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I G. WENTEN
 Faculty Member, Chemical Engineering Deparment – ITB
 Head, DSP Biotech Lab, Inter University Research center, ITB
 Postdoctoral Researcher, Unesco Center on Membrane, UNSW, Australia, 1995
 Expert Staf, X-Flow B.V., The Netherlands, 1993-1994
 Researcher, Bioseparation Research Center, RPI, New York, USA, 1991
 Internatonal Expert, Institute of Hydrogen Economy, UTM, Malaysia
 R&D Supervisor, Shanghai Megavision Membrane, China
 Senior International Supervisor, Guangdong Jin Gang New Material Co. Ltd., China
 Peneliti Utama, di hampir semua program riset nasional di Indonesia
 Plenary, Keynote, dan Invited Speaker, Invited Lecturer, Conterence Chairman, lebih dari 100 events
 Publikasi ilmiah, lebih dari 200 makalah national dan internasional
 Gugus Tugas HKI (hak atas kekayaan intelektual) ITB, KemenRistek, dan Dikti
 Editorial dan Advisory Board, beberapa Institusi Keilmuan dan Jurnal Ilmiah
 Tenaga Ahli, Team Ahli, Supervisor, dan Konsultan, beberapa Perusahaan dan Institusi di Indonesia
 Pendiri, Asean Association on Membrane dan GDPFilter Indonesia
AWARDS AND ACHIEVEMENTS
 GRANTED PATENTS, 15 Paten Nasional dan Internasional
 KARYA UNGGULAN TEKNOLOGI ANAK BANGSA, KemenRistek, Hakteknas 2014
 BJ. HABIBIE TECHNOLOGY AWARD, BPPT, 2013
 GOLD MEDAL-GANESHA INNOVATION AWARD, IA-ITB, 2013
 SOEGENG SARJADI AWARD, SSSG, 2012
 ASEAN OUTSTANDING ENGINEERING AWARD, AFEO, 2010
 ADHICIPTA REKAYASA-EMAS, PII (Persatuan Insinyur Indonesia), 2009
 COMPETENCY AWARD, Badan Nasional Sertifikasi Profesi, Indonesia, 2009
 ANUGERAH RISET UNGGULAN TERPADU, KemenRistek, 2004
 WIPO AWARD (BEST INVENTOR), WIPO-UNDP, 2002
 HABIBIE AWARD, Habibie Center, 2000
 PENELITI MUDA INDONESIA, LIPI (Lembaga Ilmu Pengetahuan Indonesia), 1996
 SCIENCE AND TECHNOLOGY AWARD, Toray Science Foundation, 1996
 ADHICIPTA REKAYASA, PII (Persatuan Insinyur Indonesia), 1995
 SUTTLE AWARD, Filtration Society, London, 1994
 ALUMNI TERBAIK ITB-82, 2002, Penghargaan yang paling dibanggakan
THE BACKSHOCK PROCESS
CONDUCTIVE ELECTRODIALYSIS
Patent Indonesia P00201000408
NO MORE MODULARITY IN MEMBRANE
ULTRAFILTRATION: Non-Modular System
MODULAR
VS
NON-MODULAR
FUTURE COMMUNITY WATER SOLUTION
ACEH TSUNAMI RELIEF
IGW EMERGENCY MEMBRANE
Capacity : 500 LPH, Weight : 30 kg
Activated carbon
Reduce unpleasant odors, organic matter and rsidual
chlorine
Hollow fine fiber Membrane
The core competence of this unit. Ultrafiltration
membrane can remove almost 100% of colloids,
bacteria, viruses and all of particulate matters
reponsible for turbidity .
