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*Corresponding author: Email: nosaidus@gmail.com;
Archives of Current Research International
4(2): 1-8, 2016, Article no.ACRI.25564
ISSN: 2454-7077
SCIENCEDOMAIN international
www.sciencedomain.org
Modelling the Corrosion Rate of Buried Pipes Using
Modified Artificial Neural Network (MANN) Coupled
with Monte Carlo Simulation
Idusuyi Nosa1,2*
and Adesoji Bolaji1
1
Department of Mechanical Engineering, University of Ibadan, Nigeria.
2
Centre for Nano Materials Science Research, University of Johannesburg,
South Africa.
Authors’ contributions
This work was carried out in collaboration between both authors. Both authors designed the study,
implemented and wrote the manuscript. The first author wrote the final draft of the manuscript and
managed correspondence. Both authors read and approved the final manuscript.
Article Information
DOI:10.9734/ACRI/2016/25564
Editor(s):
(1) R. M. Chandima Ratnayake, Department of Mechanical and Structural Engineering and Materials Science,
University of Stavanger, Norway.
Reviewers:
(1) Makanjuola Oki, Landmark University, Nigeria.
(2) Rajinder Tiwari, Amity University, India.
(3) Siva Prasad Kondapalli, Anil Neerukonda Institute of Technology & Sciences, India.
Complete Peer review History: http://sciencedomain.org/review-history/14618
Received 9
th
March 2016
Accepted 4
th
May 2016
Published 13
th
May 2016
ABSTRACT
Several researchers have developed models to predict corrosion rate in buried structures with
good results using methods such as artificial neural networks, Monte Carlo to mention a few. This
paper presents a novel approach to predicting corrosion rate in buried structures using Monte
Carlo and a modified artificial neural network (MANN). Monte Carlo Simulation is used in this paper
to estimate the probability of occurrence of uniform corrosion in buried steel pipes in different soil
locations using the fixed walk method. The central limit theory and law of large numbers were
utilised to reduce errors. While Modified Artificial Neural Networks was used to establish the
relationships. Data used for this study were obtained from weight loss study of Nickel electroplated
and non electroplatedAISI-1051 samples. The parameters measured were soil pH, soil
temperature and atmospheric temperature of different soils taken from an oil producing site in
Delta State, Nigeria. These parameters were assumed normally distributed. Corrosion Penetration
Rate (CPR) was calculated for each scenario using the weight loss method. Relating these input
Original Research Article
Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564
2
parameters to the calculated CPR was possible via the employment of Modified Artificial Neural
Networks, which makes use of the least square polynomial regression equations instead of the
neuron box to avoid complexities in neuron number determination. Weights and Scaling factors
were set appropriately to allow for easy convergence. Third degree polynomial equations were
derived from the MANN and used as inputs for the MCS. Results from the MCS showed 80%
correlation with data used and a reliable estimate for the CPR was achieved using this MCS-
MANN approach. The CPR of the Nickel Electroplated Sample was less than zero which was in
good agreement with the weight loss data. It is observed that the CPR values for Non-electroplated
samples were 60% of the time higher than the values for electroplated samples.
Keywords: Uniform corrosion; Monte Carlo; artificial neural networks; steel pipes.
1. INTRODUCTION
The word Corrosion is derived from the Latin
corrosus which means eaten away or consumed
by degrees; an unpleasant word for an
unpleasant process [1]. Corrosion is a
spontaneous chemical reaction and is defined by
the NACE as “The deterioration of a material,
usually a metal, which results from a reaction
with its environment” [2]. When corrosion occurs,
these alloys are returned back to their natural
states (ores). Corrosion cannot be totally
eliminated so researchers have devised various
programs to minimise corrosion growth rate,
these include Cathodic Protection, Protective
Coatings and Inhibitors. Pipelines play an
extremely important role throughout the world as
a means of transporting gases and liquids over
long distances from their sources to the ultimate
consumers but are subject to corrosion which
causes it to disintegrate and weaken [3] incurring
huge consequences.
Three different categories of consequences for
corrosion failure have been identified as;
safety, environmental and business/economic
consequences [4]. Parametric and non-
parametric models have been developed to
predict the corrosion rate of pipelines. The
General linear model [5] which established the
baseline of external corrosion to be 2.65 mm/
lifespan for a 20 year design life, which is similar
to the recommended values of PETRONAS
Technical Standard of 3 mm/lifespan. Other
attempts to estimate the corrosion rate for
calculating re-assessment intervals using Monte
Carlo method by considering the operating
history of the pipeline and any knowledge of its
condition such as prior in-line inspections or
direct observations of corroded areas on the
pipeline have also been made [6]. Monte Carlo
simulation and degradation models have also
been used to predict pipeline corrosion rates and
also to establish the reliability of pipelines over a
period of time [7]. The proposed methodology
was fed and tested with field data acquired from
11 onshore O&G fields. Discrete random
numbers were generated from historic data,
yearly corrosion rate was estimated using
Brownian random walk, Corrosion wastage were
predicted (with linear and power models) and
Mean Time For Failure (MTFF) of the pipelines
were estimated during the course of the study.
The conclusion of the author was that both the
Monte Carlo Simulation and the degradation
models can reasonably predict the pipeline
corrosion rate.
