3. Filtration
separates
a liquid
from a
solid
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40
Mixture of
solid and
liquid Stirring
rod
Filtrate (liquid
component
of the mixture)
Funnel
Filter paper
traps solid
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7. Separation by Chromatography
sample
mixture
a chromatographic column
stationary phase
selectively absorbs
components
mobile phase
sweeps sample
down column
detector
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http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
8. Separation by Chromatography
sample
mixture
a chromatographic column
stationary phase
selectively absorbs
components
mobile phase
sweeps sample
down column
detector
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http://antoine.frostburg.edu/chem/senese/101/matter/slides/sld006.htm
9. Ion chromatogram of orange juice
response 0 5 10 15 20 25
detector
Na+
time (minutes) K+
Mg2+ Fe3+
Ca2+
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10. Setup to heat a solution
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 42
Ring stand
Beaker
Wire gauze
Ring
Bunsen burner
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11. A Hero’s Fountain Glass retort
long spout helps
vapors to condense
mixture for distillation
placed in here
Furnace
Eyewitness Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 13 ebooks.edhole.com
12. A Distillation Apparatus
liquid with a solid
dissolved in it
thermometer
condenser
tube
distilling
flask
pure
liquid
receiving
hose connected to flask
Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 282 cold water faucet ebooks.edhole.com
13. The solution is boiled and steam
is driven off.
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 39 ebooks.edhole.com
14. Salt remains after all water is
boiled off.
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 39 ebooks.edhole.com
15. No chemical change occurs
when salt water is distilled.
Saltwater solution
(homogeneous mixture)
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40
Distillation
(physical method)
Salt
Pure water
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16. Separation of a sand-saltwater
mixture.
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Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40
17. Separation of Sand from Salt
1. Gently break up your salt-crusted sand with a plastic spoon.
Follow this flowchart to make a complete separation.
Salt-crusted
sand.
Pour into
heat-resistant
container.
Dry
sand.
Wet
sand.
Weigh the
mixture.
Decant
clear
liquid.
Evaporate
to
dryness.
Fill with
water.
Stir and let
settle 1
minute.
Weigh
sand.
Calculate
weight of
salt.
No
Repeat
Yes 3 times?
2. How does this flow
chart insure a complete
separation?
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19. Different Types of Fuel Combustion
Gasoline (octane)
2 C8H18 + 25 O2 16 CO2 + 18 H2O
Methanol (in racing fuel)
__CH3OH +__O2 __CO2 +__H2O
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20. Combustion Chamber
-The combustion chamber is the area where compression and
combustion take place.
-Gasoline and air must be mixed in the correct ratio.
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21. The Advantages of Methanol -
Burning Engines
•Methanol can run at much higher compression ratios,
meaning that you can get more power from the engine on
each piston stroke.
•Methanol provides significant cooling when it evaporates in
the cylinder, helping to keep the high-revving, high-compression
engine from overheating.
•Methanol, unlike gasoline, can be extinguished with water if
there is a fire. This is an important safety feature.
•The ignition temperature for methanol (the temperature at
which it starts burning) is much higher than that for gasoline,
so the risk of an accidental fire is lower.
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22. A Race Car - Basic Information
•At 900 hp, it has about two to three times the horsepower of a "high-performance"
automotive engine. For example, Corvettes or Vipers
might have 350- to 400-horsepower engines.
•At 15,000 rpm, it runs at about twice the rpm of a normal automotive
engine. Compared to a normal engine, an methanol engine has larger
pistons and the pistons travel a shorter distance up and down on each
stroke.
•The motor is lighter. This lowers their inertia and is another factor in the
high rpm.
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23. Centrifugation
• Spin sample very rapidly:
denser materials go to
bottom (outside)
• Separate blood into serum
and plasma
– Serum (clear)
– Plasma (contains red blood
cells ‘RBCs’)
• Check for anemia (lack of iron)
Before
Blood
AFTER
Serum
RBC’s
A B C
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25. The decomposition of two water
molecules.
Electric
current
Water
molecules
Diatomic Diatomic
oxygen molecule + hydrogen molecules
2 H2O O2 + 2 H2
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26. Electrolysis
“electro” = electricity
“lysis” = to split
*H1+
water oxygen hydrogen
*Must add acid catalyst
to conduct electricity
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 32
Water
Hydrogen
gas forms
Oxygen
gas forms
Source of Electrode
direct current
H2O(l) O2 (g) + 2 H2 (g)
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27. Electrolysis of Water
Half reaction at the cathode (reduction):
4 H2O + 4 e - 2 H2 + 4 OH 1-
Half reaction at the anode (oxidation):
2 H2O O2 + 4 H 1+ + 4 e -
hydrogen
gas
cathode
oxygen
gas
anode
D.C. power
source
water
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28. RReevviieewwiinngg CCoonncceeppttss
Physical Properties
• List seven examples of physical
properties.
