Zr2+ [Kr] 4d2 .pdf

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This document provides information on the electron configuration of the Zr2+ ion. Zr2+ has an electron configuration of [Kr] 4d2, meaning it has the same core electron configuration as the noble gas krypton and two electrons in its 4d subshell.

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The term Lewis acid refers to a definition of acid published by Gilbert N. Lewis in 1923, specifically: An acid substance is one which can employ an electron lone pair from another molecule in completing the stable group of one of its own atoms.[1] Thus, H+ is a Lewis acid, since it can accept a lone pair, completing its stable form, which requires two electrons. The modern-day definition of Lewis acid, as given by IUPAC is a molecular entity (and the corresponding chemical species) that is an electron-pair acceptor and therefore able to react with a Lewis base to form a Lewis adduct, by sharing the electron pair furnished by the Lewis base.[2] This definition is both more general and more specific—the electron pair need not be a lone pair (it could be the pair of electrons in a p bond, for example), but the reaction should give an adduct (and not just be a displacement reaction). Crystal field theory (CFT) is a model that describes the breaking of degeneracies of electronic orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colours). CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck van Vleck[1] in the 1930s. CFT was subsequently combined with molecular orbital theory to form the more realistic and complex ligand field theory (LFT), which delivers insight into the process of chemical bonding in transition metal complexes. In chemistry, valence bond (VB) theory is one of two basic theories, along with molecular orbital (MO) theory, that were developed to use the methods of quantum mechanics to explain chemical bonding. It focuses on how the atomic orbitals of the dissociated atoms combine to give individual chemical bonds when a molecule is formed. In contrast, molecular orbital theory has orbitals that cover the whole molecule. Solution The term Lewis acid refers to a definition of acid published by Gilbert N. Lewis in 1923, specifically: An acid substance is one which can employ an electron lone pair from another molecule in completing the stable group of one of its own atoms.[1] Thus, H+ is a Lewis acid, since it can accept a lone pair, completing its stable form, which requires two electrons. The modern-day definition of Lewis acid, as given by IUPAC is a molecular entity (and the corresponding chemical species) that is an electron-pair acceptor and therefore able to react with a Lewis base to form a Lewis adduct, by sharing the electron pair furnished by the Lewis base.[2] This definition is both more general and more specific—the electron pair need not be a lone pair (it could be the pair of electrons in a p bond, for example.

NHC(=O)CH3 NH2 OH .pdf

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MnO2 may act as a catalyst.in the other reaction .pdf

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What are P and R hereSolutionWhat are P and R here.pdf

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Intermolecular attractions are attractions betwee.pdf

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Intermolecular attractions are attractions between one molecule and a neighbouring molecule. The forces of attraction which hold an individual molecule together (for example, the covalent bonds) are known as intramolecular attractions. These two words are so confusingly similar that it is safer to abandon one of them and never use it. The term \"intramolecular\" won\'t be used again on this site. All molecules experience intermolecular attractions, although in some cases those attractions are very weak. Even in a gas like hydrogen, H2, if you slow the molecules down by cooling the gas, the attractions are large enough for the molecules to stick together eventually to form a liquid and then a solid. In hydrogen\'s case the attractions are so weak that the molecules have to be cooled to 21 K (-252°C) before the attractions are enough to condense the hydrogen as a liquid. Helium\'s intermolecular attractions are even weaker - the molecules won\'t stick together to form a liquid until the temperature drops to 4 K (-269°C). van der Waals forces: dispersion forces Dispersion forces (one of the two types of van der Waals force we are dealing with on this page) are also known as \"London forces\" (named after Fritz London who first suggested how they might arise). The origin of van der Waals dispersion forces Temporary fluctuating dipoles Attractions are electrical in nature. In a symmetrical molecule like hydrogen, however, there doesn\'t seem to be any electrical distortion to produce positive or negative parts. But that\'s only true on average. The lozenge-shaped diagram represents a small symmetrical molecule - H2, perhaps, or Br2. The even shading shows that on average there is no electrical distortion. But the electrons are mobile, and at any one instant they might find themselves towards one end of the molecule, making that end -. The other end will be temporarily short of electrons and so becomes +. Note: (read as \"delta\") means \"slightly\" - so + means \"slightly positive\". An instant later the electrons may well have moved up to the other end, reversing the polarity of the molecule. This constant \"sloshing around\" of the electrons in the molecule causes rapidly fluctuating dipoles even in the most symmetrical molecule. It even happens in monatomic molecules - molecules of noble gases, like helium, which consist of a single atom. If both the helium electrons happen to be on one side of the atom at the same time, the nucleus is no longer properly covered by electrons for that instant. How temporary dipoles give rise to intermolecular attractions I\'m going to use the same lozenge-shaped diagram now to represent any molecule which could, in fact, be a much more complicated shape. Shape does matter (see below), but keeping the shape simple makes it a lot easier to both draw the diagrams and understand what is going on. Imagine a molecule which has a temporary polarity being approached by one which happens to be entirely non-polar just at .

