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This document consists of 15 printed pages and 1 blank pages.
IB09 06_0620_31/5RP
© UCLES 2009 [Turn over
*5310297965*
For Examiner's Use
1
2
3
4
5
6
7
8
9
Total
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
International General Certificate of Secondary Education
CHEMISTRY 0620/31
Paper 3 (Extended) May/June 2009
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
A copy of the Periodic Table is printed on page 16.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.
First Variant Question Paper
2
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are
extracted to give a deep green solution.
(a) (i) Draw a labelled diagram to describe how you could show that there is more than
one coloured pigment in the green solution.
[3]
(ii) Given a pure sample of chlorophyll, how could you show that the green solution
from the grass contained chlorophyll?
[2]
(b) Explain the role of chlorophyll in green plants.
[3]
[Total: 8]
3
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
2 The results of experiments on electrolysis using inert electrodes are given in the table.
Complete the table; the first line has been completed as an example.
electrolyte change at negative
electrode
change at positive
electrode
change to
electrolyte
molten lead(II)
bromide
lead formed bromine formed used up
potassium formed iodine formed used up
dilute aqueous
sodium chloride
aqueous copper(II)
sulfate
hydrogen formed bromine formed potassium hydroxide
formed
[Total: 8]
4
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
3 The following is a list of the electron distributions of atoms of unknown elements.
element electron distribution
A 2,5
B 2,8,4
C 2,8,8,2
D 2,8,18,8
E 2,8,18,8,1
F 2,8,18,18,7
(a) Choose an element from the list for each of the following descriptions.
(i) It is a noble gas.
(ii) It is a soft metal with a low density.
(iii) It can form a covalent compound with element A.
(iv) It has a giant covalent structure similar to diamond.
(v) It can form a negative ion of the type X3-
. [5]
(b) Elements C and F can form an ionic compound.
(i) Draw a diagram that shows the formula of this compound, the charges on the ions
and the arrangement of the valency electrons around the negative ion.
Use o to represent an electron from an atom of C.
Use x to represent an electron from an atom of F.
[3]
(ii) Predict two properties of this compound.
[2]
[Total: 10]
5
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
4 The reactivity series of metals given below contains both familiar and unfamiliar elements.
For most of the unfamiliar elements, which are marked *, their common oxidation states are
given.
* barium Ba
* lanthanum La (+3)
magnesium
zinc
* chromium Cr (+2), (+3), (+6)
iron
copper
* palladium (+2)
Choose metal(s) from the above list to answer the following questions.
(i) Which two metals would not react with dilute hydrochloric acid?
[2]
(ii) Which two unfamiliar metals (*) would react with cold water?
[2]
(iii) What is the oxidation state of barium?
[1]
(iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon.
[1]
(v) Why should you be able to predict that metals such as iron and chromium have
more than one oxidation state?
[1]
[Total: 7]
6
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
5 Insoluble salts are made by precipitation.
(a) A preparation of the insoluble salt calcium fluoride is described below.
To 15 cm3
of aqueous calcium chloride, 30 cm3
of aqueous sodium fluoride is added.
The concentration of both solutions is 1.00 mol / dm3
. The mixture is filtered and the
precipitate washed with distilled water. Finally, the precipitate is heated in an oven.
(i) Complete the equation.
Ca2+
+ ...…….F-
………...... [2]
(ii) Why is the volume of sodium fluoride solution double that of the calcium chloride
solution?
[1]
(iii) Why is the mixture washed with distilled water?
[1]
(iv) Why is the solid heated?
[1]
7
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
16
12
8
4
0
0 2 4 6 8 10 12 14
volume of phosphate solution/cm3
height of
precipitate
/mm
(b) The formulae of insoluble compounds can be found by precipitation reactions.
To 12.0 cm3
of an aqueous solution of the nitrate of metal T was added 2.0 cm3
of
aqueous sodium phosphate, Na3PO4. The concentration of both solutions was
1.00mol/dm3
. When the precipitate had settled, its height was measured.
solution
height of
precipitate
precipitate of
the phosphate
of metal T
The experiment was repeated using different volumes of the phosphate solution. The
results are shown on the following graph.
What is the formula of the phosphate of metal T? Give your reasoning.
[3]
[Total: 8]
8
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
6 Ammonia is manufactured by the Haber process.
N2(g) + 3H2(g) 2NH3(g) the forward reaction is exothermic
(a) (i) Name the raw materials from which nitrogen and hydrogen are obtained.
nitrogen from [1]
hydrogen from [1]
(ii) Name the catalyst used in this process.
[1]
(iii) What is the most important use of ammonia?
[1]
(b) The following graph shows how the percentage of ammonia in the equilibrium mixture
changes with temperature.
0
0
% ammonia
at equilibrium
temperature
(i) Explain the term equilibrium.
[2]
(ii) How does the percentage of ammonia vary with temperature?
[1]
9
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
(c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium
mixture varies with pressure.
0
0
% ammonia
at equilibrium
pressure
[1]
(ii) Explain why the graph has the shape shown.
[2]
[Total: 10]
10
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
7 Hydrogen reacts with the halogens to form hydrogen halides.
(a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to
break one mole of a bond.
bond bond energy in kJ/mol
H─H +436
Cl─Cl +242
H─Cl +431
Use the above data to show that the following reaction is exothermic.
H─H + Cl─Cl 2H─Cl
[3]
11
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
(b) They react with water to form acidic solutions.
HCl + H2O H3O+ + Cl-
HF + H2O H3O+ + F-
(i) Explain why water behaves as a base in both of these reactions.
[2]
(ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has
formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as
molecules, only 3% has formed ions.
