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The Inter-Islamic Network On Water Resources
Development and Management Workshop in Egypt,
&
Water Chemistry & Treatment Presentation
By Inaam Ahamad Khan
Several International Organisation like
WHO, EPA, AWWA, NSF, ASTM, SM etc.
Information from Books & Cyberspace
This presentation is in two parts
โ€ข Foundation of Our Beautiful Planet
โ€ข Foundation of Things Around Us
โ€ข Essence Of Life
โ€ข Pure in Nature is Rare and Not Good For Life
โ€ข Our Planet Water Is Billions of Years Old
RAINBOWS
RAINBOWSYou See
RAIN DROP
Reflection
WHITE LIGHT
Primary Bow
Secondary Bow
RAINBOWS
โ€ข White light is the full spectrum of rainbow colors
โ€ข Red is absorbed first by seawater
โ€ข Violet Blue or Green does not penetrate as other color
โ€ข Due to some reasons you see different colors of the sea
Salt water In Oceans
2.14 % - glaciers
0.61 % - ground water
0.009 %- surface water
(lakes and rivers)
0.005 % - soil
moisture
0.001 %- water vapor
in the atmosphere
97.23 %
Oceans
(97 %)
Salt
water
Ice Caps, Glaciers
& Ground
Water
(2.9%)
Lakes, Rivers,
Atmosphere
& Soil Moisture
Water
(0.014%)
Fresh
water
End users**
30.3
Rest of
Industry
10.3
Rest of
Manufacturing
6.1Services
16.4
Metal
products
2.5
Industrial
machinery
1.9
Office
machines
0.7
Electrical
goods
3.9 Agriculture
6.4
Textile &
clothing
6.3
Construction
5.4 Automotive
5.3
Paper &
printing
products
4.5
Computer Chips 300 Steps 7570 Liter
Tire 7850 Liter
Car 14800 Liter
One Egg 50 Liter
One Chicken to Process 440 Liter
One barrel of Crude oil refining 7010 Liter
One person food to grow 6440 Liter
20
40 billion
The number
of hours spent
each year in
Africa due to
the need to
collect and
haul water
Source: Blue Planet Run, Smolan, Erwitt
5.3 billion
The number
of people -
two-thirds of
the world's
population -
who will
suffer from
water
shortages by
2025
1.1 billion
The
number of
people
worldwide -
1 in every 6
- without
access to
clean water
1.8 million
The number
of children
who die each
year from
waterborne
diseases - one
every 15
seconds
Water Scarcity is a global problem todayโ€ฆ
Inorganic substance โ€“ 1%
Carbohydrateโ€“ 5%
Fatโ€“ 10%
Proteinโ€“ 18%
Waterโ€“ 66%
The amount of water in the
hydrologic cycle never change
Its Quality Changes
6%
4%
100 70%
51%
26%
38%
6%
20%
19%
โ€ข Foundation of All Other sciences,
โ€ข Embraces All Other Sciences,
โ€ข Simplify the Understanding of Universe
โ€ข The Study of Properties and Changes in Matter
Our Atmosphere is
Primarily Nitrogen
N2
INCOMING SOLAR
RADIATION
NITROGEN
MOLECULE
INCOMING SOLAR RADIATION
NITROGEN
MOLECULE
Sunlight consists of
all the colors of the
rainbow. Of all these
colors, the blue light
interacts with
nitrogen,
The blue light is
scattered by the
Nitrogen,
What actually happens is that the outer electrons of
the Nitrogen molecule absorb just the blue light,
Dust Particles
Dust Particles in the atmosphere selectively absorb the
short wavelength radiation and allow the longer
wavelength red, orange and yellow wave to pass through,
25 of 92 natural elements are known to be
essential to life on Earth
Carbon, Oxygen, Hydrogen and Nitrogen
Four of the above make up 96%
Hydrogen Nitrogen-7
Oxygen-8Carbon-6
Electron shell
Nucleus
Hydrogen (H) Helium (He)
Orbit
Hydrogen
Element
H
Hydrogen
Element
H
Hydrogen
Molecule
H2
Hydrogen
Hydrogen
Carbon-6
Hydrogen
Hydrogen
Compounds are two or more elements that share electrons or
have taken or given electrons away.