It is insoluble in water. .pdf

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Xenodiagnosis is the method used to document presesnce of a microorganism by exposing the infected tissue to a vector and than examining the vector for the presence of microorganisms. Uninfected vectors and detection of pathogen DNA in host cell will be required for xenodiagnosis. Solution Xenodiagnosis is the method used to document presesnce of a microorganism by exposing the infected tissue to a vector and than examining the vector for the presence of microorganisms. Uninfected vectors and detection of pathogen DNA in host cell will be required for xenodiagnosis..

u(x)= ( -4x)Solutionu(x)= ( -4x).pdf

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There are many more conditions than just the norms of the culture th.pdf

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The three layers of smooth muscle that includes mucosa. innermost tu.pdf

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The three layers of smooth muscle that includes mucosa. innermost tunic of a ureter; formed by transitional epithelium that is both stretchable and impermeable to the passage of urine; external to the transitional epithelium is the lamina propria, composed of dense irregular connective tissue The correct answer is 2 Solution The three layers of smooth muscle that includes mucosa. innermost tunic of a ureter; formed by transitional epithelium that is both stretchable and impermeable to the passage of urine; external to the transitional epithelium is the lamina propria, composed of dense irregular connective tissue The correct answer is 2.

The independent variable is the one which changes in each plant. Thi.pdf

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The independent variable is the one which changes in each plant. This is the concentration of the salt solution in each case.Based on the independent variable the changes seen give us the dependent variable. This is the height of the plants. The heights of the plants[dependent variable] may be influenced by the salt solutions[independent variable]. Solution The independent variable is the one which changes in each plant. This is the concentration of the salt solution in each case.Based on the independent variable the changes seen give us the dependent variable. This is the height of the plants. The heights of the plants[dependent variable] may be influenced by the salt solutions[independent variable]..

Species diversity is more in near island as rate of immigration is m.pdf

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Solution Flies do not have teeth for chewing food.So,like human f.pdf

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Solution : Flies do not have teeth for chewing food.So,like human flies have some acid in their stomach for digestion of food.But digestion of food in flies not occur in the stomach.It is occur outside of the body.Flies vomit acids present in their stomach on solid food and convert it into liquid form.Flies can intake food in liquid form only.After converting it into liquid form it is consume by the flies..