What does this tell you about the strength of each acid?
[2]
(iii) How would the pH of these two solutions differ?
[1]
[Total: 8]
12
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
8 Lactic acid can be made from corn starch.
CH3 CH COOH
OH
lactic acid
It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable.
(a) Suggest two advantages that PLA has compared with a polymer made from petroleum.
[2]
(b) The structure of PLA is given below.
CH3 O
CHO C
CH3
O CH
(i) What type of compound contains the group that is circled?
[1]
(ii) Complete the following sentence.
Lactic acid molecules can form this group because they contain both an
group and an group. [2]
(iii) Is the formation of PLA, an addition or condensation polymerisation? Give a
reason for your choice.
[2]
13
© UCLES 2009 0620/31/M/J/09 [Turn over
For
Examiner's
Use
(c) When lactic acid is heated, acrylic acid is formed.
C C COOH
OH
H
H
H
H
lactic acid acrylic acid
C C
H
H
H
COOH
(i) Complete the word equation for the action of heat on lactic acid.
lactic acid → + [1]
(ii) Describe a test that would distinguish between lactic acid and acrylic acid.
test
result for lactic acid
result for acrylic acid [3]
(iii) Describe a test, other than using an indicator, which would show that both
chemicals contain an acid group.
test
result
[2]
[Total: 13]
14
© UCLES 2009 0620/31/M/J/09
For
Examiner's
Use
9 Quantities of chemicals, expressed in moles, can be used to find the formula of a
compound, to establish an equation and to determine reacting masses.
(a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical
formula?
[2]
(b) A compound contains only aluminium and carbon. 0.03moles of this compound reacted
with excess water to form 0.12moles of Al(OH)3 and 0.09moles of CH4.
Write a balanced equation for this reaction.
[2]
(c) 0.07moles of silicon reacts with 25g of bromine.
Si + 2Br2 SiBr4
(i) Which one is the limiting reagent? Explain your choice.
[3]
(ii) How many moles of SiBr4 are formed?
[1]
[Total: 8]
15
0620/31/M/J/09
BLANK PAGE
16
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2009 0620/31/M/J/09
Group
140
Ce
Cerium
58
141
Pr
Praseodymium
59
144
Nd
Neodymium
60
Pm
Promethium
61
150
Sm
Samarium
62
152
Eu
Europium
63
157
Gd
Gadolinium
64
159
Tb
Terbium
65
162
Dy
Dysprosium
66
165
Ho
Holmium
67
167
Er
Erbium
68
169
Tm
Thulium
69
173
Yb
Ytterbium
70
175
Lu
Lutetium
71
232
Th
Thorium
90
Pa
Protactinium
91
238
U
Uranium
92
Np
Neptunium
93
Pu
Plutonium
94
Am
Americium
95
Cm
Curium
96
Bk
Berkelium
97
Cf
Californium
98
Es
Einsteinium
99
Fm
Fermium
100
Md
Mendelevium
101
No
Nobelium
102
Lr
Lawrencium
103
1
H
Hydrogen
1
7
Li
Lithium
3
23
Na
Sodium
11
24
Mg
Magnesium
12
40
Ca
Calcium
20
45
Sc
Scandium
21
48
Ti
Titanium
22
51
V
Vanadium
23
52
Cr
Chromium
24
55
Mn
Manganese
25
56
Fe
Iron
26
59
Co
Cobalt
27
59
Ni
Nickel
28
64
Cu
Copper
29
65
Zn
Zinc
30
70
Ga
Gallium
31
27
Al
Aluminium
13
11
B
Boron
5
12
C
Carbon
6
14
N
Nitrogen
7
16
O
Oxygen
8
19
F
Fluorine
9
28
Si
Silicon
14
31
P
Phosphorus
15
32
S
Sulfur
16
35.5
Cl
Chlorine
17
40
Ar
Argon
18
20
Ne
Neon
10
4
He
Helium
2
73
Ge
Germanium
32
75
As
Arsenic
33
79
Se
Selenium
34
80
Br
Bromine
35
84
Kr
Krypton
36
39
K
Potassium
19
88
Sr
Strontium
38
89
Y
Yttrium
39
91
Zr
Zirconium
40
93
Nb
Niobium
41
96
Mo
Molybdenum
42
Tc
Technetium
43
101
Ru
Ruthenium
44
103
Rh
Rhodium
45
106
Pd
Palladium
46
108
Ag
Silver
47
112
Cd
Cadmium
48
115
In
Indium
49
119
Sn
Tin
50
122
Sb
Antimony
51
128
Te
Tellurium
52
127
I
Iodine
53
131
Xe
Xenon
54
137
Ba
Barium
56
139
La
Lanthanum
57*
178
Hf
Hafnium
72
181
Ta
Tantalum
73
184
W
Tungsten
74
186
Re
Rhenium
75
190
Os
Osmium
76
192
Ir
Iridium
77
195
Pt
Platinum
78
197
Au
Gold
79
201
Hg
Mercury
80
204
Tl
Thallium
81
207
Pb
Lead
82
209
Bi
Bismuth
83
Po
Polonium
84
At
Astatine
85
Rn
Radon
86
Fr
Francium
87
227
Ac
Actinium
89
9
Be
Beryllium
4
IIIIIIIVVVIVII0
85
Rb
Rubidium
37
133
Cs
Caesium
55
226
Ra
Radium
88
Thevolumeofonemoleofanygasis24dm3atroomtemperatureandpressure(r.t.p.).
a
X
b
a=relativeatomicmass
X=atomicsymbol
b=proton(atomic)number
Key
*58-71Lanthanoidseries
90-103Actinoidseries
DATASHEET
ThePeriodicTableoftheElements
This document consists of 15 printed pages and 1 blank page.