Hydrogen
Hydrogen
Carbon-6
Hydrogen
Hydrogen
H +
Fe +++
Fe ++
Al
+++
Ca ++
Na +
HCO3
-
Cl -
OH -
CO3
- -
PO4
- - -
NO3
-
SO4
- -
Forms water with hydroxide
and acids with anions
Forms bases with hydroxides
and salts with anions
Forms hardness compound,
bases with hydroxides and salts
with anions
Forms acid with hydrogen
and salts with metals
Forms water with hydrogen
and base with cations
Sulphuric Acid
CATIONS ANIONS
H + SO4
- -
Na + Cl -
Mg ++
Forms base with hydroxide
and soluble salts with anions
H +
Sodium Chloride
H2O
Hydrogen
Hydrogen
Oxygen
Compounds are two or more elements that share electrons or
have taken or given electrons away.
Specific heatโ€“ Resists changes in temperature
Latent heat of fusionโ€“ Heat required to change liquid state
Latent heat of vaporizationโ€“ Heat released when Its evaporates
Heat capacity highest of all liquids,
Latent heat of fusion highest except ammonia,
Thermal conductivity highest of all liquids,
Thermal expansion max. at 40 C( increases with salinity)
Surface tension highest of all liquids,
Comparison to other compounds of similar structures
( H2Te, H2Se, H2S etc.)
Should freeze at โ€“ 1000C but it freezes at 00C
Should boil at - 900C but it boils at 1000C
Should have a density of 1.84 g/cm3
but the density is 1.0 g/cm3
The maximum density at 40C (which is ice) is less then liquid
water,
Comparison to other compounds of similar structures
( H2Te, H2Se, H2S etc.)
Cohesion and Adhesionโ€“ Keeps liquid molecules close
Surface Tensionโ€“ A thin skin forms on liquid upper
layer
(The inward force, or pull that tends to minimize the surface area of a liquid)
Diffusionโ€“ When solute is added it diffuses in liquid
Osmosisโ€“ Diffusion of liquid across a permeable
membrane from high concentration low
concentration water
Up-thrustโ€“ This upward force create Buoyancy
Water-conducting
cells
Adhesion
Cohesion150 ยตm
Direction
of water
movement
Water Evaporate
Cohesion and Adhesionโ€“
Keeps liquid molecules close
Dilute
Solution
More
Concentrated
Solution
Diffusion & Osmosis is also very important for
controlling the movement of materials into and out of
the cell in our body and for interacting with the
environment surrounding the body
Its five important properties
โ€ข Physical Properties
โ€ข Solvent Properties
โ€ข Heat Capacity (Temperature Effect)
โ€ข Density
โ€ข Viscosity
A โ€“ Liquid
Property 1 โ€“ Physical states
B โ€“ Solid
C โ€“ Gas
Hydrogen
Bond
โ€ข Physical Properties
โ€ข Solvent Properties
โ€ข Heat Capacity (Temperature Effect)
โ€ข Density
โ€ข Viscosity
+
-
++ +
-
-
-
- -
-
-
+
-
+
-
104.5ยฐ
+
-
++ +
-
-
-
- -
-
-
+
-
+
-
109ยฐ
A โ€“ Liquid
B โ€“ Solid
C โ€“ Gas
Property 2 โ€“ Solvent Property
โ€ข Physical Properties
โ€ข Solvent Properties
โ€ข Heat Capacity (Temperature Effect)
โ€ข Density
โ€ข Viscosity
Negative end
Positive ends
Hydrogen Bond
Na+ Cl-
O
Oil
droplet
Oil
droplet
SO4
-
SO4
-
SO4
-
SO4
-
SO4
- SO4
-
Property 3โ€“ Heat Capacity (Temperature Effect)
Water resist change in temperature,Thus water must
gain or lose more heat for temperature to change
High heat capacity makes water a good insulator to
heat changes
Latent heat of fusion is very high and latent heat of
vaporization much greater than latent heat of fusion
โ€ข Physical Properties
โ€ข Solvent Properties
โ€ข Heat Capacity (Temperature Effect)
โ€ข Density
โ€ข Viscosity
Property 3โ€“ Heat Capacity (Temperature Effect)
Significance
Dissolved oxygen content in water
Physiological processes in bodies
Bio-organism Safety
Density implications
This prevents blood of animals & water in plant
tissue to stay as liquid and not freeze in winter
This means water does not freeze and does not
evaporates easily
A never reachable scenario โ€“ salt water never
completely freezes.