Program To change this license header, choose License Heade.pdf

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Program: /* * To change this license header, choose License Headers in Project Properties. * To change this template file, choose Tools | Templates * and open the template in the editor. */ package chegg; // A Java program for Dijkstra\'s single source shortest path algorithm. // The program is for adjacency matrix representation of the graph import java.util.*; import java.lang.*; import java.io.*; class DijkstraAlgorithem { // A utility function to find the vertex with minimum distance value, // from the set of vertices not yet included in shortest path tree static final int V=6; int minDistance(int dist[], Boolean sptSet[]) { // Initialize min value int min = Integer.MAX_VALUE, min_index=-1; for (int v = 0; v < V; v++) if (sptSet[v] == false && dist[v] <= min) { min = dist[v]; min_index = v; } return min_index; } // A utility function to print the constructed distance array void print Solution (int dist[], int n,int src) { System.out.println( \" Here Infinite=\"+Integer.MAX_VALUE); System.out.println(\" Source Vertex:\"+(src+1)); System.out.println(\"Vertex Distance from Source\"); for (int i = 0; i < V; i++) System.out.println((i+1)+\" \\t\\t \"+dist[i]); } // Funtion that implements Dijkstra\'s single source shortest path // algorithm for a graph represented using adjacency matrix // representation void dijkstra(int graph[][], int src) { int dist[] = new int[V]; // The output array. dist[i] will hold // the shortest distance from src to i // sptSet[i] will true if vertex i is included in shortest // path tree or shortest distance from src to i is finalized Boolean sptSet[] = new Boolean[V]; // Initialize all distances as INFINITE and stpSet[] as false for (int i = 0; i < V; i++) { dist[i] = Integer.MAX_VALUE; sptSet[i] = false; } // Distance of source vertex from itself is always 0 dist[src] = 0; // Find shortest path for all vertices for (int count = 0; count < V-1; count++) { // Pick the minimum distance vertex from the set of vertices // not yet processed. u is always equal to src in first // iteration. int u = minDistance(dist, sptSet); // Mark the picked vertex as processed sptSet[u] = true; // Update dist value of the adjacent vertices of the // picked vertex. for (int v = 0; v < V; v++) // Update dist[v] only if is not in sptSet, there is an // edge from u to v, and total weight of path from src to // v through u is smaller than current value of dist[v] if (!sptSet[v] && graph[u][v]!=0 && dist[u] != Integer.MAX_VALUE && dist[u]+graph[u][v] < dist[v]) dist[v] = dist[u] + graph[u][v]; } // print the constructed distance array print.

plexusFormed from anterioe rani o these spinal nervesMajor nerve.pdf

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plexus Formed from anterioe rani o these spinal nerves Major nerves formed from the plexus Cervical The cervical plexus is a plexus of the front rami of the initial four cervical spinal nerves which are situated from C1 to C4 cervical fragment in the neck. They are found along the side to the transverse procedures between prevertebral muscles from the average side and vertebral (m. scalenus, m. levator scapulae, m. splenius cervicis) from horizontal side. There is anastomosis with extra nerve, hypoglossal nerve and thoughtful trun The cervical plexus has two sorts of branches: cutaneous and strong. Cutaneous (4 branches): Incredible auricular nerve - innervates skin close concha auricle (external ear) and outer acoustic meatus (ear waterway) (C2&C3) Transverse cervical nerve - innervates front locale of neck (C2&C3) Lesser occipital - innervates the skin and the scalp posterosuperior to the auricle (C2) Supraclavicular nerves - innervate the skin above and underneath the clavicle (C3,C4) Muscular: Ansa cervicalis (circle framed from C1-C3), and so forth (geniohyoid (C1 just), thyrohyoid (C1 just), sternothyroid, sternohyoid, omohyoid) Phrenic (C3-C5 (fundamentally C4))- innervates stomach and the pericardium Segmental branches (C1-C4)- innervates front and center scalenes Brachial The brachial plexus is a system of nerves shaped by the foremost rami of the lower four cervical nerves and first thoracic nerve (C5, C6, C7, C8, and T1). This plexus stretches out from the spinal line, through the cervicoaxillary trench in the neck, over the primary rib, and into the armpit. It supplies afferent and efferent nerve strands to the mid-section, shoulder, arm and hand. The Brachial Plexus 1 Roots. 2 Trunks. 3 Divisions. 4 Cords. 5 Major Branches. 5.1 Musculocutaneous Nerve. 5.2 Axillary Nerve. 5.3 Median Nerve. 5.4 Radial Nerve. 5.5 Ulnar Nerve. 5.6 Practical Relevance: Dissecting the Brachial Plexus. 6 Minor Branches. lumbosacral The anterior divisions of the lumbar nerves, sacral nerves, and coccygeal nerve form the lumbosacral plexus, the first lumbar nerve being frequently joined by a branch from the twelfth thoracic. For descriptive purposes this plexus is usually divided into three parts: lumbar plexus sacral plexus pudendal plexus lumbar plexus sacral plexus pudendal plexus plexus Formed from anterioe rani o these spinal nerves Major nerves formed from the plexus Cervical The cervical plexus is a plexus of the front rami of the initial four cervical spinal nerves which are situated from C1 to C4 cervical fragment in the neck. They are found along the side to the transverse procedures between prevertebral muscles from the average side and vertebral (m. scalenus, m. levator scapulae, m. splenius cervicis) from horizontal side. There is anastomosis with extra nerve, hypoglossal nerve and thoughtful trun The cervical plexus has two sorts of branches: cutaneous and strong. Cutaneous (4 branches): Incredible auricular nerve - innervates skin close con.

