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Bellwork- concentration review
How many moles of H+ are in 250ml of 3M
HCl?
How many moles of OH- are produced when
25g of NaOH is dissolved in 250ml of
water?
What is the molarity of the NaOH solution?
Arrhenius concept
Acids make H+
Bases make OH-
The Brønsted-Lowry definition
of
ACIDS AND BASES
Acids donate protons (H+)
HCl  H+ + Cl-
Bases accept protons (H+)
NH3 + H+  NH4
+
The Bronsted- Lowry model is more
inclusive than the Arrhenius model.
NH3 + H+  NH4
+
Ammonia is a Bronsted-Lowry
base, but does not dissociate to
make OH-
Why Ammonia is a
Base
A-
HA + H2O 
Acid base
H3O+ +
conjugate
acid
conjugate
base
An acid donates a proton forming its
conjugate base. HA  A-
A base accepts a proton forming its
conjugate acid. NH3  NH4
+
HA  A-
• Acid conjugate base
• A- is ready to accept a proton, it is a base.
• NH3 + H+  NH4
+
• Base conjugate acid
• NH4
+ has a proton to donate. It is an acid.
Conjugate Acids and Bases
•A conjugate acid is the particle
formed when a base gains a
hydrogen ion.
•A conjugate base is the particle that
remains when an acid has donated a
hydrogen ion.
•A conjugate acid-base pair
consists of two substances related
by the loss or gain of a single
proton.
•A substance that can act as both
an acid and a base is said to be
amphoteric.
Water is amphoteric.
Water can be an acid or a base
H2O  H+ + OH-
Water can ionize and donate a
proton.
H2O  H3O+
As a base, water accepts a proton
forming the hydronium ion.
A conjugate acid-base pair consists of
two substances related to each other by
the donating and accepting of a proton
Are the following pairs conjugate acid-
base pairs?
a. H2O
b. OH-
H3O+
HNO3
c. HC2H3O2 C2H3O2
-
Brønsted-Lowry Acids and Bases
Identify conjugate acid base pairs
HCl + NH3  NH4+ + Cl-
HSO4- + OH-  H2O + SO42-
NH3 + H2O  NH4+ + OH-
Lewis Acids and Bases
Lewis definition
an acid accepts a pair of electrons
a base donates a pair of electrons.
Lewis Acids and Bases
•A Lewis acid is a substance that can
accept a pair of electrons to form a
covalent bond.
•A Lewis base is a substance that can
donate a pair of electrons to form a
covalent bond.
Animation 25 Compare the three important
definitions of acids and bases.
Lewis Acids and Bases
1. Which of the following is NOT a
characteristic of acids?
a. taste sour
b. are electrolytes
c. feel slippery
d. affect the color of indicators
19.1 Section Quiz.
1. Section Quiz.
2. Which compound is most likely to
act as an Arrhenius acid?
a. H2O
b. NH3.
c. NaOH.
d. H2SO4.
d. a pair of electrons.
1. Section Quiz.
3. A Lewis acid is any substance that
can accept
a. a hydronium ion.
b. a proton.
c. hydrogen.
The pH scale measures the
hydrogen ion
concentration[H+] of a
solution.
A pH of 7 is neutral
A pH less than 7 is acidic (litmus
red)
A pH greater than 7 is basic (litmus
blue)
The pH scale ranges from below zero (very
acidic) to above14 (very basic)
The pH scale is not linear.
The pH scale is
logarithmic. pH = -log[H+]
[H+] = 1.0 x 10-2
[H+] = 1.0 x 10-3
pH = 2
pH = 3
very acidic
acidic
A solution with pH of 2 contains 10 times
as much H+ as a solution with pH of 3.
Acidic = more H+ than OH-
Basic = more OH- than H+
From pH 0 to pH 14
the H+ concentration
decreases
100,000,000,000,000
times!!
An indicator is a valuable
tool for measuring pH
because it is a different
color in acidic solution
than when in base.
Phenolphthalein
changes from
colorless to
pink at pH
7–9.
