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Section 1- Matter and Change
Unit 1 – Matter and Energy
What is chemistry?
 Chemistry:
the study of the composition, structure, and
properties of matter, the process that matter
undergoes, and the energy changes that
accompany these processes.
 Chemicals:
any substance with a definite composition.
Examples: H2O and H2O2
Matter: anything with mass and volume.
Weight: Mass:
Force of
Gravity on
an Object
(Measured with a
scale)
Amount of
Matter in an
Object
(Measured with a
balance)
Matter and Its Properties
 Atom: Smallest unit of an element…
 Element: A pure substance that CANNOT be
broken down into a simpler substance (one type
of atom)
Example: Cu or He
 Compound: A substance that can be broken
down into a simpler substance (2 or more
elements chemically bonded together)
Example: H2O or H2SO4
Physical
Property
Measured without changing the
substance
Intensive
DOES NOT
depend on the
amount
Extensive
DEPENDS
on the
amount
Melting
Point, Density, Freezing
point
Volume, Mass, Energy
Chemical Property
Behavior of a substance interacting with
another
Coal Burning Iron Rusting
Matter and Its Properties
Physical
Change:
Chemical
Change:
Same substance
(chemically) present
BEFORE and AFTER
the change
Produces
ONE or MORE
new
substances.
Matter and Its Properties
Indicators of Chemical Change
1. Precipitate (solid formed)
2. Gas is given off
3. Color change
4. Change in energy (Hot OR
Cold)
5. Light given off (emission)
Classification of Matter
Homogeneous
Materials
Elements
Is it the same
throughout?
Is it a
combination of
things?
Can it be
separated in to
smaller
substances?
Groups = COLUMNS Periods = ROWS
Unit 1: Matter & Energy
Section 2:
Measurements and
Calculations
Scientific Method
Theory Publish Results
Units of Measure
Qualitative
Descriptive
(Non-numeric)
The fact that
the sky is blue
Quantitative
Measurement
(Numeric)
A sample of
copper ore has
a mass of 25.7
grams
Units of Measure
The International System (SI)--1960s
 Commonly used SI units in CHEMISTRY.
1. Length meters (m)
2. Mass kilograms (kg)
3. Time seconds (s)
4. Quantity moles (mol)
Units of Measure
 SI units PREFIXES
Prefi
x
Symbo
l
How many in a base unit?
Nano- n 1,000,000,000
Micro- μ 1,000,000
Milli- m 1,000
Centi- c 100
Deci- d 10
Prefix Symbo
l
How many base units?
Kilo- k 1,000
Mega- M 1,000,000
Giga- G 1,000,000,000
Example: 1 m = 100 cm
1 g = 1,000 mg
Example:
1 km = 1000 m
1 mg = 1,000,000 g
Units of Measure
 Derived Units: A combination of SI base units.
Examples: Velocity, Density
 Conversion Factors
Math used to relate 2 units that measure
the same quantity (written as a fraction);
Equal to 1
Example 1 m = 1000 mm
Units of Measure
 Conversion Factor Practice
Example 1 – Convert 22,000 g to kg.
Example 2 – Convert 0.0290 m to
mm.
Example 3 – How many seconds are
in 3.11 hours?
Units of Measure
 Example 1 – Convert 22 000 g to kg
 22000 g x 1 kg = 22000 kg =
1 1000 g 1000
 Example 2 – Convert 0.0290 m to millimeters
 0.0290 m x 1000 mm = 29 mm =
1 1 m 1
 Example 3 – How many seconds in 3.11 hours?
 3.11 hours x 60 min x 60 sec = 11196 sec =
1 1 hr 1 min 1
22 kg
29 mm
11196
sec
Using Scientific Measurement
Accuracy
Precision
Closeness of a measurement to
the true or CORRECT value.
How close a set of measurements
are to one another, regardless of
correctness
Using Scientific Measurement
 Experiments will always have errors.
(human, mechanical, environmental)
 PERCENT ERROR determines the
accuracy of the experiment. (the lower the
percent, the better)
Using Scientific Measurement
 Significant Figures
All digits that occupy places for which
ACTUAL measurement was made, including
the last estimated digit.
See Significant Figure/Scientific Notation Rules Reference Sheet
When taking
measurements,
you ALWAYS read the
instrument to one more
place than is marked. You
estimate that digit.
Significant Figures Practice
1) 30 504
 5 sig. figs.