IB09 06_0620_32/4RP
© UCLES 2009 [Turn over
*0583100121*
For Examiner's Use
1
2
3
4
5
6
7
8
9
Total
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
International General Certificate of Secondary Education
CHEMISTRY 0620/32
Paper 3 (Extended) May/June 2009
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
A copy of the Periodic Table is printed on page 16.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.
Second Variant Question Paper
2
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are
extracted to give a deep green solution.
(a) (i) Draw a labelled diagram to describe how you could show that there is more than
one coloured pigment in the green solution.
[3]
(ii) Given a pure sample of chlorophyll, how could you show that the green solution
from the grass contained chlorophyll?
[2]
(b) Explain the role of chlorophyll in green plants.
[3]
[Total: 8]
3
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
2 The results of experiments on electrolysis using inert electrodes are given in the table.
Complete the table; the first line has been completed as an example.
electrolyte change at negative
electrode
change at positive
electrode
change to electrolyte
molten lead(II)
bromide
lead formed bromine formed used up
lithium formed chlorine formed used up
dilute aqueous sodium
chloride
aqueous copper(II)
sulfate
hydrogen formed bromine formed potassium hydroxide
formed
[Total: 8]
4
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
3 The following is a list of the electron distributions of atoms of unknown elements.
element electron distribution
A 2,6
B 2,8,4
C 2,8,8,2
D 2,8,18,8
E 2,8,18,8,1
F 2,8,18,18,7
(a) Choose an element from the list for each of the following descriptions.
(i) It is a noble gas.
(ii) It is a soft metal with a low density.
(iii) It can form a covalent compound with element A.
(iv) It has a giant covalent structure similar to diamond.
(v) It is a diatomic gas with molecules of the type X2. [5]
(b) Elements C and A can form an ionic compound.
(i) Draw a diagram that shows the formula of this compound, the charges on the ions
and the arrangement of the valency electrons around the negative ion.
Use o to represent an electron from an atom of C.
Use x to represent an electron from an atom of A.
[3]
(ii) Predict two properties of this compound.
[2]
[Total: 10]
5
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
4 The reactivity series of metals given below contains both familiar and unfamiliar elements.
For most of the unfamiliar elements, which are marked *, their common oxidation states are
given.
* barium Ba
* lanthanum La (+3)
magnesium
zinc
* chromium Cr (+2), (+3), (+6)
iron
copper
* palladium (+2)
Choose metal(s) from the above list to answer the following questions.
(i) Which two metals would not react with dilute hydrochloric acid?
[2]
(ii) Which two unfamiliar metals (*) would react with cold water?
[2]
(iii) What is the oxidation state of barium?
[1]
(iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon.
[1]
(v) Why should you be able to predict that metals such as iron and chromium have
more than one oxidation state?
[1]
[Total: 7]
6
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
5 Insoluble salts are made by precipitation.
(a) A preparation of the insoluble salt iron fluoride is described below.
To 15 cm3
of aqueous iron(III) chloride, 45 cm3
of aqueous sodium fluoride is added.
The concentration of both solutions is 1.00 mol / dm3
. The mixture is filtered and the
precipitate washed with distilled water. Finally, the precipitate is heated in an oven.
(i) Complete the equation.
Fe3+
+ ...…….F-
………...... [2]
(ii) Why is the volume of sodium fluoride solution three times that of the iron(III)
chloride solution?
[1]
(iii) Why is the mixture washed with distilled water?
[1]
(iv) Why is the solid heated?
[1]
7
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
16
12
8
4
0
0 2 4 6 8 10 12 14
volume of phosphate solution/cm3
height of
precipitate
/mm
(b) The formulae of insoluble compounds can be found by precipitation reactions.
To 18.0 cm3
of an aqueous solution of the nitrate of metal T was added 2.0 cm3
of
aqueous sodium phosphate, Na3PO4. The concentration of both solutions was
1.00mol/dm3
. When the precipitate had settled, its height was measured.
solution
height of
precipitate
precipitate of
the phosphate
of metal T
The experiment was repeated using different volumes of the phosphate solution. The
results are shown on the following graph.
What is the formula of the phosphate of metal T? Give your reasoning.
[3]
[Total: 8]
8
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
6 Ammonia is manufactured by the Haber process.
N2(g) + 3H2(g) 2NH3(g) the forward reaction is exothermic
(a) (i) Name the raw materials from which nitrogen and hydrogen are obtained.
nitrogen from [1]
hydrogen from [1]
(ii) Name the catalyst used in this process.
[1]
(iii) What is the most important use of ammonia?
[1]
(b) The following graph shows how the percentage of ammonia in the equilibrium mixture
changes with pressure.
0
0
% ammonia
at equilibrium
pressure
(i) Explain the term equilibrium.
[2]
(ii) How does the percentage of ammonia vary with pressure?
[1]
9
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
(c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium
mixture varies with temperature.
0
0
% ammonia
at equilibrium
temperature
[1]
(ii) Explain why the graph has the shape shown.
[2]
[Total: 10]
10
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
7 Hydrogen reacts with the halogens to form hydrogen halides.
(a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to
break one mole of a bond.
bond bond energy in kJ/mol
H─H +436
F─F +158
H─F +562
Use the above data to show that the following reaction is exothermic.
H─H + F─F 2H─F
[3]
11
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
(b) They react with water to form acidic solutions.
HCl + H2O H3O+
+ Cl-
HF + H2O H3O+
+ F-
(i) Explain why water behaves as a base in both of these reactions.
[2]
(ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has
formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as
molecules, only 3% has formed ions.