Hence has no freezing point.
Freshwater does though.
This would mean that as more ice forms in the ocean,
the ocean gets more concentrated with salt.
Property 3โ€“ Heat Capacity (Temperature Effect)
Ice
Property 3โ€“ Heat Capacity (Temperature Effect)
Water
Property 3โ€“ Heat Capacity (Temperature Effect)
Water Hot Water
Property 3โ€“ Heat Capacity (Temperature Effect)
Steam
Property 3โ€“ Heat Capacity (Temperature Effect)
6
4
100
70
51
26
38
6
20
19
Property 4โ€“ Density ?
Density changes with temperature and
Purity of substance
mass (g)
Density (ฯ) = ---------------------
volume (cm3)
density of substance
Relative Density = ----------------------------
density of water
โ€ข Physical Properties
โ€ข Solvent Properties
โ€ข Heat Capacity (Temperature Effect)
โ€ข Density
โ€ข Viscosity
Substance Mass (g) Volume
(cm3)
Density
(g/cm3)
Wood 10 20.00 0.50
Ice 10 10.90 0.92
Water 10 10.00 1.00
Aluminum 10 3.70 2.70
Lead 10 0.88 11.00
Property 4โ€“ Density ?
โ€ข The sea has greater depths than the highest
peaks on land.
โ€ข The Marianas Trench is 11.04 km deep!
โ€ข Mt Everest is about 9 km high
Property 5โ€“ Viscosity
Water is more viscous than air
Mango juice and syrup is more viscous than water
Viscosity is the resistance of a liquid and water is
800 times more viscous than air
Again hydrogen bonds plays an important role in
viscosity of water
Physical Properties
Solvent Properties
Heat Capacity (Temperature Effect)
Density
Viscosity
Bulky animals Having difficulty in swimming
through colder, more viscous waters
Migration of whales seasonally
A 200C Decrease in temperature doubles the
viscosity
Shape of animals & plants
Water Chemistry Part I
Water Chemistry Part I
Water Chemistry Part I
Water Chemistry Part I

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Water Chemistry Part I

  • 1.
  • 2. The Inter-Islamic Network On Water Resources Development and Management Workshop in Egypt, & Water Chemistry & Treatment Presentation By Inaam Ahamad Khan Several International Organisation like WHO, EPA, AWWA, NSF, ASTM, SM etc. Information from Books & Cyberspace
  • 3.
  • 4.
  • 5. This presentation is in two parts
  • 6. โ€ข Foundation of Our Beautiful Planet โ€ข Foundation of Things Around Us โ€ข Essence Of Life โ€ข Pure in Nature is Rare and Not Good For Life โ€ข Our Planet Water Is Billions of Years Old
  • 10. โ€ข White light is the full spectrum of rainbow colors โ€ข Red is absorbed first by seawater โ€ข Violet Blue or Green does not penetrate as other color โ€ข Due to some reasons you see different colors of the sea
  • 11.
  • 12. Salt water In Oceans 2.14 % - glaciers 0.61 % - ground water 0.009 %- surface water (lakes and rivers) 0.005 % - soil moisture 0.001 %- water vapor in the atmosphere 97.23 %
  • 13.