2) 32.001 20
 7 sig. figs.
3) 0.000 123 0
 4 sig figs.
4) 560 000
 2 sig. figs.
5) 200.003
 6 sig. figs.
Math w/ Significant Figures
 Put answers in correct Sig. Figs.
1) 2.301 + 6.12 + 4.1158
 12.5368 = 12.54
2) 1500 – 301.05 – 251.223
 947.727 = 948
3) (9.554)(5.10)(1.5)
 73.0881 = 73
4) 44581.2/235.2
 189.545918367 = 189.5
Using Scientific Measurement
 Scientific Notation
 How scientists show either BIG or SMALL numbers.
 602,200,000,000,000,000,000,000 = 6.022 x 1023
Hint:
 Positive exponents – Move decimal to the right
 Negative exponents – Move decimal to the left.
 Note: Only the numbers before the scientific notation are
significant.
(ex: 6.022 x 1023 has 4 sig figs)
Scientific Notation
1) Put 325 000 000 in scientific notation
 3.25 x 108
2) Put 0.002405 in scientific notation
 2.405 x 10-3
3) Put 7.54 x 104 in regular notation
 75 400
4) Put 5.001 x 10-5 in regular notation
 0.00005001
Using Scientific Measurement
Direct proportion Inverse Proportion
As one variable
increase, so
does the other.
As one
variable
increases, the
other
decreases
Unit 1: Matter & Energy
Section 3: Energy
Transfer
What is Energy?
Energy
Chemical
Energy due to
chemical bonds
Kinetic
Energy due to
motion
Heat (q) is the
total KE in a
sample
Potential
Energy due to
position
Energy Units
Name Symbol Info
Joule J SI Unit for energy
calorie c
(lowercase)
Old energy unit
1 calorie = 4.184 J
Calorie C 1000 c = 1 Calorie
Food Calorie
Energy Transfer
 Energy in the form of HEAT moves
back and forth between a system and
its surroundings.
 Temperature: Average KE of the random
motion of particles in a substance.
Energy Transfer
 Specific Heat Capacity
Amount of HEAT needed to raise the
temperature of 1 gram of a substance 1
Kelvin (K).
 Calorimeter
 A device used to measure energy absorbed
or released during chemical or physical
change.
Energy Transfer
 How to calculate specific heat capacity:
q = (m)(ΔT)(Cp)
q = Heat (J)
m= Mass (g)
ΔT = Change in Temperature (K = °C + 273)
Cp = Specific Heat Capacity (Given)
Example Problem #1
 40.00 g of water is heated from 10.00°C to 30.00°C. The
specific heat of water is 4.184 J/gK.
q = (m)(ΔT)(Cp)
q=Heat (J)
m=Mass (g)
ΔT = Change in Temperature
(K = °C + 273)
Cp = Specific Heat Capacity (Given)
q = ?
m = 40.00 g
ΔT = (30 + 273) - (10 + 273) = 20.00 K
Cp = 4.184 J/gK
q = (40.00 g) ( 20.00 K) ( 4.184 J/gK)
q = 3347.2 J
q = 3350 J
Example Problem #2
 135.6 g of water is cooled from 95.80°C to 21.60°C. The
specific heat of water is 4.184 J/gK.
q = (m)(ΔT)(Cp)
q=Heat (J)
m=Mass (g)
ΔT = Change in Temperature
(K = °C + 273)
Cp = Specific Heat Capacity (Given)
q = ?
m = 135.6 g
ΔT = (21.6 + 273) - (95.8 + 273) =
-74.20 K
Cp = 4.184 J/gK
q = (135.6 g) ( -74.20 K) ( 4.184 J/gK)
q = -42097.39 J
q = -4.210 x 104 J
Energy Transfer Practice
Determine the amount of heat absorbed or released in each
of the following changes. Use the table of specific heat
capacity on page 533 of your text. The specific heat of
water is 4.184 J/gK.
1. 40.00 g of water is heated from 10.00°C to 30.00°C.
2. 135.6 g of water is cooled from 95.80°C to 21.60°C.
3. 30.00 g of aluminum is heated from 15.00°C to 35.00°C.
4. 450.0 g of iron is cooled from 125.0°C to 45.00°C.
5. 62.30 g of lead is heated from 21.70°C to 136.4°C.
