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DETERMINATION OF FREE FORMALDEHYDE ON TEXTILE SUBSTRATE BY HPLC ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The most effective crosslinking reagents for durable press finishing of cellulose fibers are formaldehyde adducts of urea which release formaldehyde during the production and wearing of in such way treated clothes Formaldehyde durable press finishers are applied to the textile substrate mainly in the form of N-methylol and N-alkoxymethyl  compounds
Release of formaldehyde from the textile substrate can be measured by: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
EN ISO 14184-1  standard test method Standard solutions of formaldehyde with concentration levels of 0.3, 0.6, 0.9, 3.0, 6.0, 15.0 and 30.0 mg/L in the 3,5, - diacetyl –1,4-dihydrolutidin forms were prepared. The formaldehyde derivative solution s  w ere   prepared  in water and in matrix (extract from untreated cotton fibers).  Six replicates of each concentration level were prepared From the textile substratef ormaldehyde  was  extracted  with water at 40  C , filtered and  then converted by using acetyl - acetone reagent to yellow colored compound
V alidation  of absorbance measurements on UV/Vis ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Free formaldehyde measured by HPLC   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
V alidation  of the HPLC analytical method ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
V alidation  of the HPLC analytical method ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
CONCLUSIONS   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],Bojana VON C INA U niversity of Maribor, Textile Department   Smetanova 17, 2000 Maribor, Slovenia
Introduction ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
S ources of the formaldehyde ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Experimental ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],Results and conclusions
[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Formaldehyde  measurements in essential oils:
Conclusion   ,[object Object],[object Object],[object Object],I t was proven   that the amount of formaldehyde in essential oils is negligible  ,[object Object],[object Object]

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  • 5. The most effective crosslinking reagents for durable press finishing of cellulose fibers are formaldehyde adducts of urea which release formaldehyde during the production and wearing of in such way treated clothes Formaldehyde durable press finishers are applied to the textile substrate mainly in the form of N-methylol and N-alkoxymethyl compounds
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  • 7. EN ISO 14184-1 standard test method Standard solutions of formaldehyde with concentration levels of 0.3, 0.6, 0.9, 3.0, 6.0, 15.0 and 30.0 mg/L in the 3,5, - diacetyl –1,4-dihydrolutidin forms were prepared. The formaldehyde derivative solution s w ere prepared in water and in matrix (extract from untreated cotton fibers). Six replicates of each concentration level were prepared From the textile substratef ormaldehyde was extracted with water at 40  C , filtered and then converted by using acetyl - acetone reagent to yellow colored compound
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