This document is a report from the U.S. Geological Survey that compiles gallium concentration data from bauxite deposits worldwide. It finds that gallium concentrations in bauxite deposits range from less than 10 parts per million to 812 parts per million, with an average of 57 parts per million. There is no substantial difference in gallium concentrations between karst-type and laterite-type bauxites. The report calculates that the amount of potentially recoverable gallium contained in global bauxite deposits ranges from 30 metric tons to 82,720 metric tons, averaging 14,909 metric tons. The compilation of data is intended to support ongoing studies of gallium and other critical minerals.
The document discusses how shale gas development in the US is benefiting manufacturing through lower energy and feedstock costs. It finds that annual cost savings for US manufacturers could reach $22.3 billion by 2030 and $34.1 billion by 2040 assuming continued low natural gas prices. Key beneficiary sectors are expected to be chemicals and metals due to natural gas use as an energy source and feedstock. The chemicals industry in particular is seeing major new investment in US production facilities leveraging affordable shale gas.
2013 iea - potential for CO2 storage in oil gas shale reservoirsSteve Wittrig
The document discusses potential implications of gas production from shales and coals for geological storage of CO2. It finds that exploiting gas from shales and coals increases permeability and injectivity, potentially enhancing CO2 storage capacity. However, large-scale demonstration is still needed to confirm CO2 storage capabilities and capacities. Overlap between potential shale gas areas and saline aquifer storage sites may be considerable geographically but less so in 3D, so both resources could be used with care. Injectivity issues like coal swelling upon CO2 injection require further research.
This document summarizes the Stage 1 assessment undertaken as part of the Habitats Regulations Assessment for the Severn Estuary Shoreline Management Plan Review. 30 European sites were initially considered based on their location and potential connectivity to the study area. Following an analysis of their interest features and conservation objectives, 20 sites were scoped out from further assessment because they were deemed unlikely to be affected by changes resulting from implementation of the SMP2. The remaining 10 sites were carried forward to Stage 2 assessment.
Global CCS Institute Meeting 20 June 2013. Presentation on CCS initiatives in Indonesia by Prof. Dr. Wawan Gunawan A. Kadir, Vice Rector for Research and Innovation, Institute Technology Bandung (ITB).
UNFCCC - RE Project Funding International presentationHoward Barmil
This document discusses opportunities for business development related to the Kyoto Protocol's flexible mechanisms. It outlines how developing projects to reduce greenhouse gas emissions can generate carbon credits that are valuable commodities. Specifically, it examines how developing biogas projects from waste sources could qualify for the Clean Development Mechanism. Such projects require expertise in project development, financing, carbon market rules, and managing an international business. Developing standardized project models and strategic partnerships with governments could help realize the significant potential for greenhouse gas reductions and carbon credit generation across various industry sectors.
1) The document discusses the history of the mortgage industry in the United States from the early 20th century to the present. It describes key events that led to the financial crisis of 2008 such as the rise of subprime lending and loosening of underwriting standards.
2) It warns that signs are emerging again that could signal a return to risky lending practices, such as increased subprime auto and payday loans. Loosening standards for government-backed mortgages are also a concern.
3) The summary cautions that while regulations aim to prevent past issues, lenders themselves must prioritize responsible lending over short-term profits to avoid trapping borrowers and potentially leading to another housing crisis.
The document discusses opportunities for banks to improve their customer experience and operating models in the changing digital landscape. It suggests that banks need to provide consistent services across channels to better engage customers. The existing operating models of most banks are fragmented and decentralized. The document proposes transforming operations by implementing technology to enable straight-through processing, standardizing products and processes, and consolidating operations. It provides examples of how banks can improve offline and online services, such as enabling card issuance and payments at branches, implementing multi-channel payment options, and expanding offline infrastructure and services in developing markets.
The document discusses how shale gas development in the US is benefiting manufacturing through lower energy and feedstock costs. It finds that annual cost savings for US manufacturers could reach $22.3 billion by 2030 and $34.1 billion by 2040 assuming continued low natural gas prices. Key beneficiary sectors are expected to be chemicals and metals due to natural gas use as an energy source and feedstock. The chemicals industry in particular is seeing major new investment in US production facilities leveraging affordable shale gas.
2013 iea - potential for CO2 storage in oil gas shale reservoirsSteve Wittrig
The document discusses potential implications of gas production from shales and coals for geological storage of CO2. It finds that exploiting gas from shales and coals increases permeability and injectivity, potentially enhancing CO2 storage capacity. However, large-scale demonstration is still needed to confirm CO2 storage capabilities and capacities. Overlap between potential shale gas areas and saline aquifer storage sites may be considerable geographically but less so in 3D, so both resources could be used with care. Injectivity issues like coal swelling upon CO2 injection require further research.
This document summarizes the Stage 1 assessment undertaken as part of the Habitats Regulations Assessment for the Severn Estuary Shoreline Management Plan Review. 30 European sites were initially considered based on their location and potential connectivity to the study area. Following an analysis of their interest features and conservation objectives, 20 sites were scoped out from further assessment because they were deemed unlikely to be affected by changes resulting from implementation of the SMP2. The remaining 10 sites were carried forward to Stage 2 assessment.
Global CCS Institute Meeting 20 June 2013. Presentation on CCS initiatives in Indonesia by Prof. Dr. Wawan Gunawan A. Kadir, Vice Rector for Research and Innovation, Institute Technology Bandung (ITB).
UNFCCC - RE Project Funding International presentationHoward Barmil
This document discusses opportunities for business development related to the Kyoto Protocol's flexible mechanisms. It outlines how developing projects to reduce greenhouse gas emissions can generate carbon credits that are valuable commodities. Specifically, it examines how developing biogas projects from waste sources could qualify for the Clean Development Mechanism. Such projects require expertise in project development, financing, carbon market rules, and managing an international business. Developing standardized project models and strategic partnerships with governments could help realize the significant potential for greenhouse gas reductions and carbon credit generation across various industry sectors.
1) The document discusses the history of the mortgage industry in the United States from the early 20th century to the present. It describes key events that led to the financial crisis of 2008 such as the rise of subprime lending and loosening of underwriting standards.
2) It warns that signs are emerging again that could signal a return to risky lending practices, such as increased subprime auto and payday loans. Loosening standards for government-backed mortgages are also a concern.
3) The summary cautions that while regulations aim to prevent past issues, lenders themselves must prioritize responsible lending over short-term profits to avoid trapping borrowers and potentially leading to another housing crisis.
The document discusses opportunities for banks to improve their customer experience and operating models in the changing digital landscape. It suggests that banks need to provide consistent services across channels to better engage customers. The existing operating models of most banks are fragmented and decentralized. The document proposes transforming operations by implementing technology to enable straight-through processing, standardizing products and processes, and consolidating operations. It provides examples of how banks can improve offline and online services, such as enabling card issuance and payments at branches, implementing multi-channel payment options, and expanding offline infrastructure and services in developing markets.