Bioceramic
Alkalinity agent and enhancing anti oxidant quality of
drinking water. It also enhances freshness of drinking
water
Single module that integrate three stages of
filtration
RAIN WATER HARVESTING
EMPOWERING SMALL SCALE BUSNISSES
 PATHOGENIC REMOVAL IN HATCHERY
 VEGETABLE OIL CLARIFICATION
 LUBE OIL RE-USE
 GELATIN CLARIFICATION
 COCONUT JUICE ULTRAFILTRATION
 PALM SUGAR CONCENTRATION
UF 30,000 Da
 Hatchery
 Grow-out
Membrane Based Recirculation System
for Sustainable Aquaculture
IMPLANTED ENDS-FREE MBR
National Standard of
Aquaculture Recirculation Technology
Umpan
NON-MODULAR UF FOR MICROALGAE HARVESTING (Nanochlorophyl)
 Penumbuhan dan pemanenan dalam satu alat terintegrasi
 Tidak membutuhkan tempat yang luas
 Mampu meningkatkan densitas mikroalga dalam reaktor
 Tidak membutuhkan energi yang besar
HIGH DENSITY ALGAE MEMBRANE REACTOR USING MEMBRANE DIFUSER
 Solusi Holistik untuk produksi etanol secara berkelanjutan
 Etanol yang dihasilkan memiliki konsentrasi cukup tinggi
 Rasa bir tetap terjaga
NON-POROUS MD FOR BEER DEALCOHOLIZATION
IGW
PV TECHNOLOGY FOR FUEL GRADE ALCOHOLBIOTECHNOLOGY
CANE SUGAR JUICE CLARIFICATION
SUGARINDUSTRYIGW
CANE SUGAR JUICE BEVERAGE
SUGARINDUSTRYIGW
EMPOWERING PALM SUGAR BUSNISSES
High Quality
DRINKING WATER
Membrane Concentrator
ULTRAFILTRATION OF COCONUT WATER
CLEAN PRODUCTION IN STARCH INDUSTRY
GELATIN CLARIFICATION
Feed Product
Membrane Fabrication – Melt SpinningMEMBRANEFABRICATIONIGW
Cooling tower
Process streams
requiring cooling
Cooling water
recirculation
(QR)
Tower packing
Heat exchanger
Blowdown water
Evaporation loss
1% QR per
5.6oC T drop
Windage
loss (mist)
0.2% QR
Heat Transfer
PLANT
HEAT TRANSFER
Heat exchanger
Hollow Fiber Cooling Tower
HEAT DISSIPATION VIA
EVAPORATION
Blowdown
High salt conc.
Make-up
cooling water
Soft water
Make-up
boiler feed
water
Preheater
BOILER
Vapor
Membrane
pore
Cooling
water
Condensate
Hollow fiber
Hollow fiber
Stagnant
air
HOLLOW FIBER COOLING TOWER
M
T
Hollowfibermodule
TR
WB
NaCl solution
M
T
TR
DW
M
T
WB
DW DW
M
T
Over-flow
Measuring
cylinder
Feed
pump
Permeate
pump
Needle
valve
Needle
valve
Adjustable
DC power
supply
VEGETABLE OIL FILTRATION
Virgin Coconut Oil Clarification
SIMULTANEOUS CLARIFICATION AND DEGUMMING OF
JATHROPA OIL
JATHROPAOILIGW
CONVENTIONAL
CLARIFICATION
ACID DEGUMMING
H3PO4
Oil
Particles, dirt, gum
Clarified, de-
gummed oil
ONE STEP CLARIFICATION AND DEGUMMING PROCESS
•Vibrating
screen
•Clarifier
•Purifier
NATURAL PALM KERNEL FRYING OIL
• 1 Step clarification process
• No chemical consumption
• Environmentally friendly process
Clarified PKO
Feed
(Crude PKO)
Permeate
(Clarified PKO)
Retentate
PALMOILINDUSTRYIGW
WORLD LARGEST CERAMIC MEMBRANE BIOREACTOR
Spider web
harvesting system
COOKING
TANK
MEMBRANE
EXTRACTION
Purified CPO
A NOVEL CONCEPT
ZERO SLUDGE PALM OIL MILLING PLANT
FEED PRODUCT
GAS SEPARATOR
IGW ‘08
CO2 Removal
Wet-Free Membrane Contactor
Patent App. P00200900263
CO2 Removal
Wet-Free Membrane Contactor
Patent App. P00200900263
KONTAKTOR MEMBRAN
Tipe: non-wetted Tipe: wetted
Regenerasi
absorben
secara in situ

menghilangkan
aliran sirkulasi
yang sangat
besar
I G. Wenten
Teknik Kimia - ITB, Indonesia
INDONESIA
MEMBRANE TREATING PRODUCED
WATER FOR REINJECTION
FULL SCALE OF UF MEMBRANE SYSTEM
(INDONESIA) CAPACITY 33.000 BWPD
[Argonne National Laboratory]
PRODUCED WATER TREATMENT PLANT
Ultrafiltration Unit Incinerator Unit Chemical Injection Unit
Deaerator
PRODUCED WATER TREATMENT PLANT (INDONESIA)
c
COMPARISON OF BASELINE FLUXES
FOR THE THREE DIFFERENT MEMBRANES
Mueller, et al, 1997
Op. cond.: 10 psig TMP, 250 ppm heavy oil, 40°C, and 0.24 ms -1
SCALE FORMATION
Main culprits: CaCO3 and (rarely) SiO2