However the level of complexity can serve as a
medium for distinguishing Monte Carlo Methods;
such as simple MCS and complex MCS [8]. A
simple MCS is derived when the physical
situation is stochastic in nature i.e. it involves
probabilities such as transport of metal particles
through material medium. While a complex MCS
is derived when the physical situation is not
stochastic.
The probability distributions of external corrosion,
pit depth and pit growth rate were investigated in
underground pipelines using Monte Carlo
simulations by Caleyo and his co-workers [9].
The study combined a predictive pit growth
model developed by the authors with the
observed distributions of the model variables in a
range of soils. It is pertinent to note that any of
the three maximal extreme value distributions,
i.e. Weibull, Fréchet or Gumbel, can arise as the
best fit to the pitting depth and rate data
depending on the pipeline age.
The consequence of corrosion has led many
companies to enact measures to periodically
assess their pipelines. Such assessments are
often costly to execute annually, thus measures
are taken to ensure they are carried out at
intervals sufficiently short to prevent leaks or
ruptures from metal loss on pipelines. Several
approaches have been taken towards studying
the effects of corrosion on buried steel pipes,
however literature is sparse on the use of a
probabilistic methods coupled with a Modified
Artificial Neural network which provides the
needed speed, accuracy and flexibility [8], which
is the focus of this study.
2. METHODOLOGY
2.1 Modified Artificial Neural Networks
From literature [10,11], Artificial Neural Networks
have been used tremendously in various fields of
industry and commerce. Their ability to “learn by
example” and to generalise this knowledge so as
to give correct predictions to previously unseen
data makes them extremely attractive. Attempts
have been made constantly to apply this method
to corrosion prediction. Artificial Neural Networks
can learn the behaviour of materials in various
corrosive soil locations and predict their
behaviour. Neural networks howbeit appealing
exist with certain limitations, when applied
without consideration of the potential sources of
error. Inaccurate answers can be derived from
neural networks which tend to be highly
misleading in research when used with little or no
caution.
While modelling the experiment in the MANN, the
flow chart above is used and four cases were
considered. The three inputs data were
soil temperature and atmospheric temperature
The first output is given as (
+ + . The second input is modelled
similarly which are used in generating the
respective values of a1, b1, c1 and d1
second output is thus given as
+ + . Third output is similarly
( ) = + + +
output is therefore the average of these values
given as as: = ( ( ) + ( ) +
Where Hi, Ii, Ji and Ki (i = 1, 2, 3, 4) are valid
inputs and output respectively, then the number
of cross overs could be determined from the
ranked output. The 2 cross over observed in the
model, means that the data could be modelled
using a polynomial of order 3 (i.e. a cubic
equation). In modelling therefore, the following
equations were used;
Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no.
3
approaches have been taken towards studying
the effects of corrosion on buried steel pipes,
however literature is sparse on the use of a
probabilistic methods coupled with a Modified
Artificial Neural network which provides the
flexibility [8], which
2.1 Modified Artificial Neural Networks
, Artificial Neural Networks
have been used tremendously in various fields of
industry and commerce. Their ability to “learn by
example” and to generalise this knowledge so as
to give correct predictions to previously unseen
ctive. Attempts
have been made constantly to apply this method
to corrosion prediction. Artificial Neural Networks
can learn the behaviour of materials in various
corrosive soil locations and predict their
Neural networks howbeit appealing
with certain limitations, when applied
without consideration of the potential sources of
error. Inaccurate answers can be derived from
neural networks which tend to be highly
misleading in research when used with little or no
While modelling the experiment in the MANN, the
flow chart above is used and four cases were
considered. The three inputs data were soil pH,
soil temperature and atmospheric temperature.
( ) = +
The second input is modelled
similarly which are used in generating the
c1 and d1. The
( ) = +
Third output is similarly
The final
output is therefore the average of these values
( )) / ).
= 1, 2, 3, 4) are valid
inputs and output respectively, then the number
of cross overs could be determined from the
ranked output. The 2 cross over observed in the
model, means that the data could be modelled
using a polynomial of order 3 (i.e. a cubic
uation). In modelling therefore, the following
If > , > 4, <
= ∗ + + +
= + +
= + +
= + +
Fig. 1. MANN flow chart
; Article no. ACRI.25564
(1)
(2)
+ (3)
+ (4)
+ (5)
flow chart
The equations (2) to (5) are employed for all
three input parameters (H, I, J) which is an
expanded version of Fig. 2 below.
Fig. 2. Least square matrix representation
2.2 Monte Carlo Simulation
Monte Carlo simulations MCS can be executed
using certain required entities, such as; input
distributions, relating equations and simplifying
assumptions;
The input distribution was derived from an
existing data [12]. While the relating equations
are derived from the matrix output of the MANN,
whose coefficients are however unique to each
scenario studied, but layout remains consistent
with the least square regression polynomial
equation.
The simplifying assumption made for this model
is that the measured input parameters are
assumed to be normally distributed about a
mean with a given standard deviation. The limit
of accuracy of this assumption was assessed as
shown in Figs. 4 and 5. It is observed that this
assumption of normalcy lies within acceptable
limits as there is little variance between plots
shown in the various value distributions.
chart below in Fig. 3 represents the functioning
of the Monte Carlo Simulation algor
The soil samples were taken from five locations
on the producing site namely; the tank farm,
skimmer pit, export pump area, saver pit and the
arrival manifold point designated as (location 1,
2, 3, 4 and 5 respectively.
