The document describes a method for converting used asphalt shingles into a formed product. It involves collecting and inspecting tear-off and scrap shingles, removing debris, grinding the shingles into small particles, heating the particles into a slurry while mixing in zeolite, and placing the slurry into molds to form products that are then cooled. The goal is to recover materials like asphalt, fibers and aggregate from shingles in an environmentally friendly way without releasing hazardous compounds.
A Predictive Mathematical Model for Water Absorption of Sawdust Ash - Sand Co...Dr. Amarjeet Singh
Saw Dust Ash (SDA) is an industrial waste that has been used by many researchers in concrete to achieve economic and environmental sustainability. In this study, 5% of sand was replaced with SDA to produce concrete with different mix ratios. Scheffe’s simplex theory was used for five mix ratios in a {5,2} experimental design which resulted in additional ten mix ratios. Additional fifteen mix ratios were generated from the initial fifteen, for verification and testing. Concrete cubes of 150mmX150mmX150mm were formed using the thirty concrete mix ratios generated, and soaked in water for 24hours. The water absorptions of cubes from each mix ratio were determined with the standard procedure. The results of the first fifteen water absorption values were used for the calibration of the model constant coefficients, while those from the second fifteen were used for the model verification using Scheffe’s simplex lattice design. A mathematical regression model was formulated from the results, with which the water absorptions were predicted. The model was then subjected to a two-tailed t-test with 5% significance, which ascertained the model to be adequate and fit with an R2 value of 0.8244. The study also revealed that SDA can replace 5% of sand and promote environmental sustainability without significantly changing the water absorption.
Evaluating the effect of mixing method on the performance of mortar containin...inventionjournals
ABSTRACT: There is a vital need for managing oily materials resulting from the petroleum industry as their toxic and persistent nature threatens the environment. In view of oil waste remediation, current treatment technologies are either cost prohibitive and/or the treated products have to be sent to landfill without any potential end-use. Cement-based stabilisation/solidification of oil contaminated materials is an emerging method however there is limited knowledge in terms of the effect of the mixing method on the properties of the resultant cementitious mix. For this purpose, the water wet (WW) and oil wet (OW) protocol was devised to see if the observed behaviour of the mortar was a function of the mixing method rather than the ingredients. A cement-based mortar incorporating a mineral oil addition of up to 10% of the aggregates mass was used. The results indicated that the mixing method has only a small effect on the fresh and hardened properties. Increased oil content in the cement mortar was found to increase the flow and setting time whereas there was decreased wet density and air content irrespective of the type of the mixing method used. The compressive strength decreased by 75% and 77% for water wet and oil wet respectively compared to the control at 28 days of age. The mixing method has a relatively small impact overall on the hydration process. The calorimetry results showed that both mixing methods followed the same trend whereby the hydration is inhibited due to oil incorporation.
This paper presents the findings of an investigation on the compressive strength of concrete containing
Groundnut Husk Ash (GHA) blended with Rice Husk Ash (RHA) and its resistance to acid aggression, as well
as regression models of the concrete resistance in acidic environment. The GHA and RHA used were obtained
by controlled burning of groundnut husk and rice husk, respectively in a kiln to a temperature of 600 oC, and
after allowing cooling, sieved through sieve 75 µm and characterized. The compressive strength of GHA-RHAConcrete
was investigated at replacement levels of 0, 10, 20, 30 and 40 %, respectively by weight of cement. A
total of seventy five 150 mm cubes of GHA-RHA-Concrete grade 20 were tested for compressive strength at 3,
7, 28, 60 and 90 days of curing. Also, thirty 100 mm cubes were exposed to attack from 10 % concentration of
diluted solution of sulphuric acid (H2SO4) and nitric acid (HNO3), respectively and the concrete resistance was
also modeled using Minitab statistical software to establish regression models. The result of the investigations
showed that the compressive strength of the concrete decreased with increase in GHA-RHA content. However
15 % replacement with GHA-RHA was considered as optimum for structural concrete. The use of GHA
admixed with 10 % RHA in concrete improved its resistance against sulphuric and nitric acids aggression. The
average weight loss of GHA-RHA- concrete after 28 days of exposure in sulphuric acid and nitric acid were
11.6 % and 11.7 %, respectively as opposed to 22.4 % and 15.1 %, respectively for plain Portland cement
concrete. The regression models of GHA-RHA-Concrete for resistance against sulphuric and nitric acids were
developed with R2
values of 0.668 and 0.655, respectively and were adequate for prediction of the sensitivities
of pozzolanic activity of GHA-RHA in acidic environment.