VTC Corporation is a leading digital media and online gaming company in Vietnam, established in 1988. It has over 3,200 employees and owns multiple media platforms including television broadcasting, online services, and mobile platforms. VTC has a long history of pioneering new technologies in Vietnam such as digital television and was the first to launch many services. It owns 18 television channels and is one of the top television producers. VTC also operates popular online games and web platforms, and publishes several top-grossing mobile games in Vietnam.
This document discusses how social engagement and entrepreneurship can form a partnership. It notes that traditional social work institutions are inward looking and reactive rather than proactive. However, social entrepreneurship focuses on positive returns to society, transparency, and connecting to business goals. The document then discusses how the city of Heerlen, Netherlands is shrinking due to globalization. Betawerk creates ideas and media to inspire change for organizations and communities. It concludes that social engagement and entrepreneurship can partner through public-private partnerships, bottom-up initiatives, cross-disciplinary collaboration, and using modern tools.
1) The document discusses the history of the mortgage industry and how loose lending practices in the 2000s led to the 2008 financial crisis. Subprime loans and other risky products contributed to rising defaults.
2) Government intervention was needed to stabilize the housing market and financial system. Reforms were implemented to tighten regulations and protect consumers.
3) However, the author warns that signs like increasing subprime auto loans and loosening credit standards could lay the foundation for another housing bubble if not addressed. A wave of loan resets from programs like HAMP could also increase defaults.
Telescope + SDL Web Connector is the result of collaboration between Tahzoo, North Plains and SDL. It transforms your users’
experience of Telescope and SDL Web, by bridging the divide between these standalone solutions, and enabling them to view and manipulate the assets being managed by both solutions from within the comfort zone of their existing user environments.
Coates international, rebuild libya forum v.1.2Howard Barmil
The Coates family arrived in Pennsylvania in 1717 and established an iron foundry, with their home becoming frequented by George Washington. Coates International was later founded and is now based in New Jersey. The company aims to reduce fossil fuel consumption and emissions by utilizing alternative fuels like natural gas flare off gas. Flaring releases 150 billion cubic meters of gas annually, worth $30.6 billion, including dangerous compounds like hydrogen sulfide. Coates has developed an engine that can use this waste gas to generate electricity while lowering emissions.
Telescope + SDL Web Connector is the result of collaboration between Tahzoo, North Plains and SDL. It transforms your users’
experience of Telescope and SDL Web, by bridging the divide between these standalone solutions, and enabling them to view and manipulate the assets being managed by both solutions from within the comfort zone of their existing user environments.
The document discusses a new product launch for a company. It outlines key details of the product, including its features and target market. It also provides a timeline for rolling out marketing and shipping the first units to customers over the next few months.
ISPO Academy Munich 2015 - International E-Commerce Strategies for BrandsHenning Heesen
Today´s brands are coping with traditional distributing agreements versus new channels like e-commerce and social media.
Salesupply supports over 350 brands and merchants globally with their e-commerce strategy, fulfillment and marketing activities.
In this presentation, that was presented at the ISPO 2015 in Munich we show the international challenges of brands, examples of good and bad web shops and 3 e-commerce strategies that brands can adapt to monetize their existing brand value or grow international.
A Brief Introduction to Nonviolent Communication (also called Compassionate C...Alexandria Skinner
This is a very brief summary of the principles of Nonviolent Communication, as outlined in the book Nonviolent Communication: A Language of Life by Marshall Rosenberg. Also called "compassionate communication," NVC should be of interest to anyone who is interested in better communication and conflict resolution, including professionals in the fields of mediation, counseling, legal representation, social work, and negotiation. A trainer in Nonviolent Communication has agreed to come to Columbia, South Carolina, and conduct a two day training in April of 2014. The principles which underlie this method of communicating have potential to transform relationships for the better. It is also expected to qualify for continuing professional education credit for professionals in the fields of law, social work, and counseling. There will be a fee, but it will be reasonable. Please contact me if you are interested in further information.
The 3rd annual Resources & Energy Investment Symposium (REIS) is on 19-22 May, once again held in the unique city of Broken Hill; Last year’s event exceeded the expectations of all that attended - including over 350 delegates, 12 keynote speakers and more than 30 resource companies presenting their investment opportunities.
A focus for this year’s symposium will be on the current economic climate including its challenges and opportunities, not only in the Australian resources industry, but Australia’s position in the international market.
Mandalay Resources is positioning itself for renewed future growth through organic production increases at its Costerfield and Björkdal mines. Costerfield is expected to see significant production growth to 44,000-52,000 gold equivalent ounces in 2020 as mining of the high-grade Youle vein ramps up. Björkdal is also ramping up underground production from the new Aurora zone. Exploration continues to show potential to further expand resources and discover new mineralized zones at both operations.
Mandalay Resources is positioning itself for renewed future growth through organic production increases at its Costerfield and Björkdal mines. At Costerfield, ramping up production from the high-grade Youle vein is expected to significantly increase processed grade and production over the next 12 months. Björkdal is ramping up underground production from the new Aurora zone, which provides higher grades than the current mill feed. Mandalay is also executing agreements to realize value from its non-core Chilean assets of Cerro Bayo and Challacollo.
This study examines the source rock potential of the Torquay Formation in southern
Saskatchewan using high resolution Rock-Eval pyrolysis and organic petrography on core samples.
The study finds that while two thin organic rich zones exist, the Torquay Formation has limited
source potential due to low total organic carbon values below 1 wt.%, hydrogen index below 250,
and low thermal maturity. The organic matter is Type II-III kerogen with some Type IV, suggesting
reworked or oxidized organic material rather than in-situ accumulation. This preliminary analysis
concludes the Torquay Formation has marginal source potential in southern Saskatchewan.
This paper summarizes reports from the Energy Minerals Division of the American Association of Petroleum Geologists on five unconventional energy resources: gas hydrates, gas shales, geothermal resources, oil sands, and uranium resources. It discusses current U.S. and global research and development activities related to these resources. Gas hydrates have enormous potential resources but production technologies are still under development. Gas shales, geothermal, oil sands, and uranium are increasingly being explored and developed and are becoming important energy resources.
This study analyzed sediment cores from five sites along Cockle Creek in New South Wales, Australia to assess lead (Pb) and zinc (Zn) levels. X-ray fluorescence detected increasing numbers of elements from upstream to downstream sites. No Pb was detected. ICP analysis found higher average Pb (284.68 mg/kg vs 226.12 mg/kg) and Zn (683.86 mg/kg vs 587.96 mg/kg) levels in deeper sediments. Pb levels were below 600 mg/kg at all sites except the bottom half of Site 5 sediment. Zn levels exceeded Australian guidelines at all sites. The results were consistent with prior studies conducted nearby.