3. RESULTS AND DISCUSSION
3.1 Simulating Experiment
The simulation experiment f was done using the
MATLAB R2012b software. Results were
obtained in the form of graphs (as depicted in
Figs. 6-11, and Table 1). The experiment was
Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no.
4
The equations (2) to (5) are employed for all
three input parameters (H, I, J) which is an
square matrix representation
can be executed
using certain required entities, such as; input
distributions, relating equations and simplifying
The input distribution was derived from an
While the relating equations
ved from the matrix output of the MANN,
whose coefficients are however unique to each
scenario studied, but layout remains consistent
with the least square regression polynomial
The simplifying assumption made for this model
is that the measured input parameters are
assumed to be normally distributed about a
mean with a given standard deviation. The limit
of accuracy of this assumption was assessed as
It is observed that this
assumption of normalcy lies within acceptable
limits as there is little variance between plots
shown in the various value distributions. The flow
chart below in Fig. 3 represents the functioning
ithm.
The soil samples were taken from five locations
on the producing site namely; the tank farm,
skimmer pit, export pump area, saver pit and the
arrival manifold point designated as (location 1,
3. RESULTS AND DISCUSSION
The simulation experiment f was done using the
MATLAB R2012b software. Results were
obtained in the form of graphs (as depicted in
11, and Table 1). The experiment was
executed on an HP envy dv4 laptop, 8 GB RAM,
750 GB HDD and an Intel® Core™ i5
@ 2.50 GHz. IBM SPSS is used to provide
descriptive statistics for the data source
(Table 1).
Fig. 3. MCS flow chart
3.2 Results
Based on the above described methodology, the
MANN-MCS algorithm provided the following
results described below. The input parameters
are sorted and normally distributed about a mean
at a standard deviation thus allowing for a less
complex computation of the expected value.
Little of no significant variation is noticed
; Article no. ACRI.25564
laptop, 8 GB RAM,
DD and an Intel® Core™ i5-3210 CPU
@ 2.50 GHz. IBM SPSS is used to provide
descriptive statistics for the data source
Fig. 3. MCS flow chart
Based on the above described methodology, the
MCS algorithm provided the following
results described below. The input parameters
are sorted and normally distributed about a mean
at a standard deviation thus allowing for a less
he expected value.
Little of no significant variation is noticed
between the different sample input distributions
however the sensitivity of this method captures
the slightest variation in its analysis, thus
providing different values for the relating
equations. A substantial amount of the results
Fig. 4. Empirical CDF normalcy assumption validation
Fig. 5. Normalcy assumption validation in different scenarios
Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no.
5
between the different sample input distributions
however the sensitivity of this method captures
the slightest variation in its analysis, thus
providing different values for the relating
tions. A substantial amount of the results
had negative values as the expected values
which mean a perceived increase in weight of
the steel (negation of weight loss). But this is in
agreement with the weight loss data used for this
analysis.
Empirical CDF normalcy assumption validation
Normalcy assumption validation in different scenarios
; Article no. ACRI.25564
had negative values as the expected values
which mean a perceived increase in weight of
the steel (negation of weight loss). But this is in
agreement with the weight loss data used for this
Table 1. Models’ input parameters statistical descri
N Minimum
SOIL_TEMP_NNEP 125 24.50
SOIL_TEMP_NEP 125 24.20
ATM_TEMP_NNEP 125 24.60
ATM_TEMP_NEP 125 24.60
SOIL_PH_NNEP 125 6.90
SOIL_PH_NEP 125 6.80
Valid N (listwise) 125
Fig. 6. Nickel electroplated sample input
distribution (Location 2)
Fig. 7. CDF plot for Nickel electroplated
sample. The estimated Corrosion Penetration
Rate value = -7.183714e-02 mm/yr (location 2)
It is observed that the CDF plots for the Non
Nickel electroplated samples are slanting at an
increasing rate which would further buttress the
fact that the CPR had values spread over a w
range than those of the Nickel electroplated
samples. Certain outliers however existed, for
the steel samples buried in location 3 (Export
Pump).For both the Nickel Electroplated sample
Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no.
6
Table 1. Models’ input parameters statistical description
Minimum Maximum Mean Std. deviation
24.50 29.00 26.1432 1.00083
24.20 29.00 26.0952 1.01337
24.60 31.80 27.4040 1.56918
24.60 31.80 27.4064 1.57120
8.30 7.7272 .29276
8.40 7.7384 .26237
electroplated sample input
distribution (Location 2)
electroplated
Corrosion Penetration
02 mm/yr (location 2)
It is observed that the CDF plots for the Non-
Nickel electroplated samples are slanting at an
increasing rate which would further buttress the
fact that the CPR had values spread over a wider
range than those of the Nickel electroplated
samples. Certain outliers however existed, for
the steel samples buried in location 3 (Export
Pump).For both the Nickel Electroplated sample
and Non-Nickel Electroplated samples, there
seems to be a deviation from the generally
observed trends in the CDF plots for Corrosion
Penetration Rate. This beviour can be likely
attributed to a build up of a stable oxide layer on
the steel surface which can slow down the rate of
corrosion.
