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Methods of Separating Mixtures 
• Magnet 
• Filter 
• Decant 
• Evaporation 
• Centrifuge 
• Chromatography 
• Distillation 
ebooks.edhole.com
Filtration 
separates 
a liquid 
from a 
solid 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 40 
Mixture of 
solid and 
liquid Stirring 
rod 
Filtrate (liquid 
component 
of the mixture) 
Funnel 
Filter paper 
traps solid 
ebooks.edhole.com
ebooks.edhole.com
Chromatography 
• Tie-dye t-shirt 
• Black pen ink 
• DNA testing 
– Tomb of Unknown Soldiers 
– Crime scene 
– Paternity testing 
ebooks.edhole.com
Paper Chromatography 
ebooks.edhole.com
Separation by Chromatography 
sample 
mixture 
a chromatographic column 
stationary phase 
selectively absorbs 
components 
mobile phase 
sweeps sample 
down column 
detector 
ebooks.edhole.com 
http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
Separation by Chromatography 
sample 
mixture 
a chromatographic column 
stationary phase 
selectively absorbs 
components 
mobile phase 
sweeps sample 
down column 
detector 
ebooks.edhole.com 
http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
Ion chromatogram of orange juice 
response 0 5 10 15 20 25 
detector 
Na+ 
time (minutes) K+ 
Mg2+ Fe3+ 
Ca2+ 
ebooks.edhole.com
Setup to heat a solution 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 42 
Ring stand 
Beaker 
Wire gauze 
Ring 
Bunsen burner 
ebooks.edhole.com
A Hero’s Fountain Glass retort 
long spout helps 
vapors to condense 
mixture for distillation 
placed in here 
Furnace 
Eyewitness Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 13 ebooks.edhole.com
A Distillation Apparatus 
liquid with a solid 
dissolved in it 
thermometer 
condenser 
tube 
distilling 
flask 
pure 
liquid 
receiving 
hose connected to flask 
Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 282 cold water faucet ebooks.edhole.com
The solution is boiled and steam 
is driven off. 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 39 ebooks.edhole.com
Salt remains after all water is 
boiled off. 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 39 ebooks.edhole.com
No chemical change occurs 
when salt water is distilled. 
Saltwater solution 
(homogeneous mixture) 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 40 
Distillation 
(physical method) 
Salt 
Pure water 
ebooks.edhole.com
Separation of a sand-saltwater 
mixture. 
ebooks.edhole.com 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 40
Separation of Sand from Salt 
1. Gently break up your salt-crusted sand with a plastic spoon. 
Follow this flowchart to make a complete separation. 
Salt-crusted 
sand. 
Pour into 
heat-resistant 
container. 
Dry 
sand. 
Wet 
sand. 
Weigh the 
mixture. 
Decant 
clear 
liquid. 
Evaporate 
to 
dryness. 
Fill with 
water. 
Stir and let 
settle 1 
minute. 
Weigh 
sand. 
Calculate 
weight of 
salt. 
No 
Repeat 
Yes 3 times? 
2. How does this flow 
chart insure a complete 
separation? 
ebooks.edhole.com
Four-stroke Internal 
Combustion Engine 
ebooks.edhole.com
Different Types of Fuel Combustion 
Gasoline (octane) 
2 C8H18 + 25 O2  16 CO2 + 18 H2O 
Methanol (in racing fuel) 
__CH3OH +__O2 __CO2 +__H2O 
ebooks.edhole.com
Combustion Chamber 
-The combustion chamber is the area where compression and 
combustion take place. 
-Gasoline and air must be mixed in the correct ratio. 
ebooks.edhole.com
The Advantages of Methanol - 
Burning Engines 
•Methanol can run at much higher compression ratios, 
meaning that you can get more power from the engine on 
each piston stroke. 
•Methanol provides significant cooling when it evaporates in 
the cylinder, helping to keep the high-revving, high-compression 
engine from overheating. 
•Methanol, unlike gasoline, can be extinguished with water if 
there is a fire. This is an important safety feature. 
•The ignition temperature for methanol (the temperature at 
which it starts burning) is much higher than that for gasoline, 
so the risk of an accidental fire is lower. 
ebooks.edhole.com
A Race Car - Basic Information 
•At 900 hp, it has about two to three times the horsepower of a "high-performance" 
automotive engine. For example, Corvettes or Vipers 
might have 350- to 400-horsepower engines. 