Shale gas is natural gas i.e. trapped within Shale. For to extract it we have use some extraction techniques like Horizontal Drilling or Hydraulic Fracking.
- The document discusses how giant icebergs can influence marine productivity in the Southern Ocean by providing an important source of iron-rich terrigenous material to surrounding waters. Field studies have shown that iceberg-delivered iron leads to increased primary production and a more developed food chain ecosystem.
- Remote sensing of chlorophyll concentrations revealed a 92% likelihood of higher chlorophyll values, up to 3 times background levels, within 30 days and up to 860km from giant icebergs. This suggests icebergs fertilize large areas of ocean waters.
- The melting and dispersion of iron-rich debris from icebergs supports a rich pelagic ecosystem, with higher concentrations of phytoplankton,
This document summarizes research on carbon dioxide storage and sequestration in unconventional shale reservoirs. It discusses how shale formations around the world provide ample storage opportunities due to their widespread presence and existing infrastructure from shale gas development. The document reviews modeling and simulation techniques used to understand fluid flow behavior in shale reservoirs and explains governing equations for gas and water flow in the matrix and fracture domains. It also summarizes learnings from CO2 sequestration projects in saline aquifers and the need for monitoring CO2 distribution during storage projects.
1) Mandalay Resources owns two producing gold mines, Costerfield in Australia and Björkdal in Sweden, as well as non-core assets in Chile.
2) At Costerfield, production is expected to significantly increase over the next year from ramping up mining of the high-grade Youle vein.
3) At Björkdal, production will be ramped up by increasing underground mining rates and processing stockpiled ore, supplemented by production from the Aurora zone, where mining has begun.
VTC Corporation is a leading digital media and online gaming company in Vietnam, established in 1988. It has over 3,200 employees and owns multiple media platforms including television broadcasting, online services, and mobile platforms. VTC has a long history of pioneering new technologies in Vietnam such as digital television and was the first to launch many services. It owns 18 television channels and is one of the top television producers. VTC also operates popular online games and web platforms, and publishes several top-grossing mobile games in Vietnam.
This document discusses how social engagement and entrepreneurship can form a partnership. It notes that traditional social work institutions are inward looking and reactive rather than proactive. However, social entrepreneurship focuses on positive returns to society, transparency, and connecting to business goals. The document then discusses how the city of Heerlen, Netherlands is shrinking due to globalization. Betawerk creates ideas and media to inspire change for organizations and communities. It concludes that social engagement and entrepreneurship can partner through public-private partnerships, bottom-up initiatives, cross-disciplinary collaboration, and using modern tools.
1) The document discusses the history of the mortgage industry and how loose lending practices in the 2000s led to the 2008 financial crisis. Subprime loans and other risky products contributed to rising defaults.
2) Government intervention was needed to stabilize the housing market and financial system. Reforms were implemented to tighten regulations and protect consumers.
3) However, the author warns that signs like increasing subprime auto loans and loosening credit standards could lay the foundation for another housing bubble if not addressed. A wave of loan resets from programs like HAMP could also increase defaults.
Telescope + SDL Web Connector is the result of collaboration between Tahzoo, North Plains and SDL. It transforms your users’
experience of Telescope and SDL Web, by bridging the divide between these standalone solutions, and enabling them to view and manipulate the assets being managed by both solutions from within the comfort zone of their existing user environments.
Coates international, rebuild libya forum v.1.2Howard Barmil
The Coates family arrived in Pennsylvania in 1717 and established an iron foundry, with their home becoming frequented by George Washington. Coates International was later founded and is now based in New Jersey. The company aims to reduce fossil fuel consumption and emissions by utilizing alternative fuels like natural gas flare off gas. Flaring releases 150 billion cubic meters of gas annually, worth $30.6 billion, including dangerous compounds like hydrogen sulfide. Coates has developed an engine that can use this waste gas to generate electricity while lowering emissions.
Telescope + SDL Web Connector is the result of collaboration between Tahzoo, North Plains and SDL. It transforms your users’
experience of Telescope and SDL Web, by bridging the divide between these standalone solutions, and enabling them to view and manipulate the assets being managed by both solutions from within the comfort zone of their existing user environments.
The document discusses a new product launch for a company. It outlines key details of the product, including its features and target market. It also provides a timeline for rolling out marketing and shipping the first units to customers over the next few months.
ISPO Academy Munich 2015 - International E-Commerce Strategies for BrandsHenning Heesen
Today´s brands are coping with traditional distributing agreements versus new channels like e-commerce and social media.
Salesupply supports over 350 brands and merchants globally with their e-commerce strategy, fulfillment and marketing activities.
In this presentation, that was presented at the ISPO 2015 in Munich we show the international challenges of brands, examples of good and bad web shops and 3 e-commerce strategies that brands can adapt to monetize their existing brand value or grow international.
A Brief Introduction to Nonviolent Communication (also called Compassionate C...Alexandria Skinner
This is a very brief summary of the principles of Nonviolent Communication, as outlined in the book Nonviolent Communication: A Language of Life by Marshall Rosenberg. Also called "compassionate communication," NVC should be of interest to anyone who is interested in better communication and conflict resolution, including professionals in the fields of mediation, counseling, legal representation, social work, and negotiation. A trainer in Nonviolent Communication has agreed to come to Columbia, South Carolina, and conduct a two day training in April of 2014. The principles which underlie this method of communicating have potential to transform relationships for the better. It is also expected to qualify for continuing professional education credit for professionals in the fields of law, social work, and counseling. There will be a fee, but it will be reasonable. Please contact me if you are interested in further information.
The 3rd annual Resources & Energy Investment Symposium (REIS) is on 19-22 May, once again held in the unique city of Broken Hill; Last year’s event exceeded the expectations of all that attended - including over 350 delegates, 12 keynote speakers and more than 30 resource companies presenting their investment opportunities.
A focus for this year’s symposium will be on the current economic climate including its challenges and opportunities, not only in the Australian resources industry, but Australia’s position in the international market.
Mandalay Resources is positioning itself for renewed future growth through organic production increases at its Costerfield and Björkdal mines. Costerfield is expected to see significant production growth to 44,000-52,000 gold equivalent ounces in 2020 as mining of the high-grade Youle vein ramps up. Björkdal is also ramping up underground production from the new Aurora zone. Exploration continues to show potential to further expand resources and discover new mineralized zones at both operations.
Mandalay Resources is positioning itself for renewed future growth through organic production increases at its Costerfield and Björkdal mines. At Costerfield, ramping up production from the high-grade Youle vein is expected to significantly increase processed grade and production over the next 12 months. Björkdal is ramping up underground production from the new Aurora zone, which provides higher grades than the current mill feed. Mandalay is also executing agreements to realize value from its non-core Chilean assets of Cerro Bayo and Challacollo.
This study examines the source rock potential of the Torquay Formation in southern
Saskatchewan using high resolution Rock-Eval pyrolysis and organic petrography on core samples.