A Predictive Mathematical Model for Water Absorption of Sawdust Ash - Sand Co...Dr. Amarjeet Singh
Saw Dust Ash (SDA) is an industrial waste that has been used by many researchers in concrete to achieve economic and environmental sustainability. In this study, 5% of sand was replaced with SDA to produce concrete with different mix ratios. Scheffe’s simplex theory was used for five mix ratios in a {5,2} experimental design which resulted in additional ten mix ratios. Additional fifteen mix ratios were generated from the initial fifteen, for verification and testing. Concrete cubes of 150mmX150mmX150mm were formed using the thirty concrete mix ratios generated, and soaked in water for 24hours. The water absorptions of cubes from each mix ratio were determined with the standard procedure. The results of the first fifteen water absorption values were used for the calibration of the model constant coefficients, while those from the second fifteen were used for the model verification using Scheffe’s simplex lattice design. A mathematical regression model was formulated from the results, with which the water absorptions were predicted. The model was then subjected to a two-tailed t-test with 5% significance, which ascertained the model to be adequate and fit with an R2 value of 0.8244. The study also revealed that SDA can replace 5% of sand and promote environmental sustainability without significantly changing the water absorption.
Evaluating the effect of mixing method on the performance of mortar containin...inventionjournals
ABSTRACT: There is a vital need for managing oily materials resulting from the petroleum industry as their toxic and persistent nature threatens the environment. In view of oil waste remediation, current treatment technologies are either cost prohibitive and/or the treated products have to be sent to landfill without any potential end-use. Cement-based stabilisation/solidification of oil contaminated materials is an emerging method however there is limited knowledge in terms of the effect of the mixing method on the properties of the resultant cementitious mix. For this purpose, the water wet (WW) and oil wet (OW) protocol was devised to see if the observed behaviour of the mortar was a function of the mixing method rather than the ingredients. A cement-based mortar incorporating a mineral oil addition of up to 10% of the aggregates mass was used. The results indicated that the mixing method has only a small effect on the fresh and hardened properties. Increased oil content in the cement mortar was found to increase the flow and setting time whereas there was decreased wet density and air content irrespective of the type of the mixing method used. The compressive strength decreased by 75% and 77% for water wet and oil wet respectively compared to the control at 28 days of age. The mixing method has a relatively small impact overall on the hydration process. The calorimetry results showed that both mixing methods followed the same trend whereby the hydration is inhibited due to oil incorporation.
This paper presents the findings of an investigation on the compressive strength of concrete containing
Groundnut Husk Ash (GHA) blended with Rice Husk Ash (RHA) and its resistance to acid aggression, as well
as regression models of the concrete resistance in acidic environment. The GHA and RHA used were obtained
by controlled burning of groundnut husk and rice husk, respectively in a kiln to a temperature of 600 oC, and
after allowing cooling, sieved through sieve 75 µm and characterized. The compressive strength of GHA-RHAConcrete
was investigated at replacement levels of 0, 10, 20, 30 and 40 %, respectively by weight of cement. A
total of seventy five 150 mm cubes of GHA-RHA-Concrete grade 20 were tested for compressive strength at 3,
7, 28, 60 and 90 days of curing. Also, thirty 100 mm cubes were exposed to attack from 10 % concentration of
diluted solution of sulphuric acid (H2SO4) and nitric acid (HNO3), respectively and the concrete resistance was
also modeled using Minitab statistical software to establish regression models. The result of the investigations
showed that the compressive strength of the concrete decreased with increase in GHA-RHA content. However
15 % replacement with GHA-RHA was considered as optimum for structural concrete. The use of GHA
admixed with 10 % RHA in concrete improved its resistance against sulphuric and nitric acids aggression. The
average weight loss of GHA-RHA- concrete after 28 days of exposure in sulphuric acid and nitric acid were
11.6 % and 11.7 %, respectively as opposed to 22.4 % and 15.1 %, respectively for plain Portland cement
concrete. The regression models of GHA-RHA-Concrete for resistance against sulphuric and nitric acids were
developed with R2
values of 0.668 and 0.655, respectively and were adequate for prediction of the sensitivities
of pozzolanic activity of GHA-RHA in acidic environment.
