. MOHAMMED: Experimental Study of Ageing Behaviour of Al-Cu-Mg/Bagasse Ash Particulate Composites. Trib Ind, 33 (1), 28 (2011).  6. B. BOBIC, S. MITROVIC, M. BABIC, I. BOBIC: Corrosion of Aluminium and Zinc–Alu- minium Alloys Based Metal–Matrix Composites, Trib Ind, 31 (3, 4), 44 (2009).
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