The study finds that while two thin organic rich zones exist, the Torquay Formation has limited
source potential due to low total organic carbon values below 1 wt.%, hydrogen index below 250,
and low thermal maturity. The organic matter is Type II-III kerogen with some Type IV, suggesting
reworked or oxidized organic material rather than in-situ accumulation. This preliminary analysis
concludes the Torquay Formation has marginal source potential in southern Saskatchewan.
This paper summarizes reports from the Energy Minerals Division of the American Association of Petroleum Geologists on five unconventional energy resources: gas hydrates, gas shales, geothermal resources, oil sands, and uranium resources. It discusses current U.S. and global research and development activities related to these resources. Gas hydrates have enormous potential resources but production technologies are still under development. Gas shales, geothermal, oil sands, and uranium are increasingly being explored and developed and are becoming important energy resources.
This study analyzed sediment cores from five sites along Cockle Creek in New South Wales, Australia to assess lead (Pb) and zinc (Zn) levels. X-ray fluorescence detected increasing numbers of elements from upstream to downstream sites. No Pb was detected. ICP analysis found higher average Pb (284.68 mg/kg vs 226.12 mg/kg) and Zn (683.86 mg/kg vs 587.96 mg/kg) levels in deeper sediments. Pb levels were below 600 mg/kg at all sites except the bottom half of Site 5 sediment. Zn levels exceeded Australian guidelines at all sites. The results were consistent with prior studies conducted nearby.
Shale gas is natural gas i.e. trapped within Shale. For to extract it we have use some extraction techniques like Horizontal Drilling or Hydraulic Fracking.
- The document discusses how giant icebergs can influence marine productivity in the Southern Ocean by providing an important source of iron-rich terrigenous material to surrounding waters. Field studies have shown that iceberg-delivered iron leads to increased primary production and a more developed food chain ecosystem.
- Remote sensing of chlorophyll concentrations revealed a 92% likelihood of higher chlorophyll values, up to 3 times background levels, within 30 days and up to 860km from giant icebergs. This suggests icebergs fertilize large areas of ocean waters.
- The melting and dispersion of iron-rich debris from icebergs supports a rich pelagic ecosystem, with higher concentrations of phytoplankton,
This document summarizes research on carbon dioxide storage and sequestration in unconventional shale reservoirs. It discusses how shale formations around the world provide ample storage opportunities due to their widespread presence and existing infrastructure from shale gas development. The document reviews modeling and simulation techniques used to understand fluid flow behavior in shale reservoirs and explains governing equations for gas and water flow in the matrix and fracture domains. It also summarizes learnings from CO2 sequestration projects in saline aquifers and the need for monitoring CO2 distribution during storage projects.
1) Mandalay Resources owns two producing gold mines, Costerfield in Australia and Björkdal in Sweden, as well as non-core assets in Chile.
2) At Costerfield, production is expected to significantly increase over the next year from ramping up mining of the high-grade Youle vein.
3) At Björkdal, production will be ramped up by increasing underground mining rates and processing stockpiled ore, supplemented by production from the Aurora zone, where mining has begun.
This report summarizes nine unconventional energy resources including coal, coalbed methane, gas hydrates, tight gas sands, shale gas and oil, geothermal, oil sands, oil shale, and uranium. Coal and uranium are expected to supply a significant portion of the world's energy in coming years. Recent developments in technologies like horizontal drilling and hydraulic fracturing have enabled increased production of natural gas from shale and tight sandstones in the United States and other areas of the world. Research on other unconventional resources such as gas hydrates and geothermal energy continues to advance.
Shale is the most common sedimentary rock, formed from compressed sediments and mineral transformations under heat and pressure. More than 60% of geological hydrocarbon reservoirs are sealed by shale rocks, which are predominantly composed of clay minerals. Caprocks like shale provide integrity to contain underground gas and oil storage. Understanding shale's microstructure and mechanical properties helps maintain this integrity and prevent leakage. However, failures from fracturing or fault activation can cause containment incidents. Proper geological characterization of caprocks is needed to avoid leaks from underground storage and waste disposal sites.
This document summarizes the development of a geographic information system (GIS) and prospectivity models for mesothermal gold deposits in New Zealand. The project aimed to compile geological and geochemical data from various sources into a digital format to help identify new areas of mineral potential and encourage mineral exploration. Over 100 datasets were compiled into the GIS database at a regional scale. Prospectivity models were developed to analyze spatial correlations between known gold deposits and other geological features. The models indicate areas that warrant further exploration based on similarities to known deposit models but cannot guarantee finding new deposits on their own. The GIS database and models are intended to help explorers efficiently target prospective areas and reduce exploration risks and costs in New Zealand.
Calcium and magnesium are important plant nutrients that are taken up from the soil. Calcium plays key roles in plant cell structure and is important for fruit and vegetable quality. While calcium deficiencies can occur, soils often contain adequate levels. Magnesium is part of the chlorophyll molecule and is also involved in enzyme activation. Both nutrients can be supplemented through soil or foliar applications when tissue tests indicate a need. However, over-application should be avoided as it can negatively impact nutrient availability and balance.
Scientists led by researchers from the UK and France plan to drill down over 5 miles through the Earth's crust and into the mantle, a feat that has never been accomplished before. Drilling so deep presents enormous challenges, including temperatures over 1000 degrees Fahrenheit, extreme pressures, and the need to retrieve samples without contamination. The researchers hope to begin searching for a suitable drilling site in the Pacific Ocean in 2018.
The British Columbia Geological Survey (BCGS)
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thriving, safe, and sustainable mining industry in British
Columbia (BC) in 2010. This was accomplished by
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A new multi-year rare metals project started under the auspices of the renewed Targeted Geoscience
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national initiative co-lead by George Simandl of the
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methodologies and technologies in the search for rare earth and rare metal deposits. Rare metals are important in the manufacturing of automobiles and many high-tech products such as cell phones and computers.
This document provides details for a Notice of Work application to develop the Swamp Point North Aggregate Project in British Columbia. The project will involve developing a sand and gravel quarry over 5 years to produce 235,000 tonnes per year. Project components include the quarry, a crushing and washing plant, conveyors, a barge load-out facility, and an upgraded access road. Archaeological assessments found low potential for impacts to cultural resources. The proponent has signed an agreement with the local Metlakatla First Nation regarding economic participation and regulatory approval. Management plans are included in the appendices to address operations, water management, reclamation and environmental protection.
This document provides an overview of shale gas exploration, production, and potential around the globe. It discusses what shale and shale gas/oil are, and compares unconventional and conventional reservoirs. It also covers the technologies of hydraulic fracturing and horizontal drilling used to access shale gas. Global shale gas reserves have increased in recent years, with significant production in the US, Canada, and China. Shale gas has the potential to be developed commercially in other regions as well.