Fig. 8. Non-Nickel electroplated sample
Input distribution at location 2
Fig. 9. CDF plot for Non-Nickel electroplated
sample. The estimated Corrosion Penetration
Rate value = 5.018641e-02 mm/yr at location 2
; Article no. ACRI.25564
Variance
1.002
1.027
2.462
2.469
.086
.069
Nickel Electroplated samples, there
on from the generally
observed trends in the CDF plots for Corrosion
This beviour can be likely
attributed to a build up of a stable oxide layer on
the steel surface which can slow down the rate of
electroplated sample
Input distribution at location 2
electroplated
Corrosion Penetration
02 mm/yr at location 2
Fig. 10. Comparism
Fig. 11. Plot of CPR for all samples (NEP vs NNEP)
4. CONCLUSION
In accordance with the aim of this paper, the
corrosion penetration rate of buried steel
samples was modelled using MANN
corrosion data (CPR calculations) obtained via
weight-loss method. These calculated CPR
values and specific location properties
inputs for the Modified artificial neural networks
which established a relationship between these
input parameters and the CPR. It provides a
coefficient matrix as its output. The network
made use of weights of unity value and scaling
factors that allowed for convergence of decimal
places, ranking, crossover determination,
rescaling then interpolating to regenerate the
polynomial coefficients necessary for the
Nosan and Bolaji.; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564
7
Comparism of CPR for both samples in location 2
Plot of CPR for all samples (NEP vs NNEP)
In accordance with the aim of this paper, the
corrosion penetration rate of buried steel
samples was modelled using MANN-MCS and
corrosion data (CPR calculations) obtained via
loss method. These calculated CPR
values and specific location properties serve as
inputs for the Modified artificial neural networks
which established a relationship between these
input parameters and the CPR. It provides a
coefficient matrix as its output. The network
made use of weights of unity value and scaling
t allowed for convergence of decimal
places, ranking, crossover determination,
rescaling then interpolating to regenerate the
polynomial coefficients necessary for the
generation of the outputs. This output is fed into
the MCS as its Relating equations for
execution of its probability. Using the NACE
SP0502-2010 standard [13], the 80
each plot is selected as the estimated corrosion
penetration rate.
A correlation was found to exis
model results and the results obtained from
experimental data. This model also validates
nickel electroplating as a means of corrosion
mitigation.
COMPETING INTERESTS
Authors have declared that no competing
interests exist.
; Article no. ACRI.25564
generation of the outputs. This output is fed into
the MCS as its Relating equations for the
execution of its probability. Using the NACE
2010 standard [13], the 80
th
percentile of
each plot is selected as the estimated corrosion
tbetween the
model results and the results obtained from
. This model also validates
nickel electroplating as a means of corrosion
Authors have declared that no competing
Nosan and Bolaji.; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564
8
REFERENCES
1. Syed S. Atmospheric corrosion of
materials. Emirates Journal for
Engineering Research. 2006;11(1):1-24.
2. Michael Baker Jr. Raymond R. Fessier.
Pipeline corrosion final report. U.S.
Department of Transportation, Pipeline
and Hazardous Materials Safety
Administration, Office of Pipeline Safety;
2008.
3. Petrucci et al. General chemistry: Principle
and modern application. 9
th
ed. Upper
Saddle River, N.J: Pearson Education.
2007;848.
4. Oyewole A. Characterization of external
induced corrosion degradation of Ajaokuta-
Abuja Gas Pipeline System, Nigeria.
International Journal of Engineering and
Technology. 2011;3(11):8061-8068.
5. Liew MS, Lim ES, Na KL, Mohid Sidek NF.
Parametric study of the factors of external
corrosion of pipelines in Malaysia. Recent
Advances in Engineering.
6. John F. Kiefner, Kolin M. Kolovich.
Calculation of corrosion rate using Monte
Carlo Simulation. NACE International
Corrosion Conference and Expo; 2007.
7. Chinedu I. Ossai. Pipeline corrosion and
reliability analysis: A systematic approach
with Monte Carlo Simulation and
degradation models. International Journal
of scientific & Technology Research. 2013;
2:3.
8. Adenigba E. Rotimi. Monte Carlo
Simulation of steady state heat transfer.
Department of Mechanical Engineering,
University of Ibadan; 2002.
9. Caleyo F, Velazquez JC, Valor A, Hallen
JM. Probability distribution of pitting
corrosion depths and rates in underground
pipelines: A Monte Carlo study. Corrosion
Science: The Journal on Environmental
Degradation of Materials and its Control;
2009.
10. Helliwell IS, Turega MA, Cottis RA. Neural
Networks for corrosion data reduction. The
NACE International Annual Conference
and Exposition; 1996.
11. Chukwuka G. Monyei, Aderemi O.
Adewumi, Michael O. Obolo. Oil well
characterization and artificial gas lift
optimization using neural networks
combined with genetic algorithm. Hindawi
Journal of Discrete Dynamics in Nature
and Society; 2014.
