An experimental study on the effect of alkali treatment on properties of kena...eSAT Journals
Abstract Kenaf fibers are coming into interest to use in reinforced concrete elements in recent years due to its attractive properties such as non-abrasive, lightweight and renewable. However, the properties of kenaf fiber such as high moisture absorption and weak in interfacial adhesion make the use of kenaf fiber in reinforced concrete elements become less attractive. Alkali treatment is one of the best used chemical treatment for natural fibers. It help to increase the fiber surface roughness by chemically modify and clean the fiber surface. The purpose of this research is to do a fundamental study on the effects of alkali solutions to the kenaf fiber. There are a lot of researchers conducted study on the effects of different concentrations of NaOH on kenaf fiber. However, there is no information about the study of alkali treatment of kenaf fiber with different pH. Therefore, this study seeks to determine the effects of alkali pH on the properties of kenaf fiber. By theoretically, the pH of concrete is around 13, so it is important to have a better understanding on the effects of alkaline to the kenaf fiber especially pH 13. The finding of the research can help to develop an effective use of fiber in cementitious materials. The problem of water absorption of kenaf fiber could appear if fibers are directly introduced in concrete. For these reasons, in this study, different pH of NaOH ( pH 8 to 14) were used and the effects on the colour of fiber, weight loss and water absorption of treated kenaf fibers were evaluated. Keywords: Kenaf fiber; Natural fiber; Alkali treatment; Weight loss; Water absorption
Correlation between corrosion inhibitive effect and quantum molecular structu...Al Baha University
Correlation between corrosion inhibitive effect and quantum molecular structure of Schiff bases for iron in acidic and alkaline media
Quantum chemical calculations using the density functional theory (DFT) have been applied to the five kinds of polydentate Schiff base compounds (PSCs), act as inhibitors for iron in aerated 2.0 M HNO3 and 2.0 M NaOH media. The structural parameters, such as the frontier molecular orbital energy HOMO (highest occupied molecular orbital), LUMO (lowest unoccupied molecular orbital), energy gap ΔE (ELUMO - EHOMO), the charge distribution, the absolute electronegativity (χ), the fraction of electrons transfer (ΔN) from inhibitors to iron, the dipole moment (μ), the global hardness (η) and the total energy (Etotal) were also calculated and correlated with their inhibition efficiencies (%IE). The inhibition effects of (PSCs) may be explained in terms of electronic properties. The results showed that the (%IE) of PSCs increased with the increase in EHOMO and decrease in ELUMO - EHOMO. The inhibitor molecules were first adsorbed on the iron surface and blocking the reaction sites available for corrosive attack; and the areas containing N and O atoms are most possible sites for bonding by donating electrons to the iron surface through interaction with π-electrons of the aromatic rings, and the azo methine group. Also, the adsorbed Schiff base molecules interact with iron ions in the corrosive media leading to neutral and cationic iron-Schiff base complexes. Adsorption process is spontaneous, exothermic and obeyed Temkin isotherm and regarded as physical as chemical mechanism. The polarization studied indicated that the inhibitors act as a mixed type inhibitor in HNO3; cause only inhibition of the cathode process in NaOH, and the magnitude of the displacement of the Tafel plot is proportional to its concentration. Models for the inhibition corrosion behaviour were developed based upon statistical analyses of the experimental data. Some thermodynamic and kinetic parameters (Kads, ΔGads) were estimated. Both experimental and quantum theoretical calculations are in excellent agreement. The inhibition efficiency increase in the order of: PSC_1 > PSC_2 > PSC_3 > PSC_4>PSC_5. Thus, DFT study gave further insight into the mechanism of inhibition action of PSCs. This research might provide a theoretical inhibition performance evaluation approach for homologous inhibitors.