Buchans Resources - Investor Presentation - January 2021Tyler Hosey
Buchans Resources Limited is exploring zinc-lead-silver properties located in Newfoundland, gold properties in Newfoundland and Labrador and nickel-copper-cobalt properties in Labrador. In addition the Company holds interests in other exploration companies exploring form base and precious metals in Mexico, Ireland, the UK and New Brunswick.
Commerce Resources Corp. announces the results for the 3 remaining drill holes from the 2015 winter/spring drill program at the Ashram Rare Earth Deposit located in northern Quebec.
News Release: Commerce Resources Corp. Intersects 19.71% TREO Over 0.82m at ...
ofr2013-1272_Schulte_gallium
1. U.S. Department of the Interior
U.S. Geological Survey
Open-File Report 2013–1272
Mineral Resources Program
Compilation of Gallium Resource Data for Bauxite Deposits
2.
3. Compilation of Gallium Resource Data for Bauxite Deposits
By Ruth F. Schulte and Nora K. Foley
Mineral Resources Program
Open-File Report 2013–1272
U.S. Department of the Interior
U.S. Geological Survey
4. U.S. Department of the Interior
SALLY JEWELL, Secretary
U.S. Geological Survey
Suzette M. Kimball, Acting Director
U.S. Geological Survey, Reston, Virginia: 2014
For more information on the USGS—the Federal source for science about the Earth,
its natural and living resources, natural hazards, and the environment—visit
http://www.usgs.gov or call 1–888–ASK–USGS
For an overview of USGS information products, including maps, imagery, and publications,
visit http://www.usgs.gov/pubprod
To order this and other USGS information products, visit http://store.usgs.gov
Suggested citation:
Schulte, R.F., and Foley, N.K., 2014, Compilation of gallium resource data for bauxite deposits: U.S. Geological
Survey Open-File Report 2013–1272, 14 p., 3 separate tables, http://dx.doi.org/10.3133/ofr20131272.
ISSN 2331-1258 (online)
Any use of trade, product, or firm names is for descriptive purposes only and does not imply
endorsement by the U.S. Government.
Although this report is in the public domain, permission must be secured from the individual
copyright owners to reproduce any copyrighted material contained within this report.
5. iii
Contents
Abstract ......................................................................................................................................................................... 1
Introduction.................................................................................................................................................................... 1
Bauxite Deposits............................................................................................................................................................ 2
Gallium Abundance in Bauxite....................................................................................................................................... 3
Limitations of the Gallium Data Compilation.................................................................................................................. 5
Data Fields .................................................................................................................................................................... 5
Country ...................................................................................................................................................................... 5
Bauxite Province and District ..................................................................................................................................... 5
Deposit....................................................................................................................................................................... 6
Mine........................................................................................................................................................................... 6
Bauxite Type and Host Rock...................................................................................................................................... 6
Development Status................................................................................................................................................... 6
Location ..................................................................................................................................................................... 6
Size............................................................................................................................................................................ 7
Major Oxide Compositions......................................................................................................................................... 7
Trace Elements.......................................................................................................................................................... 7
Tonnage..................................................................................................................................................................... 7
Analytical Method....................................................................................................................................................... 7
Summary....................................................................................................................................................................... 9
References Cited........................................................................................................................................................... 9
Figure
Figure 1. World map showing distribution of bauxite deposits .................................................................................. 4
Tables
[Tables are available for downloading at http://pubs.usgs.gov/of/2013/1272/]
Table 1. Compilation of gallium concentrations in global bauxite deposits, with location, deposit size, major
oxide data, and tonnage values provided.
Table 2. Ranges and averages of gallium concentrations and calculated tonnages in the major bauxite
provinces worldwide, plus average alumina and average total tonnages for deposits within the bauxite provinces.
Table 3. Ranges and averages of gallium concentrations and calculated tonnages for the major bauxite
districts worldwide, plus average alumina and average total tonnages for deposits within the bauxite districts.
6. iv
Conversion Factors
Multiply By To obtain
Length
kilometer (km) 0.6214 mile (mi)
Area
square kilometer (km2
) 247.1 acre
square kilometer (km2
) 0.3861 square mile (mi2
)
Mass
metric ton (t) 1.102 ton, short (2,000 lb)
7. 1
Compilation of Mineral Resource Data for Bauxite
Deposits
By Ruth F. Schulte and Nora K. Foley
Abstract
Gallium (Ga) concentrations for bauxite deposits worldwide have been compiled from the
literature to provide a basis for research regarding the occurrence and distribution of Ga worldwide, as
well as between types of bauxite deposits. In addition, this report is an attempt to bring together
reported Ga concentration data into one database to supplement ongoing U.S. Geological Survey studies
of critical mineral resources.
The compilation of Ga data consists of location, deposit size, bauxite type and host rock,
development status, major oxide data, trace element (Ga) data and analytical method(s) used to derive
the data, and tonnage values for deposits within bauxite provinces and districts worldwide. The range in
Ga concentrations for bauxite deposits worldwide is <10 to 812 parts per million (ppm), with an average
of 57 ppm. Gallium concentrations in lateritic bauxites range from below detection (< 8 ppm) to 146
ppm; the average concentration is 57 ppm Ga. The average Ga concentration for karst bauxite deposits
is 58 ppm with a range between <10 to 180 ppm Ga. As a result, there are no substantial differences in
gallium concentrations between karst- and laterite-type bauxites. We calculate the range in geologically
available Ga in bauxite deposits worldwide between 30 and 82,720 metric tons (t), with an average of
14,909 t.
Introduction
A global compilation of gallium (Ga) concentrations for bauxite deposits worldwide has not
been attempted in the literature, in part because of the limited number of scientific investigations
reporting Ga as a trace element in bauxite. This report is, therefore, an attempt to bring together reported
Ga concentration data into one database to supplement the study of Foley and others (in press) and to
also be used as a basis for further research on the distribution and occurrence of Ga in bauxite.
Bauxite deposits are traditionally regarded as economic sources of aluminum (Al). However,
bauxite deposits are also important sources of Ga as a byproduct commodity because the close
geochemical affinity of Ga to Al enables Ga to substitute easily in rock-forming aluminosilicates such
as feldspar (Burton and others, 1959). Gallium also shows an affinity with iron (Fe) and zinc (Zn),
which enable it to substitute for these elements in common rock-forming minerals. Gallium can also be
found in geochemical association with germanium (Ge), silicon (Si), indium (In), cadmium (Cd), and tin
(Sn) (Burton and Culkin, 1978).