Summer training project on drilling fluid at ongc pptKeshar Saini
This project “Study of drill cutting and Formulation of drilling fluid.” was performed in R&D LAB, Institute of drilling technology, ONGC, dehradun. Study of drill cutting is done in terms of CST(capillary suction time), MBC(Methylene Blue Capacity) and XRD(X-ray diffraction).
• Later than several drilling fluid with different formulation are prepared and several tests (like Rheology Test, Lubricity Test, API Filter press, Linear swell Test and pH test) are performed on drilling fluid to check the suitability of it on drill cutting. Thus the suitable formulation of drilling fluid is found.
IJERA (International journal of Engineering Research and Applications) is International online, ... peer reviewed journal. For more detail or submit your article, please visit www.ijera.com
The Influence of Calcined Clay Pozzolan, Low-Cao Steel Slag and Granite Dust ...IJERA Editor
The influence of low CaO steel slag, calcined clay and granite dust on the alkali-silica reaction was investigated over a period of 35 days under accelerated curing conditions. The mineral admixtures were used to replace varying portions of high alkali Portland limestone cement up to an admixture content of 25% in order to study their effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study had a total Na2Oeq of 4.32. XRD analysis of hydrated mortar bar samples confirmed the formation of an expansive sodium silica gel in the reference Portland cement mortar bar as the agent responsible for ASR. Stable calcium silicates were formed in the mortar bars containing calcined clay in increasing quantities whilst the presence of the sodium silicate gel decreased.The occurrence of these stable silicates in hydrated samples containing steel slag and granite dust was however minimal, compared to calcined clay cement mortars. The highest expansion was recorded for granite dust mortar bars, reaching a maximum of 25.98% at 35 days. Mortar-bar expansion decreased as calcined clay content in the cement increased;mortar bars with 25% calcined clay were the least expansive recording expansion less than 0.1% at all test ages. Whilst the expansion was reduced by between 42.5% and 107.8% at 14 days with increasing calcined clay content, expansion rather increased between 36.8% and 169.5% at 14 days with increasing granite dust content.Steel slag mortar bars experienced reduction in 14 days expansion between 14.3% - 46.2%.The study confirms that steel slag and calcined clay pozzolan have greater influence on ASR in mortar bars than granite dust and shows that calcined clay and low CaO steel slag could be considered as remedial admixtures for ASR at replacement levels of 25% and 15% respectively.
DETERMINING HEIGHT OF BENCHES IN OPEN MINING OF STEEPLY-DIPPING DEPOSITS WITH...IAEME Publication
At present stage of the development of the mineral resource complex, a trend is
seen to deterioration of geological and engineering conditions of mining ore deposits,
which entails increase of losses and dilution of mineral, causing increase of the cost
price of mineral production and processing. With consideration of the specified
limiting conditions, the maximal net present value of deposit mining will be achieved
with minimal economic loss resulted from mineral losses and dilution.
For the conditions of steeply-sloping ore pits, analysis was conducted of the
impact of the bench height on the value of mineral losses and dilution, and necessary
calculations were made to identify the degree of influence of the pit bench height and
the height of the triangle of inmixed waster rocks on the values of losses and dilution
by three possible modes of preparing a new horizon (in mining from the hanging wall
to the bottom wall, in preparation across the ore body).
According to the results of the research, conclusions were made that the economic
loss related to the losses and dilution, increase in direct proportion to the increase of
bench heights; the mode of horizon preparation significantly influences the value of
losses and dilution and the economic losses related to them; the value of losses and
dilution increases with increase of bench height, and the current stripping ratio
reduces. For this reason, for determining the optimal bench height, joint consideration
of the losses and dilution with the current stripping ratio, is required. The conducted
technical and economic calculations result in recommending the bench height in ore
zone, equal to 5 m. with maintaining the rock bench height of 20 meters
Summer training project on drilling fluid at ongc pptKeshar Saini
This project “Study of drill cutting and Formulation of drilling fluid.” was performed in R&D LAB, Institute of drilling technology, ONGC, dehradun. Study of drill cutting is done in terms of CST(capillary suction time), MBC(Methylene Blue Capacity) and XRD(X-ray diffraction).
