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Interparticle Forces and  Phase Diagrams Music: “Hold On Loosely” by 38 Special
Forces of Chemistry and Physics
Interparticle Forces
 
Hydrogen “bridge” page 178 middle
Requirements for a Hydrogen “Bond” page 178 bottom
Four cases of Hydrogen “Bonding” page 179 bottom
Making surfaces more hydrophobic
Hydrogen bonding in DNA
Inorganic examples of H-bonding
Phase Transitions (Phase Changes)
 
 
Phase Diagrams (especially one-component P vs. T graphs)
 
Temperature vs. heat added graph showing  melting point  &  boiling point  -- Boiling point _
Heat involved (per gram) in the  Phase Changes of Water
Phase transitions  (Phase changes)
 
Summary of the Information Available in the CO 2  Phase Diagram
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3-D graph of ideal gas properties
A graph of three variables (such as P, V, & T) requires three dimensions and is often a  surface rather than a line as for the 2-D graphs. A 3-D Phase diagram (with only one component): A surface representing the properties of a typical pure substance (what a theoretical equation of state would have to account for) Each point on the curving surface represents a set of values of the pressure, temperature, and molar volume that can be attained by this substance.
Two-component Phase Diagrams (Temp vs. Composition) Gibbs’ Phase rule for a  two-component system: F + P = C + 2, where C=2 so, F + P = 2 + 2 = 4 so, F = 4 – P for one phase (P=1) F=3 which is a space, not restricted to the area of  any 2-D graph. for two phases (P=2) F=2 which is an area or surface for three phases (P=3) F=1 which is a line for four phases (P=4) F=0 which must be a point, such as an azeotrope or a eutectic point.
 

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Editor's Notes

  1. p.179 top
  2. Not in Lab Manual