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Sale of Patent – WO 2012 / 089854 A PCT / ES 2010 / 000535




“Storage of Hydrogen and other gases into absorbent solids with
               treatment by Ionizing Radiation”




                       SHIR
      ..an invention to revolutionise the world
SHIR   Storage of Hydrogen using Ionizing Radiation
SHIR   Storage of Hydrogen (and other gases in absorbent solid materials treated) using Ionizing Radiations Ionizing Radiation
                                                                               Storage of Hydrogen using
COAL 80%
                                                                              COAL
                                                                                                          H2 20%




use coal as an hydrogen absorber aiming to convert it in toan improved fuel




                                                             SHIR                    Storage of Hydrogen using Ionizing Radiation
                                                                                                                           3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
Mayor       Minor      Trace  Potentially  Not
       elements   elements   elements hazardous present in
          >1%      <0.01%    <0.0001%     air     Coal
                                      pollutants




SHIR   Storage of Hydrogen using Ionizing Radiation
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
Oxigen              Typical Fixed Carbon Content in Coal
   Ash                 Ash                       Anthracite Coal : 80.5 - 85.7 weight %
                              8%
   Oxigen              10%                       Bituminous Coal : 44.9-78.2 weight %
                                                 Lignite Coal : 31.4 weight %
                               Hydrogen
   Hydrogen                       5%
   Nitrogen
                                      Nitrogen
   Sulphur    Carbon                     1%      Typical Sulphur Content in Coal
               75%                     Sulphur   Anthracite Coal :0.6 - 0.77 weight %
   Carbon                                        Bituminous Coal : 0.7 - 4.0 weight %
                                          1%     Lignite Coal : 0.4 weight %




SHIR                                              Storage of Hydrogen using Ionizing Radiation
SiO2



       Kaolinite Al2Si2O5(OH)4
       Illite KAl4(AlSi7O20)(OH)4
       Montmorillonite (½Ca,Na)0.7(Al,Mg,Fe)4[(Si,Al)4O10]2(OH)4•nH2O
       Chlorite (Mg,Al,Fe)12[(Si,Al)8O20](OH)16

       FeS2
       FeCO3




SHIR                                                                    Storage of Hydrogen using Ionizing Radiation
Cost per year
                                         Costs of plant over 10 years
Item                                        (US $)         (US $)
Irradiator Tub                               12,979.00       1,297.00
60Co   Radioisotope source (30 months)       88,000.00     35,200.00
Autoclave                                    10,963.00      1,096.00
Electrolyser & hydrogen (complete)          305,500.00     30,550.00
Electrical motor for autoclave kit               75.00           7.50
Vacuum rotary pump for autoclave              2,520.00        252.00
Pressure controller for autoclave               350.00          35.00
3 Conveyor belts                             11,427.00       1,142.00
Total                                       431,814.00     69,579.50




   SHIR                                                                 Storage of Hydrogen using Ionizing Radiation
                                                                                                              3
Prices in $/ton
                      Conventional Coal
                                                        $/ton             MJ/ton      $/MJ
0.009                 Lignite                           38.38             17,435      0.0022
0.008                 Sub- Bituminous                   71.72             18,830      0.0038
0.007
                      Bituminous coal                  102.71             21,956      0.0047
0.006
                      Anthracite                       129.58             23,865      0.0054
0.005
                      Coking coal                      172.57             22,433      0.0077
0.004
0.003   Conventional Coal
0.002   SHIR Coal                                                  Prices in $/ton
                      SHIR Coal
0.001                                                $/ton+$9.53        MJ/ton (x2)   $/MJ
   0                  SHIR Lignite                      47.91             34,870      0.0014
                      SHIR Sub Bituminous               81.25             37,660      0.0022
                      SHIR Bituminous Coal             112.24             43,912      0.0026
                      SHIR Anthracite                  139.11             47,730      0.0029
                      SHIR Coking coal                  182.1             44,866      0.0041




 SHIR                                        Storage of Hydrogen using Ionizing Radiation
                                                                                   3
Eskom estimates that about 15 new coal mines would have to come on line by 2015 and that ZAR100-billion
would have to be invested in the domestic coal mining industry by 2018. SHIR would render this redundant

