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Sedimentary
Based Microbial
Fuel Cells
Evaluated by
Power Density
Zachary Gilstrap
Alston Loper
Matthew Wieters
Problem Specifics
To design and implement a sediment based
microbial fuel.
 $20 budget
 Produce 1Watt/m3 of power
Definition of Problem
Specifics
(1) C6H12O6 + 6H20  6CO2+24H++24e-
 The oxidation or loss of electrons
(2) 24e- + 24H+  12H2O
 The reduction of gain of electrons
Overall Reaction
C6H12O6 + 6O2  6CO2 + 6H2O
 Aerobic Respiration
Definition of Problem
Specifics
V=IR
 Ohm’s Law
P=IV
 Power Equation
Power Density=P/V
 Power Density Equation
Goals
Process
 Compatibility with environment
 Aerobic environment for cathode
Structural
 General well being
 Wiring connectivity
 Stability
Mechanical
 Simplistic design
Constraints
Equipment
 75% of design from natural or recycled resources
Budget
 $20 limit for the total amount of materials used in design
Skills
 Not particularly efficient engineers
Time
 Two lab periods for fabrication and implementation
Considerations
Safety
 Weather
 Tools
Ethical
 Requisitioning resources
 Impact on location population
Environmental
 Cold weather, less prolific bacteria
Life cycle/Use/Sustainability
 Long-term functionality
 Not recommended for professional use
 Sustainable
MFC Overview
Relevant Designs
• Sediment MFC easily modified
to fit the design goal.
• Mirrored our structural design
off sediment MFC shown with
slight modifications
• Simplistic design required very
little mechanical aspect
Relevant Designs
• Larger surface area to
volume ratio was decided to
be beneficial
• Referenced design achieved
3300Watts/m3 using 100mL
anode volume
• Modifying this principle and
aforementioned structural
design, we fabricated our
own MFC
Analysis of Design
Simplistic design
 Easily implemented
 Modified for design goal
Larger SA:V principle
 Crushed graphite anode
 Smaller anode volume
Synthesis of Design
Crushed graphite had an experimentally observed
density of 0.365g/mL
Anode volume chosen to be 5g or 13.68mL
Synthesis of Design
Using this and a simplistic ratio with our second
source and a chosen anode volume of 13.68cm3,
the wattage produced would hypothetically be
.45watts/13.68cm3 for our MFC
 Article design more efficient*
Materials and Cost
Materials: Costs
2ft Bamboo N/A
5ft Copper Wire $3.29
10g Crushed Graphite (5g anode & cathode)
$5.38
Window Screen 2.5in x 2.5in (2) $1.76
Electric Tape $0.85
ZipLoc Bag $0.09
Total $11.37
Description of Design
 2ft bamboo structural
support
 Crushed graphite
anode and cathode
 Free floating cathode
 Anode buried 3in
within the sediment
 Copper wiring
Description of Alternatives
Bamboo could have been replaced with PVC
 Additional cost and environmental impact
Light blue thread could have been replaced with
purple thread
 Stylistic
Potentiometer chosen over bread board
 Potential convenience
y = -4138.2x + 0.4518
R² = 0.951
0
0.05
0.1
0.15
0.2
0.25
0.3
4.00E-05 5.00E-05 6.00E-05 7.00E-05 8.00E-05 9.00E-05 1.00E-04
Voltage(V)[V]
Current (I) [A]
Polarization Curve
Initial Polarization Curve
Resistance (R)[Ω] Voltage (V) [V] Current (I) [A]
2.8 0.00 0.00E+00
300 0.00 0.00E+00
660 0.06 9.09E-05
2090 0.16 7.66E-05
3650 0.21 5.75E-05
4820 0.24 4.98E-05
Initial Power Curve
0.00E+00
2.00E-06
4.00E-06
6.00E-06
8.00E-06
1.00E-05
1.20E-05
1.40E-05
4.00E-05 5.00E-05 6.00E-05 7.00E-05 8.00E-05 9.00E-05 1.00E-04
Power(P)[watts]
Current (I) [A]
Initial Power Curve
Resistance (R) [Ω] Voltage (V) [V] Current (I) [A] Power (P) [watts]
2.8 0 0.00E+00 0.00E+00
660 0.06 9.09E-05 5.45E-06
2090 0.16 7.66E-05 1.22E-05
3650 0.21 5.75E-05 1.21E-05
4820 0.24 4.98E-05 1.20E-05
Final Polarization Curve
y = -2148.7x + 0.3307
R² = 0.99165
0
0.05
0.1
0.15
0.2
0.25
2.00E-05 4.00E-05 6.00E-05 8.00E-05 1.00E-04 1.20E-04 1.40E-04
Voltage(V)[V]
Current (I) [A]