• Later than several drilling fluid with different formulation are prepared and several tests (like Rheology Test, Lubricity Test, API Filter press, Linear swell Test and pH test) are performed on drilling fluid to check the suitability of it on drill cutting. Thus the suitable formulation of drilling fluid is found.
IJERA (International journal of Engineering Research and Applications) is International online, ... peer reviewed journal. For more detail or submit your article, please visit www.ijera.com
The Influence of Calcined Clay Pozzolan, Low-Cao Steel Slag and Granite Dust ...IJERA Editor
The influence of low CaO steel slag, calcined clay and granite dust on the alkali-silica reaction was investigated over a period of 35 days under accelerated curing conditions. The mineral admixtures were used to replace varying portions of high alkali Portland limestone cement up to an admixture content of 25% in order to study their effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study had a total Na2Oeq of 4.32. XRD analysis of hydrated mortar bar samples confirmed the formation of an expansive sodium silica gel in the reference Portland cement mortar bar as the agent responsible for ASR. Stable calcium silicates were formed in the mortar bars containing calcined clay in increasing quantities whilst the presence of the sodium silicate gel decreased.The occurrence of these stable silicates in hydrated samples containing steel slag and granite dust was however minimal, compared to calcined clay cement mortars. The highest expansion was recorded for granite dust mortar bars, reaching a maximum of 25.98% at 35 days. Mortar-bar expansion decreased as calcined clay content in the cement increased;mortar bars with 25% calcined clay were the least expansive recording expansion less than 0.1% at all test ages. Whilst the expansion was reduced by between 42.5% and 107.8% at 14 days with increasing calcined clay content, expansion rather increased between 36.8% and 169.5% at 14 days with increasing granite dust content.Steel slag mortar bars experienced reduction in 14 days expansion between 14.3% - 46.2%.The study confirms that steel slag and calcined clay pozzolan have greater influence on ASR in mortar bars than granite dust and shows that calcined clay and low CaO steel slag could be considered as remedial admixtures for ASR at replacement levels of 25% and 15% respectively.
DETERMINING HEIGHT OF BENCHES IN OPEN MINING OF STEEPLY-DIPPING DEPOSITS WITH...IAEME Publication
At present stage of the development of the mineral resource complex, a trend is
seen to deterioration of geological and engineering conditions of mining ore deposits,
which entails increase of losses and dilution of mineral, causing increase of the cost
price of mineral production and processing. With consideration of the specified
limiting conditions, the maximal net present value of deposit mining will be achieved
with minimal economic loss resulted from mineral losses and dilution.
For the conditions of steeply-sloping ore pits, analysis was conducted of the
impact of the bench height on the value of mineral losses and dilution, and necessary
calculations were made to identify the degree of influence of the pit bench height and
the height of the triangle of inmixed waster rocks on the values of losses and dilution
by three possible modes of preparing a new horizon (in mining from the hanging wall
to the bottom wall, in preparation across the ore body).
According to the results of the research, conclusions were made that the economic
loss related to the losses and dilution, increase in direct proportion to the increase of
bench heights; the mode of horizon preparation significantly influences the value of
losses and dilution and the economic losses related to them; the value of losses and
dilution increases with increase of bench height, and the current stripping ratio
reduces. For this reason, for determining the optimal bench height, joint consideration
of the losses and dilution with the current stripping ratio, is required. The conducted
technical and economic calculations result in recommending the bench height in ore
zone, equal to 5 m. with maintaining the rock bench height of 20 meters
The clinical management of eclampsia has gone through many changes and achieved a good result with introduction of different regime. One of the most significant developments has been the recognition of the need for a multidisciplinary approach in the management of eclampsia and its complication.
