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SemiMap Objective  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Worldwide Representation Moritani & Co.,Ltd. 1-4-22 Yaesu Chuo-Ku Tokyo 103-8680 Japan Phone: 81-3-3278-6163 Fax:    81-3-3278-6021 [email_address] www.sales.moritani.co.jp Hologenix, Inc. 5932 Bolsa Avenue  Suite 104 Huntington Beach CA 92649  USA Phone : (714) 903-5999  Fax:     (714) 903-5959 [email_address] www.hologenix.com SemiMap  Scientific Instruments Tullastr. 67 79108 Freiburg  Germany Phone: *49(0)761 5577878 Fax:  *49(0)761 5577 879 [email_address] www.s e mimap.de   Japan US and East Asia Europe
SemiMap pre-History  Strong involvement in DIN/SEMI compound semiconductor standardization activities  since 1990 Sale of COREMA-WT systems to industry and academia in Europe, US and Japan 1998-2003 Representation in US/Japan/Asia by Hologenix  Inc., Los Angeles 1998 Multi- purpose application of TDCM for in-house research and material control; extensive presentation and publication activity; development of commercial system  1992 - 97 Basic paper by Stibal, Windscheif and Jantz; Delivery of prototype wafer topography system to Wacker Chemitronic, later transferred to Freiberger Compound Materials (FCM)  1991 Start of research activity at FhG-IAF to evaluate high resistivity semiconductors with contactless capacitive techniques (TDCM)  1989
SemiMap History Participation in SiC resistivity Round Robin, Presentations at ICSCRM in Otsu, Japan 2007 Cooperation with Moritani & Co Ltd. Tokyo, Japan Development of procedures to analyse locally inhomogeneous material  2006 Development and market introduction  of CORTEMA-VT/ER 2005 Extension of material analysis to SiC, InP, GaN, Cd(Zn)Te, FZ-Si 2004 First SemiMap COREMA-WT sale, development and market introduction of COREMA-RM July 2003 Foundation of Semimap Scientific Instruments GmbH, transfer of technical know how and fabrication from FhG/IAF to SemiMap  April 2003
Basics of  CO ntactless  RE sistivity  MA pping   (I) ,[object Object],[object Object],[object Object],Semi-insulating semiconductor d A
Basics of  CO ntactless  RE sistivity  MA pping (II) ,[object Object],   = R s (C s +C a ) c huck wafer guard electrode 1  mm measured volume air gap ,[object Object]
Basics of  CO ntactless  RE sistivity  MA pping (III) ,[object Object],   = R s  (C s +C a ) U Charge transient after  voltage step application 0 ¥ t t 0 Q Q
Basics of  CO ntactless  RE sistivity  MA pping   (IV) ,[object Object],[object Object],[object Object],[object Object]
SemiMap Product Line  Measurement of sheet resistance (>10 5    of epitaxial buffer layers COREMA-ER Measurement of resistivity at variable temperature up to 400  o C, evaluation of carrier activation energy via Arrhenius plot  COREMA-VT Contactless evaluation of the carrier mobility (>1000 cm 2/ Vs) manual wafer shifting for selection of measurement spot.  COREMA-RM Contactless mapping of wafers up to 200 mm  ø 1 mm resolution; resistivity range 1x10 5  to 1x10 12   cm , automated measurement routines, statistical analysis. COREMA-WT
Technical Details (I)  COREMA - WT
Technical Details (II)  COREMA - WT
Technical Details (III)  COREMA - WT
Technical Details (I)  COREMA - RM
Permanent Magnet System Design ,[object Object],[object Object],0 5 10 15 20 25 30 0 2 4 6 8 10  1 mm Magnetic Field B (10 -1 T)  Horizontal Distance (mm) M M B Technical Details (II)  COREMA-RM
Technical Details (III)  COREMA-RM Magnetic  Field  0
Technical Details (IV)  COREMA-RM ,[object Object],[object Object],[object Object],[object Object],[object Object]
Technical Details (V)  COREMA-RM new method standard method Acceptance SI material only µ > 1000 cm 2 /Vs general Applicability easy difficult Evaluation of SI material < 1% ~  5% Repeatability ~ 30 s ~ 10 min Sample insertion and measurement time  none ~ 15 min Sample preparation obsolete needed, critical Ohmic contacts nondestructive  necessary Wafer cutting COREMA - RM CONVENTIONAL HALL   ISSUE
Technical Details (I)  COREMA-VT Substrate Heated Support Sensor Charge Amplifier
Technical Details (II)  COREMA-VT
Technical Details (III)  COREMA-VT
Technical Details (IV)  COREMA  - VT ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Technical Details (I)  COREMA-ER Buffer layers on semi-insulating substrates are analysed with a COREMA-VT harware system using  a modified  measurement and evaluation procedure. The epilayer  resistance is obtained using a calibration factor depending on the design and size of the sensor. The epilayer resistivity is calulated using the layer thickness.  Epilayer Substrate Support Sensor Charge Amplifier