Ok, so the number of double bond equivalents in the compound is [C4H.pdf

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Ok, so the number of double bond equivalents in the compound is [C4H10)-(C4H8)]/2 = 1 DBE 1) IR so the large trough from 3400cm-1 to 2400cm-1 as well as the peak at ~1700cm-1 indicates an acid. That accounts for 1 carbon, both oxygens, and one hydrogen. That also accounts for the one double bond equivalent. That leaves 3 carbons and 7 hydrogens. 2) NMR Methyl groups usually give proton peaks around 0.9ppm and shift further downfield when adding electron withdrawing groups nearby. It\'s a pretty good guess that the triplet at ~1.1ppm is a methyl group. The fact that it\'s a triplet indicates the carbon next to it has two protons attached to it. That gives a CH3-CH2- (as well as the -COOH group) all that\'s left now is one carbon and two hydrogens (CH2) Looking at the other two proton peaks in the nmr ... there\'s one triplet and one sextet. The triplet would be a CH2 group that is next to another CH2 group (and not anything else), so it must be a CH2 next to the COOH Now you would have two pieces: CH3-CH2- and -CH2-COOH put them together and check the coupling of the protons... you should end up with two triplets (proton split by two others), one sextet (proton split by 5 others), and a small peak somewhere around 9-13ppm. (that\'s the peak indicated by the offset of 2.0ppm on the spectrum) So the structure would be: CH3-CH2-CH2-COOH (C4H8O2) Solution Ok, so the number of double bond equivalents in the compound is [C4H10)-(C4H8)]/2 = 1 DBE 1) IR so the large trough from 3400cm-1 to 2400cm-1 as well as the peak at ~1700cm-1 indicates an acid. That accounts for 1 carbon, both oxygens, and one hydrogen. That also accounts for the one double bond equivalent. That leaves 3 carbons and 7 hydrogens. 2) NMR Methyl groups usually give proton peaks around 0.9ppm and shift further downfield when adding electron withdrawing groups nearby. It\'s a pretty good guess that the triplet at ~1.1ppm is a methyl group. The fact that it\'s a triplet indicates the carbon next to it has two protons attached to it. That gives a CH3-CH2- (as well as the -COOH group) all that\'s left now is one carbon and two hydrogens (CH2) Looking at the other two proton peaks in the nmr ... there\'s one triplet and one sextet. The triplet would be a CH2 group that is next to another CH2 group (and not anything else), so it must be a CH2 next to the COOH Now you would have two pieces: CH3-CH2- and -CH2-COOH put them together and check the coupling of the protons... you should end up with two triplets (proton split by two others), one sextet (proton split by 5 others), and a small peak somewhere around 9-13ppm. (that\'s the peak indicated by the offset of 2.0ppm on the spectrum) So the structure would be: CH3-CH2-CH2-COOH (C4H8O2).