12. Oladipo Bolaji. External corrosion
characterization of buried Nickel plated
AISI 1015 steel pipes in Oil & Gas
environment, Unpublished BSc project,
Department of Mechanical Engineering,
University of Ibadan; 2014.
13. Standard Practice: Pipeline External
Corrosion Direct Assessment Methodology
(NACE SP0502-2010).
Available: www.nace.org
© 2016 Nosa and Bolaji; This is an Open Access article distributed under the terms of the Creative Commons Attribution
License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any
medium, provided the original work is properly cited.
Peer-review history:
The peer review history for this paper can be accessed here:
http://sciencedomain.org/review-history/14618

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Modelling Corrosion Rate Using MANN And MCS

  • 1. _____________________________________________________________________________________________________ *Corresponding author: Email: nosaidus@gmail.com; Archives of Current Research International 4(2): 1-8, 2016, Article no.ACRI.25564 ISSN: 2454-7077 SCIENCEDOMAIN international www.sciencedomain.org Modelling the Corrosion Rate of Buried Pipes Using Modified Artificial Neural Network (MANN) Coupled with Monte Carlo Simulation Idusuyi Nosa1,2* and Adesoji Bolaji1 1 Department of Mechanical Engineering, University of Ibadan, Nigeria. 2 Centre for Nano Materials Science Research, University of Johannesburg, South Africa. Authors’ contributions This work was carried out in collaboration between both authors. Both authors designed the study, implemented and wrote the manuscript. The first author wrote the final draft of the manuscript and managed correspondence. Both authors read and approved the final manuscript. Article Information DOI:10.9734/ACRI/2016/25564 Editor(s): (1) R. M. Chandima Ratnayake, Department of Mechanical and Structural Engineering and Materials Science, University of Stavanger, Norway. Reviewers: (1) Makanjuola Oki, Landmark University, Nigeria. (2) Rajinder Tiwari, Amity University, India. (3) Siva Prasad Kondapalli, Anil Neerukonda Institute of Technology & Sciences, India. Complete Peer review History: http://sciencedomain.org/review-history/14618 Received 9 th March 2016 Accepted 4 th May 2016 Published 13 th May 2016 ABSTRACT Several researchers have developed models to predict corrosion rate in buried structures with good results using methods such as artificial neural networks, Monte Carlo to mention a few. This paper presents a novel approach to predicting corrosion rate in buried structures using Monte Carlo and a modified artificial neural network (MANN). Monte Carlo Simulation is used in this paper to estimate the probability of occurrence of uniform corrosion in buried steel pipes in different soil locations using the fixed walk method. The central limit theory and law of large numbers were utilised to reduce errors. While Modified Artificial Neural Networks was used to establish the relationships. Data used for this study were obtained from weight loss study of Nickel electroplated and non electroplatedAISI-1051 samples. The parameters measured were soil pH, soil temperature and atmospheric temperature of different soils taken from an oil producing site in Delta State, Nigeria. These parameters were assumed normally distributed. Corrosion Penetration Rate (CPR) was calculated for each scenario using the weight loss method. Relating these input Original Research Article
  • 2. Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564 2 parameters to the calculated CPR was possible via the employment of Modified Artificial Neural Networks, which makes use of the least square polynomial regression equations instead of the neuron box to avoid complexities in neuron number determination. Weights and Scaling factors were set appropriately to allow for easy convergence. Third degree polynomial equations were derived from the MANN and used as inputs for the MCS. Results from the MCS showed 80% correlation with data used and a reliable estimate for the CPR was achieved using this MCS- MANN approach. The CPR of the Nickel Electroplated Sample was less than zero which was in good agreement with the weight loss data. It is observed that the CPR values for Non-electroplated samples were 60% of the time higher than the values for electroplated samples. Keywords: Uniform corrosion; Monte Carlo; artificial neural networks; steel pipes. 1. INTRODUCTION The word Corrosion is derived from the Latin corrosus which means eaten away or consumed by degrees; an unpleasant word for an unpleasant process [1]. Corrosion is a spontaneous chemical reaction and is defined by the NACE as “The deterioration of a material, usually a metal, which results from a reaction with its environment” [2]. When corrosion occurs, these alloys are returned back to their natural states (ores). Corrosion cannot be totally eliminated so researchers have devised various programs to minimise corrosion growth rate, these include Cathodic Protection, Protective Coatings and Inhibitors. Pipelines play an extremely important role throughout the world as a means of transporting gases and liquids over long distances from their sources to the ultimate consumers but are subject to corrosion which causes it to disintegrate and weaken [3] incurring huge consequences. Three different categories of consequences for corrosion failure have been identified as; safety, environmental and business/economic consequences [4]. Parametric and non- parametric models have been developed to predict the corrosion rate of pipelines. The General linear model [5] which established the baseline of external corrosion to be 2.65 mm/ lifespan for a 20 year design life, which is similar to the recommended values of PETRONAS Technical Standard of 3 mm/lifespan. Other attempts to estimate the corrosion rate for calculating re-assessment intervals using Monte Carlo method by considering the operating history of the pipeline and any knowledge of its condition such as prior in-line inspections or direct observations of corroded areas on the pipeline have also been made [6]. Monte Carlo simulation