  • 14. Oceans (97 %) Salt water Ice Caps, Glaciers & Ground Water (2.9%) Lakes, Rivers, Atmosphere & Soil Moisture Water (0.014%) Fresh water
  • 15. End users** 30.3 Rest of Industry 10.3 Rest of Manufacturing 6.1Services 16.4 Metal products 2.5 Industrial machinery 1.9 Office machines 0.7 Electrical goods 3.9 Agriculture 6.4 Textile & clothing 6.3 Construction 5.4 Automotive 5.3 Paper & printing products 4.5
  • 16. Computer Chips 300 Steps 7570 Liter Tire 7850 Liter Car 14800 Liter One Egg 50 Liter One Chicken to Process 440 Liter One barrel of Crude oil refining 7010 Liter One person food to grow 6440 Liter
  • 17. 20 40 billion The number of hours spent each year in Africa due to the need to collect and haul water Source: Blue Planet Run, Smolan, Erwitt 5.3 billion The number of people - two-thirds of the world's population - who will suffer from water shortages by 2025 1.1 billion The number of people worldwide - 1 in every 6 - without access to clean water 1.8 million The number of children who die each year from waterborne diseases - one every 15 seconds
  • 18.
  • 19. Water Scarcity is a global problem todayโ€ฆ
  • 20.
  • 21. Inorganic substance โ€“ 1% Carbohydrateโ€“ 5% Fatโ€“ 10% Proteinโ€“ 18% Waterโ€“ 66%
  • 22.
  • 23.
  • 24.
  • 25.
  • 26. The amount of water in the hydrologic cycle never change Its Quality Changes
  • 27.
  • 29. โ€ข Foundation of All Other sciences, โ€ข Embraces All Other Sciences, โ€ข Simplify the Understanding of Universe โ€ข The Study of Properties and Changes in Matter
  • 30.
  • 31.
  • 32.
  • 33.
  • 34. Our Atmosphere is Primarily Nitrogen N2 INCOMING SOLAR RADIATION NITROGEN MOLECULE
  • 35. INCOMING SOLAR RADIATION NITROGEN MOLECULE Sunlight consists of all the colors of the rainbow. Of all these colors, the blue light interacts with nitrogen, The blue light is scattered by the Nitrogen,
  • 36. What actually happens is that the outer electrons of the Nitrogen molecule absorb just the blue light,
  • 37.
  • 39. Dust Particles in the atmosphere selectively absorb the short wavelength radiation and allow the longer wavelength red, orange and yellow wave to pass through,
  • 40.
  • 41. 25 of 92 natural elements are known to be essential to life on Earth Carbon, Oxygen, Hydrogen and Nitrogen Four of the above make up 96%
  • 44.
  • 45.
  • 46.
  • 48.
  • 49. Hydrogen Hydrogen Carbon-6 Hydrogen Hydrogen Compounds are two or more elements that share electrons or have taken or given electrons away.
  • 51. H + Fe +++ Fe ++ Al +++ Ca ++ Na + HCO3 - Cl - OH - CO3 - - PO4 - - - NO3 - SO4 - - Forms water with hydroxide and acids with anions Forms bases with hydroxides and salts with anions Forms hardness compound, bases with hydroxides and salts with anions Forms acid with hydrogen and salts with metals Forms water with hydrogen and base with cations Sulphuric Acid CATIONS ANIONS H + SO4 - - Na + Cl - Mg ++ Forms base with hydroxide and soluble salts with anions H + Sodium Chloride
  • 52. H2O
  • 53. Hydrogen Hydrogen Oxygen Compounds are two or more elements that share electrons or have taken or given electrons away.
  • 54. Specific heatโ€“ Resists changes in temperature Latent heat of fusionโ€“ Heat required to change liquid state Latent heat of vaporizationโ€“ Heat released when Its evaporates Heat capacity highest of all liquids, Latent heat of fusion highest except ammonia, Thermal conductivity highest of all liquids, Thermal expansion max. at 40 C( increases with salinity) Surface tension highest of all liquids, Comparison to other compounds of similar structures ( H2Te, H2Se, H2S etc.)
  • 55. Should freeze at โ€“ 1000C but it freezes at 00C Should boil at - 900C but it boils at 1000C Should have a density of 1.84 g/cm3 but the density is 1.0 g/cm3 The maximum density at 40C (which is ice) is less then liquid water, Comparison to other compounds of similar structures ( H2Te, H2Se, H2S etc.)