•At 15,000 rpm, it runs at about twice the rpm of a normal automotive 
engine. Compared to a normal engine, an methanol engine has larger 
pistons and the pistons travel a shorter distance up and down on each 
stroke. 
•The motor is lighter. This lowers their inertia and is another factor in the 
high rpm. 
ebooks.edhole.com
Centrifugation 
• Spin sample very rapidly: 
denser materials go to 
bottom (outside) 
• Separate blood into serum 
and plasma 
– Serum (clear) 
– Plasma (contains red blood 
cells ‘RBCs’) 
• Check for anemia (lack of iron) 
Before 
Blood 
AFTER 
Serum 
RBC’s 
A B C 
ebooks.edhole.com
Water Molecules 
ebooks.edhole.com 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 8
The decomposition of two water 
molecules. 
Electric 
current 
Water 
molecules 
Diatomic Diatomic 
oxygen molecule + hydrogen molecules 
2 H2O  O2 + 2 H2 
ebooks.edhole.com
Electrolysis 
“electro” = electricity 
“lysis” = to split 
*H1+ 
water oxygen hydrogen 
*Must add acid catalyst 
to conduct electricity 
Zumdahl, Zumdahl, DeCoste, World of Chemistry  2002, page 32 
Water 
Hydrogen 
gas forms 
Oxygen 
gas forms 
Source of Electrode 
direct current 
H2O(l) O2 (g) + 2 H2 (g) 
ebooks.edhole.com
Electrolysis of Water 
Half reaction at the cathode (reduction): 
4 H2O + 4 e -  2 H2 + 4 OH 1- 
Half reaction at the anode (oxidation): 
2 H2O  O2 + 4 H 1+ + 4 e - 
hydrogen 
gas 
cathode 
oxygen 
gas 
anode 
D.C. power 
source 
water 
ebooks.edhole.com
RReevviieewwiinngg CCoonncceeppttss 
Physical Properties 
• List seven examples of physical 
properties. 
• Describe three uses of physical properties. 
• Name two processes that are used to 
separate mixtures. 
• When you describe a liquid as thick, are 
you saying that it has a high or low 
viscosity? 
ebooks.edhole.com
RReevviieewwiinngg CCoonncceeppttss 
Physical Properties 
• Explain why sharpening a pencil is an 
example of a physical change. 
• What allows a mixture to be separated by 
distillation? 
ebooks.edhole.com
RReevviieewwiinngg CCoonncceeppttss 
Chemical Properties 
• Under what conditions can chemical 
properties be observed? 
• List three common types of evidence for a 
chemical change. 
• How do chemical changes differ from 
physical changes? 
ebooks.edhole.com
RReevviieewwiinngg CCoonncceeppttss 
Chemical Properties 
• Explain why the rusting of an iron bar 
decreases the strength of the bar. 
• A pat of butter melts and then burns in a 
hot frying pan. Which of these changes is 
physical and which is chemical? 
ebooks.edhole.com

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Free ebooks download

  • 1. Free Ebooks download By: ebooks.edhole.com
  • 2. Methods of Separating Mixtures • Magnet • Filter • Decant • Evaporation • Centrifuge • Chromatography • Distillation ebooks.edhole.com
  • 3. Filtration separates a liquid from a solid Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40 Mixture of solid and liquid Stirring rod Filtrate (liquid component of the mixture) Funnel Filter paper traps solid ebooks.edhole.com
  • 5. Chromatography • Tie-dye t-shirt • Black pen ink • DNA testing – Tomb of Unknown Soldiers – Crime scene – Paternity testing ebooks.edhole.com
  • 7. Separation by Chromatography sample mixture a chromatographic column stationary phase selectively absorbs components mobile phase sweeps sample down column detector ebooks.edhole.com http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
  • 8. Separation by Chromatography sample mixture a chromatographic column stationary phase selectively absorbs components mobile phase sweeps sample down column detector ebooks.edhole.com http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
  • 9. Ion chromatogram of orange juice response 0 5 10 15 20 25 detector Na+ time (minutes) K+ Mg2+ Fe3+ Ca2+ ebooks.edhole.com
  • 10. Setup to heat a solution Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 42 Ring stand Beaker Wire gauze Ring Bunsen burner ebooks.edhole.com
  • 11. A Hero’s Fountain Glass retort long spout helps vapors to condense mixture for distillation placed in here Furnace Eyewitness Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 13 ebooks.edhole.com
  • 12. A Distillation Apparatus liquid with a solid dissolved in it thermometer condenser tube distilling flask pure liquid receiving hose connected to flask Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 282 cold water faucet ebooks.edhole.com
  • 13. The solution is boiled and steam is driven off. Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 39 ebooks.edhole.com
  • 14. Salt remains after all water is boiled off. Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 39 ebooks.edhole.com
  • 15. No chemical change occurs when salt water is distilled. Saltwater solution (homogeneous mixture) Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40 Distillation (physical method) Salt Pure water ebooks.edhole.com
  • 16. Separation of a sand-saltwater mixture. ebooks.edhole.com Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40