and degradation models have also been used to predict pipeline corrosion rates and also to establish the reliability of pipelines over a period of time [7]. The proposed methodology was fed and tested with field data acquired from 11 onshore O&G fields. Discrete random numbers were generated from historic data, yearly corrosion rate was estimated using Brownian random walk, Corrosion wastage were predicted (with linear and power models) and Mean Time For Failure (MTFF) of the pipelines were estimated during the course of the study. The conclusion of the author was that both the Monte Carlo Simulation and the degradation models can reasonably predict the pipeline corrosion rate. However the level of complexity can serve as a medium for distinguishing Monte Carlo Methods; such as simple MCS and complex MCS [8]. A simple MCS is derived when the physical situation is stochastic in nature i.e. it involves probabilities such as transport of metal particles through material medium. While a complex MCS is derived when the physical situation is not stochastic. The probability distributions of external corrosion, pit depth and pit growth rate were investigated in underground pipelines using Monte Carlo simulations by Caleyo and his co-workers [9]. The study combined a predictive pit growth model developed by the authors with the observed distributions of the model variables in a range of soils. It is pertinent to note that any of the three maximal extreme value distributions, i.e. Weibull, Fréchet or Gumbel, can arise as the best fit to the pitting depth and rate data depending on the pipeline age. The consequence of corrosion has led many companies to enact measures to periodically assess their pipelines. Such assessments are often costly to execute annually, thus measures are taken to ensure they are carried out at intervals sufficiently short to prevent leaks or ruptures from metal loss on pipelines. Several
  • 3. approaches have been taken towards studying the effects of corrosion on buried steel pipes, however literature is sparse on the use of a probabilistic methods coupled with a Modified Artificial Neural network which provides the needed speed, accuracy and flexibility [8], which is the focus of this study. 2. METHODOLOGY 2.1 Modified Artificial Neural Networks From literature [10,11], Artificial Neural Networks have been used tremendously in various fields of industry and commerce. Their ability to “learn by example” and to generalise this knowledge so as to give correct predictions to previously unseen data makes them extremely attractive. Attempts have been made constantly to apply this method to corrosion prediction. Artificial Neural Networks can learn the behaviour of materials in various corrosive soil locations and predict their behaviour. Neural networks howbeit appealing exist with certain limitations, when applied without consideration of the potential sources of error. Inaccurate answers can be derived from neural networks which tend to be highly misleading in research when used with little or no caution. While modelling the experiment in the MANN, the flow chart above is used and four cases were considered. The three inputs data were soil temperature and atmospheric temperature The first output is given as ( + + . The second input is modelled similarly which are used in generating the respective values of a1, b1, c1 and d1 second output is thus given as + + . Third output is similarly ( ) = + + + output is therefore the average of these values given as as: = ( ( ) + ( ) + Where Hi, Ii, Ji and Ki (i = 1, 2, 3, 4) are valid inputs and output respectively, then the number of cross overs could be determined from the ranked output. The 2 cross over observed in the model, means that the data could be modelled using a polynomial of order 3 (i.e. a cubic equation). In modelling therefore, the following equations were used; Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. 3 approaches have been taken towards studying the effects of corrosion on buried steel pipes, however literature is sparse on the use of a probabilistic methods coupled with a Modified Artificial Neural network which provides the flexibility [8], which 2.1 Modified Artificial Neural Networks , Artificial Neural Networks have been used tremendously in various fields of industry and commerce. Their ability to “learn by example” and to generalise this knowledge so as to give correct predictions to previously unseen ctive. Attempts have been made constantly to apply this method to corrosion prediction. Artificial Neural Networks can learn the behaviour of materials in various corrosive soil locations and predict their Neural networks howbeit appealing with certain limitations, when applied without consideration of the potential sources of error. Inaccurate answers can be derived from neural networks which tend to be highly misleading in research when used with little or no While modelling the experiment in the MANN, the flow chart above is used and four cases were considered. The three inputs data were soil pH, soil temperature and atmospheric temperature. ( ) = + The second input is modelled similarly which are used in generating the c1 and d1. The ( ) = + Third output is similarly The final output is therefore the average of these values ( )) / ). = 1, 2, 3, 4) are valid inputs and output respectively, then the number of cross overs could be determined from the ranked output. The 2 cross over observed in the model, means that the data could be modelled using a polynomial of order 3 (i.e. a cubic uation). In modelling therefore, the following If > , > 4, < = ∗ + + + = + + = + + = + + Fig. 1. MANN flow chart ; Article no. ACRI.25564 (1) (2) + (3) + (4) + (5) flow chart