Final Polarization Curve
Resistance (R) [Ω] Voltage (V) [V] Current (I) [A]
4.2 0 0
635 0.075 1.18E-04
1700 0.145 8.53E-05
2600 0.186 7.15E-05
3800 0.212 5.58E-05
4900 0.226 4.61E-05
Final Power Curve
Resistance (R) [Ω] Voltage (V) [V] Current (I) [A] Power (P) [watts]
4.2 0 0 0
635 0.075 1.18E-04 8.86E-06
1700 0.145 8.53E-05 1.24E-05
2600 0.186 7.15E-05 1.33E-05
3800 0.212 5.58E-05 1.18E-05
4900 0.226 4.61E-05 1.04E-05
0.00E+00
2.00E-06
4.00E-06
6.00E-06
8.00E-06
1.00E-05
1.20E-05
1.40E-05
0.00E+00 2.00E-05 4.00E-05 6.00E-05 8.00E-05 1.00E-04 1.20E-04 1.40E-04
Power(P)[watts]
Current (I) [A]
Final Power Curve
Power Density vs Time
Time [days] Voltage [mV] Power (watts) Voltage (V) [V] Current (I) [A] Power Density [watts/m3]
1 280 1.89E-05 0.28 6.76E-05 1.38
2 320 2.47E-05 0.32 7.73E-05 1.81
3 252 1.53E-05 0.252 6.09E-05 1.12
4 240 1.39E-05 0.24 5.80E-05 1.02
5 210 1.07E-05 0.21 5.07E-05 0.78
6 251 1.52E-05 0.251 6.06E-05 1.11
7 120 3.48E-06 0.12 2.90E-05 0.25
8 314 2.38E-05 0.314 7.58E-05 1.74
9 116 3.25E-06 0.116 2.80E-05 0.24
10 289 2.02E-05 0.289 6.98E-05 1.47
11 220 1.17E-05 0.22 5.31E-05 0.85
Volume [cm3] Volume [m3] Resistance (R) [Ω]
13.68 0.00001368 4140
Constants
Conclusions
0.00
0.50
1.00
1.50
2.00
1 2 3 4 5 6 7 8 9 10 11
PowerDensity[watts/m3]
Time [days]
Power Density vs Time
Sediment MFC design successfully achieved an
average power density of 1.07 watts/m3
Appendices
Appendices
Appendices
Literature Cited
http://www.nature.com/nrmicro/journal/v4/n7/fig
_tab/nrmicro1442_F3.html
http://www.ncbi.nlm.nih.gov/pubmed/24956566

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BE2120 MFC

  • 1. Sedimentary Based Microbial Fuel Cells Evaluated by Power Density Zachary Gilstrap Alston Loper Matthew Wieters
  • 2. Problem Specifics To design and implement a sediment based microbial fuel.  $20 budget  Produce 1Watt/m3 of power
  • 3. Definition of Problem Specifics (1) C6H12O6 + 6H20  6CO2+24H++24e-  The oxidation or loss of electrons (2) 24e- + 24H+  12H2O  The reduction of gain of electrons Overall Reaction C6H12O6 + 6O2  6CO2 + 6H2O  Aerobic Respiration
  • 4. Definition of Problem Specifics V=IR  Ohm’s Law P=IV  Power Equation Power Density=P/V  Power Density Equation
  • 5. Goals Process  Compatibility with environment  Aerobic environment for cathode Structural  General well being  Wiring connectivity  Stability Mechanical  Simplistic design
  • 6. Constraints Equipment  75% of design from natural or recycled resources Budget  $20 limit for the total amount of materials used in design Skills  Not particularly efficient engineers Time  Two lab periods for fabrication and implementation
  • 7. Considerations Safety  Weather  Tools Ethical  Requisitioning resources  Impact on location population Environmental  Cold weather, less prolific bacteria Life cycle/Use/Sustainability  Long-term functionality  Not recommended for professional use  Sustainable
  • 9. Relevant Designs • Sediment MFC easily modified to fit the design goal. • Mirrored our structural design off sediment MFC shown with slight modifications • Simplistic design required very little mechanical aspect
  • 10. Relevant Designs • Larger surface area to volume ratio was decided to be beneficial • Referenced design achieved 3300Watts/m3 using 100mL anode volume • Modifying this principle and aforementioned structural design, we fabricated our own MFC
  • 11. Analysis of Design Simplistic design  Easily implemented  Modified for design goal Larger SA:V principle  Crushed graphite anode  Smaller anode volume
  • 12. Synthesis of Design Crushed graphite had an experimentally observed density of 0.365g/mL Anode volume chosen to be 5g or 13.68mL
  • 13. Synthesis of Design Using this and a simplistic ratio with our second source and a chosen anode volume of 13.68cm3, the wattage produced would hypothetically be .45watts/13.68cm3 for our MFC  Article design more efficient*