What does this tell you about the strength of each acid?
[2]
(iii) How would the pH of these two solutions differ?
[1]
[Total: 8]
12
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
8 Lactic acid can be made from corn starch.
CH3 CH COOH
OH
lactic acid
It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable.
(a) Suggest two advantages that PLA has compared with a polymer made from petroleum.
[2]
(b) The structure of PLA is given below.
CH3 O
CHO C
CH3
O CH
(i) What type of compound contains the group that is circled?
[1]
(ii) Complete the following sentence.
Lactic acid molecules can form this group because they contain both an
group and an group. [2]
(iii) Is the formation of PLA, an addition or condensation polymerisation? Give a
reason for your choice.
[2]
13
© UCLES 2009 0620/32/M/J/09 [Turn over
For
Examiner's
Use
(c) When lactic acid is heated, acrylic acid is formed.
C C COOH
OH
H
H
H
H
lactic acid acrylic acid
C C
H
H
H
COOH
(i) Complete the word equation for the action of heat on lactic acid.
lactic acid → + [1]
(ii) Describe a test that would distinguish between lactic acid and acrylic acid.
test
result for lactic acid
result for acrylic acid [3]
(iii) Describe a test, other than using an indicator, which would show that both
chemicals contain an acid group.
test
result
[2]
[Total: 13]
14
© UCLES 2009 0620/32/M/J/09
For
Examiner's
Use
9 Quantities of chemicals, expressed in moles, can be used to find the formula of a
compound, to establish an equation and to determine reacting masses.
(a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical
formula?
[2]
(b) A compound contains only aluminium and carbon. 0.03moles of this compound reacted
with excess water to form 0.12moles of Al(OH)3 and 0.09moles of CH4.
Write a balanced equation for this reaction.
[2]
(c) 0.08moles of silicon reacts with 7.2g of fluorine.
Si + 2F2 SiF4
(i) Which one is the limiting reagent? Explain your choice.
[3]
(ii) How many moles of SiF4 are formed?
[1]
[Total: 8]
15
0620/32/M/J/09
BLANK PAGE
16
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
© UCLES 2009 0620/32/M/J/09
Group
140
Ce
Cerium
58
141
Pr
Praseodymium
59
144
Nd
Neodymium
60
Pm
Promethium
61
150
Sm
Samarium
62
152
Eu
Europium
63
157
Gd
Gadolinium
64
159
Tb
Terbium
65
162
Dy
Dysprosium
66
165
Ho
Holmium
67
167
Er
Erbium
68
169
Tm
Thulium
69
173
Yb
Ytterbium
70
175
Lu
Lutetium
71
232
Th
Thorium
90
Pa
Protactinium
91
238
U
Uranium
92
Np
Neptunium
93
Pu
Plutonium
94
Am
Americium
95
Cm
Curium
96
Bk
Berkelium
97
Cf
Californium
98
Es
Einsteinium
99
Fm
Fermium
100
Md
Mendelevium
101
No
Nobelium
102
Lr
Lawrencium
103
1
H
Hydrogen
1
7
Li
Lithium
3
23
Na
Sodium
11
24
Mg
Magnesium
12
40
Ca
Calcium
20
45
Sc
Scandium
21
48
Ti
Titanium
22
51
V
Vanadium
23
52
Cr
Chromium
24
55
Mn
Manganese
25
56
Fe
Iron
26
59
Co
Cobalt
27
59
Ni
Nickel
28
64
Cu
Copper
29
65
Zn
Zinc
30
70
Ga
Gallium
31
27
Al
Aluminium
13
11
B
Boron
5
12
C
Carbon
6
14
N
Nitrogen
7
16
O
Oxygen
8
19
F
Fluorine
9
28
Si
Silicon
14
31
P
Phosphorus
15
32
S
Sulfur
16
35.5
Cl
Chlorine
17
40
Ar
Argon
18
20
Ne
Neon
10
4
He
Helium
2
73
Ge
Germanium
32
75
As
Arsenic
33
79
Se
Selenium
34
80
Br
Bromine
35
84
Kr
Krypton
36
39
K
Potassium
19
88
Sr
Strontium
38
89
Y
Yttrium
39
91
Zr
Zirconium
40
93
Nb
Niobium
41
96
Mo
Molybdenum
42
Tc
Technetium
43
101
Ru
Ruthenium
44
103
Rh
Rhodium
45
106
Pd
Palladium
46
108
Ag
Silver
47
112
Cd
Cadmium
48
115
In
Indium
49
119
Sn
Tin
50
122
Sb
Antimony
51
128
Te
Tellurium
52
127
I
Iodine
53
131
Xe
Xenon
54
137
Ba
Barium
56
139
La
Lanthanum
57*
178
Hf
Hafnium
72
181
Ta
Tantalum
73
184
W
Tungsten
74
186
Re
Rhenium
75
190
Os
Osmium
76
192
Ir
Iridium
77
195
Pt
Platinum
78
197
Au
Gold
79
201
Hg
Mercury
80
204
Tl
Thallium
81
207
Pb
Lead
82
209
Bi
Bismuth
83
Po
Polonium
84
At
Astatine
85
Rn
Radon
86
Fr
Francium
87
227
Ac
Actinium
89
9
Be
Beryllium
4
IIIIIIIVVVIVII0
85
Rb
Rubidium
37
133
Cs
Caesium
55
226
Ra
Radium
88
Thevolumeofonemoleofanygasis24dm3atroomtemperatureandpressure(r.t.p.).