  • 4. The equations (2) to (5) are employed for all three input parameters (H, I, J) which is an expanded version of Fig. 2 below. Fig. 2. Least square matrix representation 2.2 Monte Carlo Simulation Monte Carlo simulations MCS can be executed using certain required entities, such as; input distributions, relating equations and simplifying assumptions; The input distribution was derived from an existing data [12]. While the relating equations are derived from the matrix output of the MANN, whose coefficients are however unique to each scenario studied, but layout remains consistent with the least square regression polynomial equation. The simplifying assumption made for this model is that the measured input parameters are assumed to be normally distributed about a mean with a given standard deviation. The limit of accuracy of this assumption was assessed as shown in Figs. 4 and 5. It is observed that this assumption of normalcy lies within acceptable limits as there is little variance between plots shown in the various value distributions. chart below in Fig. 3 represents the functioning of the Monte Carlo Simulation algor The soil samples were taken from five locations on the producing site namely; the tank farm, skimmer pit, export pump area, saver pit and the arrival manifold point designated as (location 1, 2, 3, 4 and 5 respectively. 3. RESULTS AND DISCUSSION 3.1 Simulating Experiment The simulation experiment f was done using the MATLAB R2012b software. Results were obtained in the form of graphs (as depicted in Figs. 6-11, and Table 1). The experiment was Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. 4 The equations (2) to (5) are employed for all three input parameters (H, I, J) which is an square matrix representation can be executed using certain required entities, such as; input distributions, relating equations and simplifying The input distribution was derived from an While the relating equations ved from the matrix output of the MANN, whose coefficients are however unique to each scenario studied, but layout remains consistent with the least square regression polynomial The simplifying assumption made for this model is that the measured input parameters are assumed to be normally distributed about a mean with a given standard deviation. The limit of accuracy of this assumption was assessed as It is observed that this assumption of normalcy lies within acceptable limits as there is little variance between plots shown in the various value distributions. The flow chart below in Fig. 3 represents the functioning ithm. The soil samples were taken from five locations on the producing site namely; the tank farm, skimmer pit, export pump area, saver pit and the arrival manifold point designated as (location 1, 3. RESULTS AND DISCUSSION The simulation experiment f was done using the MATLAB R2012b software. Results were obtained in the form of graphs (as depicted in 11, and Table 1). The experiment was executed on an HP envy dv4 laptop, 8 GB RAM, 750 GB HDD and an Intel® Core™ i5 @ 2.50 GHz. IBM SPSS is used to provide descriptive statistics for the data source (Table 1). Fig. 3. MCS flow chart 3.2 Results Based on the above described methodology, the MANN-MCS algorithm provided the following results described below. The input parameters are sorted and normally distributed about a mean at a standard deviation thus allowing for a less complex computation of the expected value. Little of no significant variation is noticed ; Article no. ACRI.25564 laptop, 8 GB RAM, DD and an Intel® Core™ i5-3210 CPU @ 2.50 GHz. IBM SPSS is used to provide descriptive statistics for the data source Fig. 3. MCS flow chart Based on the above described methodology, the MCS algorithm provided the following results described below. The input parameters are sorted and normally distributed about a mean at a standard deviation thus allowing for a less he expected value. Little of no significant variation is noticed
  • 5. between the different sample input distributions however the sensitivity of this method captures the slightest variation in its analysis, thus providing different values for the relating equations. A substantial amount of the results Fig. 4. Empirical CDF normalcy assumption validation Fig. 5. Normalcy assumption validation in different scenarios Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. 5 between the different sample input distributions however the sensitivity of this method captures the slightest variation in its analysis, thus providing different values for the relating tions. A substantial amount of the results had negative values as the expected values which mean a perceived increase in weight of the steel (negation of weight loss). But this is in agreement with the weight loss data used for this analysis. Empirical CDF normalcy assumption validation Normalcy assumption validation in different scenarios ; Article no. ACRI.25564 had negative values as the expected values which mean a perceived increase in weight of the steel (negation of weight loss). But this is in agreement with the weight loss data used for this
  • 6. Table 1. Models’ input parameters statistical descri N Minimum SOIL_TEMP_NNEP 125 24.50 SOIL_TEMP_NEP 125 24.20 ATM_TEMP_NNEP 125 24.60 ATM_TEMP_NEP 125 24.60 SOIL_PH_NNEP 125 6.90 SOIL_PH_NEP 125 6.80 Valid N (listwise) 125 Fig. 6. Nickel electroplated sample input distribution (Location 2) Fig. 7. CDF plot for Nickel electroplated sample. The estimated Corrosion Penetration Rate value = -7.183714e-02 mm/yr (location 2) It is observed that the CDF plots for the Non Nickel electroplated samples are slanting at an increasing rate which would further buttress the fact that the CPR had values spread over a w range than those of the Nickel electroplated samples. Certain outliers however existed, for the steel samples buried in location 3 (Export Pump).For both the Nickel Electroplated sample Nosa and Bolaji; ACRI, 4(2): 1-8, 2016; Article no. 6 Table 1. Models’ input parameters statistical description Minimum Maximum Mean Std. deviation 24.50 29.00 26.1432 1.00083 24.20 29.00 26.0952 1.01337 24.60 31.80 27.4040 1.56918 24.60 31.80 27.4064 1.57120 8.30 7.7272 .29276 8.40 7.7384 .26237 electroplated sample input distribution (Location 2) electroplated Corrosion Penetration 02 mm/yr (location 2) It is observed that the CDF plots for the Non- Nickel electroplated samples are slanting at an increasing rate which would further buttress the fact that the CPR had values spread over a wider range