• Describe three uses of physical properties.
• Name two processes that are used to
separate mixtures.
• When you describe a liquid as thick, are
you saying that it has a high or low
viscosity?
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29. RReevviieewwiinngg CCoonncceeppttss
Physical Properties
• Explain why sharpening a pencil is an
example of a physical change.
• What allows a mixture to be separated by
distillation?
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30. RReevviieewwiinngg CCoonncceeppttss
Chemical Properties
• Under what conditions can chemical
properties be observed?
• List three common types of evidence for a
chemical change.
• How do chemical changes differ from
physical changes?
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31. RReevviieewwiinngg CCoonncceeppttss
Chemical Properties
• Explain why the rusting of an iron bar
decreases the strength of the bar.
• A pat of butter melts and then burns in a
hot frying pan. Which of these changes is
physical and which is chemical?
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Distillation is a process of boiling a liquid and condensing and collecting the vapor. The liquid collected is the distillate. The usual purpose of distillation is purification or separation of the components of a mixture. This is possible because the composition of the vapor is usually different from that of liquid mixture from which it is obtained. Gasoline, kerosene, fuel oil, and lubricating oil are produced from petroleum by distillation.
“A Distillation Apparatus”
Description: This transparency shows an apparatus used for laboratory distillations.
Basic Concepts
The separation of substances by distillation occurs because the boiling point of the substances differ. The substance with the lowest boiling point boils away first.
Distillation is based on the principle that a substance will change from a liquid to a vapor during heating and from a vapor back to a liquid while cooling.
Teaching Strategies
Use this slide to explain to students how a distillation apparatus is used to purify liquids and to separate the components of liquid mixtures. Begin by reviewing the phases of matter, stressing the processes of evaporation and condensation. Remind students that different liquids have different boiling points. Point out that substances that are solids at room temperature usually have higher boiling points than do substances that are liquids at room temperature.
Questions
If the distilling flask shown in the diagram were open to the air (rather than being connected to the condensor), what would happen to each component of the mixture in the flask as boiling continued?
Explain your answer to question 1 in terms of the boiling points of the liquid and the dissolved solid.
In the distillation apparatus, the vaporized liquid must enter the condenser. The condenser consists of a long tube within another tube (the jacket). The substance in the central tube and the jacket cannot mix. Cold water enters at the bottom of the jacket and exits at the top.
What is the function of the condenser jacket?
How would changing the length of the condenser jacket affect how well it performs this function?
Explain why the liquid entering the receiving flask is pure.
To separate a mixture of methanol and water, you set up a distillation apparatus and heat the mixture to the boiling point of methanol, 65 oC.
What substance would you expect to collect at the receiving flask?
When you finish the experiment, you discover that the substance in the receiving flask is not pure. It still contains both water and methanol. Can you explain why? (Hint: Think about vapor pressures.)
Before automobiles were invented, crude petroleum was used mainly as a source of kerosene. The petroleum was heated in a device called a still. Gasoline, then considered to be useless, evaporated first into the air. Kerosene boiled off next and was condensed and collected. A tar-like residue remained in the still. From this information, what can you deduce about the boiling points of gasoline, kerosene, and the residue?
How will you know when all of one component has been separated?
This demonstration needs to be done using DC current (to produce a 2:1 H:O ratio).
Use of AC current will produce equal amounts of hydrogen and oxygen gas.
Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51
Viscosity, conductivity, malleability, hardness, melting point, boiling point, and density are examples of physical properties.
Physical properties are used to identify a material, to choose a material for a specific purpose, or to separate the substances in a mixture.
Filtration and distillation are two common separation methods.
Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51
Viscosity, conductivity, malleability, hardness, melting point, boiling point, and density are examples of physical properties.
Physical properties are used to identify a material, to choose a material for a specific purpose, or to separate the substances in a mixture.
Filtration and distillation are two common separation methods.
http://www.wikihow.com/images/thumb/e/eb/Sharpener-small.jpg/180px-Sharpener-small.jpg
Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51
Chemical properties can be observed only when the substance in a sample of matter are changing into different substances.
Three common types of evidence for a chemical change are a change in color, the production of a gas, and the formation of a precipitate.
When matter undergoes a chemical change, the composition of the matter changes. When matter undergoes a physical change, the composition of the matter remains the same.
Prentice Hall Physical Science Concepts in Action (Wysession, Frank, Yancopoulos) 2004 pg 51
Chemical properties can be observed only when the substance in a sample of matter are changing into different substances.
Three common types of evidence for a chemical change are a change in color, the production of a gas, and the formation of a precipitate.
When matter undergoes a chemical change, the composition of the matter changes. When matter undergoes a physical change, the composition of the matter remains the same.
http://content.answers.com/main/content/wp/en-commons/thumb/9/9e/225px-Rust03102006.JPG
http://justhungry.com/images/butter-sizzing.jpg