a
X
b
a=relativeatomicmass
X=atomicsymbol
b=proton(atomic)number
Key
*58-71Lanthanoidseries
90-103Actinoidseries
DATASHEET
ThePeriodicTableoftheElements

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0620_s09_qp_3

  • 1. Location Entry Codes As part of CIE’s continual commitment to maintaining best practice in assessment, CIE uses different variants of some question papers for our most popular assessments with large and widespread candidature. The question papers are closely related and the relationships between them have been thoroughly established using our assessment expertise. All versions of the paper give assessment of equal standard. The content assessed by the examination papers and the type of questions is unchanged. This change means that for this component there are now two variant Question Papers, Mark Schemes and Principal Examiner’s Reports where previously there was only one. For any individual country, it is intended that only one variant is used. This document contains both variants which will give all Centres access to even more past examination material than is usually the case. The diagram shows the relationship between the Question Papers, Mark Schemes and Principal Examiners’ Reports that are available. Question Paper Mark Scheme Principal Examiner’s Report Introduction Introduction Introduction First variant Question Paper First variant Mark Scheme First variant Principal Examiner’s Report Second variant Question Paper Second variant Mark Scheme Second variant Principal Examiner’s Report Who can I contact for further information on these changes? Please direct any questions about this to CIE’s Customer Services team at: international@cie.org.uk The titles for the variant items should correspond with the table above, so that at the top of the first page of the relevant part of the document and on the header, it has the words: • First variant Question Paper / Mark Scheme / Principal Examiner’s Report or • Second variant Question Paper / Mark Scheme / Principal Examiner’s Report as appropriate. w w w .Xtrem ePapers.com
  • 2. This document consists of 15 printed pages and 1 blank pages. IB09 06_0620_31/5RP © UCLES 2009 [Turn over *5310297965* For Examiner's Use 1 2 3 4 5 6 7 8 9 Total UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education CHEMISTRY 0620/31 Paper 3 (Extended) May/June 2009 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fluid. DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part questions. First Variant Question Paper
  • 3. 2 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are extracted to give a deep green solution. (a) (i) Draw a labelled diagram to describe how you could show that there is more than one coloured pigment in the green solution. [3] (ii) Given a pure sample of chlorophyll, how could you show that the green solution from the grass contained chlorophyll? [2] (b) Explain the role of chlorophyll in green plants. [3] [Total: 8]
  • 4. 3 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use 2 The results of experiments on electrolysis using inert electrodes are given in the table. Complete the table; the first line has been completed as an example. electrolyte change at negative electrode change at positive electrode change to electrolyte molten lead(II) bromide lead formed bromine formed used up potassium formed iodine formed used up dilute aqueous sodium chloride aqueous copper(II) sulfate hydrogen formed bromine formed potassium hydroxide formed [Total: 8]
  • 5. 4 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 3 The following is a list of the electron distributions of atoms of unknown elements. element electron distribution A 2,5 B 2,8,4 C 2,8,8,2 D 2,8,18,8 E 2,8,18,8,1 F 2,8,18,18,7 (a) Choose an element from the list for each of the following descriptions. (i) It is a noble gas. (ii) It is a soft metal with a low density. (iii) It can form a covalent compound with element A. (iv) It has a giant covalent structure similar to diamond. (v) It can form a negative ion of the type X3- . [5] (b) Elements C and F can form an ionic compound. (i) Draw a diagram that shows the formula of this compound, the charges on the ions and the arrangement of the valency electrons around the negative ion. Use o to represent an electron from an atom of C. Use x to represent an electron from an atom of F. [3] (ii) Predict two properties of this compound. [2] [Total: 10]
  • 6. 5 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use 4 The reactivity series of metals given below contains both familiar and unfamiliar elements. For most of the unfamiliar elements, which are marked *, their common oxidation states are given. * barium Ba * lanthanum La (+3) magnesium zinc * chromium Cr (+2), (+3), (+6) iron copper * palladium (+2) Choose metal(s) from the above list to answer the following questions. (i) Which two metals would not react with dilute hydrochloric acid? [2] (ii) Which two unfamiliar metals (*) would react with cold water? [2] (iii) What is the oxidation state of barium? [1] (iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon. [1] (v) Why should you be able to predict that metals such as iron and chromium have more than one oxidation state? [1] [Total: 7]
  • 7. 6 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 5 Insoluble salts are made by precipitation. (a) A preparation of the insoluble salt calcium fluoride is described below. To 15 cm3 of aqueous calcium chloride, 30 cm3 of aqueous sodium fluoride is added. The concentration of both solutions is 1.00 mol / dm3 . The mixture is filtered and the precipitate washed with distilled water. Finally, the precipitate is heated in an oven. (i) Complete the equation. Ca2+ + ...…….F- ………...... [2] (ii) Why is the volume of sodium fluoride solution double that of the calcium chloride solution? [1] (iii) Why is the mixture washed with distilled water? [1] (iv) Why is the solid heated? [1]