order of overlap of atomic orbitals from highest extent of overlap t.pdf

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order of overlap of atomic orbitals from highest extent of overlap to lowest is, I2 > IBr > ICl > IF Because, I2-is homo diatomic molecule and having good overlapping between the atomic orbitals of two iodine atoms. IBr-is a hetero di-atomic molecule and having almost good overlapping between the atomic orbitals of iodine and bromine atoms even though these two atoms belongs to different periods. ICl-is a hetero di-atomic molecule and having moderate overlapping between the atomic orbitals of iodine and chlorine atoms.Because, these two atoms belongs to different periods and size different is more. IF-is a hetero di-atomic molecule and having poor overlapping between the atomic orbitals of iodine and fluorine atoms.Because, these two atoms belongs to different periods and size different is too more. Solution order of overlap of atomic orbitals from highest extent of overlap to lowest is, I2 > IBr > ICl > IF Because, I2-is homo diatomic molecule and having good overlapping between the atomic orbitals of two iodine atoms. IBr-is a hetero di-atomic molecule and having almost good overlapping between the atomic orbitals of iodine and bromine atoms even though these two atoms belongs to different periods. ICl-is a hetero di-atomic molecule and having moderate overlapping between the atomic orbitals of iodine and chlorine atoms.Because, these two atoms belongs to different periods and size different is more. IF-is a hetero di-atomic molecule and having poor overlapping between the atomic orbitals of iodine and fluorine atoms.Because, these two atoms belongs to different periods and size different is too more..

Na3NSolutionNa3N.pdf

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boiling point is 82.5 c at 1 atm . i.e at 82.5 c .pdf

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Lymphoid Tissue is organized as the primary lymphoid organs includin.pdf

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Lymphoid Tissue is organized as the primary lymphoid organs including thymus and bone marrow. secondary lymphoid organs includes spleen, tonsils, lymph vessels, lymph nodes, adenoids, skin, and liver. And lymph fluid (The fluid which lies in the interstices of all body tissues). MALT (mucosa-associated lymphatic tissue) is a diffuse system of small concentrations of lymphoid tissue found in various sub-mucosa membrane sites of the body, such as the gastrointestinal tract, thyroid, breast, lung, salivary glands, eye, and skin. which is subdivided into GALT and BALT. GALT (Gut-associated lymphoid tissue or Gut-Associated Lymphatic Tissue) it works to protect the body from invasion. BALT (Bronchus-associated lymphoid tissue) is a constitutive mucosal lymphoid tissue aggregations of B and T lymphocytes in the lower respiratory tract. Solution Lymphoid Tissue is organized as the primary lymphoid organs including thymus and bone marrow. secondary lymphoid organs includes spleen, tonsils, lymph vessels, lymph nodes, adenoids, skin, and liver. And lymph fluid (The fluid which lies in the interstices of all body tissues). MALT (mucosa-associated lymphatic tissue) is a diffuse system of small concentrations of lymphoid tissue found in various sub-mucosa membrane sites of the body, such as the gastrointestinal tract, thyroid, breast, lung, salivary glands, eye, and skin. which is subdivided into GALT and BALT. GALT (Gut-associated lymphoid tissue or Gut-Associated Lymphatic Tissue) it works to protect the body from invasion. BALT (Bronchus-associated lymphoid tissue) is a constitutive mucosal lymphoid tissue aggregations of B and T lymphocytes in the lower respiratory tract..

Jacob and Monod proposed the operon model of regulation of gene expr.pdf

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Information and communication technologies for development (ICT4D) r.pdf

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Information and communication technologies for development (ICT4D) refers to the applying of knowledge and communication technologies (ICTs) toward the social, economic, and political development, with a specific stress on serving to poor and marginalized individuals and communities. It aims to assist in international development by bridging the digital divide and providing evenhanded access to technologies. ICT4D is grounded within the notions of \"development\", \"growth\", \"progress\" and \"globalization\" and is commonly taken because the use of technology to deliver a larger smart.[1] Another similar term utilized in the literature is \"digital development\".[2] ICT4D attracts on theories and frameworks from several disciplines, together with social science, economics, development studies, library and knowledge science, and communication studies.[3] ICT4D grew out of the tries to use rising computing technologies to boost conditions within the developing countries. It formalized through a series of reports, conferences, and funding initiatives that acted as key political avenues:[4] the 1998 World Development Report from the planet Bank, lightness the role of information and ICTs in development; a report from the G8 Digital Opportunities Task Force, closing that ICTs play a key role in fashionable human development, the planet Summits on the data Society command in Geneva in 2003 and port in 2005. At least 3 phases may be known in ICT4D evolution:[5] ICT4D 0.0: mid-1950s to late-1990s. the main focus of this earliest part was on the employment of IT (not ICT) in government and personal sector organizations in developing countries. one among the earliest computers utilized in a developing country was a HEC machine put in in 1956 to undertake numerical calculations within the Indian Institute of Statistics in Calcutta.[6] ICT4D 1.0: late-1990s to late-2000s. the appearance of the Millennium Development Goals combined with the increase and unfold of the net in industrial countries crystal rectifier to a fast increase in investments in ICT infrastructure and comes in developing countries. the foremost typical application was the telecentre, accustomed bring info on development problems like health, education, and agricultural extension, into poor communities. Later, telecentres were conjointly accustomed deliver government services[citation needed]. ICT4D 2.0: late-2000s forwards. there\'s no clear boundary between phases one.0 and 2.0. the main focus within the part two.0 progressively shifts toward technologies in use, like the transportable and SMS technologies. there\'s less concern with e-readiness and a lot of interest within the impact of ICTs on development. to boot, there\'s a lot of specialise in the poor as producers and innovators with ICTs (as opposition being shoppers of ICT-based information). ICT4D 2.0 is regarding reframing the poor. wherever ICT4D one.0 marginalised them, permitting a supply-driven focus, ICT4D 2.0 central.