  • 56. Cohesion and Adhesionโ€“ Keeps liquid molecules close Surface Tensionโ€“ A thin skin forms on liquid upper layer (The inward force, or pull that tends to minimize the surface area of a liquid) Diffusionโ€“ When solute is added it diffuses in liquid Osmosisโ€“ Diffusion of liquid across a permeable membrane from high concentration low concentration water Up-thrustโ€“ This upward force create Buoyancy
  • 58.
  • 59. Cohesion and Adhesionโ€“ Keeps liquid molecules close
  • 60. Dilute Solution More Concentrated Solution Diffusion & Osmosis is also very important for controlling the movement of materials into and out of the cell in our body and for interacting with the environment surrounding the body
  • 61. Its five important properties โ€ข Physical Properties โ€ข Solvent Properties โ€ข Heat Capacity (Temperature Effect) โ€ข Density โ€ข Viscosity
  • 62. A โ€“ Liquid Property 1 โ€“ Physical states B โ€“ Solid C โ€“ Gas Hydrogen Bond โ€ข Physical Properties โ€ข Solvent Properties โ€ข Heat Capacity (Temperature Effect) โ€ข Density โ€ข Viscosity
  • 63. + - ++ + - - - - - - - + - + - 104.5ยฐ + - ++ + - - - - - - - + - + - 109ยฐ A โ€“ Liquid B โ€“ Solid C โ€“ Gas
  • 64. Property 2 โ€“ Solvent Property โ€ข Physical Properties โ€ข Solvent Properties โ€ข Heat Capacity (Temperature Effect) โ€ข Density โ€ข Viscosity
  • 70. Property 3โ€“ Heat Capacity (Temperature Effect) Water resist change in temperature,Thus water must gain or lose more heat for temperature to change High heat capacity makes water a good insulator to heat changes Latent heat of fusion is very high and latent heat of vaporization much greater than latent heat of fusion โ€ข Physical Properties โ€ข Solvent Properties โ€ข Heat Capacity (Temperature Effect) โ€ข Density โ€ข Viscosity
  • 71. Property 3โ€“ Heat Capacity (Temperature Effect) Significance Dissolved oxygen content in water Physiological processes in bodies Bio-organism Safety Density implications This prevents blood of animals & water in plant tissue to stay as liquid and not freeze in winter This means water does not freeze and does not evaporates easily
  • 72. A never reachable scenario โ€“ salt water never completely freezes. Hence has no freezing point. Freshwater does though. This would mean that as more ice forms in the ocean, the ocean gets more concentrated with salt. Property 3โ€“ Heat Capacity (Temperature Effect)
  • 73. Ice Property 3โ€“ Heat Capacity (Temperature Effect)
  • 74. Water Property 3โ€“ Heat Capacity (Temperature Effect)
  • 75. Water Hot Water Property 3โ€“ Heat Capacity (Temperature Effect)
  • 76. Steam Property 3โ€“ Heat Capacity (Temperature Effect)
  • 77.
  • 79.
  • 80. Property 4โ€“ Density ? Density changes with temperature and Purity of substance mass (g) Density (ฯ) = --------------------- volume (cm3) density of substance Relative Density = ---------------------------- density of water โ€ข Physical Properties โ€ข Solvent Properties โ€ข Heat Capacity (Temperature Effect) โ€ข Density โ€ข Viscosity
  • 81. Substance Mass (g) Volume (cm3) Density (g/cm3) Wood 10 20.00 0.50 Ice 10 10.90 0.92 Water 10 10.00 1.00 Aluminum 10 3.70 2.70 Lead 10 0.88 11.00 Property 4โ€“ Density ?
  • 82. โ€ข The sea has greater depths than the highest peaks on land. โ€ข The Marianas Trench is 11.04 km deep! โ€ข Mt Everest is about 9 km high
  • 83. Property 5โ€“ Viscosity Water is more viscous than air Mango juice and syrup is more viscous than water Viscosity is the resistance of a liquid and water is 800 times more viscous than air Again hydrogen bonds plays an important role in viscosity of water Physical Properties Solvent Properties Heat Capacity (Temperature Effect) Density Viscosity
  • 84. Bulky animals Having difficulty in swimming through colder, more viscous waters Migration of whales seasonally A 200C Decrease in temperature doubles the viscosity Shape of animals & plants