The majority of the world supply of Ga metal comes from the mining of bauxite and sediment-
hosted lead-zinc (Pb-Zn) resources, the latter of which is not discussed in this manuscript (fig. 1). World
primary Ga production in 2012 was estimated by the U.S. Geological Survey (USGS) at 273 metric tons
(t), with China, Germany, Kazakhstan, and Ukraine as the leading producers (Jaksula, 2013). This
8. 2
number is down 7 percent from 292 tons in 2011, owing to a combination of delayed manufacturing
processes and a decrease in Ga prices. In the United States, primary recovery of gallium in 2012 was
nonexistent. However, the U.S.-based Molycorp Inc. recovered and refined Ga from scrap and impure
gallium metal (Molycorp Inc., 2013). Only Ga recovered from bauxite deposits will be covered in this
report.
Currently, electronic components with Ga arsenide (GaAs) wafers and (or) Ga nitride (GaN)
represent 99 percent of domestic Ga consumption (Jaskula, 2013). Approximately 71 percent of this use
is in integrated circuits, whereas optoelectronic devices (including laser diodes, light-emitting diodes
(LEDs), photodetectors, and solar cells) comprise the remaining 29 percent of Ga consumption (Jaskula,
2013). Gallium is also an important commodity because of to its expanding use in applications for thin
film photovoltaics, such as copper-In-Ga selenide (CIGS) semiconductors (Foley and others, in press).
Bauxite Deposits
Bauxite is a type of rock that consists of one or more aluminum hydroxide minerals, most
notably gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO(OH)) (Bárdossy and Aleva,
1990). Diaspore has the same general chemical composition as boehmite but is denser and harder. A
typical bauxite rock also contains a mixture of goethite (FeO(OH)), hematite (Fe2O3), the clay mineral
kaolinite, and a minor amount of anatase (TiO2).
The formation of bauxites requires intense weathering in tropical or subtropical climates
(Bárdossy, 1994). Bauxites typically occur within the thick profiles of laterites, which are formed by
the intense subaerial weathering and leaching of aluminosilicate rocks (Bárdossy and Aleva, 1990;
Ferenczi, 2001; Retallack, 2010). These bauxites are referred to as lateritic bauxites. The lateritic
bauxite horizon can be homogeneous or heterogeneous throughout, with different structures (such as
massive or columnar), textures (such as massive or heterolithic), or compositions. The color of the
bauxite can vary from almost white to pink, yellow, orange, tan, reddish brown, and brown (Bárdossy
and Aleva, 1990). An example of a lateritic bauxite deposit is Weipa in Queensland, Australia (fig. 1,
point 1; Anand and others, 1991). Alternately, bauxites may occur in paleokarst depressions as
accumulations of clayey material within carbonate (that is, limestone) sequences; these are referred to as
karst bauxites (Bárdossy, 1982; Pajović, 2009). Karst bauxites tend to be black to gray in color with
admixed organic matter and, occasionally, chemically reduced minerals such as pyrite (Retallack, 2010).
The Doğankuzu deposit in Seydişehir, Turkey, is an example of a karst bauxite deposit (fig. 1, point 2;
Öztürk and others, 2002). Roughly 88 percent of global bauxite deposits are lateritic bauxites, whereas
the remaining 12 percent belong to the karst bauxite group (Bárdossy and Aleva, 1990).
Major world bauxite resources occur in Africa, Australia, South America, and the Caribbean
(fig. 1). Guinea hosts the world’s largest bauxite reserves at an estimated 15.3 billion metric tons
(Mosier, 1986b). The Adoom mine in the Weipa bauxite deposit of Queensland, Australia, reports an
estimated 3.2 billion tons of total ore (table 11
; Taylor and others, 2008). The Darling Range bauxite
deposits in Western Australia contain an estimated 900 to 1,000 million metric tons total ore (fig. 1,
point 3; Anand and others, 1991; Mosier, 1986b). Important bauxite deposits in South America include
Pitinga, Tucuruí, Paragominos, Porto Trombetas, Cataguases, and Poço de Caldas (fig. 1, points 4–9;
Bárdossy and Aleva, 1990; Boulangé and Carvalho, 1997; Valeton and others, 1997). Jamaica is the
dominant Caribbean bauxite resource, with deposits in Saint Ann, Saint Catherine, Saint Elizabeth, and
Manchester Provinces (fig. 1, points 10–13; Bárdossy and Aleva, 1990).
1
Tables are available for downloading at http://pubs.usgs.gov/of/2013/1272/.
9. 3
Significant deposits are present in Asia and Europe. In fact, China, Germany, Kazakhstan, and
Ukraine were the leading Ga producers in 2012 (Jaksula, 2013). Chinese karst bauxite deposits include
Dajia and Xinxu in the Western Guangxi Province (table 1; fig. 1, points 14–15; Wang and others,
2011), as well as lesser deposits at Nanting, Kunmin, and Queyang (fig. 1, points 16–18). Kazakhstan
hosts the Arqalyk and Ekisbastoz-Pavlodar bauxite deposits (fig. 1, points 19–20; Bogatyrev and
Zhukov, 2009). Other deposits in Kazakhstan include Naurzum, Astana, Aqtas, Shimkent, and Ili (fig. 1,
points 21–25). The Pripyat and Vysokopl’ye deposits are the main bauxite resources in Ukraine (fig. 1,
points 26–27; Bogatyrev and Zhukov, 2009).
Refined gallium has been processed from an impure form and includes low-grade (99.9 percent
pure) gallium (Foley and others, in press; Jaksula, 2013) as well as electronic-grade and high purity
gallium (also known as semiconductor grade) that ranges from greater than 99.9 to 99.99999 percent Ga
(Bautista, 2003). In 2012, China, Japan, the United Kingdom, and the United States were the primary
producers of refined gallium (Jaksula, 2013). Past production of bauxite in the United States occurred at
the Eufaula deposit in Alabama (fig. 1, point 28; Clarke, 1966), the Pulaski and Saline deposits in
Arkansas (fig. 1, point 29; Gordon and Murata, 1952), and the Hall and Veneer deposits in Georgia
(fig. 1, point 30; Ayorinde, 2011). Potential sources of bauxite in the United States have also been
identified in Oregon (Hotz, 1964), Washington, and Hawaii (Bogatyrev and Zhukov, 2009).
Gallium Abundance in Bauxite
According to Mordberg and others (2001), the reported concentration of Ga in bauxite ranges
from <10 to 160 parts per million (ppm). However, we report a range for bauxite deposits of <10 to
812 ppm, with an average Ga concentration of 57 ppm (table 1). Lateritic bauxites have Ga
concentrations that range from below detection (< 8 ppm) to 146 ppm, with an average of 57 ppm.
Karst-type bauxite deposits have Ga concentrations that range from 6.3 to 812 ppm, though the upper
value is associated with only one deposit; the Maşatdaği deposit in Antalya, Turkey, ranges from 22 to
812 ppm, with an average Ga concentration of 106 ppm (fig. 1, point 31). Therefore, the more realistic
typical range for karst bauxite deposits is <10 to 180 ppm, with an average of 58 ppm Ga. This
comparison shows that there is no substantial difference in gallium concentrations between karst- and
laterite-type bauxites.