An experimental study on the effect of alkali treatment on properties of kena...eSAT Journals
Abstract Kenaf fibers are coming into interest to use in reinforced concrete elements in recent years due to its attractive properties such as non-abrasive, lightweight and renewable. However, the properties of kenaf fiber such as high moisture absorption and weak in interfacial adhesion make the use of kenaf fiber in reinforced concrete elements become less attractive. Alkali treatment is one of the best used chemical treatment for natural fibers. It help to increase the fiber surface roughness by chemically modify and clean the fiber surface. The purpose of this research is to do a fundamental study on the effects of alkali solutions to the kenaf fiber. There are a lot of researchers conducted study on the effects of different concentrations of NaOH on kenaf fiber. However, there is no information about the study of alkali treatment of kenaf fiber with different pH. Therefore, this study seeks to determine the effects of alkali pH on the properties of kenaf fiber. By theoretically, the pH of concrete is around 13, so it is important to have a better understanding on the effects of alkaline to the kenaf fiber especially pH 13. The finding of the research can help to develop an effective use of fiber in cementitious materials. The problem of water absorption of kenaf fiber could appear if fibers are directly introduced in concrete. For these reasons, in this study, different pH of NaOH ( pH 8 to 14) were used and the effects on the colour of fiber, weight loss and water absorption of treated kenaf fibers were evaluated. Keywords: Kenaf fiber; Natural fiber; Alkali treatment; Weight loss; Water absorption
Correlation between corrosion inhibitive effect and quantum molecular structu...Al Baha University
Correlation between corrosion inhibitive effect and quantum molecular structure of Schiff bases for iron in acidic and alkaline media
Quantum chemical calculations using the density functional theory (DFT) have been applied to the five kinds of polydentate Schiff base compounds (PSCs), act as inhibitors for iron in aerated 2.0 M HNO3 and 2.0 M NaOH media. The structural parameters, such as the frontier molecular orbital energy HOMO (highest occupied molecular orbital), LUMO (lowest unoccupied molecular orbital), energy gap ΔE (ELUMO - EHOMO), the charge distribution, the absolute electronegativity (χ), the fraction of electrons transfer (ΔN) from inhibitors to iron, the dipole moment (μ), the global hardness (η) and the total energy (Etotal) were also calculated and correlated with their inhibition efficiencies (%IE). The inhibition effects of (PSCs) may be explained in terms of electronic properties. The results showed that the (%IE) of PSCs increased with the increase in EHOMO and decrease in ELUMO - EHOMO. The inhibitor molecules were first adsorbed on the iron surface and blocking the reaction sites available for corrosive attack; and the areas containing N and O atoms are most possible sites for bonding by donating electrons to the iron surface through interaction with π-electrons of the aromatic rings, and the azo methine group. Also, the adsorbed Schiff base molecules interact with iron ions in the corrosive media leading to neutral and cationic iron-Schiff base complexes. Adsorption process is spontaneous, exothermic and obeyed Temkin isotherm and regarded as physical as chemical mechanism. The polarization studied indicated that the inhibitors act as a mixed type inhibitor in HNO3; cause only inhibition of the cathode process in NaOH, and the magnitude of the displacement of the Tafel plot is proportional to its concentration. Models for the inhibition corrosion behaviour were developed based upon statistical analyses of the experimental data. Some thermodynamic and kinetic parameters (Kads, ΔGads) were estimated. Both experimental and quantum theoretical calculations are in excellent agreement. The inhibition efficiency increase in the order of: PSC_1 > PSC_2 > PSC_3 > PSC_4>PSC_5. Thus, DFT study gave further insight into the mechanism of inhibition action of PSCs. This research might provide a theoretical inhibition performance evaluation approach for homologous inhibitors.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...suresh899
Carbon Supported PtRu nanocatalysts have been prepared by simple impregnation reduction method in which Pt and Ru precursors are reduced by ethanol under reflux conditions for different reaction times. The prepared nanocatalysts were characterized by means of XRD, EDAX, ICP-AAS, FESEM and TEM. XRD analyses showed that all nanocatalysts exhibited f.c.c crystal structure, the structure characteristic for pure Pt, except for that reduced at prolonged reaction time of 4h which showed the presence of characteristic peak for Ru metal. The lattice constant calculations indicate that all catalysts are present in unalloyed phase and the average particle size as determined by TEM was in the range of 3.7 nm. The electrocatalytic activities and stability for the prepared nanocatalysts methanol electro-oxidation reaction (MOR) were studied by cyclic voltammetry. The catalysts prepared at 2h reduction time showed higher electrocatalytic activity in terms of mass specific activity and good stability over potential sweep for 100 cycles for methanol electro-oxidation. The results showed that the prepared nanocatalysts are considered as promising electrode catalyst (anode catalyst) for electro-oxidation of methanol in direct methanol fuel cells.