Causes drop in product water quality
In severe cases causes drop in concentrate flow
(increase in pressure drop)
Need to analyze feed and concentrate for
hardness or silica
(mass balance calculation)
Scale control
• Pre-treatment
• Chemicals
• Concentration factor
FLUX ENHANCEMENT
HYDRODYNAMIC
Backwash
Turbulence
promoters
Other
methods
Modifying
membrane/confi
guration
Module
modification
Concentration
control
Novel
modification
CIP
(Clean-In-Place)
Chemical
addition
Chemical
cleaning
Chemical
sanitizer
OTHER FLUX ENHANCEMENT METHODS
Electrical Methods
Used for fouling due to charge interactions between charged solutes and the
membrane
An electric field can be applied to the flowing fluid, with one electrode being
cast on or placed against the membrane, and the other electrode within the
liquid, but away from the membrane surface
Intermittent Jets
Unsteady flows and large vortices can be generated with an intermittent jet of
the feed pumped through a nozzle placed coaxially in a membrane tube causes
the velocity of the feed to abruptly increase and then decrease resulting higher
flux.
Pulsatile Flow
Pulsations in the feed or permeate channels obtained with pistons
MEMBRANE CLEANING
Foulant Reagent Time &Temperature Mode of Action
Fats, oils, proteins,
polysaccharides, bacteria,
0.5N NaOH with 200 ppm
Cl2
30 - 60 min
25 – 55oC
Hydrolysis and oxidation
DNA, mineral salts
0.1 – 0.5M acid (acetic,
citric, nitric)
30 - 60 min
25 – 55oC
Solubilization
Fats, oils, biopolymers,
proteins
0.1%SDS; 0.1% Triton X-
100;
30 min-overnight
25 – 55oC
Wetting, emulsifying,
suspending, dispersing
Cell fragments, fats, oils,
proteins
Enzyme, detergent
30 min-overnight
30 – 40oC
Catalytic breakdown
(proteolysis)
DNA 0.5% DNAase
30 min-overnight
30 – 40oC
Enzyme hydrolysis
Fats, oils, and grease 20-50% ethanol
30 - 60 min
25 – 55oC
Solubilization
Membranes have to cleaned typically when:
- Normalized Permeate flow varies by 10-15%
- Normalized Feed pressure varies by 10-15%
- Normalized Permeate conductivity varies by 10-15%
- Pressure drop between feed and concentrate varies by 10-15%
CLEANING PARAMETERS
Membrane materials and chemistry
• This determines a membrane's ability to withstand the action of the chemical cleaners
Fluid mechanics
• should be pumped through the system under turbulent flow conditions
• the pressures should be as low as possible, but consistent with the dP required to maintain high flow
rates
Time
• most chemical cleaners complete their action within 30-60 min. Prolonged cleaning after the
optimum time may actually cause refouling of the membrane due to the filtration effect
Temperature
• the temperature of the cleaning solution should be as high as possible, consistent with temperature
limitations of the membrane/module
Water quality
• soft water should be used.
pH
• Alkaline cleaners containing NaOH or KOH are particularly effective for organics and proteins
• Acidic cleaners are primarily used to combat inorganic salt fouling
FUTURE DIRECTION
•Dialysis
•Pervaporation
•Gas Separation
•MBR
•RO
•NF
•UF
•MF
RO application •MBR
Module HF Tubular SW Flat
Manufacturing cost (4USD/m2) 5-20 50-200 30-100 100-300
Packing density High Low Moderate Low
Resistance to fouling Very poor Very good Moderate Good
Parasitic pressure drop High Low Moderate Moderate
High pressure operation yes difficult yes Difficult
Fiber Backing
120 um
Polysulfone
50 um
Active Layer
100 nm
RO/NF PORE STRUCTURE
61
Challenges
and limitations
Low
permeation
flux
Inadequate
permselectivity
Inadequate
membrane
durability
Membrane
fouling
High
equipement
or operating
costs
MEMBRANE CHALLENGES AND LIMITATIONS
Michaels, Desalination, 77 (1990) 5-34.