In addition, we calculate the average geologically available quantity of Ga in global bauxites to be
14,909 t, with a range from 30 to 82,720 t (table 1). The averages for the bauxite provinces and
districts are provided in tables 2 and 3, both of which have been compiled from data reported in table 1.
10. 4
Figure 1. World map showing distribution of bauxite deposits. Major bauxite provinces are identified. Selected deposits are indicated with numbers: 1–Weipa, Australia; 2–
Doğankuzu, Turkey; 3–Darling Range, Australia; 4–Pitinga, Brazil; 5–Tucuruí, Brazil; 6–Paragominos, Brazil; 7–Porto Trombetas, Brazil; 8–Cataguases, Brazil; 9–Poço de
Caldas, Brazil; 10–Saint Ann, Jamaica; 11–Saint Catherine, Jamaica; 12–Saint Elizabeth, Jamaica; 13–Manchester, Jamaica; 14–Dajia, China; 15–Xinxu; China; 16–
Nanting, China; 17–Kunmin, China; 18–Queyang, China; 19–Arqalyk, Kazakhstan; 20–Ekisbatoz-Pavlodar, Kazakhstan; 21–Naurzum, Kazakhstan; 22–Astana, Kazakhstan;
23–Aqtas, Kazakhstan; 24–Shimkent, Kazakhstan; 25–Ili, Kazakhstan; 26–Pripyat, Ukraine; 27–Vysokopl’ye, Ukraine; 28–Eufaula, United States; 29–Pulaski-Saline, United
States; 30–Hall-Veneer, United States; 31–Maşatdaği, Turkey; 32–Iszkaszentgyörgy, Hungary.
11. 5
Limitations of the Gallium Data Compilation
Criteria used to identify bauxite deposits worldwide were based on the classifications assigned to
the deposits in the literature. Owing to the limited number of publications reporting Ga concentrations,
only those deposits with publicly accessible Ga concentration information were included in table 1.
Some deposits are not presented in the Ga compilation despite their prominence as producers of Al ore
(for example, Iszkaszentgyörgy, Hungary (fig. 1, point 32); Saint Ann, Jamaica; and Vysokopl’ye,
Ukraine) because published Ga concentration data are not available for those deposits. Some of the
published reports cited in table 1 are from the previous century and have not been recently updated;
however, the data in table 1 are thought to be representative of Ga concentrations in bauxite.
In addition, some deposits with published Ga concentrations that are reported in table 1 may not
be currently mined. These deposits may be in the exploration phase or have ceased operations
altogether. Therefore, where possible, indication as to the production status for each deposit is also
listed in table 1. Past producers are deposits that are no longer actively mined for bauxite ore. Reasons
for the cessation of mining activity include depletion of resources, political instability, and issues with
infrastructure (Bárdossy and Aleva, 1990). Deposits identified as prospects are those that are
incompletely explored or lack complete mineral inventories. Those deposits listed as producers are
currently being mined for bauxite, whereas those listed as occurrences are those that have been
identified but not evaluated for their economic potential.
Data Fields
The attributes within the tables are defined in the following subsections.
Country
The most commonly used names and spellings for countries are provided in table 1. Where more
than one country contains the extent of the bauxite deposit, the names of all countries are listed and
separated by a comma.
Bauxite Province and District
Bauxite provinces are large terrorities (from a few hundred to a few million square kilometers)
with relationships to large tectonic units. Ancient and young platforms, continental shields, island arcs
and foldbelts, and active continental margins are the major criteria used to define bauxite provinces in
which several bauxite districts and deposits locally occur (Bárdossy and Aleva, 1990). Bauxite deposits
may differ in age and origin within one province (Bogatyrev and Zhukov, 2009).
Bogatyrev and Zhukov (2009) defined the following bauxite provinces, listed from west to east
and south to north: (I) East Pacific, (II) North American, (III), Caribbean, (IV) South American,
(V) African, (VI) Mediterranean, (VII) East European, (VIII) Ural, (IX) Kazakh, (X) Central Asian,
(XI) Salair, (XII) East Siberian, (XIII) Hindustan, (XIV) Chinese, (XV) Indochinese, (XVI) Indonesian-
Philippine, (XVII) West Australian, (XVIII) East Australian, and (XIX) Hawaiian. Bárdossy and Aleva
(1990) also included Southeast Asia as a lateritic bauxite province. The identification of metallogenic
provinces provides an opportunity to study the localization of bauxite ore deposits, which may assist in
forecasting and prospecting presently unidentified resources.
12. 6
Whereas a province consists of closely spaced bauxite districts and deposits that occur in the
same tectonic regime and are of similar age (Bárdossy and Aleva, 1990), bauxite districts are smaller
than provinces and range from 100–200 kilometers in length and 10–20 kilometers in width (Bogatyrev
and Zhukov, 2009). In addition, bauxite districts may consist of one or more orebodies that have similar
geological characteristics (Bárdossy and Aleva, 1990). The orebodies may have a simple morphology,
such as sheetlike, mantlelike, lenticular, or funnel shaped; or, the orebodies may be split and convoluted.
Neighboring bauxite deposits with different geological features are regarded as separate bauxite
districts. Isolated districts are identified by the name of the bauxite deposit according to the
classification system of Bárdossy and Aleva (1990).
Deposit
The names of the deposits within the bauxite provinces and districts are given in table 1. A
bauxite deposit is continuous in space and fundamentally composed of bauxite and genetically related
rocks, such as siliceous bauxite, ferriferous bauxite, or bauxitic laterite. A bauxite deposit may consist
of one or more orebodies.
Mine
The names of the individual orebodies from which the bauxite ore is mined are provided when
the literature specifies the exact location of the samples used to determine concentration data.
Bauxite Type and Host Rock
Depending on the type of host rock, bauxites are classified as either laterite or karst. Laterite
bauxites result from the intense subaerial weathering of aluminosilicate rocks (Bárdossy and Aleva,
1990; Ferenczi, 2001; Retallack, 2010), such as granite, gneiss, basalt, syenite, and shale. Karst bauxites
form in paleokarst depressions within carbonate sequences, such as limestone or dolomite (Bárdossy,
1982; Pajović, 2009). Detailed petrologic descriptions are provided for the host rock where descriptions
are available in the literature.
Development Status
Categories are those listed at the end of the preceding section “Limitations of the Gallium Data
Compilation.”
Location
The geographic location (latitude-longitude) of each deposit is listed. The latitude and longitude
coordinates are in decimal format, which were calculated from degrees, minutes, and seconds based on
published location data cited in table 1 and (or) identification using Google Earth Pro, an advanced
commercial 3D interactive virtual globe, map, and geographical information program (Google, 2013).
Google Earth Pro maps the Earth by superimposing images obtained from satellites, aerial photography
and geographic information system (GIS) 3D globe; this enables users to pinpoint the latitude and
longitude of a specific location, such as a building within a city, a mountain peak, or an open pit mine.