  • 17. Separation of Sand from Salt 1. Gently break up your salt-crusted sand with a plastic spoon. Follow this flowchart to make a complete separation. Salt-crusted sand. Pour into heat-resistant container. Dry sand. Wet sand. Weigh the mixture. Decant clear liquid. Evaporate to dryness. Fill with water. Stir and let settle 1 minute. Weigh sand. Calculate weight of salt. No Repeat Yes 3 times? 2. How does this flow chart insure a complete separation? ebooks.edhole.com
  • 18. Four-stroke Internal Combustion Engine ebooks.edhole.com
  • 19. Different Types of Fuel Combustion Gasoline (octane) 2 C8H18 + 25 O2  16 CO2 + 18 H2O Methanol (in racing fuel) __CH3OH +__O2 __CO2 +__H2O ebooks.edhole.com
  • 20. Combustion Chamber -The combustion chamber is the area where compression and combustion take place. -Gasoline and air must be mixed in the correct ratio. ebooks.edhole.com
  • 21. The Advantages of Methanol - Burning Engines •Methanol can run at much higher compression ratios, meaning that you can get more power from the engine on each piston stroke. •Methanol provides significant cooling when it evaporates in the cylinder, helping to keep the high-revving, high-compression engine from overheating. •Methanol, unlike gasoline, can be extinguished with water if there is a fire. This is an important safety feature. •The ignition temperature for methanol (the temperature at which it starts burning) is much higher than that for gasoline, so the risk of an accidental fire is lower. ebooks.edhole.com
  • 22. A Race Car - Basic Information •At 900 hp, it has about two to three times the horsepower of a "high-performance" automotive engine. For example, Corvettes or Vipers might have 350- to 400-horsepower engines. •At 15,000 rpm, it runs at about twice the rpm of a normal automotive engine. Compared to a normal engine, an methanol engine has larger pistons and the pistons travel a shorter distance up and down on each stroke. •The motor is lighter. This lowers their inertia and is another factor in the high rpm. ebooks.edhole.com
  • 23. Centrifugation • Spin sample very rapidly: denser materials go to bottom (outside) • Separate blood into serum and plasma – Serum (clear) – Plasma (contains red blood cells ‘RBCs’) • Check for anemia (lack of iron) Before Blood AFTER Serum RBC’s A B C ebooks.edhole.com
  • 24. Water Molecules ebooks.edhole.com Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 8
  • 25. The decomposition of two water molecules. Electric current Water molecules Diatomic Diatomic oxygen molecule + hydrogen molecules 2 H2O  O2 + 2 H2 ebooks.edhole.com
  • 26. Electrolysis “electro” = electricity “lysis” = to split *H1+ water oxygen hydrogen *Must add acid catalyst to conduct electricity Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 32 Water Hydrogen gas forms Oxygen gas forms Source of Electrode direct current H2O(l) O2 (g) + 2 H2 (g) ebooks.edhole.com
  • 27. Electrolysis of Water Half reaction at the cathode (reduction): 4 H2O + 4 e -  2 H2 + 4 OH 1- Half reaction at the anode (oxidation): 2 H2O  O2 + 4 H 1+ + 4 e - hydrogen gas cathode oxygen gas anode D.C. power source water ebooks.edhole.com
  • 28. RReevviieewwiinngg CCoonncceeppttss Physical Properties • List seven examples of physical properties. • Describe three uses of physical properties. • Name two processes that are used to separate mixtures. • When you describe a liquid as thick, are you saying that it has a high or low viscosity? ebooks.edhole.com
  • 29. RReevviieewwiinngg CCoonncceeppttss Physical Properties • Explain why sharpening a pencil is an example of a physical change. • What allows a mixture to be separated by distillation? ebooks.edhole.com
  • 30. RReevviieewwiinngg CCoonncceeppttss Chemical Properties • Under what conditions can chemical properties be observed? • List three common types of evidence for a chemical change. • How do chemical changes differ from physical changes? ebooks.edhole.com
  • 31. RReevviieewwiinngg CCoonncceeppttss Chemical Properties • Explain why the rusting of an iron bar decreases the strength of the bar. • A pat of butter melts and then burns in a hot frying pan. Which of these changes is physical and which is chemical? ebooks.edhole.com

Editor's Notes

  1. http://www.moe.gov.sg/edumall/tl/digital_resources/chemistry/images/paper_chromatography.jpg
  2. http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
  3. http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
  4. http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld009.htm
  5. Distillation is a process of boiling a liquid and condensing and collecting the vapor. The liquid collected is the distillate. The usual purpose of distillation is purification or separation of the components of a mixture. This is possible because the composition of the vapor is usually different from that of liquid mixture from which it is obtained. Gasoline, kerosene, fuel oil, and lubricating oil are produced from petroleum by distillation.