Polyethersulfone (PES) is a polymeric permeable material used in ultrafiltration (UF)
membranes due to its high thermomechanical and chemical stability. The hydrophobic nature of
PES membranes renders them prone to fouling and restricts the practical applications of PES in the
fabrication of water treatment membranes. The present study demonstrates a non-solvent-induced
phase separation (NIPS) approach to modifying PES membranes with different concentrations of
discrete TiO2 nanotubes (TNTs). Zeta potential and contact angle measurements showed enhanced
hydrophilicity and surface negative charge in TNTs/PES nanocomposite membranes compared to
unmodified PES membranes. To discern the antifouling and permeation properties of the TNTs/PES
membranes, steam assisted gravity drainage (SAGD) wastewater obtained from the Athabasca oil
sands of Alberta was used. The TiO2 modified polymer nanocomposite membranes resulted in a
higher organic matter rejection and water flux than the unmodified PES membrane. The addition of
discrete TNTs at 1 wt% afforded maximum water flux (82 L/m2 h at 40 psi), organic matter rejection
(53.9%), and antifouling properties (29% improvement in comparison to pristine PES membrane).
An enhancement in fouling resistance of TNTs/PES nanocomposite membranes was observed in
flux recovery ratio experiments.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
journal publishing, how to publish research paper, Call For research paper, international journal, publishing a paper, IJERD, journal of science and technology, how to get a research paper published, publishing a paper, publishing of journal, publishing of research paper, reserach and review articles, IJERD Journal, How to publish your research paper, publish research paper, open access engineering journal, Engineering journal, Mathemetics journal, Physics journal, Chemistry journal, Computer Engineering, Computer Science journal, how to submit your paper, peer reviw journal, indexed journal, reserach and review articles, engineering journal, www.ijerd.com, research journals,
yahoo journals, bing journals, International Journal of Engineering Research and Development, google journals, hard copy of journal
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...suresh899
Carbon Supported PtRu nanocatalysts have been prepared by simple impregnation reduction method in which Pt and Ru precursors are reduced by ethanol under reflux conditions for different reaction times. The prepared nanocatalysts were characterized by means of XRD, EDAX, ICP-AAS, FESEM and TEM. XRD analyses showed that all nanocatalysts exhibited f.c.c crystal structure, the structure characteristic for pure Pt, except for that reduced at prolonged reaction time of 4h which showed the presence of characteristic peak for Ru metal. The lattice constant calculations indicate that all catalysts are present in unalloyed phase and the average particle size as determined by TEM was in the range of 3.7 nm. The electrocatalytic activities and stability for the prepared nanocatalysts methanol electro-oxidation reaction (MOR) were studied by cyclic voltammetry. The catalysts prepared at 2h reduction time showed higher electrocatalytic activity in terms of mass specific activity and good stability over potential sweep for 100 cycles for methanol electro-oxidation. The results showed that the prepared nanocatalysts are considered as promising electrode catalyst (anode catalyst) for electro-oxidation of methanol in direct methanol fuel cells.
Polyethersulfone (PES) is a polymeric permeable material used in ultrafiltration (UF)
membranes due to its high thermomechanical and chemical stability. The hydrophobic nature of
PES membranes renders them prone to fouling and restricts the practical applications of PES in the
fabrication of water treatment membranes. The present study demonstrates a non-solvent-induced
phase separation (NIPS) approach to modifying PES membranes with different concentrations of
discrete TiO2 nanotubes (TNTs). Zeta potential and contact angle measurements showed enhanced
hydrophilicity and surface negative charge in TNTs/PES nanocomposite membranes compared to
unmodified PES membranes. To discern the antifouling and permeation properties of the TNTs/PES
membranes, steam assisted gravity drainage (SAGD) wastewater obtained from the Athabasca oil
sands of Alberta was used. The TiO2 modified polymer nanocomposite membranes resulted in a
higher organic matter rejection and water flux than the unmodified PES membrane. The addition of
discrete TNTs at 1 wt% afforded maximum water flux (82 L/m2 h at 40 psi), organic matter rejection
(53.9%), and antifouling properties (29% improvement in comparison to pristine PES membrane).