Universal Indicators
– pH Meters
Solution Red
Litmus
Blue
Litmus
pH paper Universal
indicator
Acid,
Base,
or
neutral
?
lemon juice
(diluted)
baking soda +
H2O
Drano (NaOH)
(diluted
)
Lysol (diluted)
Vinegar

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bronsted lowry.pptx

  • 1. Bellwork- concentration review How many moles of H+ are in 250ml of 3M HCl? How many moles of OH- are produced when 25g of NaOH is dissolved in 250ml of water? What is the molarity of the NaOH solution?
  • 2. Arrhenius concept Acids make H+ Bases make OH-
  • 3. The Brønsted-Lowry definition of ACIDS AND BASES Acids donate protons (H+) HCl  H+ + Cl- Bases accept protons (H+) NH3 + H+  NH4 +
  • 4. The Bronsted- Lowry model is more inclusive than the Arrhenius model. NH3 + H+  NH4 + Ammonia is a Bronsted-Lowry base, but does not dissociate to make OH-
  • 5. Why Ammonia is a Base
  • 6. A- HA + H2O  Acid base H3O+ + conjugate acid conjugate base An acid donates a proton forming its conjugate base. HA  A- A base accepts a proton forming its conjugate acid. NH3  NH4 +
  • 7. HA  A- • Acid conjugate base • A- is ready to accept a proton, it is a base. • NH3 + H+  NH4 + • Base conjugate acid • NH4 + has a proton to donate. It is an acid.
  • 8. Conjugate Acids and Bases •A conjugate acid is the particle formed when a base gains a hydrogen ion. •A conjugate base is the particle that remains when an acid has donated a hydrogen ion.
  • 9. •A conjugate acid-base pair consists of two substances related by the loss or gain of a single proton. •A substance that can act as both an acid and a base is said to be amphoteric.
  • 10. Water is amphoteric. Water can be an acid or a base H2O  H+ + OH- Water can ionize and donate a proton. H2O  H3O+ As a base, water accepts a proton forming the hydronium ion.
  • 11. A conjugate acid-base pair consists of two substances related to each other by the donating and accepting of a proton Are the following pairs conjugate acid- base pairs? a. H2O b. OH- H3O+ HNO3 c. HC2H3O2 C2H3O2 -
  • 13. Identify conjugate acid base pairs HCl + NH3  NH4+ + Cl- HSO4- + OH-  H2O + SO42- NH3 + H2O  NH4+ + OH-
  • 14. Lewis Acids and Bases Lewis definition an acid accepts a pair of electrons a base donates a pair of electrons.
  • 15. Lewis Acids and Bases •A Lewis acid is a substance that can accept a pair of electrons to form a covalent bond. •A Lewis base is a substance that can donate a pair of electrons to form a covalent bond.
  • 16. Animation 25 Compare the three important definitions of acids and bases.
  • 18. 1. Which of the following is NOT a characteristic of acids? a. taste sour b. are electrolytes c. feel slippery d. affect the color of indicators 19.1 Section Quiz.
  • 19. 1. Section Quiz. 2. Which compound is most likely to act as an Arrhenius acid? a. H2O b. NH3. c. NaOH. d. H2SO4.
  • 20. d. a pair of electrons. 1. Section Quiz. 3. A Lewis acid is any substance that can accept a. a hydronium ion. b. a proton. c. hydrogen.
  • 21. The pH scale measures the hydrogen ion concentration[H+] of a solution. A pH of 7 is neutral
  • 22. A pH less than 7 is acidic (litmus red) A pH greater than 7 is basic (litmus blue) The pH scale ranges from below zero (very acidic) to above14 (very basic)
  • 23. The pH scale is not linear. The pH scale is logarithmic. pH = -log[H+] [H+] = 1.0 x 10-2 [H+] = 1.0 x 10-3 pH = 2 pH = 3 very acidic acidic A solution with pH of 2 contains 10 times as much H+ as a solution with pH of 3.
  • 24. Acidic = more H+ than OH- Basic = more OH- than H+
  • 25. From pH 0 to pH 14 the H+ concentration decreases 100,000,000,000,000 times!!
  • 26. An indicator is a valuable tool for measuring pH because it is a different color in acidic solution than when in base.
  • 28.
  • 31. Solution Red Litmus Blue Litmus pH paper Universal indicator Acid, Base, or neutral ? lemon juice (diluted) baking soda + H2O Drano (NaOH) (diluted ) Lysol (diluted) Vinegar