is it in 12 different waysSolutionis it in 12 different ways.pdf

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In the risk prioritization step, the overall set of identified risk .pdf

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In the risk prioritization step, the overall set of identified risk events, their impact assessments, and their probabilities of occurrences are \"processed\" to derive a most-to-least-critical rank- order of identified risks. A major purpose of prioritizing risks is to form a basis for allocating resources. Multiple qualitative and quantitative techniques have been developed for risk impact assessment and prioritization. Qualitative techniques include analysis of probability and impact, developing a probability and impact matrix, risk categorization, risk frequency ranking (risks with multiple impacts), and risk urgency assessment. Quantitative techniques include weighting of cardinal risk assessments of consequence, probability, and timeframe; probability distributions; sensitivity analysis; expected monetary value analysis; and modeling and simulation. A Risk Analysis may identify a number of risks that appear to be of similar ranking or severity. When too many risks are clustered at or about the same level, a method is needed to prioritize risk responses and where to apply limited resources. Such a method should be tied to mission/business needs and maximize the use of available resources. A rational and common sense prioritization is a key component of a risk management program and becomes necessary when requirements cannot be fully satisfied. In the event the identified risk (or set of risks) materialized: ->How critical would the immediate impact be to organizational operations (including mission, functions, image, or reputation), organizational assets, individuals, other organizations, or the Nation? ->How critical would the future impact be to organizational operations (including mission, functions, image, or reputation), organizational assets, individuals, other organizations, or the Nation? The answers to the above questions provide the basis for a justifiable prioritization that is based on current and future organizational needs. Mission/business owners (or their designees) and mission/business subject matter experts can be consulted to obtain the most complete and up-to- date information. The challenge in it is the first activity within the risk assessment process which is to develop a common set of assessment criteria to be deployed across business units, corporate functions, and large capital projects. Risks and opportunities are typically assessed in terms of impact and likelihood. Many enterprises recognize the utility of evaluating risk along additional dimensions such as vulnerability and speed of onset. Assessing risks consists of assigning values to each risk and opportunity using the defined criteria. This may be accomplished in two stages where an initial screening of the risks is performed using qualitative techniques followed by a more quantitative analysis of the most important risks. Risks do not exist in isolation. Enterprises have come to recognize the importance of managing risk interactions. Even seemingly insi.

i) All 5 are subsets of AxAHence all are relations on Aii) All a.pdf

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i) All 5 are subsets of AxA Hence all are relations on A ii) All are mappings from A to A iii) Only i, iii and v are one to one relations iv) i, ii , iii and iv are all onto relations. v) All 5 vi) I and III are reflexive vii) i, II, III and IV, v are symmetric ix) i, iii are equivalence x) v is singleton Solution i) All 5 are subsets of AxA Hence all are relations on A ii) All are mappings from A to A iii) Only i, iii and v are one to one relations iv) i, ii , iii and iv are all onto relations. v) All 5 vi) I and III are reflexive vii) i, II, III and IV, v are symmetric ix) i, iii are equivalence x) v is singleton.

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