XML Schema provides a way to formally define and validate the structure and content of XML documents. It allows defining elements, attributes, and data types, as well as restrictions like length, pattern, and value ranges. DTD is more limited and cannot validate data types. XML Schema is written in XML syntax, uses XML namespaces, and provides stronger typing capabilities compared to DTD. It allows defining simple and complex element types, attributes, and restrictions to precisely describe the expected structure and values within XML documents.