Energy Transfer
Answers to previous slide
1. +3347.2 J = + 3347 J
2. -42,097.4 J = -4.210 x 104 J
3. +538.2 J
4. -16,164.0 J = -16160 J
5. +921.8 J

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Unit 1 notes_pp_12_13

  • 1. Section 1- Matter and Change Unit 1 – Matter and Energy
  • 2. What is chemistry?  Chemistry: the study of the composition, structure, and properties of matter, the process that matter undergoes, and the energy changes that accompany these processes.  Chemicals: any substance with a definite composition. Examples: H2O and H2O2
  • 3. Matter: anything with mass and volume. Weight: Mass: Force of Gravity on an Object (Measured with a scale) Amount of Matter in an Object (Measured with a balance)
  • 4. Matter and Its Properties  Atom: Smallest unit of an element…  Element: A pure substance that CANNOT be broken down into a simpler substance (one type of atom) Example: Cu or He  Compound: A substance that can be broken down into a simpler substance (2 or more elements chemically bonded together) Example: H2O or H2SO4
  • 5. Physical Property Measured without changing the substance Intensive DOES NOT depend on the amount Extensive DEPENDS on the amount Melting Point, Density, Freezing point Volume, Mass, Energy
  • 6. Chemical Property Behavior of a substance interacting with another Coal Burning Iron Rusting
  • 7. Matter and Its Properties Physical Change: Chemical Change: Same substance (chemically) present BEFORE and AFTER the change Produces ONE or MORE new substances.
  • 8. Matter and Its Properties Indicators of Chemical Change 1. Precipitate (solid formed) 2. Gas is given off 3. Color change 4. Change in energy (Hot OR Cold) 5. Light given off (emission)
  • 9. Classification of Matter Homogeneous Materials Elements Is it the same throughout? Is it a combination of things? Can it be separated in to smaller substances?
  • 10. Groups = COLUMNS Periods = ROWS
  • 11. Unit 1: Matter & Energy Section 2: Measurements and Calculations
  • 13. Units of Measure Qualitative Descriptive (Non-numeric) The fact that the sky is blue Quantitative Measurement (Numeric) A sample of copper ore has a mass of 25.7 grams
  • 14. Units of Measure The International System (SI)--1960s  Commonly used SI units in CHEMISTRY. 1. Length meters (m) 2. Mass kilograms (kg) 3. Time seconds (s) 4. Quantity moles (mol)
  • 15. Units of Measure  SI units PREFIXES Prefi x Symbo l How many in a base unit? Nano- n 1,000,000,000 Micro- μ 1,000,000 Milli- m 1,000 Centi- c 100 Deci- d 10 Prefix Symbo l How many base units? Kilo- k 1,000 Mega- M 1,000,000 Giga- G 1,000,000,000 Example: 1 m = 100 cm 1 g = 1,000 mg Example: 1 km = 1000 m 1 mg = 1,000,000 g
  • 16. Units of Measure  Derived Units: A combination of SI base units. Examples: Velocity, Density  Conversion Factors Math used to relate 2 units that measure the same quantity (written as a fraction); Equal to 1 Example 1 m = 1000 mm
  • 17. Units of Measure  Conversion Factor Practice Example 1 – Convert 22,000 g to kg. Example 2 – Convert 0.0290 m to mm. Example 3 – How many seconds are in 3.11 hours?
  • 18. Units of Measure  Example 1 – Convert 22 000 g to kg  22000 g x 1 kg = 22000 kg = 1 1000 g 1000  Example 2 – Convert 0.0290 m to millimeters  0.0290 m x 1000 mm = 29 mm = 1 1 m 1  Example 3 – How many seconds in 3.11 hours?  3.11 hours x 60 min x 60 sec = 11196 sec = 1 1 hr 1 min 1 22 kg 29 mm 11196 sec
  • 19. Using Scientific Measurement Accuracy Precision Closeness of a measurement to the true or CORRECT value. How close a set of measurements are to one another, regardless of correctness
  • 20. Using Scientific Measurement  Experiments will always have errors. (human, mechanical, environmental)  PERCENT ERROR determines the accuracy of the experiment. (the lower the percent, the better)
  • 21. Using Scientific Measurement  Significant Figures All digits that occupy places for which ACTUAL measurement was made, including the last estimated digit. See Significant Figure/Scientific Notation Rules Reference Sheet When taking measurements, you ALWAYS read the instrument to one more place than is marked. You estimate that digit.