62
Large scale plant
Space
requirement
Numbers of
component
used
(complexity)
Large brine
disposal
LARGE SCALE CHALLENGES
63
INTENSIFICATION IN LARGE SCALE
MEMBRANE BASED DESALINATION PLANT
• I G. Wenten
• Teknik Kimia-ITB, igwenten@gmail.com
1 Hydrogen Membrane for Syngas mixture Fed into Pd-Ag Mreactor
2 Membrane Crystallization For Selective Polymorph Crystallization
3.Latest Development of Polymer Electrolyte Membrane FC (PEMFC)
4 Aroma Recovery by Pervaporation
5 Membrane Crystallizer of Nanofiltration Brine Solution
6 Modified PEEK Membrane With Honey Comb Structure
7. Mega Magnum System
8. Membrane Osmotic Distillation
9. Reverse Osmosis Energy Recovery Device
10. Carbon Nanotube Membrane
11. Forward Osmosis Membrane Bioreactor
12. Fullerenes Prevent Biofouling in Membrane Microfiltration
13. Membrane Distillation Bioreactor
14. Integrated Membrane for Desalination
15. Inland Desalination
16. Membrane Sensor
17. Nanostructured Asymmetric Membrane
18. Boron Removal With SWRO
19. Well Defined Shape and Size Crystal with Membrane Crystallizer
20. Incorporating Amino Group in Polymeric network for composite
21. Aquaporin Membrane
22. Nanofiltration as Reverse Osmosis Pretreatment
23. Forward Osmosis (FO)
24. Air Separation At High Temperature
25. Membrane For Artificial Organs
26. Membrane Biohybrid System Using Hepatocytes
27. Latest Development In Enzymatic Membrane Reactor
28. Membrane in Tissue Engineering
29. Membrane Emulsifier
30. Recent Advances in Bipolar Membrane
31. Non Modular Membrane System
32. Super Hydrophobic Membrane
65
ENERGY GENERATION FROM BRINE DISPOSAL
RO-PRO
RO-RED
66
MEMBRANE DISTILLATION
Al-Obaidani et al., Journal of Membrane Science 323 (2008) 85–98
Feed
H2O
Permeate
H2O
Liquid
water
Air/vapour
Liquid
water
Hydrophobic
porous membrane
T1 > T2
T1 T2
67
ELECTRODEIONIZATION
Largest Continuous Electrodeionization Plant in Con Edison’s East
River Repowering Project, New York. Capacity 1,530 m3/day
CEDI Units
Final treatment using Continuous
electrodeionization
RO Units
Contain 2 pass reverse osmosis unit
Filter Units
Anti Scalant injection
Raw water tank Cooling HE
Polymeric Coagulant
Multi Media Filters
Antiscalant
Cartridge Filters
Sodium Bisulfite
Reverse Osmosis Electrodeionization Silos
68
BIOMIMETIC AQUAPORIN MEMBRANE
69
CAPACITIVE DEIONIZATION & MEMBRANE CAPACITIVE DEIONIZATION
Capacitive deionization (CDI)
Membrane capcitive deionization (MCDI)
www.voltea.com
MBR FOR WATER RECLAMATION
SUBMERGED HOLLOW FIBER MBR
AERATION-MBR
EXTRACTIVE-MBR
IODINE RECOVERY FROM PRODUCED WATER
Concentrating iodide in the brine
Pei Xu, Jörg E. Drewes, Dean
Heil ; Desalination 225, (2008)
Water quality of produced water extracted from a natural gas production site
(natural gas production site in Eastern Montana)
Iodide concentration in brine after membrane treatment
Ozone oxidation of produced water using ceramic membrane diffuser
P
Separator
Pressure Gauge
Flue gas
CeramicMembraneDiffuser
SampleMembraneAirFilter
Ozone Generator
Pump
Globe valve
Needle valve
Needle valve
Compressor
BTEX
solution
76
WASTE BRINE RECYCLE PROJECT
Producued water Softening Reinjection