  • 8. 7 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use 16 12 8 4 0 0 2 4 6 8 10 12 14 volume of phosphate solution/cm3 height of precipitate /mm (b) The formulae of insoluble compounds can be found by precipitation reactions. To 12.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of aqueous sodium phosphate, Na3PO4. The concentration of both solutions was 1.00mol/dm3 . When the precipitate had settled, its height was measured. solution height of precipitate precipitate of the phosphate of metal T The experiment was repeated using different volumes of the phosphate solution. The results are shown on the following graph. What is the formula of the phosphate of metal T? Give your reasoning. [3] [Total: 8]
  • 9. 8 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 6 Ammonia is manufactured by the Haber process. N2(g) + 3H2(g) 2NH3(g) the forward reaction is exothermic (a) (i) Name the raw materials from which nitrogen and hydrogen are obtained. nitrogen from [1] hydrogen from [1] (ii) Name the catalyst used in this process. [1] (iii) What is the most important use of ammonia? [1] (b) The following graph shows how the percentage of ammonia in the equilibrium mixture changes with temperature. 0 0 % ammonia at equilibrium temperature (i) Explain the term equilibrium. [2] (ii) How does the percentage of ammonia vary with temperature? [1]
  • 10. 9 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use (c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium mixture varies with pressure. 0 0 % ammonia at equilibrium pressure [1] (ii) Explain why the graph has the shape shown. [2] [Total: 10]
  • 11. 10 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 7 Hydrogen reacts with the halogens to form hydrogen halides. (a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to break one mole of a bond. bond bond energy in kJ/mol H─H +436 Cl─Cl +242 H─Cl +431 Use the above data to show that the following reaction is exothermic. H─H + Cl─Cl 2H─Cl [3]
  • 12. 11 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use (b) They react with water to form acidic solutions. HCl + H2O H3O+ + Cl- HF + H2O H3O+ + F- (i) Explain why water behaves as a base in both of these reactions. [2] (ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as molecules, only 3% has formed ions. What does this tell you about the strength of each acid? [2] (iii) How would the pH of these two solutions differ? [1] [Total: 8]
  • 13. 12 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 8 Lactic acid can be made from corn starch. CH3 CH COOH OH lactic acid It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable. (a) Suggest two advantages that PLA has compared with a polymer made from petroleum. [2] (b) The structure of PLA is given below. CH3 O CHO C CH3 O CH (i) What type of compound contains the group that is circled? [1] (ii) Complete the following sentence. Lactic acid molecules can form this group because they contain both an group and an group. [2] (iii) Is the formation of PLA, an addition or condensation polymerisation? Give a reason for your choice. [2]
  • 14. 13 © UCLES 2009 0620/31/M/J/09 [Turn over For Examiner's Use (c) When lactic acid is heated, acrylic acid is formed. C C COOH OH H H H H lactic acid acrylic acid C C H H H COOH (i) Complete the word equation for the action of heat on lactic acid. lactic acid → + [1] (ii) Describe a test that would distinguish between lactic acid and acrylic acid. test result for lactic acid result for acrylic acid [3] (iii) Describe a test, other than using an indicator, which would show that both chemicals contain an acid group. test result [2] [Total: 13]
  • 15. 14 © UCLES 2009 0620/31/M/J/09 For Examiner's Use 9 Quantities of chemicals, expressed in moles, can be used to find the formula of a compound, to establish an equation and to determine reacting masses. (a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical formula? [2] (b) A compound contains only aluminium and carbon. 0.03moles of this compound reacted with excess water to form 0.12moles of Al(OH)3 and 0.09moles of CH4. Write a balanced equation for this reaction. [2] (c) 0.07moles of silicon reacts with 25g of bromine. Si + 2Br2 SiBr4 (i) Which one is the limiting reagent? Explain your choice. [3] (ii) How many moles of SiBr4 are formed? [1] [Total: 8]
  • 17. 16 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge. © UCLES 2009 0620/31/M/J/09 Group 140 Ce Cerium 58 141 Pr Praseodymium 59 144 Nd Neodymium 60 Pm Promethium 61 150 Sm Samarium 62 152 Eu Europium 63 157 Gd Gadolinium 64 159 Tb Terbium 65 162 Dy Dysprosium 66 165 Ho Holmium 67 167 Er Erbium 68 169 Tm Thulium 69 173 Yb Ytterbium 70 175 Lu Lutetium 71 232 Th Thorium 90 Pa Protactinium 91 238 U Uranium 92 Np Neptunium 93 Pu Plutonium 94 Am Americium 95 Cm Curium 96 Bk Berkelium 97 Cf Californium 98 Es Einsteinium 99 Fm Fermium 100 Md Mendelevium 101 No Nobelium 102 Lr Lawrencium 103 1 H Hydrogen 1 7 Li Lithium 3 23 Na Sodium 11 24 Mg Magnesium 12 40 Ca Calcium 20 45 Sc Scandium 21 48 Ti Titanium 22 51 V Vanadium 23 52 Cr Chromium 24 55 Mn Manganese 25 56 Fe Iron 26 59 Co Cobalt 27 59 Ni Nickel 28 64 Cu Copper 29 65 Zn Zinc 30 70 Ga Gallium 31 27 Al Aluminium 13 11 B Boron 5 12 C Carbon 6 14 N Nitrogen 7 16 O Oxygen 8 19 F Fluorine 9 28 Si Silicon 14 31 P Phosphorus 15 32 S Sulfur 16 35.5 Cl Chlorine 17 40 Ar Argon 18 20 Ne Neon 10 4 He Helium 2 73 Ge