  • 22. Significant Figures Practice 1) 30 504  5 sig. figs. 2) 32.001 20  7 sig. figs. 3) 0.000 123 0  4 sig figs. 4) 560 000  2 sig. figs. 5) 200.003  6 sig. figs.
  • 23. Math w/ Significant Figures  Put answers in correct Sig. Figs. 1) 2.301 + 6.12 + 4.1158  12.5368 = 12.54 2) 1500 – 301.05 – 251.223  947.727 = 948 3) (9.554)(5.10)(1.5)  73.0881 = 73 4) 44581.2/235.2  189.545918367 = 189.5
  • 24. Using Scientific Measurement  Scientific Notation  How scientists show either BIG or SMALL numbers.  602,200,000,000,000,000,000,000 = 6.022 x 1023 Hint:  Positive exponents – Move decimal to the right  Negative exponents – Move decimal to the left.  Note: Only the numbers before the scientific notation are significant. (ex: 6.022 x 1023 has 4 sig figs)
  • 25. Scientific Notation 1) Put 325 000 000 in scientific notation  3.25 x 108 2) Put 0.002405 in scientific notation  2.405 x 10-3 3) Put 7.54 x 104 in regular notation  75 400 4) Put 5.001 x 10-5 in regular notation  0.00005001
  • 26. Using Scientific Measurement Direct proportion Inverse Proportion As one variable increase, so does the other. As one variable increases, the other decreases
  • 27. Unit 1: Matter & Energy Section 3: Energy Transfer
  • 28. What is Energy? Energy Chemical Energy due to chemical bonds Kinetic Energy due to motion Heat (q) is the total KE in a sample Potential Energy due to position
  • 29. Energy Units Name Symbol Info Joule J SI Unit for energy calorie c (lowercase) Old energy unit 1 calorie = 4.184 J Calorie C 1000 c = 1 Calorie Food Calorie
  • 30. Energy Transfer  Energy in the form of HEAT moves back and forth between a system and its surroundings.  Temperature: Average KE of the random motion of particles in a substance.
  • 31. Energy Transfer  Specific Heat Capacity Amount of HEAT needed to raise the temperature of 1 gram of a substance 1 Kelvin (K).  Calorimeter  A device used to measure energy absorbed or released during chemical or physical change.
  • 32. Energy Transfer  How to calculate specific heat capacity: q = (m)(ΔT)(Cp) q = Heat (J) m= Mass (g) ΔT = Change in Temperature (K = °C + 273) Cp = Specific Heat Capacity (Given)
  • 33. Example Problem #1  40.00 g of water is heated from 10.00°C to 30.00°C. The specific heat of water is 4.184 J/gK. q = (m)(ΔT)(Cp) q=Heat (J) m=Mass (g) ΔT = Change in Temperature (K = °C + 273) Cp = Specific Heat Capacity (Given) q = ? m = 40.00 g ΔT = (30 + 273) - (10 + 273) = 20.00 K Cp = 4.184 J/gK q = (40.00 g) ( 20.00 K) ( 4.184 J/gK) q = 3347.2 J q = 3350 J
  • 34. Example Problem #2  135.6 g of water is cooled from 95.80°C to 21.60°C. The specific heat of water is 4.184 J/gK. q = (m)(ΔT)(Cp) q=Heat (J) m=Mass (g) ΔT = Change in Temperature (K = °C + 273) Cp = Specific Heat Capacity (Given) q = ? m = 135.6 g ΔT = (21.6 + 273) - (95.8 + 273) = -74.20 K Cp = 4.184 J/gK q = (135.6 g) ( -74.20 K) ( 4.184 J/gK) q = -42097.39 J q = -4.210 x 104 J
  • 35. Energy Transfer Practice Determine the amount of heat absorbed or released in each of the following changes. Use the table of specific heat capacity on page 533 of your text. The specific heat of water is 4.184 J/gK. 1. 40.00 g of water is heated from 10.00°C to 30.00°C. 2. 135.6 g of water is cooled from 95.80°C to 21.60°C. 3. 30.00 g of aluminum is heated from 15.00°C to 35.00°C. 4. 450.0 g of iron is cooled from 125.0°C to 45.00°C. 5. 62.30 g of lead is heated from 21.70°C to 136.4°C.
  • 36. Energy Transfer Answers to previous slide 1. +3347.2 J = + 3347 J 2. -42,097.4 J = -4.210 x 104 J 3. +538.2 J 4. -16,164.0 J = -16160 J 5. +921.8 J