Ion exchange (softener) regeneration
Salt consumption: 90 ton/day
Waste brine disposal:
 3180–4770 m3/day
 High NaCl concentration
 High Ca and Mg concentration cause scaling
and clogging to pipe
© 2010 Chevron
WASTE BRINE
RECYCLE PROJECT
PRODUCED
WATER
REUSE
DISCHARGE
RE-INJECTION
MBR - RO
MBR
UF
PRODUCED WATER MANAGEMENT
IN OIL & GAS INDUSTRIES

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Penjernih Air karya Profesor IGD Wenten

  • 1. I G. WENTEN  Faculty Member, Chemical Engineering Deparment – ITB  Head, DSP Biotech Lab, Inter University Research center, ITB  Postdoctoral Researcher, Unesco Center on Membrane, UNSW, Australia, 1995  Expert Staf, X-Flow B.V., The Netherlands, 1993-1994  Researcher, Bioseparation Research Center, RPI, New York, USA, 1991  Internatonal Expert, Institute of Hydrogen Economy, UTM, Malaysia  R&D Supervisor, Shanghai Megavision Membrane, China  Senior International Supervisor, Guangdong Jin Gang New Material Co. Ltd., China  Peneliti Utama, di hampir semua program riset nasional di Indonesia  Plenary, Keynote, dan Invited Speaker, Invited Lecturer, Conterence Chairman, lebih dari 100 events  Publikasi ilmiah, lebih dari 200 makalah national dan internasional  Gugus Tugas HKI (hak atas kekayaan intelektual) ITB, KemenRistek, dan Dikti  Editorial dan Advisory Board, beberapa Institusi Keilmuan dan Jurnal Ilmiah  Tenaga Ahli, Team Ahli, Supervisor, dan Konsultan, beberapa Perusahaan dan Institusi di Indonesia  Pendiri, Asean Association on Membrane dan GDPFilter Indonesia
  • 2. AWARDS AND ACHIEVEMENTS  GRANTED PATENTS, 15 Paten Nasional dan Internasional  KARYA UNGGULAN TEKNOLOGI ANAK BANGSA, KemenRistek, Hakteknas 2014  BJ. HABIBIE TECHNOLOGY AWARD, BPPT, 2013  GOLD MEDAL-GANESHA INNOVATION AWARD, IA-ITB, 2013  SOEGENG SARJADI AWARD, SSSG, 2012  ASEAN OUTSTANDING ENGINEERING AWARD, AFEO, 2010  ADHICIPTA REKAYASA-EMAS, PII (Persatuan Insinyur Indonesia), 2009  COMPETENCY AWARD, Badan Nasional Sertifikasi Profesi, Indonesia, 2009  ANUGERAH RISET UNGGULAN TERPADU, KemenRistek, 2004  WIPO AWARD (BEST INVENTOR), WIPO-UNDP, 2002  HABIBIE AWARD, Habibie Center, 2000  PENELITI MUDA INDONESIA, LIPI (Lembaga Ilmu Pengetahuan Indonesia), 1996  SCIENCE AND TECHNOLOGY AWARD, Toray Science Foundation, 1996  ADHICIPTA REKAYASA, PII (Persatuan Insinyur Indonesia), 1995  SUTTLE AWARD, Filtration Society, London, 1994  ALUMNI TERBAIK ITB-82, 2002, Penghargaan yang paling dibanggakan
  • 4.
  • 6.
  • 7.
  • 8.
  • 9. Patent Indonesia P00201000408 NO MORE MODULARITY IN MEMBRANE
  • 15.
  • 16. Capacity : 500 LPH, Weight : 30 kg
  • 17.
  • 18. Activated carbon Reduce unpleasant odors, organic matter and rsidual chlorine Hollow fine fiber Membrane The core competence of this unit. Ultrafiltration membrane can remove almost 100% of colloids, bacteria, viruses and all of particulate matters reponsible for turbidity . Bioceramic Alkalinity agent and enhancing anti oxidant quality of drinking water. It also enhances freshness of drinking water Single module that integrate three stages of filtration RAIN WATER HARVESTING
  • 19.