Germanium 32 75 As Arsenic 33 79 Se Selenium 34 80 Br Bromine 35 84 Kr Krypton 36 39 K Potassium 19 88 Sr Strontium 38 89 Y Yttrium 39 91 Zr Zirconium 40 93 Nb Niobium 41 96 Mo Molybdenum 42 Tc Technetium 43 101 Ru Ruthenium 44 103 Rh Rhodium 45 106 Pd Palladium 46 108 Ag Silver 47 112 Cd Cadmium 48 115 In Indium 49 119 Sn Tin 50 122 Sb Antimony 51 128 Te Tellurium 52 127 I Iodine 53 131 Xe Xenon 54 137 Ba Barium 56 139 La Lanthanum 57* 178 Hf Hafnium 72 181 Ta Tantalum 73 184 W Tungsten 74 186 Re Rhenium 75 190 Os Osmium 76 192 Ir Iridium 77 195 Pt Platinum 78 197 Au Gold 79 201 Hg Mercury 80 204 Tl Thallium 81 207 Pb Lead 82 209 Bi Bismuth 83 Po Polonium 84 At Astatine 85 Rn Radon 86 Fr Francium 87 227 Ac Actinium 89 9 Be Beryllium 4 IIIIIIIVVVIVII0 85 Rb Rubidium 37 133 Cs Caesium 55 226 Ra Radium 88 Thevolumeofonemoleofanygasis24dm3atroomtemperatureandpressure(r.t.p.). a X b a=relativeatomicmass X=atomicsymbol b=proton(atomic)number Key *58-71Lanthanoidseries 90-103Actinoidseries DATASHEET ThePeriodicTableoftheElements
  • 18. This document consists of 15 printed pages and 1 blank page. IB09 06_0620_32/4RP © UCLES 2009 [Turn over *0583100121* For Examiner's Use 1 2 3 4 5 6 7 8 9 Total UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education CHEMISTRY 0620/32 Paper 3 (Extended) May/June 2009 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fluid. DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part questions. Second Variant Question Paper
  • 19. 2 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are extracted to give a deep green solution. (a) (i) Draw a labelled diagram to describe how you could show that there is more than one coloured pigment in the green solution. [3] (ii) Given a pure sample of chlorophyll, how could you show that the green solution from the grass contained chlorophyll? [2] (b) Explain the role of chlorophyll in green plants. [3] [Total: 8]
  • 20. 3 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use 2 The results of experiments on electrolysis using inert electrodes are given in the table. Complete the table; the first line has been completed as an example. electrolyte change at negative electrode change at positive electrode change to electrolyte molten lead(II) bromide lead formed bromine formed used up lithium formed chlorine formed used up dilute aqueous sodium chloride aqueous copper(II) sulfate hydrogen formed bromine formed potassium hydroxide formed [Total: 8]
  • 21. 4 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 3 The following is a list of the electron distributions of atoms of unknown elements. element electron distribution A 2,6 B 2,8,4 C 2,8,8,2 D 2,8,18,8 E 2,8,18,8,1 F 2,8,18,18,7 (a) Choose an element from the list for each of the following descriptions. (i) It is a noble gas. (ii) It is a soft metal with a low density. (iii) It can form a covalent compound with element A. (iv) It has a giant covalent structure similar to diamond. (v) It is a diatomic gas with molecules of the type X2. [5] (b) Elements C and A can form an ionic compound. (i) Draw a diagram that shows the formula of this compound, the charges on the ions and the arrangement of the valency electrons around the negative ion. Use o to represent an electron from an atom of C. Use x to represent an electron from an atom of A. [3] (ii) Predict two properties of this compound. [2] [Total: 10]
  • 22. 5 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use 4 The reactivity series of metals given below contains both familiar and unfamiliar elements. For most of the unfamiliar elements, which are marked *, their common oxidation states are given. * barium Ba * lanthanum La (+3) magnesium zinc * chromium Cr (+2), (+3), (+6) iron copper * palladium (+2) Choose metal(s) from the above list to answer the following questions. (i) Which two metals would not react with dilute hydrochloric acid? [2] (ii) Which two unfamiliar metals (*) would react with cold water? [2] (iii) What is the oxidation state of barium? [1] (iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon. [1] (v) Why should you be able to predict that metals such as iron and chromium have more than one oxidation state? [1] [Total: 7]
  • 23. 6 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 5 Insoluble salts are made by precipitation. (a) A preparation of the insoluble salt iron fluoride is described below. To 15 cm3 of aqueous iron(III) chloride, 45 cm3 of aqueous sodium fluoride is added. The concentration of both solutions is 1.00 mol / dm3 . The mixture is filtered and the precipitate washed with distilled water. Finally, the precipitate is heated in an oven. (i) Complete the equation. Fe3+ + ...…….F- ………...... [2] (ii) Why is the volume of sodium fluoride solution three times that of the iron(III) chloride solution? [1] (iii) Why is the mixture washed with distilled water? [1] (iv) Why is the solid heated? [1]
  • 24. 7 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use 16 12 8 4 0 0 2 4 6 8 10 12 14 volume of phosphate solution/cm3 height of precipitate /mm (b) The formulae of insoluble compounds can be found by precipitation reactions. To 18.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of aqueous sodium phosphate, Na3PO4. The concentration of both solutions was 1.00mol/dm3 . When the precipitate had settled, its height was measured. solution height of precipitate precipitate of the phosphate of metal T The experiment was repeated using different volumes of the phosphate solution. The results are shown on the following graph. What is the formula of the phosphate of metal T? Give your reasoning. [3] [Total: 8]