While Eskom is under enormous pressure to reduce its costs, coal prices are poised to rise by between 9%
and 10% a year. With SHIR coal costs would reduce by approx. 45% overnight

Eskom relies on coal to generate 85% of South Africa’s electricity and has raised concerns about the quality
and quantity of coal received from local producers. SHIR coal resolves both these issues

South Africa is one of the world’s largest suppliers of thermal coal, but most of the product is exported to
Europe and fast-growing markets in Asia, mainly China and India. SHIR coal would generate double the
income from these Exports.
Coal accounted for 18% of the revenue that South Africa generated from commodity exports and was ranked
as the fourth-largest mineral that the country produced in 2012. SHIR coal would double this revenue

While South Africa is the twenty-eighth largest economy in the world, it is the fourteenth largest contributor
of greenhouse gases (435 Mt/year). SHIR coal would reposition SA as the twenty-sixth (217 Mt/year) .



SHIR                                                                    Storage of Hydrogen using Ionizing Radiation
                                                                                                              3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
Antonio Madroñero was the Head of the Scientific Research Unit (20 years) at
            the National Institute for Aerospace Technology and a member of the High
            Council of National Scientific Research in Spain (25 years). He is an eminent
            Doctor in Physical Science with more than 45 years’ professional experience
            within the areas of metallurgy, bio-magnetism, composite materials and
storage of Hydrogen in carbonaceous fibres. Antonio has 99 published scientific papers and
has broad international experience in technology transfer and team management. He has
outstanding communication skills that allow him to align the scientific and engineering
angle with a business-oriented perspective to ensure the technologies developed are
sustainable, dependable and affordable. We believe that Antonio has developed and
patented the process that will revolutionise the world - SHIR




 SHIR                                                      Storage of Hydrogen using Ionizing Radiation
                                                                                                 3
Pilar has a degree in Environmental Science from Madrid, Spain and holds two
            Masters in Renewable Energy and Climate Change respectively and a MBA
            with specialisation in Strategic Carbon Management from the University of
            East Anglia (UK). Pilar’s expertise covers 9 years of technical management in
            the Renewable Energy industry and 3 years as a sustainability consultant
developing corporate engagement strategies for sustainability reporting and organisational
carbon footprint management. She is a seasoned international business developer in
Emerging Markets and is fluent in Spanish and English with an understanding of French,
German, Portuguese and Italian.




 SHIR                                                     Storage of Hydrogen using Ionizing Radiation
                                                                                                3
SHIR   Storage of Hydrogen using Ionizing Radiation
                                             3
THANK YOU