  • 20.
  • 21. EMPOWERING SMALL SCALE BUSNISSES  PATHOGENIC REMOVAL IN HATCHERY  VEGETABLE OIL CLARIFICATION  LUBE OIL RE-USE  GELATIN CLARIFICATION  COCONUT JUICE ULTRAFILTRATION  PALM SUGAR CONCENTRATION
  • 22. UF 30,000 Da  Hatchery  Grow-out Membrane Based Recirculation System for Sustainable Aquaculture
  • 23. IMPLANTED ENDS-FREE MBR National Standard of Aquaculture Recirculation Technology
  • 24. Umpan NON-MODULAR UF FOR MICROALGAE HARVESTING (Nanochlorophyl)
  • 25.  Penumbuhan dan pemanenan dalam satu alat terintegrasi  Tidak membutuhkan tempat yang luas  Mampu meningkatkan densitas mikroalga dalam reaktor  Tidak membutuhkan energi yang besar HIGH DENSITY ALGAE MEMBRANE REACTOR USING MEMBRANE DIFUSER
  • 26.  Solusi Holistik untuk produksi etanol secara berkelanjutan  Etanol yang dihasilkan memiliki konsentrasi cukup tinggi  Rasa bir tetap terjaga NON-POROUS MD FOR BEER DEALCOHOLIZATION
  • 27. IGW PV TECHNOLOGY FOR FUEL GRADE ALCOHOLBIOTECHNOLOGY
  • 28. CANE SUGAR JUICE CLARIFICATION SUGARINDUSTRYIGW
  • 29. CANE SUGAR JUICE BEVERAGE SUGARINDUSTRYIGW
  • 30. EMPOWERING PALM SUGAR BUSNISSES High Quality DRINKING WATER Membrane Concentrator
  • 32. CLEAN PRODUCTION IN STARCH INDUSTRY
  • 34.
  • 35. Membrane Fabrication – Melt SpinningMEMBRANEFABRICATIONIGW
  • 36. Cooling tower Process streams requiring cooling Cooling water recirculation (QR) Tower packing Heat exchanger Blowdown water Evaporation loss 1% QR per 5.6oC T drop Windage loss (mist) 0.2% QR Heat Transfer PLANT HEAT TRANSFER Heat exchanger Hollow Fiber Cooling Tower HEAT DISSIPATION VIA EVAPORATION Blowdown High salt conc. Make-up cooling water Soft water Make-up boiler feed water Preheater BOILER Vapor Membrane pore Cooling water Condensate Hollow fiber Hollow fiber Stagnant air HOLLOW FIBER COOLING TOWER M T Hollowfibermodule TR WB NaCl solution M T TR DW M T WB DW DW M T Over-flow Measuring cylinder Feed pump Permeate pump Needle valve Needle valve Adjustable DC power supply
  • 37. VEGETABLE OIL FILTRATION Virgin Coconut Oil Clarification
  • 38. SIMULTANEOUS CLARIFICATION AND DEGUMMING OF JATHROPA OIL JATHROPAOILIGW CONVENTIONAL CLARIFICATION ACID DEGUMMING H3PO4 Oil Particles, dirt, gum Clarified, de- gummed oil ONE STEP CLARIFICATION AND DEGUMMING PROCESS •Vibrating screen •Clarifier •Purifier
  • 39. NATURAL PALM KERNEL FRYING OIL • 1 Step clarification process • No chemical consumption • Environmentally friendly process Clarified PKO Feed (Crude PKO) Permeate (Clarified PKO) Retentate PALMOILINDUSTRYIGW
  • 40. WORLD LARGEST CERAMIC MEMBRANE BIOREACTOR
  • 41. Spider web harvesting system COOKING TANK MEMBRANE EXTRACTION Purified CPO A NOVEL CONCEPT ZERO SLUDGE PALM OIL MILLING PLANT
  • 44. CO2 Removal Wet-Free Membrane Contactor Patent App. P00200900263
  • 45. CO2 Removal Wet-Free Membrane Contactor Patent App. P00200900263
  • 46. KONTAKTOR MEMBRAN Tipe: non-wetted Tipe: wetted Regenerasi absorben secara in situ  menghilangkan aliran sirkulasi yang sangat besar
  • 47. I G. Wenten Teknik Kimia - ITB, Indonesia
  • 49. FULL SCALE OF UF MEMBRANE SYSTEM (INDONESIA) CAPACITY 33.000 BWPD [Argonne National Laboratory] PRODUCED WATER TREATMENT PLANT
  • 50. Ultrafiltration Unit Incinerator Unit Chemical Injection Unit Deaerator PRODUCED WATER TREATMENT PLANT (INDONESIA)
  • 51.