  • 14. Materials and Cost Materials: Costs 2ft Bamboo N/A 5ft Copper Wire $3.29 10g Crushed Graphite (5g anode & cathode) $5.38 Window Screen 2.5in x 2.5in (2) $1.76 Electric Tape $0.85 ZipLoc Bag $0.09 Total $11.37
  • 15. Description of Design  2ft bamboo structural support  Crushed graphite anode and cathode  Free floating cathode  Anode buried 3in within the sediment  Copper wiring
  • 16. Description of Alternatives Bamboo could have been replaced with PVC  Additional cost and environmental impact Light blue thread could have been replaced with purple thread  Stylistic Potentiometer chosen over bread board  Potential convenience
  • 17. y = -4138.2x + 0.4518 R² = 0.951 0 0.05 0.1 0.15 0.2 0.25 0.3 4.00E-05 5.00E-05 6.00E-05 7.00E-05 8.00E-05 9.00E-05 1.00E-04 Voltage(V)[V] Current (I) [A] Polarization Curve Initial Polarization Curve Resistance (R)[Ω] Voltage (V) [V] Current (I) [A] 2.8 0.00 0.00E+00 300 0.00 0.00E+00 660 0.06 9.09E-05 2090 0.16 7.66E-05 3650 0.21 5.75E-05 4820 0.24 4.98E-05
  • 18. Initial Power Curve 0.00E+00 2.00E-06 4.00E-06 6.00E-06 8.00E-06 1.00E-05 1.20E-05 1.40E-05 4.00E-05 5.00E-05 6.00E-05 7.00E-05 8.00E-05 9.00E-05 1.00E-04 Power(P)[watts] Current (I) [A] Initial Power Curve Resistance (R) [Ω] Voltage (V) [V] Current (I) [A] Power (P) [watts] 2.8 0 0.00E+00 0.00E+00 660 0.06 9.09E-05 5.45E-06 2090 0.16 7.66E-05 1.22E-05 3650 0.21 5.75E-05 1.21E-05 4820 0.24 4.98E-05 1.20E-05
  • 19. Final Polarization Curve y = -2148.7x + 0.3307 R² = 0.99165 0 0.05 0.1 0.15 0.2 0.25 2.00E-05 4.00E-05 6.00E-05 8.00E-05 1.00E-04 1.20E-04 1.40E-04 Voltage(V)[V] Current (I) [A] Final Polarization Curve Resistance (R) [Ω] Voltage (V) [V] Current (I) [A] 4.2 0 0 635 0.075 1.18E-04 1700 0.145 8.53E-05 2600 0.186 7.15E-05 3800 0.212 5.58E-05 4900 0.226 4.61E-05
  • 20. Final Power Curve Resistance (R) [Ω] Voltage (V) [V] Current (I) [A] Power (P) [watts] 4.2 0 0 0 635 0.075 1.18E-04 8.86E-06 1700 0.145 8.53E-05 1.24E-05 2600 0.186 7.15E-05 1.33E-05 3800 0.212 5.58E-05 1.18E-05 4900 0.226 4.61E-05 1.04E-05 0.00E+00 2.00E-06 4.00E-06 6.00E-06 8.00E-06 1.00E-05 1.20E-05 1.40E-05 0.00E+00 2.00E-05 4.00E-05 6.00E-05 8.00E-05 1.00E-04 1.20E-04 1.40E-04 Power(P)[watts] Current (I) [A] Final Power Curve
  • 21. Power Density vs Time Time [days] Voltage [mV] Power (watts) Voltage (V) [V] Current (I) [A] Power Density [watts/m3] 1 280 1.89E-05 0.28 6.76E-05 1.38 2 320 2.47E-05 0.32 7.73E-05 1.81 3 252 1.53E-05 0.252 6.09E-05 1.12 4 240 1.39E-05 0.24 5.80E-05 1.02 5 210 1.07E-05 0.21 5.07E-05 0.78 6 251 1.52E-05 0.251 6.06E-05 1.11 7 120 3.48E-06 0.12 2.90E-05 0.25 8 314 2.38E-05 0.314 7.58E-05 1.74 9 116 3.25E-06 0.116 2.80E-05 0.24 10 289 2.02E-05 0.289 6.98E-05 1.47 11 220 1.17E-05 0.22 5.31E-05 0.85 Volume [cm3] Volume [m3] Resistance (R) [Ω] 13.68 0.00001368 4140 Constants
  • 22. Conclusions 0.00 0.50 1.00 1.50 2.00 1 2 3 4 5 6 7 8 9 10 11 PowerDensity[watts/m3] Time [days] Power Density vs Time Sediment MFC design successfully achieved an average power density of 1.07 watts/m3

Editor's Notes

  1. Oxidation reaction occurs in anode Reduction reaction occurs in cathode Will cover in more detail in further slides
  2. The first step of the redox reaction
  3. Review general process
  4. HEURISTICS: BAMBOO AND SPLINT
  5. Design goal: sustainable, 20$ less
  6. On par with large surface area to volume ratio in second article but still large enough to work with
  7. Power density well over design goal --- the article used a CSTR MFC design as well as a nutrient enriched influent flow which would increase its MFC efficiency substantially
  8. Thread not taken into account
  9. Gathered voltage in the field in mV then needed to convert back to Volts for power density calculation