COREMA-ER (II)  Applicability   ,[object Object],[object Object],[object Object]
COREMA-ER (III)  Measurement Range ,[object Object],[object Object],[object Object]
Resistivity Topography  GaAs Substrate Production Control   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Resistivity Topography   Repeatability test
Resistivity Topography  GaAs Substrate Production Control
Resistivity Topography  InP Substrate Production Control ,[object Object],[object Object],[object Object],[object Object]
Resistivity Topography  SiC Substrate Production Control ,[object Object],[object Object],[object Object],[object Object]
Resistivity Topography  Exploratory SiC Material Development ,[object Object],[object Object],[object Object],[object Object],[object Object]
Resistivity Topography   Strongly and locally inhomogeneous SiC material
Identification and evaluation of locally inhomogeneous  matertial using analysis of charge transients
Bi-exponential fit
Resistivity Topography  Analysis of Persistent Photoconductivity   Mean: 1.12  x10 10   cm  Mean: 1.65  x10 11   cm Resistivity after 3h storage in darkness Resistivity after 48h storage in darkness
Resistivity Topography   CdTe sample
Magnetic Field Dependence of Resistivity ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],0.0 0.2 0.4 0.6 0.8 1.0 80  85  90  95  100  105  110  115  120  125  130  135  Time Constant     (µs)   Magnetic Field B (Tesla)
Comparison of mobility data
Mobility Measurement Plan Mobility evaluation using a customer specified  measurement plan  150 mm GaAs wafer
High Temperature Resistivity Measurement 2“ SiC wafer Temperature range 40 – 200  0 C Resistivity range 3x10 5  –   1x10 10  Ω cm Not semi-insulating at 300  0 C   E a  = (kT 1 T 2 )/(T 2 -T 1 ) * ln [  (T 1 )  /   (T 2 ) ]
High Temperature Resistivity Measurement 2“ SiC wafer Temperature range 260 –   340  0 C Resistivity range 5.6 x10 9  –   1.8x10 11  Ω cm Semi-insulating at 300  0 C
Lateral dependence of activation energy
Arrhenius Plot of exploratory Wafer
High Temperature Resistivity Measurement 2“ SiC wafer Temperature  range 92  –   256  0 C Resistivity range 9.0 x10 8  –   2.3x10 10  Ω cm High resistivity, but small activation energy Exhibits strong persistent photoconductivity
Persistent Photoconductivity Heating Curve
Evaluation of GaN epitaxial layers Epilayer thickness (µm)  Resistance SemiMap (Ω square) Resistivity  SemiMap (Ω cm) Resistance  Lehighton (Ω square) 2 6.05 E6 1.2 E 3 beyond limit 2 5.0 E4 (at lower limit) 1.0 E 1 5 E4 (at upper limit) 2 1.0 E11(at upper limit) 2.0 E 7 beyond limit
Summary ,[object Object],[object Object],[object Object],[object Object]

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Semimap Corema Presentation

  • 1.  
  • 2.
  • 3. Worldwide Representation Moritani & Co.,Ltd. 1-4-22 Yaesu Chuo-Ku Tokyo 103-8680 Japan Phone: 81-3-3278-6163 Fax:    81-3-3278-6021 [email_address] www.sales.moritani.co.jp Hologenix, Inc. 5932 Bolsa Avenue Suite 104 Huntington Beach CA 92649 USA Phone : (714) 903-5999 Fax:    (714) 903-5959 [email_address] www.hologenix.com SemiMap Scientific Instruments Tullastr. 67 79108 Freiburg Germany Phone: *49(0)761 5577878 Fax: *49(0)761 5577 879 [email_address] www.s e mimap.de Japan US and East Asia Europe
  • 4. SemiMap pre-History Strong involvement in DIN/SEMI compound semiconductor standardization activities since 1990 Sale of COREMA-WT systems to industry and academia in Europe, US and Japan 1998-2003 Representation in US/Japan/Asia by Hologenix Inc., Los Angeles 1998 Multi- purpose application of TDCM for in-house research and material control; extensive presentation and publication activity; development of commercial system 1992 - 97 Basic paper by Stibal, Windscheif and Jantz; Delivery of prototype wafer topography system to Wacker Chemitronic, later transferred to Freiberger Compound Materials (FCM) 1991 Start of research activity at FhG-IAF to evaluate high resistivity semiconductors with contactless capacitive techniques (TDCM) 1989
  • 5. SemiMap History Participation in SiC resistivity Round Robin, Presentations at ICSCRM in Otsu, Japan 2007 Cooperation with Moritani & Co Ltd. Tokyo, Japan Development of procedures to analyse locally inhomogeneous material 2006 Development and market introduction of CORTEMA-VT/ER 2005 Extension of material analysis to SiC, InP, GaN, Cd(Zn)Te, FZ-Si 2004 First SemiMap COREMA-WT sale, development and market introduction of COREMA-RM July 2003 Foundation of Semimap Scientific Instruments GmbH, transfer of technical know how and fabrication from FhG/IAF to SemiMap April 2003
  • 6.