  6. “A Distillation Apparatus”   Description: This transparency shows an apparatus used for laboratory distillations.   Basic Concepts The separation of substances by distillation occurs because the boiling point of the substances differ. The substance with the lowest boiling point boils away first. Distillation is based on the principle that a substance will change from a liquid to a vapor during heating and from a vapor back to a liquid while cooling.   Teaching Strategies Use this slide to explain to students how a distillation apparatus is used to purify liquids and to separate the components of liquid mixtures. Begin by reviewing the phases of matter, stressing the processes of evaporation and condensation. Remind students that different liquids have different boiling points. Point out that substances that are solids at room temperature usually have higher boiling points than do substances that are liquids at room temperature.   Questions If the distilling flask shown in the diagram were open to the air (rather than being connected to the condensor), what would happen to each component of the mixture in the flask as boiling continued? Explain your answer to question 1 in terms of the boiling points of the liquid and the dissolved solid. In the distillation apparatus, the vaporized liquid must enter the condenser. The condenser consists of a long tube within another tube (the jacket). The substance in the central tube and the jacket cannot mix. Cold water enters at the bottom of the jacket and exits at the top. What is the function of the condenser jacket? How would changing the length of the condenser jacket affect how well it performs this function? Explain why the liquid entering the receiving flask is pure. To separate a mixture of methanol and water, you set up a distillation apparatus and heat the mixture to the boiling point of methanol, 65 oC. What substance would you expect to collect at the receiving flask? When you finish the experiment, you discover that the substance in the receiving flask is not pure. It still contains both water and methanol. Can you explain why? (Hint: Think about vapor pressures.) Before automobiles were invented, crude petroleum was used mainly as a source of kerosene. The petroleum was heated in a device called a still. Gasoline, then considered to be useless, evaporated first into the air. Kerosene boiled off next and was condensed and collected. A tar-like residue remained in the still. From this information, what can you deduce about the boiling points of gasoline, kerosene, and the residue? How will you know when all of one component has been separated?  
  7. This demonstration needs to be done using DC current (to produce a 2:1 H:O ratio). Use of AC current will produce equal amounts of hydrogen and oxygen gas.
  8. Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51 Viscosity, conductivity, malleability, hardness, melting point, boiling point, and density are examples of physical properties. Physical properties are used to identify a material, to choose a material for a specific purpose, or to separate the substances in a mixture. Filtration and distillation are two common separation methods.
  9. Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51 Viscosity, conductivity, malleability, hardness, melting point, boiling point, and density are examples of physical properties. Physical properties are used to identify a material, to choose a material for a specific purpose, or to separate the substances in a mixture. Filtration and distillation are two common separation methods. http://www.wikihow.com/images/thumb/e/eb/Sharpener-small.jpg/180px-Sharpener-small.jpg
  10. Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51 Chemical properties can be observed only when the substance in a sample of matter are changing into different substances. Three common types of evidence for a chemical change are a change in color, the production of a gas, and the formation of a precipitate. When matter undergoes a chemical change, the composition of the matter changes. When matter undergoes a physical change, the composition of the matter remains the same.
  11. Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51 Chemical properties can be observed only when the substance in a sample of matter are changing into different substances. Three common types of evidence for a chemical change are a change in color, the production of a gas, and the formation of a precipitate. When matter undergoes a chemical change, the composition of the matter changes. When matter undergoes a physical change, the composition of the matter remains the same. http://content.answers.com/main/content/wp/en-commons/thumb/9/9e/225px-Rust03102006.JPG http://justhungry.com/images/butter-sizzing.jpg