  • 52. c COMPARISON OF BASELINE FLUXES FOR THE THREE DIFFERENT MEMBRANES Mueller, et al, 1997 Op. cond.: 10 psig TMP, 250 ppm heavy oil, 40°C, and 0.24 ms -1
  • 53. SCALE FORMATION Main culprits: CaCO3 and (rarely) SiO2 Causes drop in product water quality In severe cases causes drop in concentrate flow (increase in pressure drop) Need to analyze feed and concentrate for hardness or silica (mass balance calculation) Scale control • Pre-treatment • Chemicals • Concentration factor
  • 55. OTHER FLUX ENHANCEMENT METHODS Electrical Methods Used for fouling due to charge interactions between charged solutes and the membrane An electric field can be applied to the flowing fluid, with one electrode being cast on or placed against the membrane, and the other electrode within the liquid, but away from the membrane surface Intermittent Jets Unsteady flows and large vortices can be generated with an intermittent jet of the feed pumped through a nozzle placed coaxially in a membrane tube causes the velocity of the feed to abruptly increase and then decrease resulting higher flux. Pulsatile Flow Pulsations in the feed or permeate channels obtained with pistons
  • 56. MEMBRANE CLEANING Foulant Reagent Time &Temperature Mode of Action Fats, oils, proteins, polysaccharides, bacteria, 0.5N NaOH with 200 ppm Cl2 30 - 60 min 25 – 55oC Hydrolysis and oxidation DNA, mineral salts 0.1 – 0.5M acid (acetic, citric, nitric) 30 - 60 min 25 – 55oC Solubilization Fats, oils, biopolymers, proteins 0.1%SDS; 0.1% Triton X- 100; 30 min-overnight 25 – 55oC Wetting, emulsifying, suspending, dispersing Cell fragments, fats, oils, proteins Enzyme, detergent 30 min-overnight 30 – 40oC Catalytic breakdown (proteolysis) DNA 0.5% DNAase 30 min-overnight 30 – 40oC Enzyme hydrolysis Fats, oils, and grease 20-50% ethanol 30 - 60 min 25 – 55oC Solubilization Membranes have to cleaned typically when: - Normalized Permeate flow varies by 10-15% - Normalized Feed pressure varies by 10-15% - Normalized Permeate conductivity varies by 10-15% - Pressure drop between feed and concentrate varies by 10-15%
  • 57. CLEANING PARAMETERS Membrane materials and chemistry • This determines a membrane's ability to withstand the action of the chemical cleaners Fluid mechanics • should be pumped through the system under turbulent flow conditions • the pressures should be as low as possible, but consistent with the dP required to maintain high flow rates Time • most chemical cleaners complete their action within 30-60 min. Prolonged cleaning after the optimum time may actually cause refouling of the membrane due to the filtration effect Temperature • the temperature of the cleaning solution should be as high as possible, consistent with temperature limitations of the membrane/module Water quality • soft water should be used. pH • Alkaline cleaners containing NaOH or KOH are particularly effective for organics and proteins • Acidic cleaners are primarily used to combat inorganic salt fouling
  • 59. •Dialysis •Pervaporation •Gas Separation •MBR •RO •NF •UF •MF RO application •MBR Module HF Tubular SW Flat Manufacturing cost (4USD/m2) 5-20 50-200 30-100 100-300 Packing density High Low Moderate Low Resistance to fouling Very poor Very good Moderate Good Parasitic pressure drop High Low Moderate Moderate High pressure operation yes difficult yes Difficult
  • 60. Fiber Backing 120 um Polysulfone 50 um Active Layer 100 nm RO/NF PORE STRUCTURE