  • 25. 8 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 6 Ammonia is manufactured by the Haber process. N2(g) + 3H2(g) 2NH3(g) the forward reaction is exothermic (a) (i) Name the raw materials from which nitrogen and hydrogen are obtained. nitrogen from [1] hydrogen from [1] (ii) Name the catalyst used in this process. [1] (iii) What is the most important use of ammonia? [1] (b) The following graph shows how the percentage of ammonia in the equilibrium mixture changes with pressure. 0 0 % ammonia at equilibrium pressure (i) Explain the term equilibrium. [2] (ii) How does the percentage of ammonia vary with pressure? [1]
  • 26. 9 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use (c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium mixture varies with temperature. 0 0 % ammonia at equilibrium temperature [1] (ii) Explain why the graph has the shape shown. [2] [Total: 10]
  • 27. 10 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 7 Hydrogen reacts with the halogens to form hydrogen halides. (a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to break one mole of a bond. bond bond energy in kJ/mol H─H +436 F─F +158 H─F +562 Use the above data to show that the following reaction is exothermic. H─H + F─F 2H─F [3]
  • 28. 11 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use (b) They react with water to form acidic solutions. HCl + H2O H3O+ + Cl- HF + H2O H3O+ + F- (i) Explain why water behaves as a base in both of these reactions. [2] (ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as molecules, only 3% has formed ions. What does this tell you about the strength of each acid? [2] (iii) How would the pH of these two solutions differ? [1] [Total: 8]
  • 29. 12 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 8 Lactic acid can be made from corn starch. CH3 CH COOH OH lactic acid It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable. (a) Suggest two advantages that PLA has compared with a polymer made from petroleum. [2] (b) The structure of PLA is given below. CH3 O CHO C CH3 O CH (i) What type of compound contains the group that is circled? [1] (ii) Complete the following sentence. Lactic acid molecules can form this group because they contain both an group and an group. [2] (iii) Is the formation of PLA, an addition or condensation polymerisation? Give a reason for your choice. [2]
  • 30. 13 © UCLES 2009 0620/32/M/J/09 [Turn over For Examiner's Use (c) When lactic acid is heated, acrylic acid is formed. C C COOH OH H H H H lactic acid acrylic acid C C H H H COOH (i) Complete the word equation for the action of heat on lactic acid. lactic acid → + [1] (ii) Describe a test that would distinguish between lactic acid and acrylic acid. test result for lactic acid result for acrylic acid [3] (iii) Describe a test, other than using an indicator, which would show that both chemicals contain an acid group. test result [2] [Total: 13]
  • 31. 14 © UCLES 2009 0620/32/M/J/09 For Examiner's Use 9 Quantities of chemicals, expressed in moles, can be used to find the formula of a compound, to establish an equation and to determine reacting masses. (a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical formula? [2] (b) A compound contains only aluminium and carbon. 0.03moles of this compound reacted with excess water to form 0.12moles of Al(OH)3 and 0.09moles of CH4. Write a balanced equation for this reaction. [2] (c) 0.08moles of silicon reacts with 7.2g of fluorine. Si + 2F2 SiF4 (i) Which one is the limiting reagent? Explain your choice. [3] (ii) How many moles of SiF4 are formed? [1] [Total: 8]
  • 33. 16 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge. © UCLES 2009 0620/32/M/J/09 Group 140 Ce Cerium 58 141 Pr Praseodymium 59 144 Nd Neodymium 60 Pm Promethium 61 150 Sm Samarium 62 152 Eu Europium 63 157 Gd Gadolinium 64 159 Tb Terbium 65 162 Dy Dysprosium 66 165 Ho Holmium 67 167 Er Erbium 68 169 Tm Thulium 69 173 Yb Ytterbium 70 175 Lu Lutetium 71 232 Th Thorium 90 Pa Protactinium 91 238 U Uranium 92 Np Neptunium 93 Pu Plutonium 94 Am Americium 95 Cm Curium 96 Bk Berkelium 97 Cf Californium 98 Es Einsteinium 99 Fm Fermium 100 Md Mendelevium 101 No Nobelium 102 Lr Lawrencium 103 1 H Hydrogen 1 7 Li Lithium 3 23 Na Sodium 11 24 Mg Magnesium 12 40 Ca Calcium 20 45 Sc Scandium 21 48 Ti Titanium 22 51 V Vanadium 23 52 Cr Chromium 24 55 Mn Manganese 25 56 Fe Iron 26 59 Co Cobalt 27 59 Ni Nickel 28 64 Cu Copper 29 65 Zn Zinc 30 70 Ga Gallium 31 27 Al Aluminium 13 11 B Boron 5 12 C Carbon 6 14 N Nitrogen 7 16 O Oxygen 8 19 F Fluorine 9 28 Si Silicon 14 31 P Phosphorus 15 32 S Sulfur 16 35.5 Cl Chlorine 17 40 Ar Argon 18 20 Ne Neon 10 4 He Helium 2 73 Ge Germanium 32 75 As Arsenic 33 79 Se Selenium 34 80 Br Bromine 35 84 Kr Krypton 36 39 K Potassium 19 88 Sr Strontium 38 89 Y Yttrium 39 91 Zr Zirconium 40 93 Nb Niobium 41 96 Mo Molybdenum 42 Tc Technetium 43 101 Ru Ruthenium 44 103 Rh Rhodium 45 106 Pd Palladium 46 108 Ag Silver 47 112 Cd Cadmium 48 115 In Indium 49 119 Sn Tin 50 122 Sb Antimony 51 128 Te Tellurium 52 127 I Iodine 53 131 Xe Xenon 54 137 Ba Barium 56 139 La Lanthanum 57* 178 Hf Hafnium 72 181 Ta Tantalum 73 184 W Tungsten 74 186 Re Rhenium 75 190 Os Osmium 76 192 Ir Iridium 77 195 Pt Platinum 78 197 Au Gold 79 201 Hg Mercury 80 204 Tl Thallium 81 207 Pb Lead 82 209 Bi Bismuth 83 Po Polonium 84 At Astatine 85 Rn Radon 86 Fr Francium 87 227 Ac Actinium 89 9 Be Beryllium 4 IIIIIIIVVVIVII0 85 Rb Rubidium 37 133 Cs Caesium 55 226 Ra Radium 88 Thevolumeofonemoleofanygasis24dm3atroomtemperatureandpressure(r.t.p.). a X b a=relativeatomicmass X=atomicsymbol b=proton(atomic)number Key *58-71Lanthanoidseries 90-103Actinoidseries DATASHEET ThePeriodicTableoftheElements