  • 7.
  • 8.
  • 9.
  • 10. SemiMap Product Line Measurement of sheet resistance (>10 5  of epitaxial buffer layers COREMA-ER Measurement of resistivity at variable temperature up to 400 o C, evaluation of carrier activation energy via Arrhenius plot COREMA-VT Contactless evaluation of the carrier mobility (>1000 cm 2/ Vs) manual wafer shifting for selection of measurement spot. COREMA-RM Contactless mapping of wafers up to 200 mm ø 1 mm resolution; resistivity range 1x10 5 to 1x10 12  cm , automated measurement routines, statistical analysis. COREMA-WT
  • 11. Technical Details (I) COREMA - WT
  • 12. Technical Details (II) COREMA - WT
  • 13. Technical Details (III) COREMA - WT
  • 14. Technical Details (I) COREMA - RM
  • 15.
  • 16. Technical Details (III) COREMA-RM Magnetic Field  0
  • 17.
  • 18. Technical Details (V) COREMA-RM new method standard method Acceptance SI material only µ > 1000 cm 2 /Vs general Applicability easy difficult Evaluation of SI material < 1% ~ 5% Repeatability ~ 30 s ~ 10 min Sample insertion and measurement time none ~ 15 min Sample preparation obsolete needed, critical Ohmic contacts nondestructive necessary Wafer cutting COREMA - RM CONVENTIONAL HALL   ISSUE
  • 19. Technical Details (I) COREMA-VT Substrate Heated Support Sensor Charge Amplifier
  • 22.
  • 23. Technical Details (I) COREMA-ER Buffer layers on semi-insulating substrates are analysed with a COREMA-VT harware system using a modified measurement and evaluation procedure. The epilayer resistance is obtained using a calibration factor depending on the design and size of the sensor. The epilayer resistivity is calulated using the layer thickness. Epilayer Substrate Support Sensor Charge Amplifier
  • 24.
  • 25.
  • 26.
  • 27. Resistivity Topography Repeatability test
  • 28. Resistivity Topography GaAs Substrate Production Control
  • 29.
  • 30.
  • 31.
  • 32. Resistivity Topography Strongly and locally inhomogeneous SiC material
  • 33. Identification and evaluation of locally inhomogeneous matertial using analysis of charge transients
  • 35. Resistivity Topography Analysis of Persistent Photoconductivity Mean: 1.12 x10 10  cm Mean: 1.65 x10 11  cm Resistivity after 3h storage in darkness Resistivity after 48h storage in darkness
  • 36. Resistivity Topography CdTe sample
  • 37.
  • 39. Mobility Measurement Plan Mobility evaluation using a customer specified measurement plan 150 mm GaAs wafer
  • 40. High Temperature Resistivity Measurement 2“ SiC wafer Temperature range 40 – 200 0 C Resistivity range 3x10 5 – 1x10 10 Ω cm Not semi-insulating at 300 0 C E a = (kT 1 T 2 )/(T 2 -T 1 ) * ln [  (T 1 ) /  (T 2 ) ]
  • 41. High Temperature Resistivity Measurement 2“ SiC wafer Temperature range 260 – 340 0 C Resistivity range 5.6 x10 9 – 1.8x10 11 Ω cm Semi-insulating at 300 0 C
  • 42. Lateral dependence of activation energy
  • 43. Arrhenius Plot of exploratory Wafer
  • 44. High Temperature Resistivity Measurement 2“ SiC wafer Temperature range 92 – 256 0 C Resistivity range 9.0 x10 8 – 2.3x10 10 Ω cm High resistivity, but small activation energy Exhibits strong persistent photoconductivity
  • 46. Evaluation of GaN epitaxial layers Epilayer thickness (µm) Resistance SemiMap (Ω square) Resistivity SemiMap (Ω cm) Resistance Lehighton (Ω square) 2 6.05 E6 1.2 E 3 beyond limit 2 5.0 E4 (at lower limit) 1.0 E 1 5 E4 (at upper limit) 2 1.0 E11(at upper limit) 2.0 E 7 beyond limit
  • 47.