than those of the Nickel electroplated samples. Certain outliers however existed, for the steel samples buried in location 3 (Export Pump).For both the Nickel Electroplated sample and Non-Nickel Electroplated samples, there seems to be a deviation from the generally observed trends in the CDF plots for Corrosion Penetration Rate. This beviour can be likely attributed to a build up of a stable oxide layer on the steel surface which can slow down the rate of corrosion. Fig. 8. Non-Nickel electroplated sample Input distribution at location 2 Fig. 9. CDF plot for Non-Nickel electroplated sample. The estimated Corrosion Penetration Rate value = 5.018641e-02 mm/yr at location 2 ; Article no. ACRI.25564 Variance 1.002 1.027 2.462 2.469 .086 .069 Nickel Electroplated samples, there on from the generally observed trends in the CDF plots for Corrosion This beviour can be likely attributed to a build up of a stable oxide layer on the steel surface which can slow down the rate of electroplated sample Input distribution at location 2 electroplated Corrosion Penetration 02 mm/yr at location 2
  • 7. Fig. 10. Comparism Fig. 11. Plot of CPR for all samples (NEP vs NNEP) 4. CONCLUSION In accordance with the aim of this paper, the corrosion penetration rate of buried steel samples was modelled using MANN corrosion data (CPR calculations) obtained via weight-loss method. These calculated CPR values and specific location properties inputs for the Modified artificial neural networks which established a relationship between these input parameters and the CPR. It provides a coefficient matrix as its output. The network made use of weights of unity value and scaling factors that allowed for convergence of decimal places, ranking, crossover determination, rescaling then interpolating to regenerate the polynomial coefficients necessary for the Nosan and Bolaji.; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564 7 Comparism of CPR for both samples in location 2 Plot of CPR for all samples (NEP vs NNEP) In accordance with the aim of this paper, the corrosion penetration rate of buried steel samples was modelled using MANN-MCS and corrosion data (CPR calculations) obtained via loss method. These calculated CPR values and specific location properties serve as inputs for the Modified artificial neural networks which established a relationship between these input parameters and the CPR. It provides a coefficient matrix as its output. The network made use of weights of unity value and scaling t allowed for convergence of decimal places, ranking, crossover determination, rescaling then interpolating to regenerate the polynomial coefficients necessary for the generation of the outputs. This output is fed into the MCS as its Relating equations for execution of its probability. Using the NACE SP0502-2010 standard [13], the 80 each plot is selected as the estimated corrosion penetration rate. A correlation was found to exis model results and the results obtained from experimental data. This model also validates nickel electroplating as a means of corrosion mitigation. COMPETING INTERESTS Authors have declared that no competing interests exist. ; Article no. ACRI.25564 generation of the outputs. This output is fed into the MCS as its Relating equations for the execution of its probability. Using the NACE 2010 standard [13], the 80 th percentile of each plot is selected as the estimated corrosion tbetween the model results and the results obtained from . This model also validates nickel electroplating as a means of corrosion Authors have declared that no competing
  • 8. Nosan and Bolaji.; ACRI, 4(2): 1-8, 2016; Article no. ACRI.25564 8 REFERENCES 1. Syed S. Atmospheric corrosion of materials. Emirates Journal for Engineering Research. 2006;11(1):1-24. 2. Michael Baker Jr. Raymond R. Fessier. Pipeline corrosion final report. U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, Office of Pipeline Safety; 2008. 3. Petrucci et al. General chemistry: Principle and modern application. 9 th ed. Upper Saddle River, N.J: Pearson Education. 2007;848. 4. Oyewole A. Characterization of external induced corrosion degradation of Ajaokuta- Abuja Gas Pipeline System, Nigeria. International Journal of Engineering and Technology. 2011;3(11):8061-8068. 5. Liew MS, Lim ES, Na KL, Mohid Sidek NF. Parametric study of the factors of external corrosion of pipelines in Malaysia. Recent Advances in Engineering. 6. John F. Kiefner, Kolin M. Kolovich. Calculation of corrosion rate using Monte Carlo Simulation. NACE International Corrosion Conference and Expo; 2007. 7. Chinedu I. Ossai. Pipeline corrosion and reliability analysis: A systematic approach with Monte Carlo Simulation and degradation models. International Journal of scientific & Technology Research. 2013; 2:3. 8. Adenigba E. Rotimi. Monte Carlo Simulation of steady state heat transfer. Department of Mechanical Engineering, University of Ibadan; 2002. 9. Caleyo F, Velazquez JC, Valor A, Hallen JM. Probability distribution of pitting corrosion depths and rates in underground pipelines: A Monte Carlo study. Corrosion Science: The Journal on Environmental Degradation of Materials and its Control; 2009. 10. Helliwell IS, Turega MA, Cottis RA. Neural Networks for corrosion data reduction. The NACE International Annual Conference and Exposition; 1996. 11. Chukwuka G. Monyei, Aderemi O. Adewumi, Michael O. Obolo. Oil well characterization and artificial gas lift optimization using neural networks combined with genetic algorithm. Hindawi Journal of Discrete Dynamics in Nature and Society; 2014. 12. Oladipo Bolaji. External corrosion characterization of buried Nickel plated AISI 1015 steel pipes in Oil & Gas environment, Unpublished BSc project, Department of Mechanical Engineering, University of Ibadan; 2014. 13. Standard Practice: Pipeline External Corrosion Direct Assessment Methodology (NACE SP0502-2010). Available: www.nace.org © 2016 Nosa and Bolaji; This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Peer-review history: The peer review history for this paper can be accessed here: http://sciencedomain.org/review-history/14618