  • 62. 62 Large scale plant Space requirement Numbers of component used (complexity) Large brine disposal LARGE SCALE CHALLENGES
  • 63. 63 INTENSIFICATION IN LARGE SCALE MEMBRANE BASED DESALINATION PLANT • I G. Wenten • Teknik Kimia-ITB, igwenten@gmail.com
  • 64. 1 Hydrogen Membrane for Syngas mixture Fed into Pd-Ag Mreactor 2 Membrane Crystallization For Selective Polymorph Crystallization 3.Latest Development of Polymer Electrolyte Membrane FC (PEMFC) 4 Aroma Recovery by Pervaporation 5 Membrane Crystallizer of Nanofiltration Brine Solution 6 Modified PEEK Membrane With Honey Comb Structure 7. Mega Magnum System 8. Membrane Osmotic Distillation 9. Reverse Osmosis Energy Recovery Device 10. Carbon Nanotube Membrane 11. Forward Osmosis Membrane Bioreactor 12. Fullerenes Prevent Biofouling in Membrane Microfiltration 13. Membrane Distillation Bioreactor 14. Integrated Membrane for Desalination 15. Inland Desalination 16. Membrane Sensor 17. Nanostructured Asymmetric Membrane 18. Boron Removal With SWRO 19. Well Defined Shape and Size Crystal with Membrane Crystallizer 20. Incorporating Amino Group in Polymeric network for composite 21. Aquaporin Membrane 22. Nanofiltration as Reverse Osmosis Pretreatment 23. Forward Osmosis (FO) 24. Air Separation At High Temperature 25. Membrane For Artificial Organs 26. Membrane Biohybrid System Using Hepatocytes 27. Latest Development In Enzymatic Membrane Reactor 28. Membrane in Tissue Engineering 29. Membrane Emulsifier 30. Recent Advances in Bipolar Membrane 31. Non Modular Membrane System 32. Super Hydrophobic Membrane
  • 65. 65 ENERGY GENERATION FROM BRINE DISPOSAL RO-PRO RO-RED
  • 66. 66 MEMBRANE DISTILLATION Al-Obaidani et al., Journal of Membrane Science 323 (2008) 85–98 Feed H2O Permeate H2O Liquid water Air/vapour Liquid water Hydrophobic porous membrane T1 > T2 T1 T2
  • 67. 67 ELECTRODEIONIZATION Largest Continuous Electrodeionization Plant in Con Edison’s East River Repowering Project, New York. Capacity 1,530 m3/day CEDI Units Final treatment using Continuous electrodeionization RO Units Contain 2 pass reverse osmosis unit Filter Units Anti Scalant injection Raw water tank Cooling HE Polymeric Coagulant Multi Media Filters Antiscalant Cartridge Filters Sodium Bisulfite Reverse Osmosis Electrodeionization Silos
  • 69. 69 CAPACITIVE DEIONIZATION & MEMBRANE CAPACITIVE DEIONIZATION Capacitive deionization (CDI) Membrane capcitive deionization (MCDI) www.voltea.com
  • 70. MBR FOR WATER RECLAMATION
  • 74. IODINE RECOVERY FROM PRODUCED WATER Concentrating iodide in the brine Pei Xu, Jörg E. Drewes, Dean Heil ; Desalination 225, (2008) Water quality of produced water extracted from a natural gas production site (natural gas production site in Eastern Montana) Iodide concentration in brine after membrane treatment
  • 75. Ozone oxidation of produced water using ceramic membrane diffuser P Separator Pressure Gauge Flue gas CeramicMembraneDiffuser SampleMembraneAirFilter Ozone Generator Pump Globe valve Needle valve Needle valve Compressor BTEX solution
  • 76. 76 WASTE BRINE RECYCLE PROJECT Producued water Softening Reinjection Ion exchange (softener) regeneration Salt consumption: 90 ton/day Waste brine disposal:  3180–4770 m3/day  High NaCl concentration  High Ca and Mg concentration cause scaling and clogging to pipe
  • 77. © 2010 Chevron WASTE BRINE RECYCLE PROJECT