100 sadanand v. deshpande - 7344983 - clustered surface preparation for sil...Mello_Patent_Registry
Sadanand V. Deshpande, Ying Li, Kevin E. Mello, Renee T. Mo, Wesley C. Natzle, Kirk D. Peterson, Robert J. Purtell - Clustered Surface Preparation for Silicide and Metal Contacts
Inventors and entrepreneurs have vocations fueled by passion. Many would have done it for free or as a hobby if it hadn’t become a profession. Mark Rosenzweig is a natural creator, driven by his passion. This fuel has led Mark to develop his ideas into viable products and innovations that he has been patenting since 2003. From an innovative filter sensor and indicator for vacuum cleaners to a basket for deep fryer and methods of cooking food products to a compact cyclonic bagless vacuum cleaner. Sometimes independently and often as part of creative teams, Mark has patented just under one hundred innovative inventions between 2003 and 2017.
Utilization of waste paper sludge in construction industrySandeep Jain
This technical note is recapitulation of the work carried out by researchers round the globe on characterization of waste paper sludge based on physical, chemical and mineralogical properties, activation mechanisms, pozzolanic reactivity, reaction kinematics and durability; for its possible utilization in construction industry as supplementary cementitious material, mineral admixture, partial replacement of binders in concrete, raw material for clay brick manufacturing, production of ceramics, soil stabilization in road works, reduction in carbon-dioxide emission etc., in order to encash various socio-economic and environmental benefits.
Recycling of hydrated Portland cement paste into new clinkershivakumar m naidu
The recycling of concrete is essential because it reduces the environmental impact of concrete construction
and demolition waste. For recycling, concrete waste is crushed and the coarse fraction of crushed
material can be recycled as a coarse aggregate. Concrete waste fines, which are a mix of fine aggregates,
coarse aggregate debris, and the hydrated cement paste, are currently not a part of the recycling process.
Since hydrated cement paste has all the necessary chemical elements for clinker production but without
heavy carbon dioxide emissions associated with traditional clinker raw material, it would be beneficial to
recycle concrete fines for the production of clinker. However, the data available in the literature about the
transformations of hydrated cement paste upon heating are contradictory. It is not clear whether
hydrated cement paste can be converted back to clinker. In this research, the phase transformations in
hydrated cement paste upon heating in the temperature range from 600 to 1450 C were investigated
using thermal analysis and X-ray diffractometry. The results show that hydrated Portland cement paste
can be completely recovered into a new clinker using a thermal treatment. The main phase transformations
during heating are described and compared to the literature data. The results indicate a great potential
for the complete recycling of concrete fines for the production of cement with a low carbon footprint
Compressive strength variability of brown coal fly ash geopolymer concrete
teat off shingle patent US20130307172
1. US 20130307172A1
(19) United States
(12) Patent Application Publication (10) Pub. No.: US 2013/0307172 A1
Seder et al. (43) Pub. Date: NOV. 21, 2013
(54) METHOD OF CONVERTING TEAR-OFF (52) US. Cl.
ASPHALTIC SHINGLES TO A FORMED USPC ........................................ .. 264/401; 264/140
PRODUCT
(76) Inventors: Steven B. Seder, Colorado Springs, CO (57) ABSTRACT
(US); William E. Pounds, Colorado
Springs, CO (US); Kent A. Pugsley,
Colorado Springs, CO (US); Bruce L.
Shippey, Colorado Springs, CO (US)
A method of converting asphaltic shingles to a formed prod
(21) Appl' NO‘: 13/472,753 uct, comprising the steps ofproviding a charge ofrecovered
(22) Filed; May 16, 2012 asphaltic shingles, comminuting the charge into small par
_ _ _ _ ticles, adding to the charge a quantity of hydrated alumino
Pubhcatlon Classl?catlon silicate, heating the charge While simultaneously mixing the
51 I Cl comminuted charge to a homogeneous state, placing the
( ) C 7/24 2006 01 mixed charge into molds to form the product, applying pres
B29C 71/02 E2006'01; sure to the charge in the mold for a determinable dWell time,
B29C 37/00 (200601) ejecting the product from the mold, and cooling the product.