An enhancement in fouling resistance of TNTs/PES nanocomposite membranes was observed in
flux recovery ratio experiments.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
journal publishing, how to publish research paper, Call For research paper, international journal, publishing a paper, IJERD, journal of science and technology, how to get a research paper published, publishing a paper, publishing of journal, publishing of research paper, reserach and review articles, IJERD Journal, How to publish your research paper, publish research paper, open access engineering journal, Engineering journal, Mathemetics journal, Physics journal, Chemistry journal, Computer Engineering, Computer Science journal, how to submit your paper, peer reviw journal, indexed journal, reserach and review articles, engineering journal, www.ijerd.com, research journals,
yahoo journals, bing journals, International Journal of Engineering Research and Development, google journals, hard copy of journal
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد
عالم من كبار العلماء العاملين
نذر حياته وأوقف وقته وجهده وماله لله تعالى
يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة
علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام،
ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ /فوزى محمد أبوزيد
عالم من كبار العلماء العاملين
نذر حياته وأوقف وقته وجهده وماله لله تعالى
يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة
علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين ،وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض ,على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام ،
ومربى فاضل له تلاميذ فى جميع بلاد العالم
فضيلة الشيخ / فوزى محمد أبوزيد عالم من كبار العلماء العاملين نذر حياته وأوقف وقته وجهده وماله لله تعالى يدعو إلى الله على بصيرة بالحكمة والموعظة الحسنة علم من أعلام الدعوةإلى الله تعالى فى القرن الحادى والعشرين، وواحد من العلماء السائرين على منهاج النبى صلى الله عليه والمتمسكين بسنته والمجددين لفهم أمور الدين بما يناسب ما جد فى هذا العصر من آفات وأمراض، على منهج أهل السنة والجماعة وعلى نهج الصحابة الكرام، ومربى فاضل له تلاميذ فى جميع بلاد العالم
IA Literature Review on Synthesis and Characterization of enamelled copper wi...Editor IJCATR
This paper discusses about the survey on the various magazines, conference papers and journals for understanding the
properties of enamelled copper wires mixed with nano fillers, fundamental methods for synthesis and characterization of carbon
nanotubes. From all these papers, it was noted that the research work carried out in an enamelled copper wires filled with nano fillers
has shown better results. It was also recorded that the research work was carried mostly with single metal catalysts and very little
amount of research work has been carried out on the synthesis of carbon nanotubes using bimetallic catalysts.
1. RESUME
R. John Felix Kumar
C-1,Viswanathapuram
Kamarajar salai
Mayiladuthurai - 609001
Tamilnadu
# +91 – 9944531779 / felix1976@gmail.Com
Academic Qualification:
Ph.D. in Metallurgical and Materials Engineering, Indian Institute of
Technology, Madras, India (July 2013)
Specialized in materials used for energy devices, polymers, carbon based materials
Thesis title: “Enhanced Surface properties and Electrochemical durability of Multistage
PTFE treated Gas Diffusion Layers for Proton Exchange Membrane Fuel cells”
Research Supervisor: Prof. Prathap Haridoss (IIT Madras)
M.Tech. in Materials Science, National Institute of Technology, Tiruchirappalli, India (June
2004)
Thesis title: Synthesis of oxides and value added materials from slags and Industrial wastes
Research Supervisor: Prof. S. Raman Sankaranarayanan (NIT, Tiruchirappalli)
M.Sc., (Chemistry), St. Joseph’s College, Tiruchirappalli, India (November 1999)
Project title: Peroxidation of organic compounds in different solvents
Project Supervisor: Prof. T.V. Antony
Professional Experience:
Project Officer: (August 2012 – July 2013) in a collaborative project investigated by faculties
of Chemical Engineering and Applied Mechanics Department, IIT Madras.
Project Title: Bi- Axial Electromechanical characterization of piezzoelectric polymers
Sponsoring Agency : Aeronautics Research and Development Board, New Delhi
Project supervisors: Prof. Abhijit. P. Deshpande and Prof.C. Lakshman Rao (IIT Madras)
2. As a part of the project I extensively studied the temperature effect on deformation behavior
of Polyvinylidene Flouride (PVDF) material under static and dynamic loading conditions
Besides, I have experience as teaching faculty in the field of Materials science, Corrosion
Engineering and Non Destructive testing and failure analysis. Currently I am working as
teaching faculty in Metallurgical and Materials Engineering Department, National Institute of
Technology, Tiruchirappalli.
Characterization Techniques known:
Exposure in Cyclic Voltammetry, Impedance Spectroscopy, X-ray photoelectron spectroscopy,
FTIR, TGA-DSC, SEM, XRD, contact angle measurement and Non Destructive Techniques.