            3

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Shir technology april 2013

  • 1. Sale of Patent – WO 2012 / 089854 A PCT / ES 2010 / 000535 “Storage of Hydrogen and other gases into absorbent solids with treatment by Ionizing Radiation” SHIR ..an invention to revolutionise the world
  • 2. SHIR Storage of Hydrogen using Ionizing Radiation
  • 3. SHIR Storage of Hydrogen (and other gases in absorbent solid materials treated) using Ionizing Radiations Ionizing Radiation Storage of Hydrogen using
  • 4. COAL 80% COAL H2 20% use coal as an hydrogen absorber aiming to convert it in toan improved fuel SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 5. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 6. Mayor Minor Trace Potentially Not elements elements elements hazardous present in >1% <0.01% <0.0001% air Coal pollutants SHIR Storage of Hydrogen using Ionizing Radiation
  • 7. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 8. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 9. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 10. Oxigen Typical Fixed Carbon Content in Coal Ash Ash Anthracite Coal : 80.5 - 85.7 weight % 8% Oxigen 10% Bituminous Coal : 44.9-78.2 weight % Lignite Coal : 31.4 weight % Hydrogen Hydrogen 5% Nitrogen Nitrogen Sulphur Carbon 1% Typical Sulphur Content in Coal 75% Sulphur Anthracite Coal :0.6 - 0.77 weight % Carbon Bituminous Coal : 0.7 - 4.0 weight % 1% Lignite Coal : 0.4 weight % SHIR Storage of Hydrogen using Ionizing Radiation
  • 11. SiO2 Kaolinite Al2Si2O5(OH)4 Illite KAl4(AlSi7O20)(OH)4 Montmorillonite (½Ca,Na)0.7(Al,Mg,Fe)4[(Si,Al)4O10]2(OH)4•nH2O Chlorite (Mg,Al,Fe)12[(Si,Al)8O20](OH)16 FeS2 FeCO3 SHIR Storage of Hydrogen using Ionizing Radiation
  • 12. Cost per year Costs of plant over 10 years Item (US $) (US $) Irradiator Tub 12,979.00 1,297.00 60Co Radioisotope source (30 months) 88,000.00 35,200.00 Autoclave 10,963.00 1,096.00 Electrolyser & hydrogen (complete) 305,500.00 30,550.00 Electrical motor for autoclave kit 75.00 7.50 Vacuum rotary pump for autoclave 2,520.00 252.00 Pressure controller for autoclave 350.00 35.00 3 Conveyor belts 11,427.00 1,142.00 Total 431,814.00 69,579.50 SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 13. Prices in $/ton Conventional Coal $/ton MJ/ton $/MJ 0.009 Lignite 38.38 17,435 0.0022 0.008 Sub- Bituminous 71.72 18,830 0.0038 0.007 Bituminous coal 102.71 21,956 0.0047 0.006 Anthracite 129.58 23,865 0.0054 0.005 Coking coal 172.57 22,433 0.0077 0.004 0.003 Conventional Coal 0.002 SHIR Coal Prices in $/ton SHIR Coal 0.001 $/ton+$9.53 MJ/ton (x2) $/MJ 0 SHIR Lignite 47.91 34,870 0.0014 SHIR Sub Bituminous 81.25 37,660 0.0022 SHIR Bituminous Coal 112.24 43,912 0.0026 SHIR Anthracite 139.11 47,730 0.0029 SHIR Coking coal 182.1 44,866 0.0041 SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 14. Eskom estimates that about 15 new coal mines would have to come on line by 2015 and that ZAR100-billion would have to be invested in the domestic coal mining industry by 2018. SHIR would render this redundant While Eskom is under enormous pressure to reduce its costs, coal prices are poised to rise by between 9% and 10% a year. With SHIR coal costs would reduce by approx. 45% overnight Eskom relies on coal to generate 85% of South Africa’s electricity and has raised concerns about the quality and quantity of coal received from local producers. SHIR coal resolves both these issues South Africa is one of the world’s largest suppliers of thermal coal, but most of the product is exported to Europe and fast-growing markets in Asia, mainly China and India. SHIR coal would generate double the income from these Exports. Coal accounted for 18% of the revenue that South Africa generated from commodity exports and was ranked as the fourth-largest mineral that the country produced in 2012. SHIR coal would double this revenue While South Africa is the twenty-eighth largest economy in the world, it is the fourteenth largest contributor of greenhouse gases (435 Mt/year). SHIR coal would reposition SA as the twenty-sixth (217 Mt/year) . SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 15. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 16. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 17. Antonio Madroñero was the Head of the Scientific Research Unit (20 years) at the National Institute for Aerospace Technology and a member of the High Council of National Scientific Research in Spain (25 years). He is an eminent Doctor in Physical Science with more than 45 years’ professional experience within the areas of metallurgy, bio-magnetism, composite materials and storage of Hydrogen in carbonaceous fibres. Antonio has 99 published scientific papers and has broad international experience in technology transfer and team management. He has outstanding communication skills that allow him to align the scientific and engineering angle with a business-oriented perspective to ensure the technologies developed are sustainable, dependable and affordable. We believe that Antonio has developed and patented the process that will revolutionise the world - SHIR SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 18. Pilar has a degree in Environmental Science from Madrid, Spain and holds two Masters in Renewable Energy and Climate Change respectively and a MBA with specialisation in Strategic Carbon Management from the University of East Anglia (UK). Pilar’s expertise covers 9 years of technical management in the Renewable Energy industry and 3 years as a sustainability consultant developing corporate engagement strategies for sustainability reporting and organisational carbon footprint management. She is a seasoned international business developer in Emerging Markets and is fluent in Spanish and English with an understanding of French, German, Portuguese and Italian. SHIR Storage of Hydrogen using Ionizing Radiation 3
  • 19. SHIR Storage of Hydrogen using Ionizing Radiation 3