Homogenous
Siurry
lLoading f 30
Mold
Compress / f 31
Dweii
V
Discharge Fl f 32
Mold
Cool I 33
Wash f 34
‘7
Finishing / f 35
Coating
lProduct
2. Patent Application Publication Nov. 21, 2013 Sheet 1 0f 3 US 2013/0307172 A1
Tear-Off- f 2 Prompt f 4
Scrap Scrap
l
‘I’ 5 6
First f Not f
Inspection Suspected
RAS
-- v’ f 19 W’ Out
Suspecteci
Hazardous f 7 Remove mm M
Materials Quarantine
A
‘1!’
Load t9 f 9 Negative f 17
Quarantine Resuit
‘I’
11
Test f
Sampie
‘ll’
Positive / 13
Result
1
Redirected to
Proper f 15
Disposai
FIG. 1
3. Patent Application Publication
K22
Nov. 21, 2013 Sheet 2 of3 US 2013/0307172 A1
RAS
In
if”
Land 4..
f 28
Zeoiite '
Powder
Debris .
Recycimg
Remoyai Center
Separatlon
‘
RAS Bulk f 23
Storage
24
'/
Nails f 26VGrinding
25
V f
1/2" Minus
RAS
Tap
Water
V
Heating &
Mixing
lHomogeneous
Siurry
J29
FIG. 2
4. Patent Application Publication Nov. 21, 2013 Sheet 3 of3
Homogenous
Siurry
iLoading
Mold
Compress / f 31
DweEE
V
' Discharge F/ f 32
Mold
000E
Wash
V
Finishing /
Coating
fss
iProduct
FIG. 3
US 2013/0307172 A1
5. US 2013/0307172 A1
METHOD OF CONVERTING TEAR-OFF
ASPHALTIC SHINGLES TO A FORMED
PRODUCT
FIELD OF THE INVENTION
[0001] The present invention relates to a process ofrecov
ering the available bitumen, ?bers, aggregate, and inert mate
rials contained in used asphalt shingles and creating useful
articles therefrom.
BACKGROUND OF THE INVENTION
[0002] The ever-groWing Waste stream of asphalt shingles
that have been removed from existing roofs is putting an
increasing burden on Waste management resources. Con
tained Within this Waste stream are ?nitely available reusable
products like asphalt, ?bers, aggregate and other inert mate
rials. The need to protect the ecosystem by recovering tons of
useful materials that Would normally be discarded into land
?lls is one object of this invention. The ecosystem is also
bene?ted by the process ofthis invention by initially remov
ing haZardous materials, such as asbestos, from the shingles
being processed.
[0003] Waste shingle material is normally available from
tWo sources. The largest and most conveniently available
source is shingles removed from old or damaged roofs,
referred to as “tear-off.” The second source, “Prompt scrap,”
is the trimming produced during neW shingle manufacture.
[0004] The idea to recover materials contained in tear-off
shingles and prompt scrap is not neW. A number of US.
patents exist Which disclose methods of extracting the bitu
minous materials for reuse in manufacturing neW shingles or
providing material for roadWay pavement or making neW
products.
[0005] US. Pat. No. 2,128, 1 91 relates to the use ofrecycled
asphalt shingles (RAS) as an additive to the process ofmanu
facturing neW shingles.
[0006] US. Pat. Nos. 4,325,641 and 4,706,893, among oth
ers, described uses for RAS in roadWay construction and
repair.
[0007] RAS material is separated into its constituent parts
using various methods, as those are described in US. Pat.
Nos. 4,222,851 and 5,098,025 Which use either a solvent or
Water to disassociate the component parts ofthe shingle. The
process ofthe present invention intentionally leaves the con
stituent parts of the shingles in the ?nal mix.
[0008] Some prior patents, including US. Pat. No. 5,221,
702, suggest adding other materials like rubber from tires,
polyethylene from plastic bottles, crushedbrick andminerals
such as limestone, basalt, quartz or granite to re?ne the aggre
gate ratio or to impose a color on the ?nal product. The
present process does not change the mechanical qualities of
the ?nal product by using aggregate additives.
DESCRIPTION OF THE DRAWINGS
[0009] FIG. 1 is a block ?oW diagram ofthe initial inspec
tion phase of the process of the present invention.