Projects:
1. Title: “Enhanced Surface properties and Electrochemical durability of Multistage PTFE
treated Gas Diffusion Layers for Proton Exchange Membrane Fuel cells” (2007-2012)
Accelerated degradation tests on carbon based gas diffusion layers (GDL) were conducted
to study the durability of gas diffusion layers under PEM Fuel cell conditions
Surface chemistry changes on gas diffusion layers due to carbon corrosion and resulting
hydrophobicity loss was studied
Role of PTFE on durability of gas diffusion layers and their degradation behavior were
studied under PEM Fuel cell conditions
Developed a novel approach of multiple stages of PTFE treatment for gas diffusion layers as
opposed to conventional single stage PTFE treatment to establish hydrophobicity gradients
across the structure of gas diffusion layers
The lifetime of the existing gas diffusion layers for PEM fuel cells was increased by
enhancing their surface hydrophobicity and electrochemical durability by modified
approach of multiple stages of PTFE treatment
2. Title: Synthesis of oxides and value added materials from slags and Industrial wastes
(2003 - 2004)
Proposed a design for mini pilot plant for recovering ferrite grade iron oxides and glasses
from slags and wastes through techno - economic study as per the basis of experiments
conducted at the laboratory level at NIT, Tiruchirapalli
3. Title: Oxidation of aromatic compounds by per benzoic acid in different solvents (6 months)
The oxidation of benzyl alcohol, acetophenone, benzophenone and toluene in different
solvents was analyzed using thin layer chromatography
Positions of Responsibility:
L- Corporal in NCC (1991-1992)
3. Vice-Chairman, Material Advantage – Indian Institute of Metals- Chennai (2008-2009)
Publications:
1. Effect of Electrochemical aging on the interaction between Gas Diffusion Layers and the Flow
Field in a Proton Exchange Membrane Fuel cell, John Felix Kumar R, V. Radhakrishnan, and
Prathap Haridoss, International Journal of Hydrogen Energy, 36, 2011, 7207-7211
2. Enhanced mechanical and electrochemical durability of multistage PTFE treated gas diffusion
ilayers for proton exchange membrane fuel cells, John Felix Kumar R, V. Radhakrishnan and
Prathap Haridoss, International Journal of Hydrogen Energy, 37, 2012, 10830-10835
3. Improved Surface Properties Of Al 2024 Based Surface Hybrid Composites By Friction Stir Processing,
P. Muthukumar, Mebin T Kuruvilla, R.John Felix Kumar and S. Jerome, ICMDM 2016, Anna
University, Chennai-36
4. Cold Metal Transfer And Riveted Joint Strength On AA2024 Aircraft Sheets, S. Prakash, L.
Gopinath, S. Jerome and R. John Felix Kumar, LAMSYS 2016, ISRO,Srihrikotta
5. Temperature dependent deformation of PVDF under uniaxial extension, John Felix kumar R,
Akilesan, Abhijit P Deshpande, Susy Varughese and Lakshman Rao, INCAM 2013, IIT Madras
6. Durability assessment of PVA/SSA membranes using peroxide permeation rate”, John
Felixkumar R, P Kanakasabai, Abhijit P Deshpande, Susy Varughese and Prathap Haridoss,
FUCETECH 2009, Mumbai
7. Electrochemical aging of carbon cloth gas diffusion layer under simulated PEMFC
environment”, John Felix Kumar R and Prathap Haridoss, ISAEST 2010, Chennai
8. Durability of S-PEEK and blended membranes under humidity cycling”, John Felix Kumar R
and Prathap Haridoss, ISRS 2010, IIT Madras, Chennai
9. Development of Metal – Ceramic alloy coatings on AISI 1045 by Laser Processing”.
Jagdeesh.R, Kamachi Mudali.U, Balasubramanian,K.R, John Felix Kumar. R and Nath.A.K,
Fifth DAEBRNS National Laser Symposium (NLS-5), Dec 7-10, 2005, Vellore Institute of
Technology,Vellore, India
10. Value added oxides from metallurgical wastes”, John Felix Kumar R and Raman
Sankaranarayanan S, Presented at the 42nd National Metallurgists Day, 58th Annual
Technical Meeting of the Indian Institute of Metals, Tiruvananthapuram, November 17 – 19,
2004
4. Co-Curricular Activities:
Conducted school outreach programme through Material Advantage association in 2008
to create awareness about metallurgy and materials science among school students in
Chennai
Conducted open house programme during IIT Madras annual technical festival SAASTRA
2008 to exhibit fuel cell system and functions
Objective:
To focus research on materials for the near future
References:
1. Prof. Prathap Haridoss
Department of Metallurgical and Materials Engineering,
Indian Institute of Technology Madras,
Chennai – 36.
044 – 22574771
prathap@iitm.ac.in
2. Prof. P. Abhijit Deshpande
Department of Chemical Engineering,
Indian Institute of Technology Madras,
Chennai – 36.
044 – 22574169
abhijit@iitm.ac.in
3. Dr. Susy Varughese
Associate Professor,
Department of Chemical Engineering,
Indian Institute of Technology Madras,
Chennai – 36.
044 – 22574172
susy@iitm.ac.in