Images used by Google Earth Pro 2013 include those provided by TerraMetrics, Digital Globe, Map
Link, USGS, and Cnes/Spot Image. Data sources for Google Earth Pro 2013 include the U.S.
Department of State, Scripps Institution of Oceanography (SIO), National Oceanic and Atmospheric
Administration (NOAA), U.S. Navy, National Geospatial Agency (NGA), and General Bathymetric
Chart of the Oceans (GEBCO). Southern latitudes and western longitudes are given as negative values.
13. 7
Size
Where possible, the estimated size of the bauxite deposit or province is given. Estimates
regarding the size of bauxite deposits are difficult to obtain because of their extensive distribution across
several orebodies, only some of which may be mined.
Major Oxide Compositions
Major oxide concentrations of ore for Al2O3, Fe2O3, CaO, Na2O, and K2O are provided in
table 1. Compositional data are reported in weight percent (wt%). Where data are available, the range
and average concentrations for each major oxide are listed. The abbreviation “n” represents the number
of data points used to determine the range and average values. Error is provided in percent when
reported.
Trace Elements
Although more complete trace element concentrations have been reported for bauxite deposits
(for example, see Patterson and others, 1986), Ga is the only trace element reported here. Gallium
compositional data are expressed in parts per million (ppm); the abbreviation “n” represents the number
of data points used to determine the range and average values.
Tonnage
The tonnage for the total ore in a listed bauxite deposit is reported where data are available.
These values are estimates provided in the literature and reflect the estimated tonnage associated with
the lowest cutoff grades (Cox and Singer, 1986). Using the total tonnage and average Ga concentrations,
the amount of Ga available in the deposits has been calculated and is reported in metric tons. The same
calculation has been done with the average alumina (Al2O3) concentration, although the average
alumina tonnage is reported in million metric tons.
Analytical Method
Various analytical techniques have been used to determine the concentration of gallium in
bauxite. Early work involved techniques such as Hilger quartz spectrography (for example, Wolfenden,
1965) and rhodamine B fluorometry (for example, Chowdhury and others, 1965). Hilger quartz
spectrography is a spectrophotometric technique using quartz prisms and lenses that enables the whole
spectrum to be photographed; rhodamine B fluorometry is a spectrophotometric technique that uses the
chemical compound rhodamine B as a tracer dye (Potts, 2003). Rhodamine S and crystal violet also
have been used as colorimetric reagents for gallium (Thakur and Sant, 1972).
Atomic absorption spectrometry (AAS) has been known as an analytical technique since the first
quarter of the 19th century (Potts, 2003). However, practical instrumentation was not successfully
developed until the 1960s after the pioneering work of Walsh (1955) and Alkemade and Milatz (1955).
Pattan and Appangoudar (1988) is one example of a bauxite study that reports major and trace element
concentration data (including gallium) obtained by using AAS (table 1).
Neutron activation analysis (NAA) has also been applied to the geochemical analysis of bauxites
(for example, see Chen and Tsai, 1983). NAA involves “activation” of the samples by irradiation with
neutrons in a nuclear reactor, after which samples are removed and allowed to decay or “cool” (Potts,
2003). This procedure enables unwanted short-lived radioactivity to dissipate. After cooling, the
measurement of gamma-ray spectra is made by using solid-state germanium gamma-ray detectors.
14. 8
Accuracy of determining 68
Ga has been shown to improve with an increase in the cooling period
(Tustanovskii and others, 1968). The limit of determination is reported to be ± 6 percent (Tustanovskii
and others, 1968).
X-ray fluorescence (XRF) became a standard instrumental technique for trace element
geochemistry in the 1950s and 1960s with the advent of commercial instrumentation (Potts, 2003).
Unlike AAS, XRF has the benefit of analyzing multiple elements at the same time, and this increases
the speed at which samples can be analyzed. The XRF technique uses X-ray radiation to excite electrons
in pressed powdered pellets or fused glass discs and then measures them in an X-ray spectrometer; the
detection limit of Ga for pellets is 6 ppm (Potts, 2003). The work by Valeton and others (1991) in the
Cataguases bauxite deposit, Brazil, is an example of trace element geochemical data obtained by XRF
(table 1).
Inductively coupled plasma atomic emission spectrometry (ICP-AES), also known as
inductively coupled optical emission spectrometry (ICP-OES), is an optical emission spectrometry
analytical technique that employs argon gas as an emission source for spectrographic measurements
(Potts, 2003). The advantage of ICP-AES over AAS is the ability to measure multiple elements
simultaneously. However, all samples must be reproducibly dissolved in order to analyze them by using
ICP-AES (unlike XRF, which only requires powdered pellets for analysis). Hieronymus and others
(2001) analyzed bauxites from the Bamiléké Plateau, Cameroon, and the Pará state of Brazil using both
AAS and ICP-AES (table 1).
Electron microprobe analysis (EPMA) differs from other analytical techniques in that areas of a
sample can be examined that are as small as a few micrometers in diameter, which requires that
specimens be prepared as polished thin sections mounted on a glass slide or within a resin block (Potts,
2003). As a result, the composition of individual minerals or compositional variations within a single
mineral grain can be obtained. For example, Valeton and others (1987) analyzed karst bauxites and
associated lithologies from the Parnass Khiona region deposit in Greece by using EPMA, which enabled
them to evaluate the degree of contamination by weathered debris, the paleogeography of the region, the
transport of the detrital source material and depositional environment, and the amount of chemical
alteration during diagenesis and epigenesis.
Inductively coupled plasma-mass spectrometry (ICP-MS) is a type of mass spectrometry in
which the sample is taken up into solution and subsequently atomized and ionized in an argon plasma.
The detection limits of trace element concentrations by using ICP-MS can reach as low as one part in
1012
(parts per trillion) (Potts, 2003). Compared to AAS, ICP-MS has the ability to simultaneously
measure multiple elements, which increases the speed at which analyses can be done. Horbe and Anand
(2011), for instance, used ICP-MS to measure the major and trace element data of bauxites from the
Boddington deposit of the Darling Range in Western Australia and the Pitinga deposit in the Amazon
District of Brazil (table 1).
In this report, the analytical method used to determine the Ga concentration of the bauxites is
listed where information is available. However, not all research articles report their analytical methods.
In those cases, the column cell is left blank.
15. 9
Summary
Although bauxite deposits are traditionally mined for their Al content, they are also important
sources of Ga as a byproduct commodity. Bauxite deposits occur worldwide due to intense weathering
in tropical or subtropical climates. Depending on the type of host rock, such as aluminosilicate or
carbonate, bauxites are classified as either laterite or karst, respectively. However, based on our
extensive dataset, there is no substantial difference in Ga concentrations between laterite and karst
bauxite deposits. As a result, either type of bauxite could be a potential source of Ga for subsequent
refinement and use in modern technological applications.
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