[0010] FIG. 2 is a block ?oW diagram ofthe secondphase of
the process through the heating step.
[0011] FIG. 3 is a block ?oW diagram ofthe last phase ofthe
process Where the asphaltic slurry is loaded into and removed
from molds for the purpose of forming a useful article.
Nov. 21,2013
DETAILED DESCRIPTION OF PREFERRED
EMBODIMENT
[0012] Referring ?rst to FIG. 1 of the draWings, the raW
material for the conversion process, tear-offand prompt scrap
2 and 4 are inspected at 5 for the presence of haZardous
materials, such as asbestos. The raW material that is not sus
pected of containing haZardous material 6 is sent directly to
the ?rst step ofthe second phase, debris removal and separa
tion 20 (FIG. 2). The batch or lot of raW material 7 that is
suspected ofcontaining haZardous material is quarantined at
9 and a sample of the lot is tested at 11 to positively identify
suspected substances. If the test sample is positive for haZ
ardous material 13, the quarantined batch is redirected to a
proper disposal 15. If the tested sample returns a negative
result 17, the batch is removed from quarantine 19 and sent to
the ?rst step ofthe second phase, debris removal and separa
tion 20.
[0013] The second phase ofthe conversion process begins
at 20 Withthe removal from the RAS offoreign materials such
as aluminum, steel, plastic and construction debris. This
material is collected and sent to an appropriate recycling
center 21. Unusable debris is directed to a land ?ll 22. Pref
erably, the output ofthe separation step contains less than one
percent by Weight of deleterious material.
[0014] The “clean” RAS may, if necessary, be stored for
processing at a later time at step 23. Whether taken from
storage or directly from the separation stage, a charge ofthe
clean RAS is placed into a grinder 24 Where the charge of
tear-offand/or prompt scrap is comminuted to a mix of small
siZed particles, preferably of less than one half inch in Width
25. The grinder can be any one of many commercially avail
able grinders that incorporate an exit conveyor having an
electro-magnetic ?nal roller 26 that attracts and redirects the
small steel particles and roo?ng nails that may remain in the
mix.
[0015] The charge of comminuted shingles 25 is trans
ferred to a heating and mixing vessel Where the amount oftap
Water 27 necessary to form slurry is added. In addition to the
Water, a quantity of aluminosilicate (Zeolite) that is approxi
mately tWo percent (2%) by Weight is added to the slurry at
28. At step 29 the slurry is heated to a temperature ofbetWeen
225 and 275 degrees Fahrenheit, While at the same time being
physically agitated by a stirring or mixing device.
[0016] The formation of the slurry and the heating and
mixing functions 29 are signi?cant steps in achieving the
ecosystem protection objectives of the invention. Avoiding
high temperature in the slurry precludes the release ofpoly
cyclic aromatic hydrocarbons (PAH) and volatile organic
compounds (VOC) that are knoWn to be haZardous to health.
[0017] As the bitumen melts in the heating step 29 With
increased temperature, the solids (aggregate/ceramic) con
tained inthe RAS are mechanically released from the paper or
?berglass matting. Gravity causes the heavier solids to settle
out due to sedimentation and the asphalt’ s increased viscosity
Which requires mechanical agitation to distribute the solids
homogeneously throughout the slurry. The heat added to the
closed system also induces a measure of thermodynamic
entropy Which, Whencontrolled, increases the tendency ofthe
process reaction to become entropically favored to proceed in
a particular direction.
[0018] The goal of the process is to change the RAS and
Zeolite mixture from its initial condition to a homogeneous
mixture With a uniform dispersion ofthe base materials Which
6. US 2013/0307172 A1
can be acted on by pressure in the third phase to change the
state of the slurry material into a useful article.
[0019] The Zeolite creates a catalysis effect on the chemical
reaction in the bituminous slurry (Which is basically an ion
exchange) because the cations are free to migrate in and out of
the Zeolite structures Which are tiny channels formed by eight
tetrahedrally coordinated silicon or aluminum atoms and
eight oxygen atoms Which measure around six angstroms.
This structure mechanically sets the maximum siZe of the
molecular or ionic species that can enter the pores and limits
the absorption to Water molecules Which can then evaporate
With continued heating and provide a micro-stirring effect on
the RAS slurry. The Zeolite thus provides a mechanism for the
reaction to successfully occur With loWer activation energy.
The end result of the heating and mixing step is a homoge
neous mixture of the constituent parts of the recovered
asphaltic shingles comprising approximately 97% recovered
and reclaimed materials after deducting 2% for the alumino
silicate minerals added and the 1% inert deleterious materials
contained in the mixture.
[0020] The third phase ofthe process begins With loading
the homogenous slurry into molds 30 for shaping the ?nal
product. Pressure on the slurry in the molds, in excess of4000
pounds per square inch, With a dWell time of at least three
seconds at 31, serves to stabiliZe and ?x the solids Within the
slurry. The pressure on the slurry in the molds increases the
kinetic energy of the its particles Which in turn increases the
number of collisions betWeen reactants in the slurry. This
increases the possibility of successful molecular collisions
and shortens the time for all ofthe material to have been acted
upon by the reaction. This feature contributes to loWering the
amount of heat necessary to obtain the same chemical reac
tion.
[0021] Following the application of pressure on the con
tents of the mold, the article is discharged from the mold at
step 32. The resultant solid homogeneous material created
after the material is cooled at step 33 is mechanically stronger
due to the absence of gas pockets that reduce the ?nal mate
rial’s mechanical strength.
[0022] The ?nal steps ofthe process are Washing the cooled
product at 36 and applying the desired ?nish or coating to the
article at 38.
What is claimed is:
1. A method of converting asphaltic shingles to a formed
product, comprising the steps of,
providing a charge ofrecovered asphalt shingles,
comminuting the charge into small particles,
addingto the charge a quantity ofhydratedaluminosilicate,
heating the charge While simultaneously mixing the com
minuted charge to a homogeneous state,
placing the mixed charge into molds to form the product,
applying pressure to the charge in the mold for a determin
able dWell time,
Nov. 21,2013
ejecting the product from the mold, and
cooling the product.
2. The method of claim 1 Where the step of providing a
charge ofrecovered asphalt shingles includes separating haZ
ardous materials from the charge.
3. The method of claim 2 Where the step of providing a
charge ofrecovered asphalt shingles further includes removal
ofaluminum, steel, plastic and debris from the charge.
4. The method of claim 2 Where the step of comminuting
the charge includes reducing the siZe of the particles to less
than one half inch.
5. The method of claim 4 Where the step of comminuting
the charge further includes removing nails from the charge by
magnetic means.
6. The method of claim 4 Where the step of heating the
charge is to a temperature ofbetWeen 225 and 275 degrees F.
7. The method of claim 6 Where the step of applying pres
sure to the charge in the mold includes pressure of at least
4,000 pounds per square inch for a dWell time ofat least three
seconds.
8. A method of converting asphaltic shingles, comprising
the steps of,
providing a charge oftear-off asphaltic shingles,
removing from said charge suspected haZardous materials,
testing the suspected materials,
rejecting positively tested materials,
removing foreign materials from negatively tested materi
als and not suspected materials,
grinding the charge,
creating a slurry ofthe ground charge by adding Water and
aluminosilicate,
heating the slurry to a temperature ofless than 300 degrees
F.
agitating the heated slurry,
loading the homogeneous slurry into a product mold,
applying pressure to the slurry in the mold to form a sold
mass, and
ejecting the solidi?ed mass from the mold.
9. The process of creating a homogeneous slurry Whose
initial constituent components are predominately solid bitu
men and a lesser quantity ofaggregate including the steps of,
creating a slurry by adding Water to a mix of comminuted
bitumen and aggregate,
adding to the slurry a catalyst of at least tWo percent by
Weight of aluminosilicate,
heating the slurry to a Fahrenheit temperature ofnot more
than 300 degrees, and
agitating the slurry.
10. The process of claim 9 Where the solid bitumen com
prises at least 97% ofthe slurry by Weight.
11. The process ofclaim 10 Where the aggregate comprises
ceramic and solid materials included in asphaltic shingles.
12. The process ofclaim 10 Where the Fahrenheit tempera
ture of the slurry is betWeen 225 and 275 degrees.
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